Vidyamandir Classes

Solutions to Test Series - 2/Paper - 1/IITJEE - 2014

[CHEMISTRY]

1.(A) Covalent bonds are formed by orbital overlapping. It must take place is some direction.
Ionic bonds are electrostatic attraction in the lattice, which can be in any direction

106 10 4 104 104

2.(D) [H ] : Hence pH = log

4 log 2 4.3
2 2 2
3.(A) I3 linear
XeF2 linear
V2
4.(C) V1 25 V1 = Volume of NaOH in mixture.
2
V1 + V2 = 30 V2 = volume of HCl in mixture.
V2 = 10
V1 = 20
1
Moles of NaOH in 25 ml = 20 2 m moles
10
Moles in 500 ml = 40 m moles
gms = 1.6 gm
5.(B) LiCl, RbCl, BeCl2, MgCl2
Least ionic BeCl2
Most ionic RbCl FAJANS RULE

6.(D)

7.(B) C5 H12 O
4 O 1 4
6
3 O 2 2

8.(D) COCl CN CHO OH NH 2

1 3 2 4 5

9.(A)

10.(B) NH 4 OH HCl
1/3rd neutralization

Salt = 1/3 S
Base = 2/3 pOH pK b log
B
1
= 4.7 log
2
p(OH) = 4.4
pH = 9.6

VMC/JEE-2014/Solutions 1 Test Series-2/ACEG/Paper-1

 Vidyamandir Classes

11.(D)

II, III are chain isomers

I, II are chain isomers
I, III are position isomers

12.(C) 2BCl3 3H 2 2B 6HCl

For 21.6 g B 2 moles
3 moles H2 will be consumed 67.2L
n He MSO2
13.(D) 16 4
n SO2 M HE
m He mSO2
4
4 64
3 64
mSO2 12g
4 4

C rms ) He T M T 16
14.(D) 1 . 2 1 1
Crms )CH4 T2 M1 4 600
600
T1 150 K 123C
4
5 H 1300
15.(A) (i) C2 H 2 O2 2 H 2 O( l )
2CO
2
1 H 394
(ii) C(g) O(g) CO2 (g)
2
1 H 286
(iii) H 2(g) O 2(g) H 2 O( l )
2
We have to calculate
2C(s) H 2(g) C2 H 2(g)
2(ii) (iii) (i) gives us the desired reaction
2(394) 286 (1300) 226 .
1
16.(A) H 2(g) O 2(g) H 2 O(g)
2
1
H (H H) (O O) (2 O H)
2
1
249 433 492 2 x x = 464 KJ/mole.
2
17.(D) pH is maximum when (H+) is least.
CH3COONa is basic salt
Hence pH is max.
[salt]
18.(C) pH pKa log
[acid]
On dilution [salt] and [acid] remains the same.
Hence pH remains the same (neglecting minor changes)
z H Z n
19.(C) 2.18 106 H
n 2 Z 2 1
Li Li

1
1 n n3
3

VMC/JEE-2014/Solutions 2 Test Series-2/ACEG/Paper-1

 Vidyamandir Classes

M 98
20.(A) Equivalent weight = 98 21.(C) 3 lone pairs around I
n factor 1
22.(C) After balancing
2 moles of K 3 [Fe(CN) 6 ] 1 mole of H 2 O2
Hence 4.5 moles of H2O2 will consume 9 moles of K3[Fe(CN)6]
23.(B) MgSO4
Assume density of water = 1 Kg/lt.
So 106 ml = 103 kg
Hence 6 gm of MgSO4 in 103kg of water
6
10 gm of CaCO2 in 103 kg of water 5 gm in 103 kg of water
120
O O O
|| || ||
24.(D) O Br Br Br O Br 6, 4
|| || ||
O O O
Br3O8

25.(C)

26.(B) PV Pb RT
PV = Pb + RT
R
V Tb (Compare with y = mx + c)
P
R 0.0821
slope m 2
P 0.04105

27.(B)

sp2 sp2 sp2 sp2 sp

28.(C) For 100 KW reactor
105 J/s
In one second
105J will be used.
100 1.6 10 19 J produces one molecule.
1 105 1022
Molecules of H2 produced = 19
=
100 1.6 10 1.6
1022
Moles = : 102 moles
1.6 6.023 1023
Hence volume of H 2 102 22.4 lt
: 224 ml
29.(A)

30.(A) Statement 1 is correct

Statement 2 is also correct and reason also.

VMC/JEE-2014/Solutions 3 Test Series-2/ACEG/Paper-1

 Vidyamandir Classes

Solutions to Test Series - 2/Paper - 1/IITJEE - 2014

[PHYSICS]

31.(D) 32.(B) Total distance = (5 1) + (10 1) + (15 1) = 30 m.

gn 2 1 1 10 3 1 1
33.(C) y x tan 3 2 u 40 m / s
2
2u cos 2 2 3 2u 3 / 4 u2 40

34.(C) Components of the velocities of the block along the strings are equal
V1 cos 1 V2 cos 2

35.(B) Let T1 and T2 are tensions in AB and BC

T1 T2 T2
At B: At C:

T2
mg
Mg
T1 cos Mg T2 cos 2T2 cos mg
5 13 mg
and T1 sin T2 sin 2T2 T2
13 10
4 mg 3 13mg 12
36.(C) T1 Mg and T1
5 2 5 10 13
8mg mg 3T1 6mg 8 1 11m
Mg T1 2m M m
5 2 5 5 5 2 10
37.(C) 38.(A)

39.(B) To lift the block 2 kg, tension in the string is 2 g = 20 N

Let x: elongation in the spring for which the tension is 20 N.
kx = T 40x = 20 x = 0.5 m
For 5 kg: loss in GPE = gain in KE + gain in EPE
1 1
5 10 0.5 5 V 2 40 0.5 2
2 2
v 2 2 m/ s

40.(B) Minimum horizontal force required to apply on 4 kg block to slide it on 5 kg block

4
= 4 5 10 0.25 18 N .
5
6
For F = 6 kg both are blocks are moving together with same acceleration a 2 / 3 m / s2
45
Force of static friction f = 5a = 10/3 N.
Displacement of the slab in the given interval
1

= 5 2 / 3 32 2 2 5 / 3m
2
work done = f s = 10/3 5/3 = 50/9 = 5.55 J

41.(A) Let B falls by x then elongation in the spring is 2x, loss in GPE of B = gain in EPE of spring
1 mg
mg x k 2 x
2
x
2 2k

42.(D) Velocity is maximum when net force (on both the blocks) is zero.
Let T: tension in the string connecting A & x, elongation in spring at this instant
VMC/JEE-2014/Solutions 4 Test Series-2/ACEG/Paper-1
 Vidyamandir Classes

mg
mg = 2T and T = kx1 x block B falls by x1/2
2k
loss in GPE of A = gain in KE of A & B + gain in EPE
2 2
mg 1 2 1 v 1 mg
mg 2 mv 2 m 2 k V: velocity of A
4k 2 2k

m2 g 2 5 2 m2 g 2 mg 2 m
mv velocity of B = V/2 v vg
4k 8 8k 5k 5k

43.(A) Let : angular velocity of rod just before impact & V: velocity of ball just after impact
V e l .
m l 2 l
About axis L 0 mvl e l e = 1/3
3 3
T
44.(C) N T f mg sin
N mg cos
f About centre of mass: TR = fR
mg sin
mg sin f
mg cos 2
mg sin tan
And to avoid sliding f N mg cos 2/3 Ans. (C)
2 2
T
N
45.(D) mg sin T ma
1
TR mR 2
2
mg sin a R
mg cos
a
2 2 4
a g sin = 10 16 / 3 m / s 2 Ans. (D)
3 3 5

2
ml 2 ml 2 ml 2 3 l
46.(D) I m 3 / 2 ml 2 .
3 3 2
12

47.(C) Acceleration of point 1 = acceleration of point 2
4m/s2 2 4 2
1 3 rad / s
2m/s2
2
md
48.(D) Frictional torque on the ring is 2
g R mg R

mg R
Angular retardation = g / R .
mR 2
0 g 0 R
f i t 0 t t
2 R 2g

49.(C) About the triangular edge 16l 1 ml 2 and l 1 4l 2 m = 8 kg

P0 V0 P0V0
PV nRT RT RT
3 2
50.(B) 1 V0
V0

3 3P V
Tr . KE n R T 0 0
2 4
VMC/JEE-2014/Solutions 5 Test Series-2/ACEG/Paper-1
 Vidyamandir Classes

51.(D) Q1 2 W1 2 60 J ; U1 2 0
Q2 3 U 2 3 40 J
U1 2 U 2 3 U 3 1 0 0 40 U 3 1 0 U 3 1 40 J

8 7 22
52.(A) PV n R T P 3 103 8.31 300 P = 8.31 105 N/m2
32 28 44
53.(C) T = constant.
T
54.(C) AT 4 for edge length l
t
T
l 3S 6 l 2T 4
t
T 1 1 1 1
in first case 1 in second case t 200 sec
t l 100 t 2
55.(B)

56.(C) H yz H zx

KA 40 2
KA 40
l 2l
120
80 2 40 49.7oC
2 1
57.(B) P T isochoric with increasing pressure.
mg u cos t 2
58.(A)

L dt mg u x t dt
2
; parabola passing through origin opening upwards.

59.(A) ycm
yd m
d d m

m d
= R cos 2 R sin


m
Work done = inc. in GPE
R sin
= mg ycm 2 R g = 2 R 2 g sin

60.(C) Net acceleration is vector addition of tangential & radian acceleration.

VMC/JEE-2014/Solutions 6 Test Series-2/ACEG/Paper-1

 Vidyamandir Classes

Solutions to Test Series - 2/Paper - 1/IITJEE - 2014

[MATHEMATICS]
61.(D)
62.(C) Equality holds if f x g x 0

x , 1 2,

63.(A) u 2 2u 2 0 u 1 i

x n x n

cot 1 1 i n
cot 1 1 i

n


2i
Q cot 1 x

cos i sin n cos i sin n
sin n 2i
2i sin n

sin n 2i
sin n

sin n
2

5
5 1 i 1 3
2 2
i
1 i 5 1
2 2
3i 2 2
2 2
64.(C)

2i 3 i 2i . 2
3i

2 2
5 2 19
argument =
4 3 2 6 12
5
principal argument is
12
1 1
65.(A) Tn , n = 3, 4, 5, . . .
n2 n 2 n 2 n 1
1 1 1

3 n 1 n 2

Tn 3
1 1 1 1 1 1 1 1 1 1 1 1
S
3 5 8
: : . .......
n 3
2 5 3 3 6 3 4 7

1 1 1 1
S
3 2 3 4

1 6 4 3 13

3 12 36

3 1
2
66.(A) 2 2 3 42 3

2 3 3 5 6 3 10 2 2 3 3 1 3 1
3

3 1 3 1 3 1 2 3
So sum 1 3
1 3 1 2 3 1

VMC/JEE-2014/Solutions 7 Test Series-2/ACEG/Paper-1

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67.(D) We have, a b cos 2 x c sin 2 x 0 for all x

a b c 2b sin 2 x 0 for all x a b 0 and c 2b 0 a b and c 2b

Thus, the triplets are b, b, 2b , where b R .

Hence, there are infinitely many triplets.
68.(B) Line y x 1 0 is equally inclined to axes as slope is 1. As y x 1 0 is equidistant from the points

4
1, 2 and (3, 4), 4 2
2 2
69.(B) The lines PQ and PR will be inclined at an angle of 45 with the line 2 x y 3 .
m2 1
1 m ,3
1 2m 3
1
Therefore, the lines are y 1 x 2 and y 1 3 x 2
3
Find the equation of pair of lines by multiplying these two equations.
70.(A) r 4 C1C3

r 10 C2 C3

2r 14 C1C2 10 4 14
r 14
Now, PC3 x 14 8 6

l 2 r 2 x 2 142 62 160 l 4 10

2l 8 10
x 10

1 2 1
x 5 tan 3 x 7 x 5 tan 3x 2 7
71.(B) x 2
x2
lim 3
lim
x x 7 x 8 x x3 7 x 8

3 71 x2 1 3 7
x 2 tan tan 3
x 2
x x3 x2 x x 1
lim lim
x 7
1 2 3
8 x 7
1 2 3
8
x x x x

72.(A) lim
2 sin x

1 sin x ln 1 sin 2 x
.
x0 sin x x tan1 x
sin x ln 1 sin 2 x sin x x ln 1 sin 2 x 2 sin 2 x
ln 2 lim . lim ln 2 lim . . lim .
x0 tan 1
x x0 x x0 x 1
tan x x 0 sin 2 x 2x
2 ln 2 ln 4

x
1 tan x , if x 0

73.(B) f x 0 , if x 0
x
, if x 0
1 tan x

So, lim f x f 0 lim f x

x 0 x 0

i.e., f (x) is continuous at x = 0.

VMC/JEE-2014/Solutions 8 Test Series-2/ACEG/Paper-1

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1 tan x x sec 2 x
, if x 0

1 tan x 2
Now, f x
1 tan x 1 x sec 2 x
, if x 0

1 tan x 2
f 0 1 1 0 1 and f 0 11 0 1

So, f x is not differentiable at x = 0.

74.(A) Let f x x 2a x a 4

x 2 3a 4 x 2a a 4

f x 0 for all 1 x 1 if f x 0 has two distinct real roots and f 1 and f 1 are negative.

D 3a 4 4 1 2a a 4 0
2

f 1 1 3a 4 1 2a a 4 0
2

f 1 1 3a 4 1 2a a 4 0
2
and
1
These conditions give a3
2
1 1 1 1 1 1 1 1 1
..... ..... 2 2 2 .....
a 2 2 1 2 2 2
3 5 2 2 4 6
75.(C) 1 2 3
b 1 1 1 1 1 1
2 2 ..... 2 2 2 .....
12 3 5 1 3 5
1 1 1
2
2 2 .....
1 1 2 3 1 a a 4
= 1 2 1 .
2 1 1 1 4 b b 3
2 2 2 .....
1 3 5
76.(D) Given that cos 1 x cos 1 y cos 1 z
cos 1 x cos 1 y cos 1 z

cos 1 xy 1 x 2 1 y 2 cos 1 z xy z 1 x 1 y
2 2

Squaring both sides, we get : x 2 y 2 z 2 2 xyz 1

1 1 1 1
Trick : Put x y z so that cos 1 cos 1 cos 1
2 2 2 2
77.(A) Put x cos
1 1
x ,
2 2 4 3
x 1 x 2
cos 1 cos 1 cos cos 45 sin sin 45
2 2

cos 1 cos 45 45
VMC/JEE-2014/Solutions 9 Test Series-2/ACEG/Paper-1
 Vidyamandir Classes

cos 1 x 1 x 2
So, cos 1 x
12 2 4


tan 1
4

78.(B) Graph of | f | x| | x 1, 0 0, 1 and Graph of | f x | x 1, 0 0, 1

1 1 1 1

Graph of g (x) = | f | x|| | f x | is :

1 O 1

1
graph of [ | g (x) |] is :
range of is {0, 1} O

Tr
2r 1

r 1 2 r 2
1

1
79.(D)
r 2
r 1 2
r 2 r 1
2
r 2
r 1 2
n n 1 1
Sn Tr Vr Vr 1 1 n 1 2 , where Vr
r2
r 1 r 1
1 1
41 1681
2
S40 1
41 2 1 S40
lim sin x ln |x|

ln |x|
f 0 lim | x |sin x e x 0 lim
80.(B) x 0 cosec x
[Apply L.H. rule]
x 0 e 1

f 0 g 0 1 (As f (x) is continuous)
Let g x ax b b 1 g x ax 1
sin x ln |x| sin x
For x 0, f x e cos xln | x |
x
f 1 1 0 sin1 sin1
f 1 a 1 a 1 sin1
g x 1 sin1 x 1

1 1 1/ 3
...
81.(C) 3 32 11 / 3
x 9 9 3
1 1 1 / 3
...
3 32 11 / 3
y 4 4 2

1
z wr where w
1 i
r 1
1
w 1 1i 1
z as |w| 1 z= i
1 w 2 1 i
1
1i
x yz 3 2i
1 2
Its argument is tan

3

VMC/JEE-2014/Solutions 10 Test Series-2/ACEG/Paper-1

 Vidyamandir Classes
2008
3 r 3 r
82.(C) f 3 3 2008
r 1
2008
3 r 3 r
3 Q 3 r 3 r .
r 1
2008
3 0 3

83.(B) Q f 1 x g x f g x x

f g x g x 1

1
1 g x
n
g x
f g x

2 sin 2 A 2 B cos 2 A sin 2 A 2 B 3

84.(A) 3
2 sin 2 A cos 2 A sin 2 A 1

sin 2 A B B 3 sin 2 A B B
sin 2 A B cos B cos 2 A B sin B 3 sin 2 A B cos B 3 cos 2 A B sin B
4 cos 2 A B sin B 2 sin 2 A B cos B tan 2 A B 2 tan B

85.(B) Let f x ax 2 bx c

g x 2a 2ax b ax 2 bx c

b 2a 4a b c 2a
2
Determinant

b2 4a 2 4ab 4ab 4ac 8a 2

b2 4ac 4a 2
But for f x , f x 0 x R
b2 4ac 0, a 0
So determinant < 0, a > 0 for g (x)
Hence g x 0 x R

86.(A) Given O(0, 0) is the orthocenter. Let A(h, k) be the third vertex, B 2, 3 ,

and C 5, 1 the other two vertices. Then the slope of the line through

4
A and O is k/h, while the line through B and C has the slope . By the
7
property of the orthocenter, these two lines must be perpendicular, so we
have
k 4 k 7
h 7 1 h 4 . . . .(i)

k 3
Also, Slope of AB
h2
1
Slope of OC
5
1 k 3
Q AB OC 1
5 h2
5h k 13 0 . . . .(ii)
Solving it with (i) we get :
h 4 , k 7
87.(B) cot cot 0 tan tan 0 i.e. m 1 + m 2 = 0
VMC/JEE-2014/Solutions 11 Test Series-2/ACEG/Paper-1
 Vidyamandir Classes
where m1 and m 2 are the slopes of the tangents from P(h, k).
If y mx a 1 m 2 is a tangent from P(h, k) then k mh a 2 1 m2
2

i.e. h 2

a 2 m2 2hkm k 2 a 2 0
m1 and m2 are the roots of this equations such that m1 + m2 = 0
2hk
i.e. 0 locus of P(h, k) is xy = 0
h a2
2

88.(B) 0 x 2 x 1 1 and 0 x2 x 1
x 1, 0
For x 1
3
L.H.S. 2 sin 1 1 cos 1 0
2
x 1 is a solution
3
For x = 0 L.H.S. 2 sin 1 1 cos 1 0
2
x = 0 is a solution
sum of the solutions = 1

b ic
1 i
1 iz 1 a
89.(A)
1 iz b ic
1 i
1 a
1 a c ib

1 a c ib

1 a c ib 1 a c ib Q a 2 b 2 c 2 1

1 a c 2 b2
1 2a a 2 b 2 c 2 2ib 2iab 2a 2a 2 2ib 2iab

1 a 2 c 2 b 2 2ac 2 a c 2 2ac 2 a c

a a 2 ib iab

1 ac a c
a ib

c 1
1
90.(C) log3 k , k l
x
1
log3 k x 3 k
x
Possible values of k are 1, 0 , 1, 2 , 3, . . . .

1 1 1
S 3 1 2 3 . . . .
3 3 3

4
1 3 4
1 9

1 1 3 2 2

VMC/JEE-2014/Solutions 12 Test Series-2/ACEG/Paper-1