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molar mass of solute is
M M d MM B d MM B
m m m m
d MM B d MM B M M
1) 2) 3) 4)
12.To a 4L of 0.2M solution NaOH, 2L of 0.5M NaOH are added. The molarity
of resulting solution is
1) 0.9 M 2) 0.3 M 3) 1.8 M 4) 0.18 M
13.A 0.2 molal aqueous solution of a weak acid (HX) is 20 per cent ionized.
PTotal 120 75 X B
components A and B is given by hence, vapour pressure of
pure A and B respectively ( in torr) are
1) 120, 75 2) 120, 195 3) 120, 45 4) 75, 45
16.The correct relationship between the boiling points of very dilute solutions
AlCl3 t1 CaCl2 t2
of and , having the same molar concentration, is
t1 t2 t1 t2 t2 t1 t2 t1
1) 2) 3) 4)
17.The vapour pressure of a solvent decreased by 10 mm of Hg when a non
volatile solute was added to the solvent. The mole fraction of solute in
solution is 0.2, what would be the mole fraction of solvent if decrease in
vapour pressure is 20 mm of Hg?
1) 0.8 2) 0.6 3) 0.4 4) 0.2
18.Liquids A and B form an ideal solution. The correct one is
1) The enthalpy of mixing is zero 2) The entropy of mixing is zero
3) The free energy of mixing is zero
4) The free energy as well as the entropy of mixing are each zero
19.Acetic acid exists in benzene solution in the dimeric form. In an actual
experiment, the Vant Hoff factor was found to the 0.52. Then the degree of
association of acetic acid is
1) 0.48 2) 0.88 3) 0.96 4) 0.52
20.The boiling point of an azeotropic mixture of water ethanol is less than that
of both water and ethnol. Then
1) The mixture will show negative deviation form Raoults
2) The mixture will shows positive deviation from Raoults law
3) The mixture will show no deviation from Raoults law
4) This mixture cannot be considered as true solution
K 18.6 K mol 1 100 g
21.The amount of urea to be dissolved in 500 mL of water (
0.1860 C
solvent) to produce a depression of in freezing point is
1) 5g 2) 3g 3) 6g 4) 8g
22.Which of the following plots correctly represents the behaviour of an ideal
binary liquid solution ?
(A) Plot of xA (mole fraction of A in liquid phase) versus y A (mole fraction
of A in vapour phase) is linear
(B) Plot of xA versus yB is linear
(C) Plot of 1/xA versus 1/yA is linear
(D) Plot of 1/xA versus 1/yB is linear
23.Identify the correct statement.
(A) 1 M NaCl has higher freezing point than 1 M glucose solution.
(B) 1 M NaCl solution has almost same boiling point as 1 M KCl solution,
assuming 100% ionisation.
(C) Apparent molecular weight of NaCl will be less than 58.5 in water
because it undergoes dissociation.
(D) i = 1 when acetic acid is dissolved in benzene.
24.To 10 mL of 1M BaCl2 solution 5 mL of 0.5 M K2SO4 is added. BaSO4 is
precipitated out. What will happen?
(A) Freezing point will increase (B) Boiling point will increase
(C) Freezing point will lower down (D) Boiling point will lower down
25.Kb of solvent X is 0.42 and Kf of solvent Y is 1.62, match the following for
possible values :
Column I Column II
(A) Kf of solvent X P) 0.62
(B) Kb of solvent Y Q) 1.82
(C) Boiling point of X R) 48C
(D) Boiling point of Y S) 55C
21 10 20 m 2 .
be taken to be The value of x is
29.Which of the following are correct about Tyndall effect?
(A) True solution do not show Tyndall effect due to very small size of the
particles.
(B) The diameter of the particles of the dispersed phase must not be much
smaller than the wavelength of light used.
(C) Tyndall effect is very weak in case of lyophobic sols.
(D) The refractive index of the dispersed phase and dispersion medium
must differ considerably.
30.Which of the following is required in lowest concentration for coagulating a
sol having positively charged colloidal particle ?
(A) KCl (B) K2SO4 (C) K3[Fe(CN)6] (D) K4[Fe(CN)6]
31. Adsorption isostere is
(A) The curve showing the effect of temperature on the extent of adsorption at a given
pressure
(B) The curve showing the variation of pressure with temperature, for a given amount
of
adsorption.
(C) The curve showing the variation of adsorption with pressure at a constant
temperature.
(D) A line parallel to x-axis.
32. The protective power of a lyophilic colloid is measured by the property called
(A) flocculation value (B) gold number
(C) Hardy-Schulze rule (D) peptization
33. The Brownian motion is due to
(A) temperature fluctuation within the liquid phase
(B) attraction and repulsion between charges on the colloidal particles
(C) impact of the molecules of the dispersion medium on the colloidal particles
(D) convectional currents
34. Correct order of coagulating power is
K Mg2 Ca2 Al3 Mg2 K
(A) (B)
Sn4 Al3 Mg2 Sn4 Al3 Mg2
(C) (D)
100ml
35. The coagulation of of gold sol is completely prevented by addition of 0.25 g of
starch. The gold number of starch is
(A) 0.025 (B) 0.25
(C) 2.5 (D) 25
36.
Column I Column II
x 1.8
0.18
m 10
4.24V 6.023 10 23
256
0.0239 cm 3