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Vapor-Liquid Equilibrium Data

The experimental data shown in these pages are freely available and have been published
already in the DDB Explorer Edition. The data represent a small sub list of all available data in
the Dortmund Data Bank. For more data or any further information please search the DDB or
contact DDBST.

Vapor-Liquid Equilibrium Data Set 466

Components

No. Formula Molar Mass CAS Registry Number Name


1 CH4O 32.042 67-56-1 Methanol
2 H2O 18.015 7732-18-5 Water
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Constant Value

Pressure 97.99 kPa

Data Table

T [K] x1 [mol/mol] y1 [mol/mol]


369.65 0.00840 0.10300
365.45 0.02580 0.22700
360.65 0.06800 0.39100
353.25 0.13700 0.56800
349.05 0.24000 0.68000
343.75 0.48000 0.79000
341.85 0.57200 0.82000
339.55 0.74100 0.90600

(T - temperature, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Bennett G.W.: A Laboratory Experiment on the Boiling-Point Curves of Non-Azeotropic Binary
Mixtures. J.Chem.Educ. 6 (1929) 1544-1549
Vapor-Liquid Equilibrium Data Set 467

Components

No. Formula Molar Mass CAS Registry Number Name


1 CH4O 32.042 67-56-1 Methanol
2 H2O 18.015 7732-18-5 Water
Search the DDB for all data of this mixture

Constant Value

Temperature 312.91 K

Data Table

P [kPa] x1 [mol/mol] y1 [mol/mol]


9.079 0.04780 0.25590
11.412 0.09250 0.45620
11.506 0.09250 0.46280
13.012 0.13350 0.62140
13.786 0.15230 0.61640
14.639 0.18090 0.64860
15.785 0.20320 0.67340
15.879 0.20270 0.67960
16.319 0.22280 0.69540
17.599 0.25570 0.72630
18.425 0.28660 0.73830
19.025 0.30650 0.76120
20.705 0.37160 0.80530
21.532 0.41720 0.80480
22.318 0.43620 0.82380
23.385 0.50330 0.84570
25.091 0.59330 0.86190
26.998 0.69170 0.88350
27.518 0.69490 0.89740
29.744 0.80020 0.95360
32.571 0.92700 0.97610

(P - pressure, x - liquid mole fraction, y - vapor mole fraction)


Reference

Source
Bredig G.; Bayer R.: Die Dampfdrcke des binren Systems Methylalkohol-Wasser.
Z.Phys.Chem.(Leipzig) 130 (1927) 1-14

Vapor-Liquid Equilibrium Data Set 468

Components

No. Formula Molar Mass CAS Registry Number Name


1 CH4O 32.042 67-56-1 Methanol
2 H2O 18.015 7732-18-5 Water
Search the DDB for all data of this mixture

Constant Value

Temperature 322.91 K

Data Table

P [kPa] x1 [mol/mol] y1 [mol/mol]


15.932 0.04860 0.27410
20.932 0.12180 0.47410
22.625 0.14780 0.52200
26.131 0.21310 0.62940
29.024 0.26930 0.71060
31.544 0.32520 0.75800
37.730 0.51430 0.82030
40.850 0.62790 0.86540
43.210 0.70830 0.90070
46.450 0.80370 0.94060
49.796 0.90070 0.96270
52.142 0.94610 0.97360

(P - pressure, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Bredig G.; Bayer R.: Die Dampfdrcke des binren Systems Methylalkohol-Wasser.
Z.Phys.Chem.(Leipzig) 130 (1927) 1-14

Diagrams

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List of All References

Source
Bredig G.; Bayer R.: Die Dampfdrcke des binren Systems Methylalkohol-Wasser.
Z.Phys.Chem.(Leipzig) 130 (1927) 1-14
Bennett G.W.: A Laboratory Experiment on the Boiling-Point Curves of Non-Azeotropic Binary
Mixtures. J.Chem.Educ. 6 (1929) 1544-1549

Vapor-Liquid Equilibrium Data Overview