CODE - X

NEET2017 TEST PAPER WITH ANSWER & SOLUTIONS

(HELD ON SUNDAY 07th MAY, 2017)
136. Namethegasthatcanreadilydecolouriseacidified 141. Predictthecorrectintermediateandproductinthe
KMnO 4 solution: followingreaction:
(1)SO 2 (2)NO 2 (3)P2 O 5 (4)CO 2 H 2O,H 2SO 2
H 3CC CH HgSO 4
Intermediateproduct
Ans. (1) (A) (B)
137. Mechanismofahypotheticalreaction (1)A: H 3CC=CH 2 B: H 3CC=CH 2

X2 +Y 2 2XYisgiven below: OH SO 4

(i)X2 X+ X(fast) (2)A: H 3CCCH 3 B:H 3 CCCH

O
XY+ Y(slow)
(ii)X+Y2 (3)A: H 3CC=CH 2
B: H 3CCCH 3
(iii)X+ YXY (fast) OH O
Theoverallorderofthereactionwillbe: (4)A: H 3CC=CH 2
H
B: 3CCCH 3

SO 4 O
(1)2 (2)0 (3)1.5 (4)1
Ans. (3)
Ans. (3)
142. Theequilibriumconstantofthefollowingare:
138. TheelementZ=114hasbeendiscoveredrecently. 2NH 3
N2 +3H 2 K1
Itwillbelongtowhichofthefollowingfamily/group
2NO
N2 +O 2 K2
andelectronicconfiguration?
(1)Carbonfamily,[Rn]5f 14
6d 10 7s 2 7p 2 1
H2 O 2 H 2O K3
2
(2)Oxygenfamily,[Rn]5f 14 6d 10 7s 2 7p 4
14 Theequilibriumconstant(K)ofthereaction:
(3)Nitrogenfamily,[Rn]5f 6d 10 7s 2 7p 6

(4)Halogenfamily,[Rn]5f 14
6d 10 7s 2 7p 5 5 K
2NH 3
O 2
2NO 3H O
2 ,willbe:
2
Ans. (1)
139. The heating of phenylmethyl ethers with HI (1) K2 K33 / K 1 (2)K2 K3 /K 1
produces
(3) K32 K3 / K 1 (4) K1 K33 / K 2
(1)iodobenzene (2)phenol

(3)benzene (4)ethylchlorides Ans. (1)

143. Whichoneisthemostacidiccompound?
Ans. (2)
140. Whichoneisthecorrectorderofacidity? OH OH
(1)CH CH>CH 3 C CH>CH 2 =CH 2 > (1) (2)
CH 3 CH 3
NO 2
(2)CH CH>CH 2 =CH 2 >CH 3 C CH>

CH 3 CH 3
OH OH
(3)CH 3 CH 3 >CH 2 =CH 2 >CH 3 C CH> O 2N NO 2
(3) (4)
CH CH
NO 2 CH 3
(4)CH 2 =CH 2 >CH 3 CH=CH 2 >CH 3 C
CH>CH CH Ans. (3)
Ans. (1)

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NEET-2017
144. The correct increasingorderofbasicstrengthfor 151. Match the interhalogencompounds of column-I
thefollowingcompoundsis: with the geometry in column II and assign the
correct.code.
NH 2 NH 2 NH 2

(I) (II) (III) Column-I Column-II

NO 2 CH 3 (a) XX' (i) T-shape
(1)III <I <II (2)III <II <I
(b) XX'3 (ii) Pentagonal
(3)II <I <III (4)II <III <I bipyramidal
Ans. (3)
(c) XX'5 (iii) Linear
145. Ionicmobilityofwhichofthefollowingalkalimetal
ionsislowestwhenaqueoussolutionoftheirsalts (d) XX'7 (iv) Square-pyramidal
areputunderan electricfield?
(v) Tetrahedral
(1)K (2)Rb
(3)Li (4)Na Code :
Ans. (3) (a) (b) (c) (d)
146. Themostsuitablemethodofseparationof1:1
(1) (iii) (i) (iv) (ii)
mixtureoforthoandpara-nitrophenolsis: (2) (v) (iv) (iii) (ii)
(1)Chromatography (2)Crystallisation (3) (iv) (iii) (ii) (i)
(4) (iii) (iv) (i) (ii)
(3)Steamdistillation (4)Sublimation
Ans. (1)
Ans. (3)
152. Concentration of the Ag + ions in a saturated
147. HgCl 2 and I 2 both when dissolved in water
solutionofAg 2 C 2 O 4 is2.210 4 molL 1 Solubility
containingI ionsthepairofspeciesformedis:
productofAg 2 C 2 O 4 is:-

(1)HgI2 ,I (2) HgI24 , I3 (1) 2.6610 12 (2)4.510 11
(3) 5.3 10 12 (4)2.42 10 8
(3)Hg 2 I2 ,I (4) HgI2 , I3 Ans. (3)
153. Intheelectrochemicalcell:-
Ans. (2)
Zn|ZnSO 4 (0.01M)||CuSO 4 (1.0M)|Cu,theemf
148. Mixtureofchloroxylenolandterpineolactsas:
ofthisDanielcellisE 1 .Whentheconcentrationof
(1)antiseptic (2)antipyretic

ZnSO 4 is changed to 1.0M and that of CuSO 4

(3)antibiotic (4)analgesic changedto0.01M,theemfchangestoE 2 .From
Ans. (1) the followings, which one is the relationship
149. An example of a sigma bonded organometallic
RT
compoundis: betweenE 1 andE 2 ?(Given, = 0.059 )
F
(1)Grignard'sreagent (2)Ferrocene
(3)Cobaltocene (4)Ruthenocene (1) E1 < E 2 (2)E1 > E 2
Ans. (1) (3) E2 = 0 E1 (4)E1 = E 2
Ans. (2)
150. Afirstorderreactionhasaspecificreactionrate
154. Which of the following pairs of compounds is
of10 2 sec 1 .Howmuchtimewillittakefor20g
isoelectronicandisostructural?
ofthereactanttoreduceto5g?
(1) TeI2 ,XeF 2
(1)138.6 sec (2)346.5 sec
(2)IBr2,XeF 2
(3)693.0 sec (4)238.6 sec
(3) IF3 ,XeF 2
Ans. (1) (4)BeCl2 ,XeF 2
Ans. (2)
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155. TheIUPACnameofthecompound 158. Thespecies,havingbondanglesof120is:-
(1) CIF3 (2)NCl3 (3)BCl3 (4)PH 3
O O Ans. (3)
HC 159. For a given reaction, H = 35.5 kJ mol 1 and
is:- S=83.6JK 1 mol 1 .Thereactionisspontaneous
at : (Assume that H and Sdo not vary with
tempearature)
(1)T> 425 K (2)Alltemperatures
(1) 5-formylhex-2-en-3-one
(3) T >298 K (4)T< 425 K
(2) 5-methyl-4-oxohex-2-en-5-al
Ans. (1)
(3) 3-keto-2-methylhex-5-enal
160. WhichofthefollowingisasinkforCO?
(4) 3-keto-2-methylhex-4-enal (1)Microorganismpresentinthesoil
Ans. (4) (2) Oceans

156. Whichoneisthewrongstatement? (3) Plants

(4) Haemoglobin
(1) Theuncertaintyprincipleis E t h/4
Ans. (1)
(2) Halffilledandfullyfilledorbitalshavegreater
stability due to greater exchange energy, 161. Ifmolalityofthedilutesolutionsisdoubled,thevalue
greater symmetry an d mo re balan ced ofmolaldepressionconstant(K f)willbe:-
arrangement. (1) halved (2)tripled
(3) Theenergyof2sorbitalislessthantheenergy (3) unchanged (4)doubled
of2porbitalincaseofHydrogenlikeatoms

Ans. (3)

162. Which o f th e fo llowing is depen dent on

h
(4) de-Broglies'swavelengthisgivenby , temperature?
m
(1) Molarity
where m= mass of the particle, = group
velocityoftheparticle (2)Molefraction

Ans. (3) (3) Weightpercentage

157. Whichisthe incorrect statement? (4)Molality

Ans. (1)
(1) Density decreases in case of crystals with
Schottky'sdefect 163. Which one of the following statements is not
correct?
(2) NaCl(s) is insulator,silicon is semiconductor,
silverisconductor,quartzispiezoelectriccrystal (1) Thevalueofequilibriumconstantischanged
inthepresenceofacatalystinthereactionat
(3) Frenkel defect is favoured in those ionic
equilibrium
compoundsinwhichsizesofcationandanions
(2) Enzymescatalysemainlybio-chemicalreactions
arealmostequal
(3) Coenzymes increase the catalytic activity of
(4) FeO 0.98 hasnonstoichiometricmetaldeficiency
enzyme
defect
(4) Catalystdoesnotinitiateanyreaction
Ans. (3)
Ans. (1)
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NEET-2017
164. IdentifyAandpredictthetypeofreaction 167. A gas is allowed to expand in a well insulated
OCH 3 containeragainstaconstantexternalpressureof
2.5atmfromaninitialvolumeof2.50Ltoafinal
NaNH 2 volumeof4.50L.Thechangeininternalenergy
A
Br Uofthegasinjouleswillbe:-
(1)500J (2)505J
OCH 3
(3)+505J (4)1136.25J
NH 2
Ans. (2)
(1) an d elimin atio n addition
168. Whichofthefollowingreactionsisappropriatefor
convertingacetamidetomethanamine?
reaction
(1)Hoffmarnnhypobromamidereaction
OCH 3
(2)Stephensreaction
Br
(3)Gabrielsphthalimidesynthesis
(2) andcinesubstitutionreaction
(4)Carbylaminereaction
Ans. (1)
OCH 3
169. Withrespecttotheconformersofethane,which
ofthefollowingstatementsis true ?
(3) andcinesubstituionreaction
(1) Bondanglechangesbutbondlengthremains
same
OCH 3 (2) Bothbondangleandbondlengthchange
(3) Both bond angles and bond length remains
(4) andsubstitutionreaction same
NH 2 (4) Bond angle remains same but bond length
Ans. (4) changes
165. The correct order of the stoichiometries of Ans. (3)

AgClformedwhenAgNO 3 inexcessistreatedwith 170. In which pair of ions both the species contain
the complexs : CoCl 3 .6NH 3 , CoCl 3 .5NH 3 , SSbond?
CoCl 3 .4NH 3 respectivelyis:-
(1) S 4 O 62 , S 2 O 32 (2) S 2 O 72 , S 2 O 82
(1) 3AgCl,1 AgCl,2 AgCl
(2) 3AgCl,2AgCl,1AgCl (3) S 4 O 62 , S 2 O 72 (4) S 2 O 72 , S 2 O 32
(3) 2AgCl,3AgCl,1AgCl
Ans. (1)

(4) 1AgCl,3 AgCl,2 AgCl

Ans. (2)
166. The correct statementregardingelectrophileis:-
(1) Electrophileisanegativelychargedspeciesand
canformabondbyacceptingapairofelectrons
fromanotherelectrophile
(2) Electrophilesaregenerallyneutralspeciesand
canformabondbyacceptingapairofelectrons
fromanucleophile
(3) Electrophilecanbeeitherneutralorpositively
charged species and can form a bond by
acceptingapairofelectronsfromanucleophile
(4) Electrophileisanegativelychargedspeciesand
canformabondbyacceptingapairofelectrons
fromanucleophile
Ans. (3)
2
171. It is because of inability of ns
electrons of the
valenceshelltoparticipateinbondingthat:-
(1) Sn2+ isoxidisingwhilePb 4+ isreducing
(2) Sn2+ andPb 2+ arebothoxidisingandreducing
(3) Sn4+ isreducingwhilePb 4+ isoxidising
(4) Sn2+ isreducingwhilePb 4+ isoxidising
Ans. (In English-4, In Hindi-1)
172. Correct increasing order for the wavelengths of
absorptioninthevisibleregionthecomplexesof
Co 3+ is :-
(1) [Co(H2 O)6 ]3+ ,[Co(en) 3 ]3+ ,[Co(NH 3 )6 ]3+
(2) [Co(H2 O)6 ]3+ ,[Co(NH 3 )6 ]3+ ,[Co(en) 3 ]3+
(3) [Co(NH3 )6 ]3+ ,[Co(en) 3 ]3+ ,[Co(H 2 O)6 ]3+
(4) [Co(en)3 ]3+ ,[Co(NH 3 )6 ]3+ ,[Co(H 2 O)6 ]3+
Ans. (4)

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 CODE - X
173. Considerthereactions:- 177. A20litrecontainerat400KcontainsCO 2 (g)at
pressure0.4atmandanexcessofSrO(neglect
Cu [Ag(NH3 )2 ] +
the volume of solid SrO). The volume of the
X A Silvermirror
573K
OH containerisnowdecreasedbymovingthemovable
(C2 H6 O)
observed
OH pistonfittedinthecontainer.Themaximumvolume
O Y
ofthecontainer,whenpressureofCO 2 attainsits
NH 2NHCNH 2
maximumvalue,willbe:-
Z

(Given that : SrCO 3(s)

SrO(s) CO 2 (g),
IdentifyA,X,YandZ
(1) A-Methoxymethane,X-Ethanol,Y-Ethanoic Kp=1.6atm)
acid,Z-Semicarbazide. (1)10litre (2)4litre
( 2 ) A - E t h a n a l , X- E t h a n o l ,
(3)2litre (4)5litre
Y - B u t - 2 - e n a l , Z - S e m i c a r b a z o n e
Ans. (4)
(3) A- Et h an o l, X- Ace t aldeh yde,
Y- B ut a n o n e, Z- H yd raz o n e 178. Pick out the correct statement with respect to

(4) A-Methoxymethane,X-Ethanoicacid,

Ans. (2)
Y-Acetateion,Z-hydrazine

174. Ofthefollowing,whichistheproductformedwhen
[Mn(CN)6 ]3 :-

(1) Itissp3 d2 hybridisedandtetrahedral

(2) Itisd2 sp 3 hybridisedandoctahedral

cyclohexanone undergoes aldol condensation (3) Itisdsp 2 hybridisedandsquareplanar

followedbyheating?:- (4) Itissp3 d2 hybridisedandoctahedral

Ans. (2)

(1) (2)
O OH 179. Thereasonforgreaterrangeofoxidationstates
O
inactinoidsisattributedto:-

(3) (4) (1) actinoidcontraction

O O
OH (2) 5f,6dand7slevelshavingcomparableenergies
Ans. (1)

175. Whichofthefollowingpairsofspecieshavethe (3) 4fand5dlevelsbeingcloseinenergies

samebondorder? (4) theredioactivenatureofactinoids
(1)O 2 ,NO + (2)CN,CO
Ans. (2)
(3)N2 , O 2 (4)CO,NO
180. Whichofthefollowingstatementsisnotcorrect:-
Ans. (2)
(1) Ovalbuminisasimplefoodreserveinegg-white
176. Extractionofgoldandsilverinvolesleachingwith
CN ion.Silverislaterrecoveredby:- (2) Blood proteins thrombin and fibrinogen are
(1)distillation involvedinbloodclotting
(2)zonerefining (3) Denaturationmakestheproteinsmoreactive
(3)displacementwithZn
(4) Insulinmaintanissugarlevelinthebloddofa
(4)liquation
Ans. (3) humanbody

Ans. (3)