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(H Y D ER A BA D C L A SSES) L I M I T ED
EXAM PAPER
TOPIC : KVPY_3_CAV

31. Which of the following compounds will not show resonance ?

CH2

(A) (B) CH2 CH2 CH CH C H2

H
H N H
(C) (D)

32. Which of the following acids has lowest pKa value ?


(A) CH2(NO2)COOH (B) CH2(NO2)CH2COOH
(C) CH2(Cl)COOH (D) H3CC(Cl)2COOH

33. Which of the following is not isostructural with SiCl4 ?


(A) PO34 (B) NH4 (C) SCl4 (D) SO24

34. In which of the following molecule all the bond lengths are not equal ?
(A) AlF3 (B) NF3 (C) ClF3 (D) BF3

35. Which of the following have undistorted octahedral structures?


1. SF6 2. PF6 3. SiF62 4. XeF6
(A) 2, 3 and 4 (B) 1, 3 and 4 (C) 1, 2 and 3 (D) 1, 2 and 4

36. Among tri halides of nitrogen, which one is least basic ?


(A) NI3 (B) NBr3 (C) NCl3 (D) NF3

37. CO2 gas along with solid (Y) is obtained when sodium salt (X) is heated (X) is again obtained when
CO2 gas is passed into aqueous solution of (Y). (X) and (Y) are
(A) Na2CO3, Na2O (B) Na2CO3NaOH (C) NaHCO3, Na2cO3 (D) Na2CO3, NaHCO3

38. Gallium has smaller atomic radius than aluminium because of


(A) poor shielding power of d electrons of Ga atom
(B) poor shielding power of s electrons of Ga atom
(C) Greater shielding power of s electrons of Al atom
(D) greater shielding power of d electrons of Ga atom

39. Which of the following is the correct order of mobility ?


(A) Li+ < Na+ < K+ (B) Na+ < Mg2+ < Al3+ (C) Al3+ < Mg2+ > Na+ (D) Li+ > Na+ > K+

40. In the hetero genius equilibrium


CaCO3 s CaO s CO2 g . What would be the effect of addition of CaCO 3 on the
equilibrium concentration of CO2 /
(A) Increases (B) Unpredictable (C) Decreases (D) Remains unaffected

FIITJEE (Hyderabad Classes) Limited., 5-9-14/B, Saifabad, (Opp. Secretariat) Hyderabad500 063. Phone: 040-66777000-03 Fax: 040-66777004
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(H Y D ER A BA D C L A SSES) L I M I T ED
EXAM PAPER
41. Equimolar concentration of H 2 and I2 are heated to equilibrium in a 2 litre flask at equilibrium, the
forward and backward rate constants are found to be equal. What % of initial concentration of H 2 has
reacted at equilibrium ?
(A) 33% (B) 66% (C) 50% (D) 40%

42. A certain zero order reaction has K = 0.025 for the disappearance of A. What will be the
concentration of A after 15 seconds if the initial concentration is 0.5 M ?
(A) 0.5 M (B) 0.32 M (C) 0.12 M (D) 0.06 M

43. The electronic configuration of an element is 1s22s22p63s23p63d5, 4s1 this represents


(A) excited state (B) ground state (C) cationic state (D) anio sala

44. Which compound will not give friedelcrafts reaction ?


(A) C6H5NO2 (B) C6H5CH3 (C) C6H5OCH3 (D) C6H5Cl

45. The reaction condition leading to the best yield of C 6H5CH2Cl is


h
(A) C6H5 CH3 Cl2 h
(B) C6 CH3 Cl2
excess excess
dark
(C) C6H5 CH3 Cl2 brown (D) C6H5 CH3 Cl2

excess excess

TWO MARKS

71. If 1021 molecules are removed from 100mg CO2, then number of moles of CO2 left are
(A) 6.10 x 104 (B) 2.8 x 103 (C) 2.28 x 103 (D) 1.36 x 102

72. 250 ml of Na2CO3 solution contains 2.65g of Na2CO3. 10 ml of this solution is added to x ml of water
to obtain 0.001 M Na2CO3 solution, the value of x is
(A) 1000 (B) 990 (C) 9990 (D) 90

73. An open vessel at 27C is heated until threefifth of the air in it has been expelled. Asssuming that
the volume of the vessel remains constant, find the temperature to which the vessel has been
heated ?
(A) 477C (B) 177C (C) 377C (D) none

74. The pH of 0.02M NH4Cl() (Pkb = 4.73) is equal to


(A) 3.78 (B) 4.73 (C) 5.48 (D) 7.00

75. Which one of the following compounds will give SN1 reaction most readily ?

(A) CH3O CH2Br (B) NO 2 CH2Br

(C) H3 C CH2Br (D) CH2 Br

FIITJEE (Hyderabad Classes) Limited., 5-9-14/B, Saifabad, (Opp. Secretariat) Hyderabad500 063. Phone: 040-66777000-03 Fax: 040-66777004
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(H Y D ER A BA D C L A SSES) L I M I T ED
EXAM PAPER
ANSWERS

31. C 32. D 33. C 34. C


35. C 36. D 37. C 38. A
39. A 40. D 41. A 42. C
43. B 44. A 45. B 71. A
72. B 73. A 74. C 75. A

FIITJEE (Hyderabad Classes) Limited., 5-9-14/B, Saifabad, (Opp. Secretariat) Hyderabad500 063. Phone: 040-66777000-03 Fax: 040-66777004

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