Вы находитесь на странице: 1из 11

TARGET CH EMISTRY

DAILY PRACTICE PROBLEMS

JEE (ADVANCED) : 2014 DPP


COURSE NAME : UMANG (UP) DATE : 29.07.2013 to 03.08.2013 DPP NO. 39

* Marked Questions are having more than one correct option.


DPP No. # 39
1. Maganese achieves its maximum oxidation state in which of these compounds :
(A) MnO2 (B) Mn3O4 (C) KMnO4 (D) K2MnO4

2. Oxidation number of underlined elements in N2O5, SO2


3
, NH+4 are :
(A) + 5, + 2, 3 (B) + 6, 2, + 3 (C) + 6, + 2, 3 (D) + 5, + 4, 3

3. Phosphorous has the oxidation state of + 3 in :


(A) Phosphorus acid (H3PO3) (B) Orthophosphoric acid (H3PO4)
(C) Metaphosphoric acid (HPO3) (D) Pyrophosphoric acid (H4P2O7)

4. Which statement is wrong :


(A) Oxidation number of oxygen is + 1 in peroxides
(B) Oxidation number of oxygen is + 2 in oxygen difluroide

1
(C) Oxidation number of oxygen is in superoxides
2

(D) Oxidation number of oxygen is 2 in most of its compounds

5. The oxidation number and covalency of sulphur in the sulphur molecule (S8) are respectively :
(A) 0 and 2 (B) + 6 and 8 (C) 0 and 8 (D) + 6 and 2

6. The oxidation number of oxygen in F2O is :


(A) + 1 (B) 2 (C) + 2 (D) 3

7. Calculate individual and average oxidation number (if required) of the marked element and also draw the
structure of the following compounds or molecules :
(1) Na2S2O3 (2) Na2S4O6 (3) H2SO5 (4) H2S2O8 (5) H2S2O7 (6) S8
(7) HNO4 (8) C3O2 (9) OsO4 (10) PH3 (11) CrO42 (12) Cr2O72
(13) CrO2Cl2 (14) CrO5 (15) Na2HPO4 (16) FeS2 (17) C6H12O6 (18) NH4NO3

8. Calculate individual and average oxidation number (if required) of the marked element and also draw the
structure of the following compounds or molecules :
(1) FNO3 (2) CaOCl2 (3) XeO3F2 (4) LiAlH4 (5) Na3AlF6
(6) P4 (7) O3 (8) I (IO3)3 (9) Fe3O4 (10) CsI3
(11) KO3 (12) O2F2 (13) H2SiF6 (14) H3PO3 (15) POCl3
(16) Si(OH)4 (17) Mg2C3 (18) CaC2 (19) Be2C

ETOOS ACADEMY Pvt. Ltd


F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303 PAGE NO. # 1
ANSWER KEY
DPP No. # 39
1. (C) 2. (D) 3. (A) 4. (A) 5. (A) 6. (C)

7. (1) + 2 (6, 2) (2) + 5/2 (5, 5, 0, 0) (3) + 6

(4) + 6 (+ 6, + 6) (5) + 6 (+ 6, + 6) (6) 0

(7) + 5 (8) 4/3 (+ 2, + 2, 0) (9) + 8 (10) 3 (11) + 6

(12) + 6 (+ 6, + 6) (13) + 6 (14) + 6

(15) + 5 (16) + 2 (17) 0 (18) 3, + 5

8. (1) + 5 (2) 0 ( 1, + 1) (3) + 8

(4) + 3 (5) + 3 (6) 0 (0, 0, 0, 0) (7) 0 (0, 1, + 1)

8 1
(8) + 3, + 5 (9) ( 2, 3) (10)
3 3

1
(11) (12) + 1 (+ 1, + 1) (13) + 4
3

(14) + 3 (15) + 5 (16) + 4

4
(17) (0, 4, 0) (18) 1 ( 1, 1) (19) 4
3

ETOOS ACADEMY Pvt. Ltd


F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303 PAGE NO. # 2
TARGET CH EMISTRY
DAILY PRACTICE PROBLEMS

JEE (ADVANCED) : 2014 DPP


COURSE NAME : UMANG (UP) DATE : 05.08.2013 to 10.08.2013 DPP NO. 40 TO 42

* Marked Questions are having more than one correct option.

DPP No. # 40
1. Identify the reactants, if any, oxidized or reduced.
(a) NaH + H2O NaOH + H2
(b) 2FeCl3 + H2S 2FeCl2 + S + 2HCl
(c) 3Mg + N2 Mg3N 2
(d) AgCN + CN Ag(CN)2
(e) SnCl2 + Br2 SnCl2.Br 2
(f) AlCl3 + K Al + 3KCl
(g) 2CuSO4 + 4KI Cu2I2 + K2SO4 + I2
(h) NH4NO2 N2 + 2H2O
(i) CaC2 + 2H2O Ca(OH)2 + C2H2
(j) SnS2 + S2 SnS32
(k) 3O2 2O3

2. Select the oxidants and reductants in the given reactions .


(a) Ag(NH3)2+ + 2H+ Ag+ + 2NH4+
(b) KIO3 + 5KI + 6HCl 3I2 + 6KCl + 3H2O
(c) 2CuSO4 + SO2 + 2KBr + 2H2O 2CuBr + 2H2SO4 + K2SO4
(d) C2H4 + Br2 C2H4Br2
(e) 2I + H2O2 2OH + I2
(f) Si + 2KOH + H2O K2SiO3 + 2H2
(g) 2Cu+2 + 4I Cu2I2 + I2

3. Balance the following equation using desired medium


(a) C2H5OH + Cr2O72 + H+ Cr3+ + C2H4O + H2O

(b) Sn(OH)3 + Bi(OH)3 + OH Sn(OH)62 + Bi

(c) IO3 + N2H4 + HCl N2 + ICl2 + H2O

(d) Hg2Cl2 + NH3 Hg + HgNH2Cl + NH4Cl

(e) Zn + NO3 + H+ Zn2+ + NH4+ + H2O

(f) I2 + NO3 + H+ IO3 + NO2 + H2O

(g) MnO4 + SO22 + H2O MnO2 + SO42 + OH

(h) H2O2 + ClO2 + OH ClO2 + O2 + H2O

(i) ClO + CrO2 + OH Cl + CrO42 + H2O

(j) Cl2 + KOH KClO3 + KCl + H2O

ETOOS ACADEMY Pvt. Ltd


F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303 PAGE NO. # 1
DPP No. # 41
Balance the following equation using desired medium
1. H2O2 + KMnO4 MnO2 + KOH + O2 + H2O
2. HNO2 + KMnO4 + H2SO4 HNO3 + KMnO4 + K2SO4 + H2O
3. N2H4 + AgNO3 + KOH N2 + Ag + KNO3 + H2O
4. P + HNO3 HPO3 + NO + H2O
5. K2Cr2O7 + HCl KCl + CrCl3 + H2O + Cl2
6. MnO4 + C2O42 + H+ CO2 + Mn2+ + H2O
7. Cr2O72 + C2O42 + H+ Cr3+ + CO2 + H2O
8. KMnO4 + H2S + H2SO4 KHSO4 + MnSO4 + S + H2O
9. Cu(NH3)4Cl2 + KCN + H2O K2Cu(CN)3 + NH3 + KCNO + NH4Cl + KCl
10. Ag + KCN + H2O + O2 KAg(CN)2 + KOH
11. Fe3O4 + MnO4 + H2O Fe2O3 + MnO2 + OH
12. C2H5OH + MnO4 + OH C2H3O + MnO2 + H2O
13. Cr2O72 + SO32 + H+ Cr3+ + SO42 + H2O
14. ClO3 + SO2 + H+ ClO2 + HSO4
15. Mn2+ + S2O82 + H2O MnO4 + HSO4 + H+
DPP No. # 42
* Equivalent weight of any substance is the weight in gram which combines with 1 gram of hydrogen ,
8 grams of oxygen, 35.5 grams of Cl and 108 grams of Ag.
Molecular weight
* Equivalent weight =
' n' factor
1. The equivalent weight of a metal is 36. What weight of the metal would give 9.322 gm of its chloride?
2. On heating 5 103 equivalent of CaCl2.xH2O, 0.18 gm of water is obtained, what is the value of x ?
3. The equivalent weight of a metal is double that of oxygen. How many times is the weight of its oxide
greater than the weight of the metal ?
4. 0.224 gm of a metal when dissolved in dilute acid liberates 285 cc of hydrogen, measured at 17C
and 78 cm of mercury pressure. Find the equivalent weight of the metal.
5. 1.82 g of a metal required 32.5 mL of N HCl to dissolve it. What is equivalent weight of metal ?
6. The equivalent weight of a metal is 30. What volume of chlorine would be liberated at 27C and 750
mm pressure by 0.6 gm of the metal ? [Aqueous tension at 27C = 26.6 mm]
7. The molecular formula of an oxide of an element X is X mOn what is the equivalent weight of themetal?
[Given atomic weight of X = a]
8. 12 g of an element combines with 32 g of oxygen. What is the equivalent weight of the element if the
equivalent weight of oxygen is 8 ?
9. Equivalent weight of sulphur in SCl2 is 16, what is the equivalent weight of S in S2Cl2 ?
[S = 32 , Cl = 35.5]
10. 1.60 gm of a metal were dissolved in HNO3 to prepare its nitrate. The nitrate was strongly heated to
give 2 g oxide. Calculate equivalent weight of metal.
11. From 3.36 gm of Fe, 4.80 gm of iron oxide is obtained. What is the equivalent weight of Fe?
12. 1.0 g of metal nitrate gave 0.86 g of metal sulphate. Calculate equivalent weight of metal.
13. An element forms two oxides, the weight ratio composition in them, A : O = x : y in the first oxide and
y : x in the second oxide. If the equivalent weight of A in the first oxide is 10.33, Calculate the equivalent
weight of A in the second oxide.
ETOOS ACADEMY Pvt. Ltd
F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303 PAGE NO. # 2
ANSWER KEY
DPP No. # 40
1. Rxn. No. (a) (b) (c) (d) (e) (f) (g) (h) (i) (j) (k)
Oxidized : NaH, H2S, Mg, none, SnCl2, K, KI, NH4+, none, none none.
Reduced : H2O, FeCl3, N2 none, Br2, AlCl3, CusO4, NO2, none, none, none
2. (a) not (b) KIO3-oxidant, I reductant
(c) CuSO4-oxidant, SO2 reductant (d) Br2-oxidant, C2H4 reductant
(e) H2O2-oxidant, I reductant (f) KOH-oxidant, Si reductant
(g) Cu++-oxidant, I reductant

3. (a) 3C2H5OH + Cr2O72 + 8H+ 2Cr3+ + 3C2H4O + 7H2O


(b) 3Sn(OH)3 + 2Bi(OH)3 + 3OH 3Sn(OH)62 + 2Bi
(c) IO3 + N2H4 + 2HCl N2 + ICl2 + 3H2O
(d) 2Hg2Cl2 + 4NH3 2Hg + 2HgNH2Cl + 2NH4Cl
(e) 4Zn + NO3 + 10H+ 4Zn2+ + NH4+ + 3H2O
(f) I2 + 10NO3 +8H+ 2IO3 + 10NO2 + 2H2O
(g) 2MnO4 + 3SO22 + H2O 2MnO2 + 3SO42 + 2OH
(h) H2O2 + 2ClO2 + 2OH 2ClO2 + O2 + 2H2O
(i) 3ClO + 2CrO2 + 2OH 3Cl + 2CrO42 + H2O
(j) 3Cl2 + 5KOH KClO3 + 5KCl + 3H2O
DPP No. # 41
1. 3H2O2 + 2KMnO4 2MnO2 + 2KOH +3O2 + 2H2O
2. 5HNO2 + 2KMnO4 + 3H2SO4 5HNO3 + 2KMnO4 + K2SO4 + 3H2O
3. N2H4 + 4AgNO3 + 4KOH N2 + 4Ag + 4KNO3 + 4H2O
4. 3P + 5HNO3 3HPO3 + 5NO + H2O
5. K2Cr2O7 + 8HCl 2KCl + 2CrCl3 + 7H2O + 3Cl2
6. 2MnO4 + 5C2O42 + 16H+ 10CO2 + 2Mn2+ + 8H2O
7. Cr2O72 + 3C2O42 + 14H+ 2Cr3+ + 6CO2 + 7H2O
8. 2KMnO4 + 5H2S + 4H2SO4 2KHSO4 + 2MnSO4 + 5S + 8H2O
9. 2Cu(NH3)4Cl2 + 7KCN + H2O K2Cu(CN)3 + 6NH3 + KCNO + 2NH4Cl + 2KCl
10. 4Ag + 8KCN + 2H2O + O2 4KAg(CN)2 + 4KOH
11. 6Fe3O4 + 2MnO4 + H2O 9Fe2O3 + 2MnO2 + 2OH
12. 3C2H5OH + 2MnO4 + OH 3C2H3O + 2MnO2 + 5H2O
13. Cr2O72 + 3SO32 + 8H+ 2Cr3+ + 3SO42 + 4H2O
14. 2ClO3 + SO2 + H+ 2ClO2 + HSO4
15. 2Mn2+ + 5S2O82 + 8H2O 2MnO4 + 10HSO4 + 6H

DPP No. # 42

1. 4.6935 gm 2. x=4 3. 1.5 4. 9.105 5. 56

6. 0.2584 lit 7. m a/2n 8. 3 9. 32 10. 32

11. 18.67 12. 38 13. 6.2

ETOOS ACADEMY Pvt. Ltd


F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303 PAGE NO. # 3
TARGET CH EMISTRY
DAILY PRACTICE PROBLEMS

JEE (ADVANCED) : 2014 DPP


COURSE NAME : UMANG (UP) DATE : 12.08.2013 to 17.08.2013 DPP NO. 43 & 44

* Marked Questions are having more than one correct option.

DPP No. # 43
1. White phosphorus reacts caustic soda, the products are PH3 and NaH2PO2. The reaction is an example
of :
(A) Oxidation (B) Reduction (C) Disproportionation (D) Neutralisation

2. The reaction 3 ClO (aq) ClO3 (aq) + 2Cl (aq) is an example of :


(A) Oxidation (B) Reduction (C) Disproportionation (D) Decomposition

3. Which of the following changes does not involve either oxidation or reduction :
(A) VO2+ V2O3 (B) Na Na+ (C) Zn2+ Zn (D) CrO42 Cr2O72

4. Which of the following is not a redox reaction?


(A) Mg + N2 Mg3N2 (B) MnO4 + C2O42 Mn2+ + CO2
(C) CuSO4 + KI 2CuI + I2 + K2SO4 (D) AgCl + NH3 [Ag(NH3)2]Cl

5.* Which of the following can show disporoportionation reaction :


(A) ClO4 (B) Cl (C) ClO2 (D) ClO3

6. Identify the oxidant and the reductant in the following reactions :


(a) KMnO4 + KCl + H2SO4 MnSO4 + K2SO4 + H2O + Cl2
(b) FeCl2 + H2O2 + HCl FeCl3 + H2O
(c) Cu + HNO3 (dil) Cu (NO3)2 + H2O + NO
(d) Na2HAsO3 + KBrO3 + HCl NaCl + KBr + H3AsO4
(e) I2 + Na2S2O3 Na2S4O6 + NaI

7. Balance the following redox equations and determine the valency factor (n-factor) for oxidant and
reductant involved in the reactions :
(i) K2Cr2O7 + H2O2 + H2SO4 K2SO4 + Cr2(SO4)3 + H2O + O2
(ii) Zn + NaNO3 + NaOH Na2ZnO2 + H2O + NH3
(iii) Al [Al(OH)4] + H2 (basic)
2 2+
(iv) Cu3P + Cr2O7 Cu + H3PO4 + Cr3+ + H2O (acidic)
2+ + 3+
(v) ClO3 + Fe

+ H Cl + Fe
+ H 2O
(vi) N2O4 + BrO3 NO3 + Br

(vii) S2O32 + Sb2O5 SbO + H2SO3


(viii) Cr2O72 + I + H+ Cr3+ + I2 + H2O
(ix) IO4 + I + H+ I2 + H2O

ETOOS ACADEMY Pvt. Ltd


F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303 PAGE NO. # 1
DPP No. # 44

1. In the reaction 2S2O32 + I2 S4O62 + 2I, the equivalent wt. of S4O62 is equal to :
(A) Mol wt. (B) Mol. wt./2 (C) 2 Mol. wt. (D) Mol. wt./6

2. Equivalent weight of NH3 in the change N NH3 is :


(A) 17/6 (B) 17 (C) 17/2 (D) 17/3

3. The molecular weight of the compounds (a) Na2SO4, (b) Na3PO4. 12H2O and (c) Ca3(PO4)2 respectively
are X, Y and Z. The correct set of their equivalent weights will be :

X Y Z Y Z
(A) (a) (b) (c) (B) (a) x (b) (c)
2 3 6 3 3

X Z
(C) (a) (b) Y (c) (D) (a) X (b) Y (c) Z
2 3

4. In the following reaction :


3Fe + 4H2O Fe3O4 + 4H2, if the atomic weight of iron is 56, then its equivalent weight will be :
(A) 42 (B) 21 (C) 63 (D) 84

5. When one mole NO3 is converted into 1 mole NO2, 0.5 mole N2 and 0.5 mole N2O respectively, it
accepts x, y and z mole of electrons. Then, x, y and z are respectively :
(A) 1, 5, 4 (B) 1, 2, 3 (C) 2, 1, 3 (D) 2, 3, 4

6. In the equation, SnCl2 + 2HgCl2 Hg2Cl2 + SnCl4 :


The equivalent weights of Stannous chloride (molecular weight = 190) will be :
(A) 190 (B) 95 (C) 47.5 (D) 154.5

7. In the reaction
2CuSO4 + 4KI 2CuI + I2 + 2K2SO4
the equilvalent weight of CuSO4 will be :
(A) 79.75 (B) 159.5 (C) 329 (D) None of these

8. In the following half-reaction, hydrazine is oxidized to N2.


N2H4 + OH N2 + H2O + e
The equivalent weight of N2H4 (hydrazine) is :
(A) 8 (B) 16 (C) 32 (D) 64

ETOOS ACADEMY Pvt. Ltd


F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303 PAGE NO. # 2
ANSWER KEY
DPP No. # 43
1. (C) 2. (C) 3. (D) 4. (D) 5.* (CD)
6. (a) (+ 7) ( 1) (+ 2) (0)
KMnO4 + KCl + H2SO4 MnSO4 + K2SO4 + H2O + Cl2
(+ 7) (+ 2)
KMnO4 (oxidant) MnSO4 (reduction half)
( 1) (0)
KCl (reducant) Cl2 (oxidant half)
(b) (+ 2) ( 1) (+ 3) (2)
FeCl2 + H2O2 + HCl FeCl3 + H2O (oxidant half)
(+ 2) (+ 3)
FeCl2 (reductant) FeCl3 (oxidation half)
( 1)
H2O2 (oxidant) H2O2 (reduction half)
(c) (0) (+5) 2+ 2+
Cu + HNO3 (dil) Cu (NO3)2 + H2O + NO
(0) 2+
Cu (reductant) Cu (NO3)2 (oxidation half)
+5 +2
HNO3 (oxidant) NO (reduction half)
(d) +3 +5 1 +5
Na2HAsO3 + KBrO3 + HCl NaCl + KBr + H3AsO4
+3 +5
Na2HAsO3 (reductant) H3AsO4 (oxidation half)
+5 1
KBrO3 (oxidant) KBr
(e) 0 +2 + 2.5 1
I2+ Na2S2O3 Na2S4O6 + NaI
0 1
I2 (oxidant) NaI (reduction half)
+2 +2.5
Na2S2O3(reducant) Na2S4O6(oxidant half)

7. (i) K2Cr2O7 + 3H2O2 + 4H2SO4 K2SO4 + Cr2(SO4)3 + 7H2O + 3O2


v.f. = 6 v.f. = 2
(ii) 4Zn + NaNO3 + 7NaOH = 4Na2ZnO2 + 2H2O + NH3
v.f. = 2 v.f. = 8
(iii) 2OH + 6H2O + 2Al 3H2 + 2(Al(OH)4]
v.f. = 3
(iv) 6Cu3P + 11Cr2O72 + 124H+ 18Cu2+ + 6H3PO4 + 22Cr3+ + 53H2O
v.f. = 11 v.f. = 6
(v) 6H+ + ClO3 + 6Fe2+ Cl + 6Fe3+ + 3H2O
v.f. = 6 v.f. = 1
(vi) 3N2O4 + BrO3 + 3H2O 6NO3 + Br + 6H+
v.f. = 2 v.f. = 6
(vii) 3S2O32 + 2Sb2O5 + 6H+ + 3H2O 4SbO + 6H2SO3
v.f. = 4 v.f. = 6
(viii) Cr2O72 + 6I + 14H+ 2Cr3+ + 3I2 + 7H2O
v.f. = 6 v.f. = 1
(ix) IO4 + 7I + 8H+ 4I2 + 4H2O
v.f. = 7 v.f. = 1
DPP No. # 44
1. (B) 2. (D) 3. (A) 4. (B) 5. (A) 6. (B) 7. (B)
8. (A)

ETOOS ACADEMY Pvt. Ltd


F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303 PAGE NO. # 3
TARGET CH EMISTRY
DAILY PRACTICE PROBLEMS

JEE (ADVANCED) : 2014 DPP


COURSE NAME : UMANG (UP) DATE : 26.08.2013 to 31.08.2013 DPP NO. 45 & 47

* Marked Questions are having more than one correct option.


DPP No. # 45

1. Suppose a compound contains atoms A, B and C. The oxidation number of A is +2, B is +5 and C is
2. The possible formula of the compound would be :
(A) ABC2 (B) A2(BC3)2 (C) A3(BC4)2 (D) A3(B4C)2

2. 50 mL of 5.6% KOH (w/v) is added to 50 mL of a 5.6% HCI (w/v) solution. The resulting solution will
be
(A) neutral (B) alkaline (C) strongly alkaline (D) acidic

3. Number of moles of electrons taken up when 1 mole of NO3 ions is reduced to 1 mole of NH2OH is :
(A) 2 (B) 4 (C) 5 (D) 6

4. As 2O3 is oxidised to H3AsO4 by KMnO4 in acidic medium. Volume of 0.02M KMnO4 required for this
purpose by 1mmol of As 2O3 will be :
(A) 10 mL (B) 20 mL (C) 40 mL (D) 80 mL

5. A 25-mL HCl solution containing 3.65 g HCl/L is neutralized by 50 mL an NaOH solution. Again, 25 mL
of the same NaOH solution neutralized by 50 mL of an H2SO4 solution of unknown strength.The
normality of the H2SO4 solution is
(A) 0.25 N (B) 0.025 N (C) 0.05 N (D) 0.50 N

6. The total volume of 0.1 M KMnO4 solution that are needed to oxidize 144 mg of ferrous oxalate and 152 mg
of ferrous sulphate in a mixture in acidic medium is :
(A) 5 mL (B) 2 mL (C) 8 mL (D) None of these

7. The equivalent weight of a metal is double than of oxygen. How many times is the weight of its oxide
greater than the weight of the metal ?
(A) 1.5 (B) 2 (C) 3 (D) 4

8. How much mass of K2C2O4 is require for complete oxidation in titration with 0.2 M, KMnO4 . The
volume of KMnO4 used in acidic medium is 500 ml and calculate the volume of CO2 obtained at S.T.P.
in the reaction.

9. The percent yield for the following reaction carried out in carbon tetrachloride (CCI4) solution is 80%
Br2 + CI2 2BrCI
(a) What amount of BrCI would be formed from the reaction of 0.025 mol Br2 and 0.025 mol CI2?
(b) What amoumt of Br2 is left unchanged?

10. 24 ml of a solution of Fe2+ ions was titrated with a solution of the oxidizing agent Cr2O72. 40 ml of 0.02 M
K2Cr2O7 solution was required.What is the molarity of the Fe2+ solution.

ETOOS ACADEMY Pvt. Ltd


F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303 PAGE NO. # 1
DPP No. # 46

1. 25 mL of 2N HCl, 50 mL of 4N HNO3 and x mL of 2M H2SO4 are mixture together and the total volume is
made up to 1 L after dilution. 50 mL of this acid mixture completely reacted with 25 mL of a 1N Na2CO3
solution. The value of x is :
(A) 250 mL (B) 62.5 mL (C) 100 mL (D) None of these

2. One mole of H2SO4 will exactly neutralize


(A) 4 moles of an ammonia solution (B) 1 mole of Ba(OH)2
(C) 3 moles of Al (OH)3 (D) 0.5 mole of Ba(OH)2

3. When ferrous oxalate is titrated against K2Cr2O7, meq of Fe2+, C2O42 and Cr2O72 in this redox reac-
tion are x, y and z respectively. Then
(A) x = y (B) x + y = z (C) x + 2y = z (D) 2x + 6y = 6z

4. What volume of 2N K2Cr2O7 solution is required to oxidise 0.81 g of H2S in acid medium?
(A) 47.8 ml (B) 23.8 ml (C) 40 ml (D) 72 ml

5. The number of moles of KMnO4 that will be needed to react with one mole of sulphite ion in acid
solution is
(A) 4/5 (B) 3/5 (C) 1 (D) 2/5

6. 4 mole of a mixture of Mohrs salt and Fe2(SO4)3 requires 500 mL 1M K2Cr2O7 for complete oxidation in
acidic medium. The mole % of the Mohrs salt in the mixture is :
(A) 25 (B) 50 (C) 60 (D) 75

7. A solution of Na2S2O3 is standardized iodometrically against 0.167 g of KBrO3. This process requires 50 mL
of the Na2S2O3 solution. What is the normality of the Na2S2O3 ?
(A) 0.2 N (B) 0.12 N (C) 0.72 N (D) 0.02 N

8. In an iodometric estimation, the following reaction occur


2Cu2+ + 4I Cu2I2 ; I2 + 2Na2S2O3 2NaI + Na2S4O6
0.12 mole of CuSO4 was added to excess of KI solution and the liberated iodine required 120 mL of hypo.
The molarity of hypo solution was :
(A) 2 (B) 0.20 (C) 0.1 (D) 1.0

9. It requires 20 ml of 1 M X 3+ to titrate 10 ml of 2 M Sn2+ to Sn4+. What is the oxidation state of the 'X'
in the product.

10. 25 ml of a solution of H2S (it convert into S) was titrated with a solution of the oxidizing agent Cr2O72. 100
ml of 0.01 M K2Cr2O7 solution was required. What is the molarity of the H2S solution ?

11. How many ml of 0.3M K2Cr2O7 (acidic) is required for complete oxidation of 10 ml of 0.1 M FeC2O4
solution.

12. Calculate the mass of oxalic acid which can be oxidized by 100ml of MnO4 solution, 10ml of same solution
of MnO4 is capable of oxidizing 50ml of 1 N I to I2.

13. Butane, C4H10, burns with the oxygen in air to give carbon dioxide and water.
What is the amount (in moles) of carbon dioxide produced from 0.15 mol C4H10 ?
C4H10(g) + O2(g) CO2(g) + H2O(g) (not balanced)

DPP No. # 47
1. A 10-volume H2O2 solution is equal to
(A) 3% (w/v) H2O2 (B) 30 g/L H2O2 (C) 1.76 N (D) all of these

2. A 5.0-mL solution of H2O2 liberates 0.508 g of iodine from an acidified Kl solution. The volume strength
of the H2O2 solution at STP is approximately :
(A) 4.00 (B) 4.5 (C) 6.05 (D) 5.5

ETOOS ACADEMY Pvt. Ltd


F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303 PAGE NO. # 2
3. What volume of O2 measured at standard conditions will be formed by the action of 100 ml of 0.5 N
KMnO4 on hydrogen peroxide in an acid solution? The skeleton equation for the reaction is
KMnO4 + H2SO4 + H2O2 K2SO4 + MnSO4 + H2O + O2
(A) 0.12 l (B) 0.28 l (C) 0.56 l (D) 1.12 l

4. 100 ml of 0.1M NaAl(OH)2CO3 is neutralised by 0.25 N HCl to form NaCl, AlCl3 and CO2. Volume of
HCl required is
(A) 10 mL (B) 40 mL (C) 100mL (D) 160 mL

5. 100 mL of 0.1N I2 oxidizes Na2S2O3 in 50 ml solution to Na2S4O6. The normality of this hypo solution
against KMnO4 (which oxidizes it to Na2SO4) would be
(A) 0.1 (B) 0.2 (C) 1.0 (D) 1.6.

6. Which of the following has two unpaired electrons ?


(A) Si, Mg (B) S, Mg (C) S, Si (D) S, Fe.

7. Total number of electrons contained in all the p-orbitals of bromine is:


(A) 5 (B) 17 (C) 19 (C) 23

8. The number of unpaired electrons in Mn2+ is:


(A) 5 (B) 3 (C) 4 (D) 1

9.* 1M 100 ml NaCl is mixed with 3M 100 ml HCl solution and 1M 200 ml CaCl2 solution. Find the ratio of the
concentration of cation and anion.
(A) The ratio of concentration of cation and anion = 3/4 M
(B) The ratio of concentration of cation and anion = 2 M
(C) [Cl] = 2 M (D) [Cl] = 3/2 M

Subjective
10. The reaction Cl2(g) + S2O32- SO42- + Cl- is to be carried out in basic medium. Starting with 0.15 mol
of Cl2, 0.01 mol S2O32- and 0.3 mol of OH-, how many moles of OH- will be left in solution after the
reaction is complete. Assume no other reaction occurs.

11. A piece of brass weighing 304.8 mg was dissolved and prepared for iodometric titration. Excess K was
added and the liberated iodine required 30.0 ml of 0.08 M hypo. Find the % of Cu in the brass.

ANSWER KEY : DPP No. # 45


1. (C) 2. (D) 3. (D) 4. (C) 5. (B) 6. (C) 7. (A)
8. 41.5 gm K2CO4 ; 11.2 lt CO2 .
9. (a) Br2 + CI2 2BrCI
1 mol 1mol 2mol
0.025 0.025 0.050 mol
(b) Theoretical yield of BrCI = 0.050 mol
0.05 80
actual yield is = = 0.04 mole
100
Br2 left unreacted = 0.025 0.02 = 0.005 mol.
10. 0.2 M.
DPP No. # 46
1. (B) 2. (B) 3. (B) 4. (B) 5. (D) 6. (D) 7. (B)
8. (D) 9. +1 10. 0.12 M. 11. 1.67 ml . 12. 22.5 g 13. 0.60 mol CO2

DPP No. # 47
1. (D) 2. (B) 3. (C) 4. (D) 5. (D) 6. (C) 7. (B)
8. (A) 9.* (AC) 10. 0.2 moles OH-. 11. 50%

ETOOS ACADEMY Pvt. Ltd


F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303 PAGE NO. # 3

Похожие интересы