ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT JEE: 2015 CRASH COURSE(C-3) DATE:

TOPIC:THERMODYNAMICS

SECTIONI (Multiple Choice Questions)

This section contains 05 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out which ONLY ONE is correct.

1. For evaporation of water at 900 C

(a) H < TS (b) H > TS (c) H = TS (d) Cant be co-related

1
2. For a reaction M 2 O ( s ) 2M ( s ) O 2 ( g ) ; H = =
30 kJ mol and S 0.07 kJ K mol at 1 atm.
2
Calculate upto which temperature the reaction would not be spontaneous
(a) T > 428.6 K (b) T > 300.8 K (c) T < 300.8 K (d) T < 428.6 K

3. A sample of gas is compressed from an initial volume of 2v 0 to v 0 using three different processes.
First: Using reversible isothermal
Second: Using reversible adiabatic
Third: Using irreversible adiabatic under a constant external pressure then
(a) Final temperature of gas will be highest at the end of third process
(b) Final temperature of gas will be highest at the end of second process.
(c) Enthalpy change of sample will be highest in isothermal process. (magnitude wise)
(d) Final pressure of gas will be highest at the end of second process

3
4. A monatomic gas C v = R is allowed to expand adiabatically and reversibly from initial valume
2
of 8L at 300 K to a volume of v 2 at 250 K. V2 is
(a) 10.5 L (b) 23 L (c) 8.5 L (d) 50.5 L

5. 0.1 mole H 2 O 2 is present in 1 L aqueous solution contain in a open container at 300 K. On complete
1
decomposition H 2 O 2 ( aq ) H 2 O ( ) + O 2 at constant temperature, how much work is done by
2
oxygen on surrounding
(a) 1.46 atm L (b) 1.23atm L (c) 2.46 atm L (d) 3.69 atm L

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 1

 SECTION-II (Multiple Choice Questions)
This section contains 3 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out which ONE OR MORE is/are correct.

6. For the process H 2 O ( )(1bar,373K ) H 2 O ( g )(1bar,373K, ) the correct set of thermodynamic

parameters is:
(a) G = 0 (b) S > 0 (c) H > 0 (d) G = ve

7. The incorrect figure representing isothermal and adiabatic expansions of an ideal gas from a
particular initial state is

(a) (b) (c) (d)

8. The P-T graph as given below was observed for a process on an ideal gas. Which of the following
statement is incorrect

(a) w =+ ve, H =+ ve (b) w = ve, H = ve

(c) w = ve, H =+ ve (d) w =+ ve, H = ve

SECTION III (Integer Answer Type)

This section contains 5 questions. The answer to each of the questions is a single
digit integer, ranging from 0 to 9. The correct digit below the question number in
the ORS is be bubbled.

9. If heat of dissociation of H3PO3 acid is 106.68 kJ mol using NaOH . If enthalpy of neutralization
of HCl by NaOH is 55.84 kJ mol . Calculate enthalpy change of H3PO3 into its ions?

10. In a constant calorimeter, 3.5g of a gas with molecular weight 28 was burnt in excess oxygen at
298.0 K. The temperature of the calorimeter was found to increases from 298.0 K to 298.45 K due to
the combustion process. Given that the heat capacity of the calorimeter is 2.5 kJ K , the numerical
value for the enthalpy of combustion of the gas in kJ mol will be?

11. A sample of an ideal gas is expanded 1m3 to 3m3 to 3m3 in a reversible process for which
= =
P KV 2
, with K 6 bar m 6 . What is work done by the gas? Given answer by dividing by 100.

12. AB, A2 and B2 are diatomic molecules. If the bond enthalpies of A2, AB and B2 are in the ratio
1:1:0.5 and enthalpy of formation of AB from A2 and B2 is 100 kJ mol . What is the bond enthalpy
of A2?

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 2

13. There is 1 mol liquid (molar volume 100 mL) in an adiabatic container, initial pressure being 1bar.
Now the pressure in steeply increased to 100 bar, and the volume decreased by 1mL under constant
pressure of 100 bar. Calculate internal energy change? (Given : 1 bar = 100000 pascal)

SECTION IV (Paragraph Type)

This section contains 2 multiple choice questions relating to 1 paragraph. Each
question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Paragraph for (Question Nos. 14 to 15)

Two moles of an ideal monoatomic gas is taken from state A to state B the ough a process AB in
which the pressure and the temperature of the gas vary such that PT = constant. The process can be
represented on a P T graph as follows:

Given: T1 = 300 K
Now, answer the following questions:
14. The magnitude of heat observed or evolved by the gas during process AB is: (R is gas constant)
(a) 2100 R (b) 1500 R (c) 900 R (d) Data insufficient

15. The magnitude of work done by the gas or on the gas during the process AB is: (R is constant)
(a) 2700 R (b) 900 R (c) 1500 R (d) 1200 R

SECTION - IV (Matrix Match Type)

This section 1 Question. Each question has four statements Given in Column - I and
four statements in Column II. Any given statement in Column I can have correct
matching with one or more statement (s) given in column II.

16.
Column I Column II
(A) q =0 (p) Adiabatic reversible process

(B) PV = constant (q) Adiabatic Ir-reversible process
(C) T =0 (r) Expansion of ideal gas in vacuum
(D) H =0 (s) Cyclic process

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 3

 ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI
TOPIC: THERMODYNAMICS
(ANSWER KEY) C-3

1 [a] 2 [d] 3 [a] 4 [a] 5 [b] 6 [abc] 7 [bcd]

8 [abd] 9 [5] 10 [9] 11 [52] 12 [400] 13 [10]

14 [a] 15 [d] 16 [ A p,q, r; B p;C r,s; D r,s ]

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 4