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Select form type to navigate to the emission calculator for the source type:

Company Name: Note: Don't forget to enable macros.


Insert Company and/or site name here.

Choose form type:

Blowdown and/or process vents Throughout this workbook:

Boilers and Heaters Input variables into the blue boxes.

Compressor engines Emissions will be in the green boxes.

Flares
Frac tanks
Glycol dehydrators To be notified of any updates to this workbook:

Loading
Piping component fugitive areas The Barnett Shale Special Inventory list server has been created to distribute
messages about the agencys special inventory efforts in the Barnett Shale area.
Separators If you haven't already done so, we recommend you subscribe to this list server
to receive any important updates concerning the inventory, including this
Condensate storage tanks emission calculator. To do so, you will need to create a profile with the
TCEQs distribution service, GovDelivery.com, so that you can add and
Crude oil storage Tanks manage your subscriptions. To create a profile or update your current
subscriptions, please visit: http://service.govdelivery.com/ service/user.html?
Produced water storage tanks code=TXTCEQ.

Turbines

Other:

Non-flare combustive device

Complete a form for each piece of equipment (listed above) that meets one of the
following criteria for 2009:
Emitted 1 ton or more of NOx,
Emitted 1 ton or more of volatile organic compounds (VOC), or
Emitted 0.1 tons per year or more of a hazardous air pollutant (HAP)

If individual pieces of equipment do not meet the requirements listed above, they
may be omitted from the inventory provided that the total emissions from all such
unreported sources are:
less than 5 tons of NOx,
less than 5 tons of VOC, and
less than 1 ton of aggregate HAPs

If the total emissions from the omitted pieces of equipment do not satisfy these
requirements, report each source starting with the piece of equipment with the
highest emissions until the total emissions of the remaining omitted sources
satisfy the above requirements.
VENTING EMISSION CALCULATION (for blowdowns, starter vents, gas operated controllers, etc): Back to Workbook Navigation Tab.

Barnett Shale Phase II Identification Information: Input variables into the blue boxes
Company Name: Insert Company and/or site name here. Emissions will be in the green boxes.
Blowdown #:
Company's Unique
Identification Number:

Molecular
Weight grams per
(grams/m 100 moles
mole % ole) of gas weight %
Gas Analysis: Nitrogen 28.01348 0 #DIV/0! VOC content of total gas sample (VAPOR)
CO2 44.0095 0 #DIV/0! VOC weight% = #DIV/0!
H2S 34.08188 0 #DIV/0! VOC weight fraction = #DIV/0!
methane (C1) 16.04246 0 #DIV/0! (VOC: total sample)
ethane (C2) 30.06904 0 #DIV/0!
propane (C3) 44.09562 0 #DIV/0! HAP content of gas sample
i-butane (C4) 58.1222 0 #DIV/0! Benzene weight% = #DIV/0!
n-butane (C4) 58.1222 0 #DIV/0! Toluene weight% = #DIV/0!
i-pentane (C5) 72.14878 0 #DIV/0! Ethylbenzene weight% = #DIV/0!
n-pentane (C5) 72.14878 0 #DIV/0! Xylene weight% = #DIV/0!
n-hexane (C6) 86.17 0 #DIV/0! n-hexane weight% = #DIV/0!
heptanes (C7+)* 100.2 0 #DIV/0!
octanes (C8+)* 114.23 0 #DIV/0!
nonanes (C9+)* 128.26 0 #DIV/0!
decanes (C10+)* 142.29 0 #DIV/0!
benzene 78.11 0 #DIV/0!
toluene 92.14 0 #DIV/0!
ethylbenzene 106.16 0 #DIV/0!
xylenes (M, P, O) 106.16 0 #DIV/0!
undecanes (C11+)* 156.31 0 #DIV/0!
TOTALS: 0.0000 0 #DIV/0!

* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value, or if Molecular Weight of Gas = 0 lb/lb-mole or grams/mole
MW or SG of total sample available on lab analysis, can adjust this value until MW or SG fields (to the right) match Specific Gravity of Gas = 0
the lab analysis.
1 lb-mole of gas = 379.48322 SCF
Enter Venting Volume per Event (SCF): (standard cubic feet) at STP (standard temperature (60F) and pressure (14.696
Enter number of events per year: psia))

tpy
Report Total VOC emissions
VOC emissions: #DIV/0! on Blowdown(s) tab.
benzene #DIV/0!
toluene #DIV/0! Report HAP emissions on
ethylbenzene #DIV/0! Blowdown(s) tab or HAP
speciation tab if the values are
greater than or equal to 0.1
xylene #DIV/0! tpy.
n-hexane (C6) #DIV/0!
Heater and Boiler Emission Calculations (fueled by natural gas)
Back to Workbook Navigation Tab.

Barnett Shale Phase II Identification Information: Input variables into the blue boxes
Company Name: Insert Company and/or site name here. Emissions will be in the green boxes.
Heater or Boiler #:
Company's Unique Identification
Number:

Heater/Boiler rating (MMBtu/hr):

Rating above is (select from list): pick from list


Operating hours/year:
Fuel Heat Value (Btu/SCF):

pollutant emission factor (lb/MMCF)* tpy


VOC 5.5 #DIV/0!
NOX 0 #DIV/0!

* Emission Factors from AP-42, Chapter 1, Tables 1.4-1 and 1.4-2.


Engine Emission Calculations (fueled by natural gas)
Back to Workbook Navigation
Tab.
Barnett Shale Phase II Identification Information:
Company Name: Insert Company and/or site name here. Input variables into the blue boxes

Engine #: Emissions will be in the green boxes.


Company's Unique
Identification Number:
Notes:
Horsepower: The TCEQ preference for emission factor sources:
1. Stack test data from the engine
Fuel consumption (Btu/hp-hr):
2. Manufacturer's specification sheet and control specification
Hours of operation per year: sheet (if control used)

Type of engine (select from 3. AP-42 emission factors


list): pick from list
(If no stack testing or manufacturer's emission factors are
available, the spreadsheet will automatically use appropriate AP-
Engine Load: pick from list 42 factors based on the type of engine and load.)

If present, enter the


If available, enter efficiency of any
stack test or control device
manufacturer's Appropriate (ex: catalytic Annual
emission factor AP-42 factor (From emission factor Uncontrolled Uncontrolled converter) Emissions
(g/hp-hr) AP-42 Section 3.2) used units lb/hr tpy (%) (tpy) Contaminant
VOC 0.0296 0.0296 lb/MMBtu 0.0000 0.0000 0.000 VOC
NOX 2.21 2.21 lb/MMBtu 0.0000 0.0000 0.000 NOx
Formaldehyde 0.0205 0.0205 lb/MMBtu 0.0000 0.0000 0.000 Formaldehyde*
* If formaldehyde emissions are greater than or equal to 0.1 tpy,
report the emission rate on the Phase II form.

If bold, value is greater than or equal to 0.1 ton and should be included on
the "HAPS >=0.1" Tab in the Barnett Shale Phase II workbook for this piece
of equipment.
If VOC factor used
above was a non-AP-
If VOC factor used 42 factor (stack test
above was from AP- or manufacturer), use
42, use this column this column to check
Hazardous Air Pollutant (HAP): to check for HAPs for HAPs % (AP-42 speciated/total)
1,1,2,2-Tetrachloroethane Choose Engine Type Choose Engine Type Choose Engine Type
1,1,2-Trichloroethane Choose Engine Type Choose Engine Type Choose Engine Type
1,2,4-Trimethylbenzene Choose Engine Type Choose Engine Type Choose Engine Type
1,2-Dichloropropane Choose Engine Type Choose Engine Type Choose Engine Type
1,3-Dichloropropene Choose Engine Type Choose Engine Type Choose Engine Type
2,2,4-trimethlypentane Choose Engine Type Choose Engine Type Choose Engine Type
Acenaphthylene Choose Engine Type Choose Engine Type Choose Engine Type
Acetaldehyde Choose Engine Type Choose Engine Type Choose Engine Type
Acrolein Choose Engine Type Choose Engine Type Choose Engine Type
Benzene Choose Engine Type Choose Engine Type Choose Engine Type
Biphenyl Choose Engine Type Choose Engine Type Choose Engine Type
Carbon Tetrachloride Choose Engine Type Choose Engine Type Choose Engine Type
Chloroform Choose Engine Type Choose Engine Type Choose Engine Type
Ethylbenzene Choose Engine Type Choose Engine Type Choose Engine Type
Ethylene Dibromide Choose Engine Type Choose Engine Type Choose Engine Type
Fluoranthene Choose Engine Type Choose Engine Type Choose Engine Type
Methanol Choose Engine Type Choose Engine Type Choose Engine Type
Methylene Chloride Choose Engine Type Choose Engine Type Choose Engine Type
n-Hexane Choose Engine Type Choose Engine Type Choose Engine Type
Naphthalene Choose Engine Type Choose Engine Type Choose Engine Type
Phenanthrene Choose Engine Type Choose Engine Type Choose Engine Type
Phenol Choose Engine Type Choose Engine Type Choose Engine Type
Pyrene Choose Engine Type Choose Engine Type Choose Engine Type
Styrene Choose Engine Type Choose Engine Type Choose Engine Type
Toluene Choose Engine Type Choose Engine Type Choose Engine Type
Vinyl Chloride Choose Engine Type Choose Engine Type Choose Engine Type
Xylene-u Choose Engine Type Choose Engine Type Choose Engine Type
Flare
Back to Workbook Navigation
Tab.
Barnett Shale Phase II Identification Information: Notes:
Company Name: Insert Company and/or site name here. Input variables into the blue boxes
Flare #: Emissions will be in the green boxes.
Company's Unique
Identification Number: Instructions are shaded.

General Information Emission Factors


Emission Factors from TCEQ Guidance (lb/MMBtu)
(1) What type of flare is
non-steam assisted flare with high Btu stream flared
this? Pick from list. Non-steam assisted, high Btu Steam assisted, high Btu
Emission Factors for Waste Gas Stream(s) (lb/MMBtu) NOx 0.138 NOx 0.0485
NOx 0.138 Non-steam assisted, low Btu Steam assisted, low Btu
NOx 0.0641 NOx 0.068

(2) Is there one or more


continuous pilot streams? Yes
Pick Yes or No. Follow Emission Factors from AP-42 Table 1.4-1
instructions below. and 1.4-2 (lb/MMscf) Emission Factors from AP-42 Table 1.4-3 (lb/MMscf)
Enter pilot stream information into the boxes in the column for
Stream No. 1 below. If there is more than one continous pilot
stream, please enter it as one combined stream. NOx 100 Total VOC 5.5
Emission Factors for Pilot Stream (lb/MMscf) benzene 2.10E-03
NOx 100 toluene 3.40E-03
ethylbenzene 0 none listed
xylene 0 none listed

(3) Is there an added fuel No


stream? Pick Yes or No.
Follow instructions below. n-hexane 1.8

Enter zeros into the boxes in the column for Stream No. 2 below.

Emission Factors for Added Fuel Stream (lb/MMBtu)


NOx 0

(4) VOC percent destruction


98
efficiency (%)

Stream Information

Stream Sent to Flare No. 1 2 3 4 5 6 7 8 9 10 11 12 Total for all


Streams
Enter Names of Each ex: glycol
Stream sent to the flare Added ex: glycol ex: amine unit flash ex: amine unit ex: truck
Here Pilot(s) fuel ex: oil tank ex: water tank unit vent unit vent tank flash tank loading

Annual Volumetric Flow


Rate of Stream (scf/yr) 0

Heat Value of Stream


(Btu/scf) #DIV/0!

Uncontrolled VOC and HAP ex: glycol Total for all


Added ex: glycol ex: amine ex: amine unit ex: truck Streams
Emissions for each of these Pilot(s) ex: oil tank ex: water tank unit flash 0
fuel unit vent unit vent flash tank loading
stream
Total VOC Annual Emissions tank
(tpy)
benzene Annual Emissions - - 0
(tpy)
toluene Annual Emissions - - 0
(tpy)
ethylbenzene Annual - - 0
Emissions (tpy) - - 0
xylene Annual
n-hexane Annual Emissions (tpy)
Emissions - - 0
(tpy)
other HAP (fill in name) - - 0
Annual
other Emissions
HAP (tpy)
(fill in name) - - 0
Annual Emissions (tpy) - - 0

Flare Total Emissions


Annual
Emissions
(tpy)
NOX 0.00
Total VOC 0.00 Report NOx and Total VOC on the "Flare(s)" tab in the Phase II workbook.
Benzene 0.00
Toluene 0.00
Ethylbenzene 0.00
Xylene(s) 0.00 Report Benzene, Ethylbenzene, Toluene, Xylene(s), and n-hexane and any other
n-hexane 0.00 HAPs on the Phase II workbook if they are 0.1 tpy on the "Flare(s)" tab.
other HAP 0.00
other HAP 0.00
Frac Storage Tank

Barnett Shale Phase II Identification Information:


Company Name: Insert Company and/or site name here.
Frac Tank#:

Company's Unique
Identification Number:

Tank emissions are made up of 3 different components, working, breathing and flash losses.

Using EPA TANKS 4.0 Software to calculate Working and Breathing losses

Working and Breathing Losses

EPA TANKS 4.0


This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html

Working Breathing

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com
Component Controlled Emissions [ton/yr]

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
224Trimethylp
Back to Workbook Navigation
Tab.
Notes:
Enter variables into blue boxes
Emissions will be in green boxes

ing and flash losses.

Flash losses Total Emissions


Valid Methods for Condensate (Use one of the
following accepted methods):
Direct Measurement of Emissions
Process Simulator Models
the gas/oil ratio (GOR) method

Flash losses

VOCs, C3+ VOCs, C3+ 0.0000


Benzene Benzene 0.0000
Toluene Toluene 0.0000
E benzene E benzene 0.0000
Xylenes Xylenes 0.0000
n-hexane n-C6 0.0000
2,2,4 - Trimethylpentane 2,2,4 - Trimethylpentane 0.0000
Any Additional HAP (if applicable): Any Additional HAP (if applicable):
0.0000
0.0000
0.0000
0.0000

Annual Emissions tons per year

VOCs, C3+ 0.0000


Benzene 0.0000
Toluene 0.0000
E benzene 0.0000
Xylenes 0.0000
n-C6 0.0000
2,2,4 - Trimethylpentane 0.0000
Report VOC emissions on
Frac Tank(s) Tab.

Report HAP emissions on


Frac Tank(s) tab or HAP
speciation tab if the values
are greater than or equal
to 0.1 tpy.

Report VOC emissions on


Frac Tank(s) Tab.

Report HAP emissions on


Frac Tank(s) tab or HAP
speciation tab if the values
are greater than or equal
to 0.1 tpy.
Glycol Dehydrator Emission Calculations

Company Name: Insert Company and/or site name here.


Still#:

Company's Unique Identification Number:

There are two options that are used most commonly to determine the emissions from a glycol dehydrator.
Please chose the option you prefer:
GRI-GLYCalc Software Program
Rich/Lean Analysis

GRI-GLYCalc Program
Run the software program making sure to using a wet gas analysis for your input. This analysis should include an extended ga

The total emissions for a glycol dehydrator should include both the "Controlled Regenerator Emissions" or "Uncontrolled Regen
present and if the flash tank is not 100% controlled with the recycled/recompression option). By reviewing the GRI-GLYCalc Ag
emissions.
Click to see example reports:
Controlled regenerator with flash tank
Uncontrolled regenerator with flash tank
Uncontrolled regenerator vent with a flash tank with recycle/recompression option

Uncontrolled/ Controlled Regenerator Emissions Flash Gas Emissions


Component tpy Component
Propane Propane
Isobutane Isobutane
n-butane n-butane
Isopentane Isopentane
n-pentane n-pentane
cyclopentane cyclopentane
n-hexane n-hexane
cyclohexane cyclohexane
other hexanes other hexanes
heptanes heptanes
methylcyclohexane methylcyclohexane
2,2,4 Trimethylpentane 2,2,4 Trimethylpentane
Benzene Benzene
Toluene Toluene
Ethylbenzene Ethylbenzene
Xylene(s) Xylene(s)
C8+ Heavies C8+ Heavies
Total VOC Total VOC

Rich/Lean Analysis
Using a laboratory analysis of enriched and lean glycol samples that includes benzene, toluene, ethylbenzene and xyl
following information.

Glycol recirculation rate (gal/min)


Annual hour of operation (hr)

Component Rich (mg/L) Lean (mg/L) tpy


Total VOC 0.00
n-hexane 0.00
2,2,4 Trimethylpentane 0.00
Benzene 0.00
Toluene 0.00
Ethylbenzene 0.00
Xylene(s) 0.00
Additional HAPs
0.00
0.00
0.00
0.00

Equation used in Rich/Lean Analysis:

(Crich - Clean) * Qrecirc * t * 3.785 L/gal * 60 min/hr * lb/453,600 mg * ton/2,000 lb = tpy

Where:
Crich = concentration of the contaminant in rich sample
Clean = concentration of the contaminant in lean sample
Qrecirc = glycol recirculation rate (gal/min)
t = annual hours of operation
Back to Workbook Navigation
Tab.
Notes:
Enter variables into blue boxes

Emissions will be in green boxes


Instructions for using this form.
ycol dehydrator.

nalysis should include an extended gas analysis that includes but not limited to BTEX.

or Emissions" or "Uncontrolled Regenerator Emissions" and the "Flash Gas Emissions" (if the flash tank is
n). By reviewing the GRI-GLYCalc Aggregate Calculations report you will be able to determine your total

ecompression option

sh Gas Emissions Total Glycol Still Emissions


tpy Component tpy
Total VOC 0
Benzene 0
Toluene 0
Ethylbenzene 0
Xylene(s) 0
2,2,4 Trimethylpentane 0
n-hexane 0
zene, toluene, ethylbenzene and xylene(s), complete the
ading Emission Calculations Back to Workbook
on LL = 12.46* SPM/T from AP-42, Chapter 5, Section 5.2-4 Navigation Tab.

e Phase II Identification Information: Notes:


Insert Company and/or site name here. Enter variables into blue boxes
Emissions will be in green boxes

Use these cells to convert data, completion is optional.


for your convenience (completion is optional)

T
Temperature in Enter Barrels of Gallons of liquid per
Rankine (R): Liquid per year year:
459.67 0

List additional HAPs if present and


Composition of Material Loaded percentages:

True Vapor Molecular Annual Loading Total VOC Percentage


(This should be 100% unless
Pressure (P) Weight (M) Temperature in Rate produced water is being
Saturation Factor (S) (See
(psia)
below table(lb/lb-mole)
for list of options) Rankine (R) (gallons/year) Control Efficiency (%)* See discussionloaded)
below before applying
% Benzene
an efficiency. % Ethylbenzene % Toluene % Xylene(s) % n-Hexane
0 100 ###
0 100 ###
0 100 ###
0 100 ###
0 100 ###
0 100 ###
0 100 ###
0 100 ###
0 100 ###
0 100 ###
0 100 ###
0 100 ###
0 100 ###
###

tpy
0.0000 Report VOC emissions on "Loading" Tab.
0.0000
0.0000
0.0000 Report Benzene, Ethylbenzene, Toluene, Xylene, and n-hexane on the Phase II
0.0000 calculator if they are greater than 0.1 tpy on the "Loading" tab.
0.0000

0.0000
0.0000 Report any Additional HAPs if they are greater than or equal to 0.1 tpy.
0.0000

Note: According to AP-42, 5.2-6, if a control is being claimed (such as from a VRU or flare), even though the control device may have a very high efficiency, not all the truck vapors actually get there (due to leaks). See
the following
Can assume for control
99.2% limitations:
of loading emissions get to control device if tanker truck passes the MACT-level annual leak test (not more than 1 inch water column pressure change in 5 minutes after pressurizing to 18 inches
water followed by pulling a vacuum of 6 inches water).
Can assume 98.7% of loading emissions get to control device if tanker truck passes the NSPS-level annual test (3 inches pressure change)
Otherwise, can only assume 70% of loading emissions reach the control device.
Fugitives Emission Calculations
Back to Workbook Navigation
Complete this form for each type of each stream type. Tab.

Barnett Shale Phase II Identification Information: Notes:


Company Name: Insert Company and/or site name here. Input variables into the blue boxes
Fugitive Area #: Emissions will be in the green boxes.
Company's Unique
Identification Number:

Gas Analysis:

Molecular grams per


Weight 100 moles
mole % (grams/mole) of gas weight %
Nitrogen 28.01348 0 #DIV/0! VOC content of hydrocarbon fraction only (VAPOR)
CO2 44.0095 0 #DIV/0! VOC weight% = #DIV/0!
H2S 34.08188 0 #DIV/0! VOC weight fraction = #DIV/0!
methane (C1) 16.04246 0 #DIV/0! (VOC:THC)
ethane (C2) 30.06904 0 #DIV/0!
propane (C3) 44.09562 0 #DIV/0! HAP content of gas sample
i-butane (C4) 58.1222 0 #DIV/0! Benzene weight% = #DIV/0!
n-butane (C4) 58.1222 0 #DIV/0! Toluene weight% = #DIV/0!
i-pentane (C5) 72.14878 0 #DIV/0! Ethylbenzene weight% = #DIV/0!
n-pentane (C5) 72.14878 0 #DIV/0! Xylene weight% = #DIV/0!
n-hexane (C6) 86.17 0 #DIV/0! n-hexane weight% = #DIV/0!
heptanes (C7+)* 100.2 0 #DIV/0!
octanes (C8+)* 114.23 0 #DIV/0!
nonanes (C9+)* 128.26 0 #DIV/0!
decanes (C10+)* 142.29 0 #DIV/0!
benzene 78.11 0 #DIV/0!
toluene 92.14 0 #DIV/0!
ethylbenzene 106.16 0 #DIV/0!
xylenes (M, P, O) 106.16 0 #DIV/0!
undecanes (C11+)* 156.31 0 #DIV/0!
TOTALS: 0.0000 0 #DIV/0!
* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value.

Liquids Analysis:

Molecular grams per


Weight 100 moles
mole % (grams/mole) of gas weight %
Nitrogen 28.01348 0 #DIV/0! VOC content of hydrocarbon fraction only (LIQUIDS)
CO2 44.0095 0 #DIV/0! VOC weight% = #DIV/0!
H2S 34.08188 0 #DIV/0! VOC weight fraction = #DIV/0!
methane (C1) 16.04246 0 #DIV/0!
ethane (C2) 30.06904 0 #DIV/0!
propane (C3) 44.09562 0 #DIV/0! HAP content of gas sample
i-butane (C4) 58.1222 0 #DIV/0! Benzene weight% = #DIV/0!
n-butane (C4) 58.1222 0 #DIV/0! Toluene weight% = #DIV/0!
i-pentane (C5) 72.14878 0 #DIV/0! Ethylbenzene weight% = #DIV/0!
n-pentane (C5) 72.14878 0 #DIV/0! Xylene weight% = #DIV/0!
n-hexane (C6) 86.17 0 #DIV/0! n-hexane weight% = #DIV/0!
heptanes (C7+)* 100.2 0 #DIV/0!
octanes (C8+)* 114.23 0 #DIV/0!
nonanes (C9+)* 128.26 0 #DIV/0!
decanes (C10+)* 142.29 0 #DIV/0!
benzene 78.11 0 #DIV/0!
toluene 92.14 0 #DIV/0!
ethylbenzene 106.16 0 #DIV/0!
xylenes (M, P, O) 106.16 0 #DIV/0!
undecanes (C11+)* 156.31 0 #DIV/0!
TOTALS: 0.0000 0 #DIV/0!
* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value.

Fugitives Emission Calculations


Back to Workbook Navigation Tab.
LDAR Program (Choose
from list) Please choose from the following:

Gas Gas
emission factor emission factor VOC Control
(kg/hr per (lb/hr of TOC per content* (wt Ethylbenz Efficiency
number component component)* component) lb/hr tpy %) Benzene Toluene ene Xylene n-hexane (%)
Valve 0.0045 0.00992 0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
Pump Seal 0.0024 0.00529 0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
Connector 0.0002 0.00044 0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
Flange 0.00039 0.00086 0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
Open-ended Line 0.002 0.00441 0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
Other 0.0088 0.01940 0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
Total: 0 0 Total:

Light Oil Light Oil


emission factor emission factor VOC Control
(kg/hr per (lb/hr of TOC per content* Ethylbenz Efficiency
number component component) component) lb/hr tpy (%) Benzene Toluene ene Xylene n-hexane (%)
Valve 0.0025 0.00551 0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
Pump Seal 0.013 0.02866 0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
Connector 0.00021 0.00046 0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
Flange 0.00011 0.00024 0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
Open-ended Line 0.0014 0.00309 0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
Other 0.0075 0.01653 0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
Total: 0 0 Total:
Heavy Oil Heavy Oil
emission factor emission factor VOC Control
(kg/hr per (lb/hr of TOC per content* Ethylbenz Efficiency
number component component) component) lb/hr tpy (%) Benzene Toluene ene Xylene n-hexane (%)
Valve 0.0000084 0.0000185 0 0 100.0000 0
Pumps** - 0.00113 0 0 100.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0
Connector 0.0000075 0.0000165 0 0 100.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0
Flange 0.00000039 0.0000009 0 0 100.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0
Open-ended Line 0.00014 0.0003086 0 0 100.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0
Other** - 0.0000683 0 0 100.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0
Total: 0 0 Total:
Water/Oil Water/Oil
emission factor emission factor VOC Control
(kg/hr per (lb/hr of TOC per content* Ethylbenz Efficiency
number component component) component) lb/hr tpy (%) Benzene Toluene ene Xylene n-hexane (%)
Valve 0.000098 0.0002161 0 0 100.0000 0
Pump Seal 0.000024 0.0000529 0 0 100.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0
Connector 0.00011 0.0002425 0 0 100.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0
Flange 0.0000029 0.0000064 0 0 100.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0
Open-ended Line 0.00025 0.0005512 0 0 100.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0
Other 0.014 0.0308649 0 0 100.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0
Total: 0 0 Total:

Annual Emission Totals


Contaminant tpy
Total VOC #DIV/0! Report Total VOC emissions on the "Fugitives" tab.
Benzene #DIV/0!
Toluene #DIV/0!
Report Benzene, Ethylbenzene, Toluene,
Ethylbenzene #DIV/0! Xylene, and n-hexane on the Phase II
Xylene(s) #DIV/0! calculator if they are greater than 0.1 tpy on
n-Hexane #DIV/0! the "Fugitive(s)" tab.

Emission factors are for oil and gas production facilities (not refineries), and come from the EPA's "Protocol for Equipment Leak Emission Estimates" November 1995, EPA 4531,
R-95-017, Table 2-4.

Emission factors that are not based on the EPA document are from the TCEQ "Air Permit Technical Guidance for Chemical Source Equipment
Leak Fugitives (Draft October 2000)

* For fugitive calculations, VOC content should be VOC content of total hydrocarbons, not of total sample.
VOC Benzene Toluene Ethylbenzene Xylene n-hexane

tpy tpy tpy tpy tpy tpy


#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

tpy tpy tpy tpy tpy tpy


#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

tpy tpy tpy tpy tpy tpy


0.000 0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000 0.000
0 0 0 0 0 0

tpy tpy tpy tpy tpy tpy


0.000 0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000 0.000
VENTED SEPARATOR EMISSION CALCULATION
Back to Workbook Navigation
For separators that vent to the atmosphere under normal operating conditions. This does not Tab.
include separators that vent to the atmosphere through a pressure relief valve only under upset
conditions.

Barnett Shale Phase II Identification Information: Input variables into the blue boxes
Company Name: Insert Company and/or site name here. Emissions will be in the green boxes.
Separators #:
Company's Unique
Identification Number:

Gas Analysis of separator vent gas:


Molecular
Weight grams per
(grams/m 100 moles
mole % ole) of gas weight %
Nitrogen 28.01348 0 #DIV/0! VOC content of total gas sample (VAPOR)
CO2 44.0095 0 #DIV/0! VOC weight% = #DIV/0!
H2S 34.08188 0 #DIV/0! VOC weight fraction = #DIV/0!
methane (C1) 16.04246 0 #DIV/0! (VOC: total sample)
ethane (C2) 30.06904 0 #DIV/0!
propane (C3) 44.09562 0 #DIV/0! HAP content of gas sample
i-butane (C4) 58.1222 0 #DIV/0! Benzene weight% = #DIV/0!
n-butane (C4) 58.1222 0 #DIV/0! Toluene weight% = #DIV/0!
i-pentane (C5) 72.14878 0 #DIV/0! Ethylbenzene weight% = #DIV/0!
n-pentane (C5) 72.14878 0 #DIV/0! Xylene weight% = #DIV/0!
n-hexane (C6) 86.17 0 #DIV/0! n-hexane weight% = #DIV/0!
heptanes (C7+)* 100.2 0 #DIV/0!
octanes (C8+)* 114.23 0 #DIV/0!
nonanes (C9+)* 128.26 0 #DIV/0!
decanes (C10+)* 142.29 0 #DIV/0!
benzene 78.11 0 #DIV/0!
toluene 92.14 0 #DIV/0!
ethylbenzene 106.16 0 #DIV/0!
xylenes (M, P, O) 106.16 0 #DIV/0!
undecanes (C11+)* 156.31 0 #DIV/0!
TOTALS: 0.0000 0 #DIV/0!

* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value. If Molecular Weight of Gas = 0 lb/lb-mole or grams/mole
MW or SG of total sample available on lab analysis, can adjust this value until MW or SG fields (to the right) match Specific Gravity of Gas = 0
the lab analysis.
1 lb-mole of gas = 379.48322 SCF
at STP (standard temperature (60F) and pressure
Enter Venting Volume (SCF): (standard cubic feet) (14.696 psia))

tpy

Report Total VOC emissions


VOC emissions: #DIV/0! on Separator(s) tab.
benzene #DIV/0!
toluene #DIV/0! Report HAP emissions on
ethylbenzene #DIV/0! Separator(s) tab or HAP
speciation tab if the values are
greater than or equal to 0.1
xylene #DIV/0! tpy.
n-hexane (C6) #DIV/0!
Condensate Storage Tank
Gas condensate is defined as a liquid hydrocarbon with an API gravity greater than 40 at 60F (and a specific gravity les

Barnett Shale Phase II Identification Information:


Company Name: Insert Company and/or site name here.
Condensate Tank#:
Company's Unique
Identification Number:

Tank emissions are made up of 3 different components, working, breathing and flash losses.

Using EPA TANKS 4.0 Software to calculate Working and Breathing losses

Working and Breathing Losses

EPA TANKS 4.0


This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html

Working Breathing

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com
Component Controlled Emissions [ton/yr]

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
224Trimethylp
Back to Workbook Navigation
at 60F (and a specific gravity less than 0.8252). Tab.
Notes:
Enter variables into blue boxes
Emissions will be in green boxes

ing and flash losses.

Flash losses Total Emissions


Valid Methods for Condensate (Use one of the following
accepted methods):
Direct Measurement of Emissions
Process Simulator Models
the gas/oil ratio (GOR) method

Flash losses

VOCs, C3+ VOCs, C3+


Benzene Benzene
Toluene Toluene
E benzene E benzene
Xylenes Xylenes
n-hexane n-C6
2,2,4 - Trimethylpentane 2,2,4 - Trimethylpentane
Any Additional HAP (if applicable): Any Additional HAP (if applicable):

Annual Emissions

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
ook Navigation
ab.

Report VOC emissions on


0.0000 Condensate Tank(s) Tab.
0.0000
0.0000
0.0000
0.0000 Report HAP emissions on
Condensate Tank(s) tab or
0.0000 HAP speciation tab if the
0.0000 values are greater than or
equal to 0.1 tpy.
HAP (if applicable):
0.0000
0.0000
0.0000
0.0000

tons per year


Report VOC emissions on
0.0000 Condensate Tank(s) Tab.
0.0000
0.0000
0.0000 Report HAP emissions on
0.0000 Condensate Tank(s) tab or
HAP speciation tab if the
0.0000 values are greater than or
0.0000 equal to 0.1 tpy.
Crude Oil Storage Tank
Crude oil is defined as heavy, low volatility oil approximated by a GOR less than 1,750 cubic feet per barrel and an A

Barnett Shale Phase II Identification Information:


Company Name: Insert Company and/or site name here.
Crude Oil Tank#:
Company's Unique Identification
Number:

Tank emissions are made up of 3 different components, working, breathing and flash losses.

Using EPA TANKS 4.0 Software to calculate Working and Breathing losses

Working and Breathing Losses

EPA TANKS 4.0


This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html

Working Breathing

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com
Component Controlled Emissions [ton/yr]

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
224Trimethylp
ubic feet per barrel and an API gravity less than 40. Back to Workbook Navigation
Tab.

Notes:
Enter variables into blue boxes
Emissions will be in green boxes

d flash losses.

Flash losses Total Emissions


Valid Methods for Crude Oil (Use one of the following
accepted methods):
Direct Measurement of Emissions
Process Simulator Models
Vasquez-Beggs correlation
Rollins, McCain, and Creeger correlations
the gas/oil ratio (GOR) method

Flash losses

VOCs, C3+ VOCs, C3+


Benzene Benzene
Toluene Toluene
E benzene E benzene
Xylenes Xylenes
n-hexane n-C6
2,2,4 - Trimethylpentane 2,2,4 - Trimethylpentane
Any Additional HAP (if applicable): Any Additional HAP (if applicable):

Annual Emissions

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
ck to Workbook Navigation
Tab.

Report VOC emissions on Crude


0.0000 Oil Tank(s) Tab.
0.0000
0.0000
0.0000
0.0000
0.0000 Report HAP emissions on Crude
0.0000 Oil Tank(s) tab or HAP speciation
tab if the values are greater than
HAP (if applicable): or equal to 0.1 tpy.
0.0000
0.0000
0.0000
0.0000

tons per year


Report VOC emissions on Crude
0.0000 Oil Tank(s) Tab.
0.0000
0.0000
Report HAP emissions on Crude
0.0000 Oil Tank(s) tab or HAP speciation
0.0000 tab if the values are greater than
or equal to 0.1 tpy.
Report HAP emissions on Crude
Oil Tank(s) tab or HAP speciation
tab if the values are greater than
or equal to 0.1 tpy.
0.0000
0.0000
Produced Water Storage Tank

Barnett Shale Phase II Identification Information:


Company Name: Insert Company and/or site name here.
Produced Water Tank#:
Company's Unique Identification Number:

Tank emissions are made up of 3 different components, working, breathing and flash losses.

Using EPA TANKS 4.0 Software to calculate Working and Breathing losses
Working and Breathing Losses
EPA TANKS 4.0*
This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html

Working Breathing

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

*It is possible to create a mixture in the EPA TANKS program similar to the composition of the produced
water stored in the tanks (e.g., a mixture of 99% water and 1% condensate) to determine the emissions.

Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com
Component Controlled Emissions [ton/yr]

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
224Trimethylp
Back to Workbook Navigation
Tab.

Notes:
Enter variables into blue boxes
Emissions will be in green boxes

ng and flash losses.

Flash losses Total Emissions


Direct Measurement of Emissions
Process Simulator Models
the gas/oil ratio (GOR) method
Vasquez-Beggs correlation
Flash losses

VOCs, C3+ VOCs, C3+


Benzene Benzene
Toluene Toluene
E benzene E benzene
Xylenes Xylenes
n-hexane n-C6
2,2,4 - Trimethylpentane 2,2,4 - Trimethylpentane
Any Additional HAP (if applicable): Any Additional HAP (if applicable):

Annual Emissions

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
k Navigation

Report VOC emissions on


Produced Water Tank(s)
0.0000 Tab.
0.0000
0.0000
0.0000
0.0000
0.0000 Report HAP emissions on
Produced Water Tank(s)
0.0000 tab or HAP speciation tab if
HAP (if applicable): the values are greater than
or equal to 0.1 tpy.
0.0000
0.0000
0.0000
0.0000

tons per year


Report VOC emissions on
Produced Water Tank(s)
0.0000 Tab.
0.0000
0.0000
0.0000 Report HAP emissions on
0.0000 Produced Water Tank(s)
tab or HAP speciation tab if
0.0000 the values are greater than
0.0000 or equal to 0.1 tpy.
Turbine Emission Calculations (fueled by natural gas)
Back to Workbook Navigation Tab.

Barnett Shale Phase II Identification Information: Input variables into the blue boxes
Company Name: Insert Company and/or site name here. Emissions will be in the green boxes.
Turbine #:
Company's Unique Identification
Number:

Turbine rating (MMBtu/hr):


Operating hours/year:

pollutant emission factor (lb/MMBtu)* tpy


VOC 0.0021 0.000
NOX 0.32 0.000

* Emission Factors from AP-42, Chapter 3, Tables 3.1-1 and 3.1-2a.


Non-Flare Combustive Devices
Back to Workbook Navigation
Tab.

Barnett Shale Phase II Identification Information: Notes:

Company Name: Insert Company and/or site name here. Input variables into the blue boxes
Other #: Emissions will be in the green boxes.
Company's Unique
Identification Number: Instructions are shaded.

General Information Emission Factors

(1) What kind of device is


this? Enter a short
description of the device Emission Factors from AP-42 Table 1.4-1 and 1.4-2 Emission Factors from AP-42 Table 1.4-3
type. (lb/MMscf) (lb/MMscf)

Emission Factors for Waste Gas Stream(s) (lb/MMscf) NOx 100 VOC 5.5
NOx 100 Other Vendor Factor benzene 2.10E-03
toluene 3.40E-03

(2) Is there one or more


continuous pilot streams? Yes
Pick Yes or No. Follow
instructions below. ethylbenzene 0 none listed
Enter pilot stream information into the boxes in the column for
Steam No. 1 below. If there is more than one continous pilot
stream, please enter it as one combined stream. xylene 0 none listed
Emission Factors for Pilot Stream (lb/MMscf) n-hexane 1.8
NOx 100

(3) Is there an added fuel Yes


stream? Pick Yes or No.
Follow instructions below.
Enter added fuel stream information into the boxes in the
column for Steam No. 2 below.
Emission Factors for Added Fuel Stream (lb/MMscf)
NOx 100

(4) VOC percent destruction


98
efficiency (%)

Stream Information

Stream Sent to Flare No. 1 2 3 4 5 6 7 8 9 10 11 12 Total for all


Streams
Enter Names of Each
Stream sent to the flare Added ex: glycol ex: amine ex: glycol unit ex: amine unit flash ex: truck
Here Pilot(s) fuel ex: oil tank ex: water tank unit vent unit vent flash tank tank loading

Volumetric Flow Rate of


Stream (scf/yr) 0
Heat Value of Stream - from
program results or gas
analysis (Btu/scf) 0

Uncontrolled VOC and HAP Total for all


Added ex: glycol ex: amine ex: glycol unit ex: amine unit flash ex: truck Streams
Emissions for each of these Pilot(s) ex: oil tank ex: water tank
fuel unit vent unit vent flash tank tank loading
stream
Total VOC Annual Emissions
(tpy)
benzene Annual Emissions - - 0
(tpy)
toluene Annual Emissions - - 0
(tpy)
ethylbenzene Annual - - 0
Emissions (tpy) - - 0
xylene Annual
n-hexane Annual Emissions (tpy)
Emissions - - 0
(tpy)
other HAP (fill in name) - - 0
Annual
other Emissions
HAP (tpy)
(fill in name) - - 0
Annual Emissions (tpy) - - 0

Other Combustion Device


Total Emissions
Annual
Emissions
(tpy)
NOX 0.00
Total VOC 0.00 Report NOx and Total VOC on the "Other Source(s)" tab in the Phase II workbook.
benzene 0.00
toluene 0.00
ethylbenzene 0.00
xylene 0.00 Report Benzene, Ethylbenzene, Toluene, Xylene(s), and n-hexane and any other HAPs on
n-hexane 0.00 the Phase II workbook if they are 0.1 tpy on the "Other Source(s)" tab.
other HAP 0.00
other HAP 0.00
Flash Emission Calculation - Vasquez-Beggs Solution Gas/Oil Ratio Correlation Method Back to Crude Oil Storage
(For Estimating VOC Flashing Emissions, Using Stock Tank Gas-Oil Ratios For Crude Oil Facilities) Tank Tab.

Back to Workbook Navigation


Barnett Shale Phase II Identification Information: Notes: Tab.
Company Name: Insert Company and/or site name here. Enter variables into blue boxes
Tank#: Emissions will be in green boxes

Company's Unique
Identification
Number:
Within Valid
INPUTS: CONSTRAINTS: Range?
Stock Tank API Gravity API 16 >API> 40 API No
Separator Pressure (psig) P 50 > P+Patm > 5250 (psia) No
Separator Temperature (F) Ti 70 > Ti > 295 (F) No
Separator Gas Gravity at Initial Condition SGi 0.56 > SGi > 1.18 (MW/28.97) No
Stock Tank Barrels of Oil per day (BOPD) Q None >Q > None (BOPD) Yes
Stock Tank Gas Molecular Weight MW 18 > MW > 125 (lb/lb-mole) No
Fraction VOC (C3+) of Stock Tank Gas VOC 0.5 > VOC > 1.00 fraction No
Atmospheric Pressure (psia) Patm None > Patm > None (psia) Yes

OUTPUTS:
SGx = Dissolved gas gravity at 100 psig = SGi [1.0+0.00005912*API*Ti*Log(Pi/114.7)]

SGx = 0.00

Rs = (C1 * SGx * Pi^C2) exp ((C3 * API) / (Ti + 460))

Where: Rs Gas/Oil Ratio of liquid at pressure of interest


SGx Dissolved gas gravity at 100 psig
Pi Pressure of initial condition (psia)
API API Gravity of liquid hydrocarbon at final condition
Ti Temperature of initial condition (F)

Constants
API Gravity
APTI < 30 >= 30 Given API
C1 0.0362 0.0178 0.0362
C2 1.0937 1.187 1.0937
C3 25.724 23.931 25.724
CONSTRAINTS:
Rs = 0.00 scf/bbl for P + Patm = 0 20 > Rs > 2070 (scf/STB)

THC = Rs * Q * MW * 1/385 scf/lb-mole * 365 D/Yr * 1 ton/2000 lbs

THC Total Hydrocarbon (tons/year)


Rs Solution Gas/Oil Ratio (scf/STB)
Q Oil Production Rate (bbl/day)
MW Molecular Weight of Stock Tank Gas (lb/lb-mole)
385 Volume of 1 lb-mole of gas at 14.7 psia and 68 F (WAQS&R Std Cond)

THC = 0.000 TPY

VOC = THC * Frac. of C3+ in the Stock Tank Vapor

VOC* = 0.00 TPY from "FLASHING" of oil from separator to tank press
*Before reporting these emissions, make sure to review the Within Valid Range section to verify this method is valid for your conditions.
GOR Method for Estimating Flash Emissions

Barnett Shale Phase II Identification Information:


Company Name: Insert Company and/or site name here.
Tank#:
Company's Unique
Identification Number:
Enter variables into blue boxes
Emissions will be in green boxes

Gas Oil Ratio: in standard cubic feet of flash gas per barrel (SCF/bbl) of oil/condensate produced
Barrels of Oil or Condensate per day:

This information is based on an analysis submitted by the applicant. Flash Gas MW =

Flash Gas Speciation:

molecular weight grams per 100


mole % (grams/mole) moles of gas weight % Total gas emitted:
Nitrogen 28.01348 0 #DIV/0! tpy:
CO2 44.0095 0 #DIV/0!
H2S 34.08188 0 #DIV/0!
methane (C1) 16.04246 0 #DIV/0! VOC wt% =
ethane (C2) 30.06904 0 #DIV/0! Benzene weight% =
propane (C3) 44.09562 0 #DIV/0! Toluene weight% =
i-butane (C4) 58.1222 0 #DIV/0! Ethylbenzene weight% =
n-butane (C4) 58.1222 0 #DIV/0! Xylene weight% =
i-pentane (C5) 72.14878 0 #DIV/0! n-hexane weight% =
n-pentane (C5) 72.14878 0 #DIV/0!
hexanes (C6) 86.18 0 #DIV/0!
heptanes (C7+)* 100 0 #DIV/0!
octane (C8+)* 114.23 0 #DIV/0!
nonane (C9+)* 128.26 0 #DIV/0!
decane (C10+)* 142.29 0 #DIV/0! Contaminant TPY
benzene 78.11 0 #DIV/0! Total VOC #DIV/0!
toluene 92.14 0 #DIV/0! benzene #DIV/0!
ethylbenzene 106.16 0 #DIV/0! toluene #DIV/0!
xylenes (M, P, O) 106.16 0 #DIV/0! ethylbenzene #DIV/0!
undecanes (C11+)* 156.31 0 #DIV/0! xylene #DIV/0!
TOTALS: 0.0000 0 #DIV/0! n-hexane (C6) #DIV/0!

* If MW of heptanes plus is given, you can change the value in the table above.
* If the MW of the total sample is given, you can adjust the MW of heptanes+ until the "Flash Gas MW" value above equals the value on the lab report.
Back to Workbook Navigation
Tab.

es into blue boxes


ll be in green boxes

ate produced

Total gas emitted:


0

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Report Total VOC emissions on the


appropriate tank tab.

Report HAP emissions on the


appropriate tank tab or HAP
speciation tab if the values are
greater than or equal to 0.1 tpy.
Report HAP emissions on the
appropriate tank tab or HAP
speciation tab if the values are
greater than or equal to 0.1 tpy.
Example First page of a GRI-GLYCalc Report:

Controlled Regenerator with Flash Tank


Controlled Regenerator Emissions section example:

Report these emissions as


the uncontrolled/controlled
regenerator emissions

Total VOC is 1.2836 tpy for


this example for the
uncontrolled /controlled
regenerator emissions.
Flash Gas Emissions section example:

Report these emissions as


the flash tank emissions.

Total VOC is 0.0168 tpy for


the flash tank emissions for
this example.

Uncontrolled Regenerator with Flash Tank


Uncontrolled Regenerator Emissions section example:
Report these emissions as
the "uncontrolled/controlled
regenerator emissions".

Total VOC is 2.1251 tpy for


this example for the
uncontrolled /controlled
regenerator emissions.
Flash Gas Emissions section example:

Report these emissions as


the flash tank emissions.

Total VOC is 0.0168 tpy for


the flash tank emissions for
this example.

Uncontrolled Regenerator with Flash Tank with recycle/recompression option


Uncontrolled Regenerator Emissions section example:
Report these emissions as
the "uncontrolled/controlled
regenerator emissions".

Total VOC is 2.1251 tpy for


this example for the
uncontrolled /controlled
regenerator emissions.
Flash Gas Emissions section example:

No emissions to report for flash


tank that is
recycled/recompressed. You
may leave this section blank or
enter zeros.
Back to Glycol Dehydrator Tab.

Back to Glycol Dehydrator Tab.


Back to Glycol Dehydrator Tab.

Back to Glycol Dehydrator Tab.


Back to Glycol Dehydrator Tab.
E&P Tank Example
Back to Condensate Tanks Tab.
Look for the "Calculation Results" Section of
the E&P Tank printout for emissions data.
Back to Crude Tanks Tab.

Back to Produced Water Tanks


Tab.
From the "Controlled [ton/yr]" column, read
the VOCs, C3+ emissions. This is your
Total VOC emissions. (For this example Back to Frac Tanks Tab.
74.897 tpy)

Report the Benzene through 2,2,4 Trimethylpentane


emissions.
IC Engines List of Types
2 Stroke Lean
4 Stroke Lean
4 Stroke Rich

2 Stroke Lean 4 Stroke Lean 4 Stroke Rich


Nox (90-105% Load) 3.17 4.08 2.21
Nox (<90% Load) 1.94 0.847 2.27
CO (90-105 Load) 0.386 0.317 3.72
CO (<90% Load) 0.353 0.557 3.51
SO2 0.000588 0.000588 0.000588

VOC total 0.12 0.118 0.0296


PM total 0.04831 0.009987 0.01941
For Error Finding Only:
TOC 1.64 1.47 0.358
PM filterable 0.0384 0.0000771 0.0095
PM condensable 0.00991 0.00991 0.00991

VOC Speciation C or better 2 Stroke Lean 4 Stroke Lean 4 Stroke Rich BOILERS turbines
1,1,2,2-Tetrachloroethane 6.63E-05 2.53E-05
1,1,2-Trichloroethane 5.27E-05
1,1-Dichoroethane 3.91E-05
1,2,4-Trimethylbenzene 1.11E-04 1.43E-05
1,2-Dichloropropane 4.46E-05
1,3-Dichloropropene 4.38E-05
2-Methylnapththalene 2.14E-05 3.32E-05
Acenaphthene 1.33E-06 1.25E-06
2,2,4-trimethlypentane 8.46E-04 2.50E-04
Acenaphthylene 3.17E-06 5.53E-06
Acetaldehyde 7.76E-03 8.36E-03 2.79E-03 4.00E-05
Acrolein 7.78E-03 5.14E-03 2.63E-03 6.40E-06
Anthracene 7.18E-07
Benz(a)anthracene 3.36E-07
Benzene 1.94E-03 4.40E-04 1.58E-03 2.10E-03 1.20E-05
Biphenyl 3.95E-06
Butane 4.75E-03
Butyr/isobutyaldehyde 4.37E-04 1.01E-04
Carbon Tetrachloride 6.07E-05
Chlorobenze 4.44E-05
Chloroform 4.71E-05
Chrysene 6.72E-07 6.93E-07
Cyclohexane 3.08E-04
cyclopentane 9.47E-05 2.27E-04
Ethylbenzene 1.08E-04 3.97E-05 3.20E-05
Ethylene Dibromide 7.34E-05
Fluoranthene 3.61E-07 1.11E-06
Fluorene 1.37E-06 5.67E-06
Formaldehyde 5.52E-02 5.28E-02 2.05E-02 7.50E-02 7.10E-04
Isobutane 3.75E-03
Methanol 2.48E-03 2.50E-03
Methycyclohexane 3.38E-04 1.23E-03
Methylene Chloride 1.47E-04 2.00E-05 4.12E-05
n-Hexane 4.45E-04 1.11E-03
n-Nonane 3.08E-05 1.10E-04
n-Octane 7.44E-05 3.51E-04
n-Pentane 1.53E-03 2.60E-03
Naphthalene 9.63E-05 7.44E-05 1.30E-06
Phenanthrene 3.53E-06
Phenol 4.21E-05
Propane 2.87E-02 4.19E-02
Pyrene 5.84E-07 1.36E-06
Styrene 5.48E-05
Toluene 9.63E-04 4.08E-04 5.58E-04 3.40E-03
Vinyl Chloride 2.47E-05 1.49E-05
Xylene-u 2.68E-04 1.84E-04 1.95E-04
BOILER
NOX CO
Large Wall Fired (>100 MMBtu/hr) - 100 84
Large Wall Fired (>100 MMBtu/hr) - 140 84
Large Wall Fired (>100 MMBtu/hr) - 190 84
Large Wall Fired (>100 MMBtu/hr) - 280 84
Residential Furnaces - (< 0.3) Uncon 94 40
Small Boilers (<100 MMBtu/hr) - Co 50 84
Small Boilers (<100 MMBtu/hr) - Con 32 84
Small Boilers (<100 MMBtu/hr) - Unc 100 84
Tangential Fired Boilers (All) - Low 76 98
Tangential Fired Boilers (All) Uncon 170 24

Digester Gas - Uncontrolled

Distillate Oil - Uncontrolled


Distillate Oil - Water-Steam Injection
Landfill Gas - Uncontrolled
Natural Gas - Lean Premix
Natural Gas - Uncontrolled
Natural Gas - Water-Steam Injection

TURBINES Digester Gas - Uncontrolled Distillate Oil - Uncontrolled


Nox 1.60E-01 8.80E-01
CO 1.70E-02 3.30E-03
SO2 6.50E-03 3.30E-02
VOC total 5.80E-03 4.10E-04
PM total 1.20E-02 1.20E-02
For Error Finding Only:
PM filterable 1.20E-02
PM condensable
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichoroethane
1,2,4-Trimethylbenzene
1,2-Dichloropropane
1,3-Dichloropropene
2-Methylnapththalene
Acenaphthene
2,2,4-trimethlypentane
Acenaphthylene
Acetaldehyde
Acrolein
Anthracene
Benz(a)anthracene
Benzene 5.50E-05
Biphenyl
Butane
Butyr/isobutyaldehyde
Carbon Tetrachloride
Chlorobenze
Chloroform
Chrysene
Cyclohexane
cyclopentane
Ethylbenzene
Ethylene Dibromide
Fluoranthene
Fluorene
Formaldehyde 2.80E-04
Isobutane
Methanol
Methylcyclohexane
Methylene Chloride
n-Hexane
n-Nonane
n-Octane
n-Pentane
Naphthalene 3.50E-05
Phenanthrene
Phenol
Propane
Pyrene
Styrene
Toluene
Vinyl Chloride
Xylene-u
Distillate Oil - Water-Steam Injec Landfill Gas - Uncontrolled
2.40E-01 1.40E-01
7.60E-02 4.40E-01
4.50E-02
4.10E-04 1.30E-02
1.20E-02 2.30E-02

1.20E-02

5.50E-05 2.10E-05
2.80E-04

3.50E-05

1.10E-04

3.10E-05
Natural Gas - Lean Premix Natural Gas - Uncontrolled Natural Gas - Water-Steam Injection
9.90E-02 3.20E-01 1.30E-01
1.50E-02 8.20E-02 3.00E-02
3.40E-03
2.10E-03 2.10E-03 2.10E-03
6.60E-03 6.60E-03 6.60E-03

1.90E-03 1.90E-03 1.90E-03

4.00E-05 4.00E-05 4.00E-05


6.40E-06 6.40E-06 6.40E-06

1.20E-05 1.20E-05 1.20E-05


3.20E-05 3.20E-05 3.20E-05

7.10E-04 7.10E-04 7.10E-04

1.30E-06 1.30E-06 1.30E-06

1.30E-04 1.30E-04 1.30E-04

6.40E-05 6.40E-05 6.40E-05

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