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V1 M1 V M2
Dissolve the tablets 2
N1 N2
Crush the tablets in a mortar and pestle.
Add some conc.sulphuric acid to help it 10 M1 8.4 0.02
dissolve. 5 1
Transfer the mixture to a beaker. 8.4 0.02 5
M1
Slowly add the mixture to a beaker of 10
deionised water. M1 0.084 moles per litre
Rinse the pestle and mortar several times
and add to beaker.
grams per litre = 0.084(152)g/L
Transfer to volumetric flask
12.77
Transfer the mixture from the beaker to = 12.77g = g in 250ml
the volumetric flask using a funnel. 4
Rinse the beaker several times and add to = 3.19g in 8 tablets.
the flask. = 0.399g in 1 tablet
Top up to 250 ml with deionised water in = 399mg per tablet
the usual manner.
As the iodine is used up the red fades to Prepare the conical flask
yellow. Place 10ml of the bleach solution into
Starch is introduced and the titration is conical flask.
concluded when the black colour disappears. Add 10ml dilute sulphuric acid to the
Overall, flask.
2KMnO4 = 5I2 = 10NaS2O3 Add 10ml 0.5M KI to the flask.
Carry out the calculations as if 1KMnO4 Red iodine is released.
directly with 5 NaS2O3.
Titrate with sodium thiosulphate solution
Results Titrate in the usual manner, swirling,
Volume KMnO4 =10ml rinsing regularly, add solution drop by
Molarity KMnO4= 0.02M drop.
Factor for KMnO4 = 1 When red fades to pale yellow add 4
Volume of Thiosulphate = 9.95ml drops of starch.
Molarity of thiosulphate = ? Resume titrating until black colour
Factor for thiosulphate = 5 clears.
Results
molarity thiosulphate = 0.1M
volume thiosulphate = 11.2ml
factor thiosulphate = 2
molarity hypochlorite = ?
volume hypochlorite = 10ml
factor hypochlorite = 1
Calculations
V1 M1 V2 M 2 10 M1 11.2 0.1
=
n1 n2 1 2
11.2 0.1
M1 0.056moles per l
2 10
= 0.056 74.5 = 4.175g per l
41.75g per l for the real soln.
= 4.175g per 100ml = 4.175% (w/v)