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Abstract
This paper proposes an approach to determine the influence of non-ideal detonation characteristics
related to the charge diameter, explosive type and confinement conditions on the available shock
energy of ANFO and a representative chemically-sensitised (gassed) emulsion. The proposed
degrees of non-ideality of the two different blasting agents are indicated by the Gurney ratios,
determined from existing cylinder expansion testing data. The influence of the non-ideal detonation
properties on blast design and performance are also compared using a series of theoretical, equal
powder factor open pit blasting patterns with hole diameters ranging from 102 mm to 270mm.
The non-ideal shock energy factor (NSEF), which is the available shock energy per tonne
of blasted material (MJ/t), is used to compare the different blasting patterns as charged with either
ANFO or the gassed emulsion of equal charge density (0.85 g/cm3). The intended purpose of this
investigation is to provide explosive users with an approach to compare different explosive types
or charge diameters in the absence of dedicated non-ideal detonation modelling, which is generally
not available to explosives users.
The results of the comparisons suggest that at low charge densities, the example gassed emulsion
displays a higher velocity of detonation (VOD) than ANFO in smaller charge diameters but
similar degrees of non-ideality (based on proposed Gurney ratios). The results also suggest that
the confined, non-ideal gassed emulsion VOD at hole diameters greater than 270 mm can be less
than ANFO due to the low density effects on the emulsion matrix. The differences in nonideal
detonation properties and Gurney ratios between the ANFO and gassed emulsion resulted
in gassed emulsion NSEF values ranging from 15 per cent lower to 65 per cent higher than ANFO
for equal powder-factor patterns in blasthole diameters from 102 mm to 270 mm.
introduction
The management of successful blasting operations requires comparing different explosive products over a large range in
some level of understanding of the influence of explosive blasthole diameters. This loss of reliability is due to variability
distribution on the resulting fragmentation. The parameter in the non-ideal detonation characteristics of commercial
most widely used in the field of explosives engineering and explosives as a function of charge diameter, type of explosive,
drill and blast design for describing explosive concentration explosive density and confinement.
is powder factor. The term powder factor refers to the ratio The introduction of chemically-sensitised bulk emulsion
between the mass of explosive within a blast and the volume explosives, capable of delivery at densities close to or equal
or mass of blasted material. Some fundamental issues exist to ANFO, has resulted in increased use in some blasting
when using powder factor as a blast design parameter, applications (eg quarry blasting, buffer blasting in open pits and
especially when comparing different explosive products underground production blasting). The powder factor design
or blasthole diameters. These issues include the lack of scale approach would suggest that the two different explosives of
sensitivity, lack of a standardised unit across different blasting the same density would be interchangeable without an impact
applications, no consideration of non-ideal explosive effects, on the resulting breakage. Differences between the degrees of
no explicit integration of rock properties or confinement non-ideality of ANFO and emulsion would suggest otherwise.
conditions and no consideration of explosive type or explosive A more meaningful design parameter that takes into account
energy release characteristics. The use of powder factor for the influence of the explosive type, blasthole diameter and
comparing expected fragmentation for identical explosive degree of confinement (rock properties) on the available
products over a small range in blasthole diameters can energy for fragmentation and muck pile displacement should
be relatively reliable, but this reliability is reduced when therefore be considered. The energy-based blast design criteria
1. Senior Research Fellow, Western Australian School of Mines, Department of Mining Engineering and Surveying, Locked Bag 30, Kalgoorlie WA 6430. Email: k.fleetwood@curtin.edu.au
2. Professor of Mining Geomechanics, Western Australian School of Mines, Department of Mining Engineering and Surveying, Locked Bag 30, Kalgoorlie WA 6430. Email: villaee@wasm.curtin.edu.au
proposed in this paper will concentrate on the influence is a function of the degree of non-ideality; less ideal explosives
of these factors on the non-ideal shock energy factor (NSEF), such as ANFO exhibit a higher degree of diameter sensitivity,
expressed in megajoules of useful work per tonne of blasted whereas more ideal emulsion explosives are less sensitive
ore, for equal powder factor blasting patterns charged with to diameter effects. This increase in ideality of emulsion
ANFO or a gassed emulsion of equal density (0.85 g/cm3). explosives is due to increased oxidiser/fuel intimacy and
smaller oxidiser particle size.
Explosive Energy as a Blast Design The same relationship between charge diameter and VOD
Approach can also be observed between explosive density and VOD.
In general, higher explosive densities yield higher VODs.
Downstream ore crushing, grinding and milling typically track
The relationship between in-hole density and confined
energy consumption per unit weight of processed material. It
VOD for gassed emulsion explosives over a range of charge
therefore becomes logical to adopt an energybased design
diameters is not well defined for explosives users, though.
criteria for blasting that can be compared with the other
The sensitivity of VOD to gassed emulsion density becomes
energy consumptions. Energy consumption from blasting,
an important aspect when comparing the performance
when compared with crushing and milling, represents
of ANFO and gassed emulsions of similar densities in open
a small, but not insignificant percentage. Effective
pit and underground blasting applications.
breakage during blasting therefore is important in reducing
downstream energy consumption. Arbitrary descriptors
of blast performance such as powder factor cannot be Chemically-sensitised (gassed) emulsions
standardised with the downstream processes. Field data on the measured velocities of detonation
A number of past researchers have proposed the inclusion of gassed emulsions as functions of gassed density, AN prill
of explosive energy as a method of designing blasts or content (for doped emulsions) and borehole diameter are
describing explosive performance (eg Mohanty, 1981; limited in the published literature. The relationship between
Ducey, 2000; Rustan, 2010). Research into the influence borehole diameter, density and VOD for gassed emulsions
of non-ideal detonation and confinement on the VOD of has therefore been assumed to be similar in shape to that of
commercial explosive formulations (eg Sun, Later and Chen, micro-balloon sensitised emulsions. The assumed similarity is
2001; Esen, 2004) has provided useful information on the based on data published by Araos (2002) and Ravi-Shankar,
detonation characteristics of ANFO and emulsion explosives Kumar and Krishna-Mohan (1996). Araos (2002) published
in medium to large charge diameters. Additionally, research data on the influence of the emulsion sensitiser on the lightly-
into the available work energy or Gurney energy of more confined VODs at identical densities. These tests revealed an
substantial charge diameters (up to 100 mm) has confirmed approximate ten per cent greater VOD for gassed emulsion
the differences in the degrees of non-ideality of ANFO and when compared with the glass micro-balloon sensitised
emulsion explosives (Nyberg et al, 2003; Sanchidrin and product. Ravi-Shankar, Kumar and Krishna-Mohan (1996)
Lpez, 2006). One important note is that Gurney energy published VOD values where the micro-balloon sensitised
ratios derived from cylinder expansion tests only represent emulsion was from less than one to ten per cent higher than
the unconfined detonation condition (and primarily shock the gassed emulsion over a range in water contents. Many
loading) and are unlikely to translate directly into confined different chemical and physical attributes contribute to the
explosive performance. No reliable method exists for VOD of bulk emulsions and therefore a generalised behaviour
measuring the release of explosive energy under realistic is difficult to characterise without specific testing data.
confinement conditions, and therefore the Gurney ratio The relationship between the emulsion gassed density and the
approach has been proposed for relative comparison unconfined or lightly confined VOD of chemicallysensitised
of the degrees of non-ideality of the different explosive types emulsions has been assumed to be approximately linear.
and densities. Some research does suggest that the Gurney This assumption is based on data published by Araos (2002)
energy can be closely correlated with the useful explosive and Nyberg et al (2003) where an almost linear relationship
energy calculated through partial reaction detonation codes between the charge density and the lightly-confined VOD
(Sanchidrin and Lpez, 2006). over a range of practical delivered densities (60-90 percent
One issue of concern in the field of blast engineering is the of matrix density) was observed (Figure 1). At densities
reporting of explosive energy content and VOD by explosives above 90 - 95 per cent of the unsensitised matrix density,
manufacturers. No standardised form of reporting exists in
product technical data sheets, and reported values of energy 6500
and VOD are typically a result of ideal detonation modelling
Lightly Confined VOD (m/s)
the VOD was dramatically reduced. Additional studies on and borehole diameter. The general form of the VOD surface
microballoon sensitised emulsions have revealed similar is given in Equation 2:
trends (eg Lee and Persson, 1990). Only the linear range
in densities (60 - 90 per cent of matrix density) has been VODU = (C $ te + D) $ c 1 (2)
m
considered in the proposed energy factor model. 1 + A $ ^1/zh + B $ ^1/zh2
where:
Non-ideal velocities of detonation as a result VODu = unconfined or lightly-confined velocity
of borehole diameter of detonation (m/s)
It is widely accepted that the VOD of an explosive is sensitive e = emulsion density after gassing (g/cm3)
to the charge diameter. Charge diameters approaching the
critical diameter reduce the VOD until deflagration and z = borehole diameter (mm)
subsequent detonation failure occurs. The effects of diameter A, B, C, D = fitting parameters
on VOD in larger charge diameters are less pronounced,
increasing gradually towards the ideal VOD or VODCJ, which The values of A, B, C and D in Equation 2 have been
represents the infinite charge diameter. determined for an example emulsion using multi-variable
non-linear estimation of the data published by Lee and
A number of researchers have published approaches to Persson (1990) and listed in Table 1.
define the shape of the diameter sensitivity in both small and
large charge diameters (eg Sun, Later and Chen, 2001 and
Esen, 2004). At larger charge diameters common to open pit
TABLE 1
blasting applications, the model proposed by Esen (2004) has Regression constants from nonlinear multi-variable regression
provided a better fit to the data analysed in this study. This of Equation 2 using the data of Lee and Persson (1990).
model has therefore been employed in the current work to
describe the diameter-VOD relationship for ANFO. A modified
Regression constant Values
form of the approach is proposed for gassed emulsions, which A 7.68
takes into account the VOD dependence on density as well B -124.33
as charge diameter. The general equation proposed by Esen
(2004) is listed below: C 4828.56
D -64.24
VOD = VODCJ c 1
m (1)
1 + a $ ^1/zh + b $ ^1/zh2 The data used in the regression and the surface defined by
where: the regression constants listed in Table 1 have been plotted
VOD = velocity of detonation (m/s) in Figure 2 to display the relationship between the emulsion
density, charge diameter and unconfined VOD (VODU).
VODCJ = velocity of detonation (m/s) at CJ plane
(ideal VOD)
= borehole diameter (mm)
a, b = fitting parameters
The regression constants a and b for ANFO have been
determined in this study through nonlinear regression
of unconfined or lightly confined test data published by Bauer
et al (1984) and Thomas (2005). The value of VODCJ for this
analysis was 4845 m/s and the resulting regression constants
a and b were 12.2 and 7497.7, respectively. The regression
resulted in a correlation R-value of 0.95.
The relationship between the charge diameter and the
unconfined VOD of ANFO would suggest that in the charge
diameters common of large-scale open pit mines and coal
cast blasting, minimal VOD reduction would occur compared
with the VODCJ value (approximately ten to 15 per cent below
ideal). The effects of charge diameter become significantly
pronounced for ANFO in blasthole diameters typical
of quarrying and underground production blasting (64 mm
to 165 mm), where the VOD reduction versus ideal is up to
67percent according to the analysis.
Fig 2 - Three-dimensional surface defined by the relationship between
Suggested empirical relationship between emulsion density, charge diameter and unconfined velocity of detonation
gassed emulsion density, charge diameter for the low density emulsion of Lee and Persson (1990).
and velocity of detonation
The dependence of VODCJ and subsequent unconfined Equations 1 and 2 and the proposed regression constants
VOD (VODU from Equation 1) on density and diameter for ANFO and the example gassed emulsion at density
simultaneously has been proposed using a modified 0.85g/cm3 have been used to estimate the unconfined VODs
form of Equation 1. The modified equation represents over a range of blasthole diameters. These diameters represent
a threedimensional surface over which the lightly-confined those common to open pit and large-scale quarry blasting.
VOD can be determined in relation to both emulsion density Table 2 lists the resulting estimated VODU values.
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