US20100048941

Assumption
coconut oil 100
1
oil 0.98 oil 98
water 0.01 water 1 drying
salt 0.01 salt 1

3
water 0.9

851 1150.8924
30 0
32 50.28576
56 0
92 8309.95704
285 780.0849
18 0.045
100584.3496

molar mass Fresh feed

851
18 coconut oil
30

32
18
56

production

851 bio prod

30
32
56
92
 285
18

851 glyc prod

30
32
56
92
285
18

1
mol oil 98.00
salt 1.00
methanol 0.00
CaO 0.00
glycerol 0.00
biodiesel 0.00
water 1.00
nitrogen 0.00
oxygen 0.00
in
molar mass total 83446.00
mass 851 oil 83398.00
30 salt 30.00
32 methanol 0.00
56 CaO 0.00
92 glycerol 0.00
285 biodiesel 0.00
18 water 18.00
28 nitrogen 0.00
32 oxygen 0.00

in 516534.0087
out 516534.0087
 conversion 0.931
4
CaO 0.49 extent of reaction
drying 91.238

transesterification
2 mol
oil 98
salt 1
water 0.1 6
oil 6.762
salt 1
5 methanol 314.286
methanol 588 CaO 0.49
glycerol 91.238
biodiesel 273.714
water 0.1
oil + 3 methanol = 3 bio + glycerol

10291.2651 wt 18
11.18319651 % oil 1.3524
0% salt 0
0.48862564 % methanol 1.57143
0% CaO 0
80.74767251 % glycerol 90.32562
7.580068072 % biodiesel 2.73714
0.000437264 % water 0.0025
Distillation
To Top
oil 1
salt 0
methanol 1
CaO 0
glycerol 1
 bio 1
water 1

20
nitrogen 3.724285714
oxygen 0.99
Calcination

oil
salt
methanol
21 CaO
oil 0 glycerol
salt 0 biodiesel
methanol 0 water
CaO 0.4851
glycerol 0
biodiesel 0
water 0
22
nitrogen 3.724285714
oxygen 0.99
salt 0.99

mass
oil 98 83398 98572.66265 kmol/year
water 1 18 83446 1005.843496 kmol/year
salt 1 30 1005.843496 kmol/year

methanol 300.7708817 9624.668216 302528.4353 kmol/year

water 20705.5675 372700.2149 20826560.41 kmol/year
CaO 0.0049 0.2744 4.928633133 kmol/year

mass composition wt
79535.23613
oil 2.7048 2301.7848 0.028940441
salt 0 0 0
methanol 0.02828574 0.90514368 1.13804E-05 scaling
CaO 0 0 0
glycerol 0 0 0
bio 270.97686 77228.4051 0.970996113
water 0.230060388 4.141086987 5.20661E-05
10291.2651
oil 1.3524 1150.8924 0.111831965
salt 0 0 0
methanol 1.57143 50.28576 0.004886256
CaO 0 0 0
glycerol 90.32562 8309.95704 0.807476725
biodiesel 2.73714 780.0849 0.075800681
water 0.0025 0.045 4.37264E-06

2 3 4 5 6 7 8
98.00 0.00 0.00 0.00 6.76 5.41 1.35
1.00 0.00 0.00 0.00 1.00 0.01 0.99
0.00 0.00 0.00 588.00 314.29 282.86 31.43
0.00 0.00 0.49 0.00 0.49 0.00 0.49
0.00 0.00 0.00 0.00 91.24 0.91 90.33
0.00 0.00 0.00 0.00 273.71 270.98 2.74
0.10 0.90 0.00 0.00 0.10 0.05 0.05
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00
out in in
83429.80 16.20 27.44 18816.00 102273.24 90968.82 11304.42
83398.00 0.00 0.00 0.00 5754.46 4603.57 1150.89
30.00 0.00 0.00 0.00 30.00 0.30 29.70
0.00 0.00 0.00 18816.00 10057.15 9051.44 1005.72
0.00 0.00 27.44 0.00 27.44 0.27 27.17
0.00 0.00 0.00 0.00 8393.90 83.94 8309.96
0.00 0.00 0.00 0.00 78008.49 77228.41 780.08
1.80 16.20 0.00 0.00 1.80 0.90 0.90
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00
 assumption to stripper 7
oil 0.8 oil 5.4096
salt 0.01 salt 0.01
methanol 0.9 methanol 282.8574
CaO 0.01 CaO 0.0049
glycerol 0.01 glycerol 0.91238
biodiesel 0.99 biodiesel 270.97686
water 0.5 water 0.05

settling distillation

17
oil 0
8 salt 0
oil 1.3524 methanol 29.85717
salt 0.99 CaO 0
methanol 31.4286 glycerol 0
CaO 0.4851 biodiesel 0
glycerol 90.32562 water 0.0475
biodiesel 2.73714
water 0.05

distillation

To Top
oil
Distillation salt
methanol
16 CaO
oil 1.3524 glycerol
salt 0.99 bio
methanol 1.57143 water
CaO 0.4851
 glycerol 90.32562
biodiesel 2.73714
water 0.0025

19
0
0.99
0
0.4851
0
0
0

10
oil
salt
methanol
CaO
glycerol
bio
water

SCALE COCONUT OIL MOL FEED PER YEAR

100584.35

requirement
80,000,000 kg/year

1005.843496
 9 10 11 12 13 14 15
5.41 0.00 0.00 2.70 2.70 2.70 0.00
0.01 0.00 0.00 0.00 0.01 0.00 0.00
28.29 254.57 0.00 2.83 25.46 0.03 2.80
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.91 0.00 0.00 0.00 0.91 0.00 0.00
270.98 0.00 0.00 270.98 0.00 270.98 0.00
0.00 0.05 23006.03 2300.60 20705.43 0.23 2300.37
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00
out in out out out
82821.72 8147.10 414108.61 121031.57 375898.76 79535.24 41496.34
4603.57 0.00 0.00 2301.78 2301.78 2301.78 0.00
0.30 0.00 0.00 0.00 0.30 0.00 0.00
905.14 8146.29 0.00 90.51 814.63 0.91 89.61
0.27 0.00 0.00 0.00 0.27 0.00 0.00
83.94 0.00 0.00 0.00 83.94 0.00 0.00
77228.41 0.00 0.00 77228.41 0.00 77228.41 0.00
0.09 0.81 414108.61 41410.87 372697.83 4.14 41406.73
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00
 10 5x mass of other feed
oil 0 11
salt 0 oil 0
methanol 254.57166 salt 0
CaO 0 methanol 0
glycerol 0 CaO 0
bio 0 glycerol 0
water 0.045 biodiesel 0
water 23006.03382
recovery
oil 0
distillation salt 0
methanol 0.9
CaO 0
glycerol 0
bio 0
water 0.9

washing

9 molar mass
oil 5.4096 851
salt 0.01 30
methanol 28.28574 32
CaO 0.0049 56
glycerol 0.91238 92
biodiesel 270.97686 285
water 0.005 18
mass = 82821.72174

0
0
0.95
0
0
0
0.95
17
 oil 0
salt 0
methanol 29.85717
CaO 0
glycerol 0
biodiesel 0
water 0.0475

0
0
254.57166
0
0
0
0.045

15
oil 0
salt 0
methanol 2.80028826
CaO 0
glycerol 0
bio 0
water 2300.373821
 16 17 18 19 20 21 22
1.35 0.00 1.35 0.00 0.00 0.00 0.00
0.99 0.00 0.00 0.99 0.00 0.00 0.99
1.57 29.86 1.57 0.00 0.00 0.00 0.00
0.49 0.00 0.00 0.49 0.00 0.49 0.00
90.33 0.00 90.33 0.00 0.00 0.00 0.00
2.74 0.00 2.74 0.00 0.00 0.00 0.00
0.00 0.05 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 3.72 0.00 3.72
0.00 0.00 0.00 0.00 0.99 0.00 0.99
out out in out out
10348.13 956.28 10291.27 56.87 135.96 27.17 165.66
1150.89 0.00 1150.89 0.00 0.00 0.00 0.00
29.70 0.00 0.00 29.70 0.00 0.00 29.70
50.29 955.43 50.29 0.00 0.00 0.00 0.00
27.17 0.00 0.00 27.17 0.00 27.17 0.00
8309.96 0.00 8309.96 0.00 0.00 0.00 0.00
780.08 0.00 780.08 0.00 0.00 0.00 0.00
0.04 0.86 0.04 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 104.28 0.00 104.28
0.00 0.00 0.00 0.00 31.68 0.00 31.68
 in
recycle
waste
product

Total to dryer
oil 0.5
salt 0
methanol 0.1
CaO 0 12
glycerol 0 oil 2.7048
bio 1 salt 0
water 0.1 methanol 2.828574
CaO 0
ng glycerol 0
bio 270.97686
water 2300.603882

drying

13
oil 2.7048 drying effectiveness
salt 0.01 oil 0
methanol 25.457166 salt 0
CaO 0.0049 methanol 0.99
glycerol 0.91238 CaO 0
biodiesel 0 glycerol 0
water 20705.43494 bio 0
water 0.9999
distillation
 15
oil 0
salt 0
methanol 2.80028826
CaO 0
glycerol 0
bio 0
water 2300.373821

g
14
oil 2.7048 851 oil
salt 0 30 salt
methanol 0.02828574 32 methanol
CaO 0 56 CaO
glycerol 0 92 glycerol
bio 270.97686 285 bio
water 0.230060388 18 water

Biodiesel Product
72.7 mg/kg Ca

0.0000727 g/g
mol mass mol
7.27E-11 40 1.8175E-12
1 285 0.003508772
0.003508772
oil 0
salt 0 negligible amounts of Ca
methanol 287.2291183
CaO 0
glycerol 0
biodiesel 0
water 0

oil 0
salt 0
methanol 0
CaO 0
glycerol 0
biodiesel 0
water 2300.466321
mass 79535.23613
2301.7848 2.894044089 %wt
0 0 %wt
0.90514368 0.001138041 %wt
0 0 %wt
0 0 %wt
77228.4051 97.09961126 %wt
4.141086987 0.005206607 %wt

mol comp
5.17987E-10
1