S GD T TP.

HCM THI TH LN 2 THPT QUC GIA NM 2017

THPT TRN HNG O Mn: KHOA HC T NHIN HA HC
Thi gian lm bi: 50 pht, khng k thi gian pht
( thi c 40 cu / 4 trang)

Cho bit nguyn t khi ca cc nguyn t :

H =1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S =32; Cl = 35,5; K = 39; Ca = 40; Cr
= 52; Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.

Cu 1: C bao nhiu amin bc 2 c cng cng thc phn t C4 H11 N?

A. 3 B. 8 C. 4 D. 1
Cu 2: Cho mt ipeptit Y c cng thc phn t C6 H12 N2 O3 . S ng phn peptit ca Y (ch
cha gc a-aminoaxit) mch h l:
A. 5 B. 4 C. 7 D. 6
Cu 3: Cho cc nhn nh sau:
(1) Alanin lm qu tm ha xanh.
(2) Axit glutamic lm qu tm ha .
(3) Lysin lm qu tm ha xanh.
(4) Axit aipic v hexametyleniamin l nguyn liu sn xut t nilon-6,6
(5) Methionin l thuc b thn.
S nhn nh ng l:
A. 2 B. 5 C. 3 D. 4
Cu 4: Dy gm cc cht c dng tng hp cao su Buna-S l:
A. CH2 = C(CH3) - CH = CH2, C6H5CH = CH2 B. CH2 = CH - CH = CH2, C6H5CH = CH2
C. CH2 = CH - CH = CH2, lu hunh D. CH2 = CH - CH = CH2 , CH3 - CH = CH2
Cu 5: Cho cc cht sau
(I) H2 N-CH2 -CH2 -CO-NH-CH2 -CO-NH-CH2 -CH2 -COOH
(II) H2 N-CH2 CO-NH-CH2 -CO-NH-CH2 -COOH
(III) H2 N-CH(CH3 )-CO-NH-CH2 -CO-NH-CH2 -CO-NH-CH2 -COOH
Cht no l tripeptit?
A. III B. I C. II D. I,II
Cu 6: Cc dung dch u tc dng c vi Cu(OH) 2 l:
A. glucoz, xenluloz, glixerol B. fructoz, saccaroz, tinh bt.
C. glucoz, glixerol, tinh bt D. fructoz, saccaroz, glixerol
Cu 7: Poli (vinyl clorua) (PVC) c iu ch t kh thin nhin (cha 95% th tch kh metan)
theo s chuyn ha v hiu sut mi giai on nh sau:

hs15% hs95% hs90%

Metan Axetilen Vinylclorua PVC
Mun tng hp 3,125 tn PVC th cn bao nhiu m3 kh thin nhin (o ktc)?
(H=1, C=12, O=16, Cl=35,5)
A. 17466 m3 B. 18385 m3 C. 2358 m3 D.
5580 m3
Cu 8: Thy phn este C4 H6 O2 trong mi trng axit th ta thu c mt hn hp cc cht u
c phn ng trng
gng. Vy cng thc cu to ca este c th l p n no sau y?
A. H-COO-CH=CH-CH3 B. CH2=CH-COO-CH3
C. CH3-COO-CH=CH2 D. H-COO-CH2-CH=CH2
Cu 9: trung ha 200 ml dung dch aminoaxit 0,5M cn 100 g dung dch NaOH 8%, c cn
dung dch c 16,3 g mui khan. X c cng thc cu to (cho H=1; C=12; N=14; O=16;
Na=23):
A. (H2 N)2 CH-COOH B. H2 N-CH2 -CH(COOH) 2
C. H2NCH(COOH)2 D. H2 N-CH2 -CH2 -COOH
Cu 10: Cho cc pht biu sau v cacbohirat:
(a) Glucoz v saccaroz u l cht rn, mu trng, c v ngt, d tan trong nc.
(b) Tinh bt v xenluloz u l polisaccarit.
(c) Trong dung dch, glucoz v saccaroz u ho tan Cu(OH)2, to phc mu xanh lam.
(d) Khi thu phn hon ton hn hp gm tinh bt v xenluloz trong mi trng axit, ch thu
c mt loi monosaccarit duy nht.
(e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3trong NH3 thu c Ag.
(f) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol.
S pht biu ng l
A. 5. B. 6. C. 4. D. 3.
Cu 11: Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t
clo phn ng vi k mt xch trong mch PVC. Gi tr ca k l (cho H = 1, C = 12, Cl = 35,5)
A. 6. B. 3. C. 4. D. 5.
Cu 12: phn bit glucoz vi etanal ta dng cch no sau y?

A. tc dng vi Cu(OH)2 nhit cao B. tc dng vi Cu(OH)2 nhit phng

C. thc hin phn ng trng gng D. dng dung dch B2
Cu 13: Cho m gam glucoz ln men thnh ancol etylic vi H= 75%. Ton b kh CO 2 sinh ra
c hp th ht vo dung dch Ca(OH)2 ly d to ra 500g kt ta. Gi tr ca m l: (C=12;
H=1, O=16; Ca=40)
A. 720 B. 540 C. 1080 D. 600
Cu 14: Chn Cu sai:
A. xenluloz v tinh bt khng phn ng c vi dung dch AgNO3/NH3
B. tinh bt v xenluloz c tnh cht ca ancol a chc, tc dng vi Cu(OH)2, to thnh dung
dch phc cht mu xanh lam
C. tinh bt v xenluloz l nhng polime thin nhin c khi lng phn t rt ln
D. iu kin thng, tinh bt v xenluloz l nhng cht rn mu trng khng tan trong nc
Cu 15: Fructoz khng phn ng c vi:
A. dung dch Br2. B. H2/M, to.
C. dung dch AgNO3/NH3. D. Cu(OH)2.
Cu 16: Cho cc loi t: bng, t capron, t xenluloz axetat, t tm, t nitron, nilon-6,6. S t
tng hp l A. 5. B. 3. C. 4. D. 2.
Cu 17: Nhm cc vt liu c ch to t polime trng ngng l
A. t axetat, nilon-6,6, poli(vinylclorua) B. cao su, nilon-6,6; t nitron
C. nilon-6,6; t lapsan; thy tinh Plexiglas D. nilon-6,6; t lapsan; nilon-6
Cu 18: un nng x gam hn hp A gm 2a mol tetra peptit mch h X v a mol tri peptit mch
h Y vi 550 ml dung dch NaOH 1M (va ). Sau khi cc phn ng kt thc, c cn dung dch
thu c 45,5 gam mui khan ca cc amino axit u c 1-COOH v 1-NH2 trong phn t. Mt
khc thu phn hon ton x gam hn hp A trn bng dung dch HCl d thu c m gam mui.
Gi tr ca m l? (cho C=12; H=1; O=16, N=14 , Na=23)
A. 56,125 B. 56,175 C. 46,275 D. 53,475
Cu 19: Cc este c cng thc C4H6O2 c to ra t axit v ancol tng ng c th c cng
thc cu to nh th no?
A. CH2=CH-COO-CH3; H- COO- CH2-CH= CH2; H-COO- CH=CH- CH3
B. CH2=CH-COO-CH3; CH3COO-CH= CH2; H- COO- CH2-CH= CH2
C. CH2=CH-COO-CH3; H- COO- CH2-CH= CH2
D. CH2=CH-COO-CH3; CH3COO-CH=CH2; H-COO-CH2-CH=CH2; H-COO-C(CH3)=CH2.
Cu 20: Trong cc cht di y, cht no l glyxin?
A. H2N-CH2-COOH B. CH3-CH(NH2)-COOH
C. HOOC-CH2CH(NH2)COOH D. H2N-CH2-CH2-COOH
Cu 21: Cho 0,1 mol H2NC3H5(COOH)2(axit glutamic) vo 150 ml dung dch HCl 2M, thu c
dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol
NaOH phn ng l (cho H=1; C=12; N=14; O=16 ,Na=23):
A. 0,55. B. 0,70. C. 0,65. D. 0,50.
Cu 22: Trong s cc cht: phenylamoni clorua, natri phenolat, ancol etylic, phenyl benzoat, t
nilon-6, ancol benzylic, alanin, tripeptit Gly-Gly-Val, m-crezol, phenol, anilin, triolein, cumen .
S cht phn ng c vi dung dch NaOH long, un nng l:
A. 10 B. 7 C. 8 D. 9
Cu 23: Bnh nhn phi tip ng (tim hoc truyn dung dch ng vo tnh mch), l
loi ng no?
A. Glucoz B. Fructoz C. Mantoz D. Saccaroz
Cu 24: Cht no di y khng phi l este?
A. CH3COOH B. CH3COOCH3 C. HCOOCH3 D. HCOOC6H5
Cu 25: Mt este c cng thc phn t l C3H6O2 c phn ng trng gng vi dung dch
AgNO3 trong NH3. Cng thc cu to ca este l cng thc no?
A. HCOOC3H7 B. HCOOC2H5 C. C2H5COOCH3 D. CH3COOCH3
Cu 26: Hp cht X c cng thc cu to CH3CH2 - COO - C2H5. Tn gi ca X l:
A. vinyl axetat B. metyl propionat
C. etyl propionat D. metyl metacrylat
Cu 27: Cho cc polime sau : si bng (1), t tm (2), si ay (3), t enang (4), t visco (5), t
axetat (6), nilon-6,6 (7). Loi t c ngun gc xenluloz l?
A. 1, 2, 3, 5, 6 B. 5, 6, 7 C.1, 2, 5, 7 D. 1, 3, 5, 6
Cu 28: T no di y l t nhn to?
A. T nitron B. T xenluloz axetat. C. T tm. D. T capron.
Cu 29: Lm bay hi 3,7 gam este n chim th tch bng th tch ca 1,6 gam O 2 trong cng
iu kin. Este trn c s ng phn l: (cho C=12; H=1; O=16)
A. 3 B. 2 C. 4 D. 1
Cu 30: t chy hon ton a mol mt peptit X (c to ra t aminoaxit no, mch h trong
phn t c 1- NH2 v 1-COOH) thu c b mol CO2 v c mol H2O v d mol N2. Bit b - c = a.
Thu phn hon ton 0,2 mol X bng dung dch NaOH (ly gp i so vi lng cn thit phn
ng) ri c cn dung dch sau phn ng th thu c cht rn c khi lng tng m gam so vi
peptit ban u. Gi tr ca m l? (cho C=12; H=1; O=16, N=14, Na=23)
A. 60,4 B. 76,4 C. 30,2 D. 28,4
Cu 31: Este C4H8O2 c to bi ancol metylic th c cng thc cu to l:
A. HCOOC3H7. B. CH3COOC2H5. C. C2H5COOCH3. D. C2H3COOCH3.
Cu 32: T nilon-6,6 l
A. hexacloxiclohexan B. poliamit ca axit aipic v
exametyleniamin
C. poli amit ca axit s - aminocaproic D. polieste ca axit aipic v etylenglicol
Cu 33: Cho 3,52 gam cht A C4H8O2 tc dng vi 0,6 lt dung dch NaOH 0,1M. Sau phn ng
c cn dung dch thu c 4,08 gam cht rn. Cng thc ca A l:
A. C2H5COOCH3 B. HCOOC3H7 C. CH3COOC2H5 D. C3H7COOH
Cu 34: Polime no di y c cng cu trc mch polime vi nha bakelit?
A. cao su lu ha B. amiloz C. xenluloz D. Glicogen
Cu 35: Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng CO2
hp th vo dung dch nc vi trong thu c 275g kt ta v dung dch Y. un k dung dch Y
thu thm 150g kt ta na. Khi lng m l? (cho H = 1, C =12, O = 16, Ca=40)
A. 375g B. 750g C. 450g D. 575g
Cu 36: C4H8O2 c bao nhiu ng phn mch h phn ng c vi dung dch NaOH?
A. 5 B. 7 C. 6 D. 8
Cu 37: Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t nilon-6,6. C bao
nhiu t thuc loi t poliamit?
A. 4 B. 1 C. 2 D. 3
Cu 38: Th tch ca dung dch axit nitric 63% (D = 1,4 g/ml) cn va sn xut c 59,4
kg xenluloz trinitrat (hiu sut 80%) l? (Cho H = 1;C =12; O = 16; N=14)
A. 34,29 lt. B. 42,34 lt. C. 53,57 lt. D. 42,86 lt.
Cu 39: Thy phn hon ton hn hp E gm 2 este X, Y n chc, ng phn, mch h, bng
mt lng dung dch NaOH va thu c 13,2 gam hn hp 2 mui (Z) v 7,8 gam hn hp
2 ancol (ch hn km nhau 1 nguyn t C trong phn t). Nung Z thu 0,075 mol Na2CO3. Xc
nh CTCT thu gn ca X v Y: (Cho H = 1; C =12; O = 16; Na=23)
A. CH2 = CHCOOC2 H5 v CH3 COOCH = CHCH3
B. HCOOCH2 CH = CHCH3 v CH3 COOCH2 CH = CH2
C. C2 H5 COOCH2 CH = CH2 v CH3 CH = CHCOOC2 H5
D. CH3 COOCH2 CH = CH2 v CH2 = CHCOOC2 H5
Cu 40: Cho cc pht biu sau:
(a) C th dng nc brom phn bit glucoz v fructoz.
(b) Trong mi trng baz, glucoz v fructoz c th chuyn ho ln nhau.
(c) Tinh bt v xenluloz l ng phn cu to ca nhau
(d) Khi un nng glucoz b kh bi dung dch AgNO3 trong NH3 to ra Ag.
(e) Trong dung dch, glucoz v fructoz u ho tan Cu(OH) 2 nhit cao cho dung dch
mu xanh lam.
(f) Trong dung dch, fructoz tn ti ch yu dng vng 5 cnh a - fructoz v 3-fructoz.
S pht biu ng l:
A. 4. B.5. C. 3. D. 2
P N
1 A 11 B 21 D 31 C
2 A 12 B 22 C 32 B
3 C 13 D 23 A 33 C
4 B 14 B 24 A 34 A
5 C 15 A 25 B 35 D
6 D 16 B 26 C 36 C
7 B 17 D 27 D 37 C
8 A 18 D 28 B 38 C
9 C 19 C 29 B 39 D
10 C 20 A 30 A 40 C

Cu 1: p n A
Cc amin bc 2 c cng cng thc phn t C 4H11N l : CH3NHCH2CH2CH3,
CH3NHCH(CH3)CH3; CH 3CH 2 NHCH 2CH 3 .
Ch : Bc ca amin khc vi bc ca ancol.
Cu 2: p n A
Phn tch: Cc -aminaxit to nn ipeptit Y c th l :
A: H2N-CH2-COOH;B: CH3-CH2-CH(NH2)-COOH;
C: (CH3)2C(NH2)COOH;D: CH3-CH(NH2)-COOH
Cc ng phn ipeptit ca Y(C6H12N3O2) l:
A-B; B-A A-C; C-A v D-D.
Cu 3: p n C
Phn tch : Cc nhn nh ng l : 2, 3, 4.
Nhn nh 1 sai v Alanin c CTCT l CH3-CH(NH2)- COOH nn khng lm qu tm ha xanh.
Nhn nh 5 sai v methionin l thuc b gan.
Cu 4: p n B
Cc cht dng tng hp Cao su buna-S l : stiren ( C 6H5CH=CH2) v buta-1,3-ien vi xc
tc Na.
Cu 5: p n C Cht l tripeptit l : III
Ch : Ta cn xem xt k cc aminoaxit to nn peptit c phi l -aminaxit khng.
Cu 6: p n D
Phn tch: D thy p n A ta loi xenluloz, p n B v C loi tinh bt.
Vy cc dung dch u tc dng c vi Cu(OH)2 l fructoz, saccaroz, glixerol.
Cu 7: p n B
Phn tch : Ta c th tm tt ton b qu trnh phn ng nh sau
15%
2nCH4 95%
nC2H2 90%
nCH2CHCl (CH2 - CHCl )n

3,125.106
nPVC = = 5.104 mol
62,5
Cu 8: p n A
Phn tch: D dng tnh nhanh c nC4H6O2 = 2. Este ny khi thy phn trong mi trng axit thu
c mt hn hp cc cht u c phn ng trng gng nn CTCT ca n l COO-CH=CH-
CH3.
Cu 9: p n C
Phn tch:
naminoaxit = 0,5.0,2 = 0,1; nNaOH = 0,2mol.
aminoaxit c hai nhm-COOH trong phn t .
Ta c
16,3
Mmui = = 163
0,1
Suy ra CTCT ca mui l H2N-CH-(COONa)2 Vy CTCT ca aminoaxit l H2N-CH-(COOH)2
Cu 10: p n C
Phn tch: Ta nhn thy cc pht biu ng l b, c, d, e. Pht biu a sai v glucoz v saccaroz
l cc cht rn khng mu ch khng phi l mu trng. Pht biu f sai v saccaroz khi tc dng
vi H2 khng to ra sobitol, ch c glucoz .
Cu 11: p n B

k(C2H3Cl ) + CI 2 C2kH3k-1Cl(k+1) + HCl

Theo bi, c :

(k + 1).35,5
63,96% = k= 3
12.2k + 3k - 1+ (k + 1).35,5
Cu 12: p n B
Phn tch: Khi cho glixerol v etanal tc dng vi Cu(OH)2 nhit phng th ch c glixerol
to dung dch mu xanh lm cn etanal khng c hin tng g.
Cu 13: p n D
Phn tch:
nCaCO3 = nCO2 = 5mol
 nCO2 1 5 1 10
nGlu = . = . =
2 H% 2 0,75 3
10
mGlu = = 600gam
3.180
Vy khi lng Gluocoz l 600 gam.
Cu 14: p n B
Phn tch: Nhn thy ngay p n sai l B. Tinh bt v xenluloz khng c tnh cht cu ancol
a chc, tc dng vi Cu(OH)=
Cu 15: p n A
Phn tch: Fructoz khng phn ng c vi dung dch Br2.
Cu 16: p n B
Phn tch: Cc t tng hp l t nilon-6,6; t nitron(hay olon), t capron.
Cu 17: p n D
Phn tch: Cc vt liu c ch to t polime trng ngng l nilon-6,6; t lapsan; nilon-6.
Cu 18: p n D
Phn tch: Ta c Khi cho peptit tc dng vi NaOH ta lun
nNaOH = 2a.4+ a.3 = 0,55 a = 0,05

c
nH2Osinhra = npeptit
nH2O = 2aa + a = 0,15

Bo ton khi lng, ta c :

mA + mNaOH = mmui + mH 2O
mA = 45,5+ 0,15.18- 0,55.40 = 26,2gam

Khi cho peptit tc dng vi HCl th

nHC1 = nNaOH = 0,55mol
C :
tetrapeptit X + 4HCl + 3H2O Mu
i
0,1 0,4 0,3

tripeptit Y + 3HCl + 2H2O Mu

i
0,05 0,15 0,1

mA + mHCl + mH 2 O = mmui
mmui = 26,2 + 0,55.36,5+ 0,4.18 = 53,475gam
Vy khi lng mui thu c l 53,475gam.
Cu 19: p n C
Phn tch: Cc este c CT C4H6O2 c to ra t axit v ancol tng ng c th c CTCT l:
CH2=CH-COO-CH3; H-COO-CH2-CH=CH2 .
Cu 20: p n A
Phn tch: Glyxin c CTCT l H2N-CH2-COOH.
Cu 21: p n D
Phn tch: Ta coi NaOH tc dng ring vi HCl v axit glutamic

nNaOH = nH+ = 2nGlutamic - nHCl = 0,5mol

Vy s mol NaOH phn ng l 0,5mol.

Cu 22: p n C
Phn tch: Cc cht tc dng vi dung dch NaOH long, un nng l phenylamoni clorua,
phenyl benzoat, t nilon-6, alanin, tripeptit Gly-Gly-Ala, m-crezol, phenol, triolein.
Cu 23: p n A
Phn tch: Bnh nhn phi tip ng Glucoz (tim hoc truyn dung dch ng vo tnh
mch).
Cu 24: p n A
Phn tch: D dng nhn thy CH3COOH l axit ch khng phi este.
Cu 25: p n B
Phn tch: D dng tnh nhanh c nn este X c kh nng tham gia phn ng
nC3H6O2 = 1
trng gng th X l este ca axit fomic. Vy CTCT ca X l HCOOC2H5 .
Cu 26: p n C
Phn tch: Hp cht X c CTCT CH3CH2-COO-C2H5 nn X c tn l etyl propionat.
Cu 27: p n D
Phn tch: Nhng loi t c ngun gc t xenluloz l : si bng(1), si ay(3), t visco(5), t
axetat(6).
Cu 28: p n B
Phn tch: Ta c t nitron v t capron l t tng hp; t tm l t thin nhin; t xenluloz
axetat l t nhn to.
Cu 29: p n B
Phn tch:
neste = nO2 = 0,05mol

3,7
Meste = = 74
0,05
Vy este trn c cc ng phn l HCOOC2H5, CH3COOCH3 .
Cu 30: p n A
Phn tch: Ta t cng thc ca peptit l CnH2n+2-xOx+1Nx v a = 1

nCO2 = b = n; nH2O = c = n + 1- 0,5x

M b - c = a nn
n- (n+ 1- 0,5x) = 1 x = 4
Suy ra X l tetra peptit.
Ta c :
X + 4NaOH Mu
i + H2O
Suy ra
mrnZ = mNaOH - mH2O = 0,2.4.2.40 - 0,2.18 = 60,4gam

Ch : Nu khng c k l lng NaOH ly gp i so vi lng cn thit th ta s tnh thiu

lng NaOH d sau phn ng cng l cht rn. V d bi ny nu tnh thiu th ta s khoanh
ln p n D.
Cu 31: p n C
Phn tch: Este C4H8O2 c to bi ancol metylic th c CTCT l C2H5COOCH3
Cu 32: p n B
Phn tch: T nilon-6,6 l poliamit ca axit aipic v hexametyleniamin
PTHH:

( )
nH2N - [ CH2 ] 6 - NH2 + nHOOC - [ CH2 ] 4- COOH NH - [ CH2 ] 6 - NH - CO - [ CH2 ] 4 - CO + 2nH2O
n

Cu 33: p n C

3,52
nC4H8O2 = = 0,04mol ;
88
Ta c
4,08 = mNaOH d+ mmui = 0,02.40+ mmui
mmui = 3,28gam Mmui = 82

CTCT ca mui l CH3COONa CTCT ca A l CH3COOC2H5

Cu 34: p n A
Phn tch: Cao su lu ha c cng cu trc mch polime vi nha bakelit(mch khng gian).
Cu 35: p n D
Phn tch:
Ta c
nCO 2-
3
= 1,5.2+ 2,75 = 5,75mol
 5,75 1
mtinh bt = . .162 = 575gam
2 81%
Vy khi lng tinh bt l 575 gam
Cu 36: p n C
Phn tch: D dng tnh nhanh c . Cc ng phn l este hoc axit ca C4H8O2 s
nC4H8O2 = 1

tc dng c vi dung dch NaOH. 6 ng phn 2 axit v 4 este) l :

CH3CH2CH2COOH, CH3CH(CH3)COOH, HCOOCH2CH2CH3,
HCOOCH(CH3)CH3, CH3COOCH2CH3, CH3CH2COOCH3 .
Cu 37: p n C
Phn tch: Cc t thuc loi t poliamit l t capron, t nilon-6,6.

Ch : Khi c qu nhanh ta c th nhm t nitron cng thuc loi t poliamit.

Cu 38: p n C

59,4
nxenluloztrinitrat = = 0,2mol
297

[C6H7O2(OH)3]n + 3nHNO3 [C6H7O2(ONO2 )3]n + 3nH2O

0,2.3
nHNO3 = = 0,75mol
80%
mHNO3 = 47,25gam
CmHNO3 = D.VHNO3
1 mHNO3
Vdung dch = . = 53,57l
t
63% D
Cu 39: p n D
Phn tch: D dng tnh c
nNaOH = 2nNa2 CO3 = 0,15mo1

nancol = nmui = neste = nNaOH = 0,15

7,8
M ancol = = 5,2
0,15
Hai ancol c C2H5OH(M=46) v C3HxO. Da vo 4 p n ta suy ra c ngay ancol cn
li phi l CH2=CH-CH2OH hay C3H6O. Loi p n A v B
t
nC2H6O = a; nC3H6O = b
Ta c :
a + b = 0,15
a = b = 0,075
46a + 58b = 7,8
Ta c (bo ton khi lng)
meste = mmui + mancol - mNaOH = 15g
t cng thc este l RCOOC2H5 v R'COOC3H5.

0,075.( R + 67) + 0,075(R'+ 67) = 13, 2R + R' = 42

Th p n C v D, ta thy p n D tha mn vi R' l gc CH3-(M=15) v R l gc

CH2=CH(M=27).
Cu 40: p n C
Phn tch: Nhn thy ngay pht biu C sai v glucoz v fructoz khng phi l ng phn cu
to ca nhau ; pht biu d sai v glucoz b oxi ha bi dung dch AgNO3 trong NH3 to ra Ag
ch khng phi b kh. Pht biu e sai v khi cho Cu(OH) 2 tc dng vi glucoz v fructoz
nhit cao th cho cht rn mu gch(Cu2O) ch khng phi dung dch mu xanh lam. Ba
pht biu cn li ng.