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TABLE OF CONTENT
PHYSICAL CHEMISTRY
ATOMIC STRUCTURE. .................................................................................................................... 1
CHEMICAL BONDING. .................................................................................................................... 2
CHEMICAL EQUILIBRIUM. ............................................................................................................. 3
ACID BASE. ....................................................................................................................................... 4
IONIC EQULIBRIUM. ........................................................................................................................ 5
CHEMICAL KINETICS. ..................................................................................................................... 6
OXIDATION-REDUCTION. .............................................................................................................. 7
VOLUMETRIC ANALYSIS. .................................................................................................................... 8
MOLE CONCEPT............................................................................................................................................ 9
CHEMICAL ENERGETICS. ............................................................................................................. 9 - 10
ELECTRO CHEMISTRY .............................................................................................................................. 11
SOLUTION AND COLLIGATIVE PROPERTIES. ........................................................................ 11 - 12
NUCLEAR CHEMISTRY............................................................................................................................... 12
GASEOUS STATE. ............................................................................................................................................... 13
SOLID AND LIQUID STATE. ............................................................................................................................14
SURFACE CHEMISTRY & COLLOIDAL STATE.................................................................................... 15
INORGANIC CHEMISTRY
PERIODIC TABLE. ..................................................................................................................................16
EXTRACTIVE METALLURGY ....................................................................................................................17
s- BLOCK ELEMENTS. .................................................................................................................... 17
BORON FAMILY............................................................................................................................................................ 18
CARBON FAMILY ......................................................................................................................................................... 18
OXYGEN FAMILY ......................................................................................................................................................... 19
HALOGEN FAMILY....................................................................................................................................................... 20 - 21
TRANSITION ELEMENTS (D-BLOCK ELEMENTS). ................................................................. 21
COORDINATION COMPOUNDS. .................................................................................................... 21
ORGANIC CHEMISTRY
GOC. .................................................................................................................................................... 22
ALKANES. ...........................................................................................................................................23
ALKENES. .......................................................................................................................................... 23
ALKYNES. .......................................................................................................................................... 23
HALOGEN COMPOUNDS. .............................................................................................................. 23
ALCOHOLS. ....................................................................................................................................... 24
PHENOLS. ...........................................................................................................................................24
ETHERS. .............................................................................................................................................. 25
CARBONYL COMPOUNDS. ........................................................................................................... 25
CARBOXYLIC ACIDS. ...................................................................................................................... 26
NITROGEN COMPOUNDS. ............................................................................................................. 26
CARBOHYHYDRATES, AMINO ACIDS AND POLYMERS. .........................................................26
CHARACTERISTIC REACTIONS OF DIFFERENT ORGANIC COMPOUNDS. .................... 27
IMPORTANT REAGENT .............................................................................................................................. 28 -29
MAIN USE OF COMPOUNDS. .........................................................................................................29
SMELL OF SOME COMPOUNDS. .................................................................................................. 29
IDENTIFICATION TESTS. ................................................................................................................. 30
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Class 1
PHYSICAL CHEMISTRY
ATOMIC STRUCTURE
n
2 2 2
n h
rn 0.529 A,rn n r1
2
1. 2 2
4 mZe Z
PE Z2
ET KE 13.6 eV
2. 2 n2
hc2 2me4 1 1
3. E 2 2 2
h n1 n2
4. 1 1 1
v RZ 2 , R 1.0968107 m1
2 2
n1 n2
n(n 1)
5. Total no. of spectrum lines=
2
6. Heisenberg Uncertainty Principle xp h / 4
13.7
7. Moseley's law : v a (Z b), En eV / atom
n2
8. Nodes (n -1) = total nodes, l= angular nodes, (n l 1) = Radial nodes
1
9. Photoelectric effect: hv hv0 mv
2
2
h
10. Orbital angular momentum: l(l 1)
2
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Class 2
CHEMICAL BONDING
1. % ionic character
Actual dipole moment 100
Calculated dipole moment
2. Fajan's Factors: following factors are helpful in including covalent
character in ionic compounds
(a) Small cation
(b) Big anion
(c ) High charge on cation
(d) High charge on anion
(e) Cation having pseudo inert gas configuration
(ns2p6d10) e.g. Cu+, Ag+, Zn2+, Cd2+
1
3. H H H IE H E
d EG L
f S
2
4. M.O. theory:
(a) Bond order 1 N N
b a
2
(b) Higher the bond order, higher is the bond dissociation energy, greater
is the stability, and shorter is the bond length.
(c ) Species Bond order Magnetic properties
H2 1 Diamagnetic
+
H2 0.5 Paramagnetic
Li2 1 Diamagnetic
5. Q 1 V SA (q )
2
6. Former charge = V- L 1 S
2
7. VSEPR theory
(a) (LP LP) repulsion > (LP BP) > (BP BP)
(b) For NH3Bond Angle 106045' because H O 2 molecule contains 2LP
and 2BP where as NH3has ILP and 3BP.
8. Bond angle:
Decrease in bond angle down the gp is due to LP BP repulsion
(a) NH3> PH3 > AsH3
(b) H2O > H2S > H2Se
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Class 3
CHEMICAL EQUILIBRIUM
1. K p Kc( RT )? n g where ng =n p -n R
4. Le chatelier's principle
(i) Increase of reactant conc. (Shift forward)
(ii) Decrease of reactant conc. (Shift backward)
(iii) Increase of pressure (from more moles to less moles)
(iv) Decrease of pressure (from less moles to more moles)
(v) For exothermic reaction decrease in temp. (Shift forward)
(vi) For endothermic increase in temp. (Shift forward)cTime Total
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Class 4
ACID BASE
1.(a). Lewis Acid (e- pair acceptor) CO2 , BF3 , Alcl3, Zncl2, Fecl 3, PCl ,Sicl
3
,SF
4
,6 normal cation
(b). Lewis Base (e- pair donor) NH3, ROH, ROR, H2O, RNH2 , R2NH,R3N, normal anion
2. Dissociation of Weak Acid & Weak Base
3. Buffer solution:
Acidic pH pKa log{salt / Acid}for Maximum buffer action pH = pKa
(a)
Range of Buffer pH = pKa 1
(b) Alkaline pOH = pKb +log {Salt/ Base} for max.
Buffer range for basic buffer = pKb 1
Moles/lit of Acid or Base Mixed
Buffer Capacity =
(c ) Change in pH
dCBOH dCHB
B
dpH dpH
4. Necessary condition for showing neutral colour of Indicator pH = pKln or [HIn] = [In- ] or [InOH]=[In+ ]
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Class 5
IONIC EQULIBRIUM
(B). If solubility product > ionic product then the solution is unsaturated
and more of the substance can be dissolved in it.
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Class 6
CHEMICAL KINETICS
k2 T T
E
6. log
a
2 1
k1 2.303R T1T2
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Class 7
OXIDATION-REDUCTION
3. (a) Electro Chemical Series:- Li, K, Sr, Ca, Na, Mg, Al, Mn, Zn, Cr, Fe,
Cd, Co, Ni, Sn, Pb, H2, Cu, I2, Hg, Ag, Br2, Cl2, Pt, Au, F2
(b)As we move from top to bottom in this series
(1) Standard Reduction Potential
(2) Standard Oxidation Potential
(3) Reducing Capacity
(4) Ip
(5) Reactivity
4. (a) Formal charge = Group No. [No. of bonds+ No. of non- bonded e-s]
(b)At A node Oxidation, Cathode Reduction
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Class 8
VOLUMETRIC ANALYSIS
MOLE CONCEPT
1.Mole concept
GAM 1gm atom 6.021023 atom.
GAM 1gm molecule 6.021023 molecules.
23
NA =6.0210
volume(L)
2. Moles (gases)at NTP=
22.4
3.Molecular mass=2 vapour density
CHEMICAL ENERGETICS
1. First Law: E= Q + W
Expression for pressure volume work W = -PV
Maximum work in a reversible expansion:
V2 P
W = -2.303n RT log 2.303nRT log 1
V1 P2
2. Enthalpy and heat content: H = E + PV
[q( p) =q( v) +ngRT] H = E + ngRT
[ng np( g) nr ( g) ]
3.Kirchoff's equation:
ET2 ET 1 Cv (T2 T1)[cons tantV ]
HT2 HT1 Cp (T2 T1)[cons tantP]
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Class 10
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Class 11
ELECTRO CHEMISTRY
1. M = Z. I.t
eq Equivalent conductance at given concentration
2. Degree of dissociation: =
eq equivalent conductance at infinite dilution
3. Kohlrausch 'slaw : x y
0 0 0
m A B
4. Nernst Equation
& Keq = antilog nFE
0
E = E0 - 0.0591 log [Pr oducts] & E0 =E0 +E0
0.0591
10 cell anode cathode
n [Re ac tan ts]
G = -nFEcell & G 0 = -nFE0cell
G
-G0 2.303RT log Kc &Wma x nFE & G H T
0
T p
5. Calculation of pH of an electrolyte by using a calomel electrode:
Ecell - 0.2415
pH
0.0591
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Class 12
NUCLEAR CHEMISTRY
tdn
0 1 1.44t
1/ 2
N0
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Class 13
GASEOUS STATE
PV
5. Z (compressibility factor)= ; Z 1for ideal gas
nRT
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Class 14
4. Relationship between radius of void (r) and the radius of the sphere (R ):
r (tetrahedral) = 0.225 R; r(octahedral) = 0.414 R
5. Paramagnetic : Presence of unpaired electrons [attracted by magnetic
field]
6. Ferromagnetic: Permanent magnetism []
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Class 15
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Class 16
INORGANIC CHEMISTRY
PERIODIC TABLE
s- block ns1-2
p- block ns2np1-61-10 1-2
d-block (n -1)d ns
f- block (n-2)s2p6d10f1-14 (n-1)s2p6d0 or 1 ns2
3. IP 1 1 1 1
Metallic character Reducing character Basic Nature of oxide Basic nature of hydroxide
1
4. EA size neclear charge
Second electron affinity is always positive.
Electron affinity of chlorine is greater than fluorine.
5. The first element of a group has similar properties with the second
element of the next group. This is called diagonal relationship.
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Class 17
EXTRACTIVE METALLURGY
s- BLOCK ELEMENTS
2. Ionic radii: Li+ < Na+ < K+ < Rb+ < Cs+
7. Colour of the flame Li- red, Na- Golden, K- Violet, Rb- Red, Cs- Blue, Ca-
Brick Red, Sr- Blood red, Ba- Apple green
9. Stability of hydrides: LiH > NaH > KH > RbH > CsH
10. Basic nature of hydroxides: [LiOH < NaOH < KOH < RbOH < CsOH]
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Class 18
BORON FAMILY
CARBON FAMILY
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Class 19
OXYGEN FAMILY
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Class 20
HALOGEN FAMILY
10. Acidic strength of halogen acids: HI > HBr > HCI > HF
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Class 21
HALOGEN FAMILY
19. Stability
-
of anions
-
of- oxyacids
-
of chlorine
CIO > CIO2 > CIO3 > CIO4
COORDINATION COMPOUNDS
1. Coordination number is the number of the nearest atoms or groups in the
coordination sphere.
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Class 22
ORGANIC CHEMISTRY
GOC
1. The order of decreasing electro negativity of hybrid orbital's is sp > sp2 >
sp3
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Class 23
ALKANES
ALKENES
1. In dehydration and dehydro halogenations the order for removal of
hydrogen is 30 > 20 > 10 (Saytzeff's rule)
2. The lower the hh (heat of dehydrogenation) the more stable the alkene is.
ALKYNES
1. All o and p-directing groups ring activating groups (expect X)
They are: -OH, -NH2, -X, R, -OR etc.
HALOGEN COMPOUNDS
1. The order of reactivity is
(a) RI > RBr > RCl > RF
(b) Ally halide > Alkyl halide > Vinyl halide
(c) Alkyl halide > Aryl halide
2. SN1 reaction: mainly 30 alkyl halides undergo this reaction and form
racemic mixture. SN1 is favoured by polar solvent and low concentration
of nuclephile.
2
3. SN2 reaction:Mainly 10 alkyl halides undergo this substitution. SN reaction
is preferred by non-polar solvents and high concentration of nucleophile.
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Class 24
ALCOHOLS
2. Oxidation of
10 alcohol aldehyde carboxylic acid
(with same (with same
no. of C atom) no. of C atom)
PHENOLS
CHCl3/OH
1. Phenol Salicyaldehyde
(Reimer- Tieman reaction)
CO2
2. Phenol Salicyclic acid (Kolbe reaction)
3. Acidity of phenols
(a) Increase by electron withdrawing substituents like
-NO2, -CN, -CHO, -COOH, -X, -NR 3
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Class 25
ETHERS
Al2O3
1. 2ROH R - O - R + H2 O
2500c
2. RONa + X R' ROR' + NaX
(Williamson's synthesis)
3. ROR + 2 H2SO4 2RHSO4 + H2O
(conc.)
dil. H2SO4
2ROH
4. ROR + H2O
CARBONYL COMPOUNDS
1. Formation of alcohols using RMgX
Hydrolysis
(a) Formaldehyde + RMgX 10 alcohol
Hydrolysis
(b) Aldehyde + RMgX 20 alcohol
Crossed- cannizzaro reaction gives alcohol with aryl group or bigger alkyl
group.
3. Aldol condensation:
Carbonylcompound+dil. alkali - hydroxycarbonyl compound
(With H-atom)
4. Benzoin condensation
ethanolic
Benzaldehyde Benzoin
NaCN
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Class 26
CARBOXYLIC ACIDS
NITROGEN COMPOUNDS
1. Order
0 0
of basicity:
0
(R = -CH3 or C2H5)
2 > 1 > 3 > NH3
2. Hofmann degradation
Br2/KOH
Amides 10 amine
Medium Product
Acidic Aniline
Basic Azoxy, Azo and finally hydrazobenzene
Neutral Phenyl hydroxyl amine
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Class 27
Test to differentiate:
10, 20, and 30 nitro compounds Test with HNO2 and KOH
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Class 28
IMPORTANT REAGENT
3. Cu or ZnO / 3000C
" " "
10 alc ald, 20 alc ketone, 30 alc alkene (exception)
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Class 29
SnCl2 / HCl
C6H5NO2 C6H5NH2
6H
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Class 30
IDENTIFICATION TESTS
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