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Alkenes
with H2 (hydrogenation) H2C=CH2 + H2 CH3CH3 Heat, Ni
Alkenes Polymerisation H H
H H
n C C C C
H X
H X
n
1
Edexcel AS Chemistry Unit 1+ Unit 2 equations
Group 7
Group 7 elements with H2O Cl2 + H2O HCl + HOCl
Group 7 elements with NaOH (Disproportionation)
- - -
In Cold Dilute Alkali: Cl2 + 2OH Cl + ClO + H2O
- - -
In Hot Conc. Alkali: 3Cl2 + 6OH ClO3 + 5Cl + 3H2O
2
Edexcel AS Chemistry Unit 1+ Unit 2 equations
- -
Group 7 Displacement Cl2(g) + 2Br (aq) Br2(aq) + 2Cl (aq) Green gas orange bromine solution
reactions - - -
Br2(g) + 2I (aq) I2(aq) + 2Br (aq) Green gas brown solution of I3
- -
(I2 + I I3 )
Halide ions with conc H2SO4 NaCl(s) + H2SO4 NaHSO4(s) + HCl(g) Steamy fumes (HCl)
Vigorous reaction
NaBr(s) + H2SO4 NaHSO4(s) + HBr(g) Steamy fumes (HBr)
2HBr(g) + H2SO4 Br2(g) + SO2(g) + 2H2O(l) Brown vapour (Br2)
Vigorous reaction
NaI(s) + H2SO4 NaHSO4(s) + HI(g) Steamy fumes (HI)
6HI(g) + H2SO4(l) 3I2(g) + S(s) + 4H2O(l) purple fumes (I2 vapour)
8HI(g) + H2SO4(l) 4I2(g) + H2S(s) + 4H2O(l) black solid (I2 solid)
yellow solid (S solid)
+ -
Test for halide ions Ag (aq) + Cl (aq) AgCl(s) White ppt
+ -
Ag (aq) + Br (aq) AgBr(s) Pale yellow ppt
+ -
Ag (aq) + I (aq) AgI(s) Yellow ppt
2- 2- -
Iodine titration 2S2O3 (aq) + I2(aq) S4O6 (aq) + 2I Sodium thiosulphate
(brown straw colour blue black colourless) decolorize iodine solution.
Solubility of Silver halides in concentrated / dilute ammonia solution
concentrated ammonia dilute ammonia Equation Effect of light
AgCl AgCl(s) + 2NH3(aq) The ppt darkens
+ -
[Ag(NH3)2] (aq) + Cl (aq) AgCl Ag + Cl2
AgBr AgBr(s) + 2NH3(aq) The ppt darkens
+ -
[Ag(NH3)2] (aq) + Br (aq) AgBr Ag + Br2
AgI -- The ppt darkens AgI Ag + I2
AgCl and AgBr cannot be distinguished by just dissolving in conc.NH3 as both of them dissolve in it. They can be
distinguished by addition of dilute ammonia.
Example
3
The student acidified about 2 cm of a solution of A (FeCl2) with dilute nitric acid in a test tube and then added
a few drops of aqueous silver nitrate solution. A white precipitate was formed.
-
(i) Give the formula of the anion present in A. Cl ion is present.
(ii) The test in (i) is usually followed by the addition of ammonia solution to test the solubility of the precipitate.
Explain why this is not a useful procedure in this case.
2+
The dissolving of white precipitate by concentrated ammonia is masked. Ammonia reacts with Fe to form iron(II)
2+ +
hydroxide. Fe (aq) + 2NH3(aq) Fe(OH)2(s) + 2NH4 (aq)
Colour of halogens
At r.t.p. Vapour form when it is heated In water In cyclohexane In KI
Cl2 Greenish Greenish yellow gas Pale green Pale yellow --
yellow gas (chlorine water)
Br2 Brown liquid Brown vapour Brown solution Orange --
(bromine water)
I2 Shiny black Purple vapour Brown solution Purple Brown solution
- -
solid (iodine solution) (I2(s)+I (aq)I3 (aq)
3
Edexcel AS Chemistry Unit 1+ Unit 2 equations
Organic Chemistry
Halogenoalkanes
Reagents Equations Mechanism Remarks
- -
with aqueous OH CH3CH2Br + NaOH CH3CH2OH + NaBr Nucleophilic OH acts as nucleophile and
[halogenoalkane alcohol] substitution attack +C of C Br
(Sn1 or Sn2)
- -
with OH dissolve CH3CH2Br + NaOH H2C=CH2 + NaBr + H2O Elimination OH acts as a base and
+
in ethanol [halogenoalkane alkene] accept H from CH3CH2Br
- - -
with CN CH3CH2Br + CN CH3CH2CN + Br Nucleophilic :CN acts as nucleophile
[halogenoalkane nitrile] substitution and attack +C of C Br
+
with aqueous CH3CH2Br + H2O + Ag CH3CH2OH + AgBr Fastest Ethanol is sometime added
silver nitrate H2O (in aqueous solution) is a weak nucleophile halogenoalkane to acts as solvent of
= Iodo halogenoalkane so that it
attack +C of C Br, forming alcohol. mixes better with AgNO3
C-I bond is solution. But rememeber
- +
Br is released and form ppt with Ag . weaker than that the OH of the ethanol is
C-Br and C-Cl not the nucleophile.
with NH3 CH3CH2Br + NH3 CH3CH2NH2 + HBr Nucleophilic :NH3 acts as nucleophile
[Conc NH3 / heat / [halogenoalkane amine] substitution and attack +C of C Br
closed vessel]
Preparation of halogenoalkanes
Chloroalkanes CH3CH2OH + PCl5 CH3CH2Cl + POCl3 + HCl PCl5(s) room temperature
from alcohols
Bromoalkanes (1) KBr + H2SO4 KHSO4 + HBr NaBr / 50% H2SO4 / Heat under reflux
from alcohols (2) CH3CH2OH + HBr CH3CH2Br + H2O Not conc H2SO4 / NaBr / heat as Br2 will form
Iodoalkanes (1) 2P + 3I2 2PI3 Moist red P / I2
from alcohols (2) 3CH3CH2OH + PI3 3CH3CH2I + H3PO3 Not conc H2SO4 / NaI / heat as I2 will form
Alcohols
Reagent Equations Conditions / observation
o
1 Alcohols Partial Oxidation CH3CH2OH + [O] CH3CHO + H2O Distil aldehyde product once it is
K2Cr2O7 / dil.H2SO4 formed
o
1 Alcohols Complete Oxidation CH3CH2OH + 2[O] CH3COOH + H2O Heat under reflux
K2Cr2O7 / dil.H2SO4 Orange to green
o
2 Alcohols Oxidation CH3CHOHCH3 + [O] CH3COCH3 + H2O Heat under reflux
K2Cr2O7 / dil.H2SO4 Orange to green
- +
Reaction with sodium CH3CH2OH + Na CH3CH2O Na + H2 Colourless effervescence
Sodium dissolves