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PROFESOR :
INTEGRANTES :
FECHA DE ENTREGA :
Lima, 2017
1) INTRODUCCIN
C2 H 4 0.5O2 C2 H 4O
C2 H 4 3O2 2CO2 2H 2O
Empleo de OE (en %)
Producto Mundo USA Eur. Japn
Occ.
Etilenglicol 61 57 44 59
1
Tensoactivos no inicos 16 11 28 17
Etanolaminas 6 11 9 4
teres gliclicos 4 7 7 5
Otras aplicaciones2 13 14 12 15
6
Uso total (10 Tm) 14,5 3,8 2,2 0,97
1. Polioxietilenos; 2. Poliuretanos, etilenglicoles superiores
Stream 1 2 3 4
Temp (C) 25.00 25.00 159.19 45.00
Pres (bar) 1.01325 50.00 3.00 2.70
Vapor mole fraction 1.00 1.00 1.00 1.00
Flowrate (kg/h) 500,000.00 20,000.00 500,000.00 500,000.00
Flowrate (kmol/h) 17,381.45 712.91 17,381.45 17,381.45
Component Flowrates (kmol/h)
Ethylene 712.91
Ethylene Oxide
Carbon Dioxide
Oxygen 3281.35 3281.35 3281.35
Nitrogen 14,100.09 14,100.09 14,100.09
Water
Stream 5 6 7 8
Temp (C) 206.11 45.00 195.21 -6.30
Pres (bar) 9.00 8.70 27.00 27.00
Vapor mole fraction 1.00 1.00 1.00 1.00
Flowrate (kg/h) 500,000.00 500,000.00 500,000.00 20,000.00
Flowrate (kmol/h) 17,381.45 17,381.45 17,381.45 712.91
Component Flowrates (kmol/h)
Ethylene 712.91
Ethylene Oxide
Carbon Dioxide
Oxygen 3281.35 3281.35 3281.35
Nitrogen 14,100.09 14,100.09 14,100.09
Water
Stream 9 10 11 12
Temp (C) 26.34 106.74 240.00 240.00
Pres (bar) 27.00 26.80 26.50 25.75
Vapor mole fraction 1.00 1.00 1.00 1.00
Flowrate (kg/h) 524,042.00 1,023,980.01 1,023,980.01 1,023,979.79
Flowrate (kmol/h) 18,260.29 35,639.59 35,639.59 35,539.42
Component Flowrates (kmol/h)
Ethylene 1047.95 1047.91 1047.91 838.67
Ethylene Oxide 6.48 6.47 6.47 206.79
Carbon Dioxide 31.71 31.71 31.71 49.56
Oxygen 3050.14 6331.12 6331.12 6204.19
Nitrogen 14,093.02 28,191.39 28,191.39 28,191.39
Water 30.99 30.98 30.98 48.82
Stream 13 14 15 16
Temp (C) 45.00 63.72 25.00 30.30
Pres (bar) 25.45 30.15 30.00 30.00
Vapor mole fraction 1.00 1.00 0.00 1.00
Flowrate (kg/h) 1,023,979.79 1,023,979.79 360,300.00 1,015,668.84
Flowrate (kmol/h) 35,539.42 35,539.42 20,000.00 35,357.65
Component Flowrates (kmol/h)
Ethylene 838.67 838.67 837.96
Ethylene Oxide 206.79 206.79 15.45
Carbon Dioxide 49.56 49.56 49.56
Oxygen 6204.19 6204.19 6202.74
Nitrogen 28,191.39 28,191.39 28,188.72
Water 48.82 48.82 20,000.00 63.24
Stream 17 18 19 20
Temp (C) 51.92 240.0000 239.9476 240.0000
Pres (bar) 30.00 29.7000 26.5000 25.7500
Vapor mole fraction 0.00 1.0000 1.0000 1.0000
Flowrate (kg/h) 368,611.02 1,015,668.84 1,015,668.84 1,015,668.84
Flowrate (kmol/h) 20,181.77 35,357.65 35357.66 35,277.47
Component Flowrates (kmol/h)
Ethylene 0.70 837.96 837.96 670.64
Ethylene Oxide 191.34 15.45 15.45 175.83
Carbon Dioxide 0.01 49.55 49.55 63.44
Oxygen 1.45 6202.74 6202.74 6101.72
Nitrogen 2.68 28,188.72 28,188.72 28,188.72
Water 19,985.58 63.24 63.24 77.13
Stream 21 22 23 24
Temp C 45.00 63.78 25.00 30.0851
Pres bar 25.45 30.15 30.00 30.00
Vapor mole fraction 1.00 1.00 0.00 1.00
Total kg/h 1,015,668.84 1,015,668.84 360,300.00 1,008,083.53
Total kmol/h 35,277.47 35,277.47 20,000.00 35094.76
Flowrates in kmol/h
Ethylene 670.64 670.64 670.08
Ethylene Oxide 175.83 175.83 12.96
Carbon Dioxide 63.44 63.44 63.43
Oxygen 6101.72 6101.72 6100.28
Nitrogen 28,188.72 28,188.72 28,186.04
Water 77.13 77.13 20,000.00 61.96
Stream 25 26 27 28
Temp (C) 52.26 30.09 30.09 29.48
Pres (bar) 30.00 30.00 30.00 27.00
Vapor mole fraction 0.00 1.00 1.00 1.00
Flowrate (kg/h) 367,885.27 504,042.00 504,042.00 504,042.00
Flowrate (kmol/h) 20,182.72 17,547.38 17,547.38 17,547.38
Component Flowrates (kmol/h)
Ethylene 0.57 335.04 335.04 335.04
Ethylene Oxide 162.88 6.48 6.48 6.48
Carbon Dioxide 0.01 31.71 31.71 31.71
Oxygen 1.43 3050.14 3050.14 3050.14
Nitrogen 2.68 14,093.02 14,093.02 14,093.02
Water 20,015.15 30.99 30.99 30.99
Stream 29 30 31 32
Temp (C) 52.08 45.00 45.02 86.40
Pres (bar) 30.00 29.70 10.00 10.00
Vapor mole fraction 0.00 0.00 0.00 0.00
Flowrate (kg/h) 73,6497.00 736,497.00 736,218.00 15,514.72
Flowrate (kmol/h) 40,364.48 40,364.48 40,354.95 352.39
Component Flowrates (kmol/h)
Ethylene 1.27 1.27 1.27
Ethylene Oxide 354.22 354.22 354.22 352.04
Carbon Dioxide 0.02 0.02 0.02
Oxygen 2.89 2.89 2.89
Nitrogen 5.35 5.35 5.35
Water 40,000.74 40,000.74 40,000.74 0.35
Stream 33 34
Temp (C) 182.30 182.30
Pres (bar) 10.50 10.50
Vapor mole fraction 0.00 1.00
Flowrate (kg/h) 720,703.00 278.78
Flowrate (kmol/h) 40,002.57 9.53
Component Flowrates (kmol/h)
Ethylene 1.27
Ethylene Oxide 2.18
Carbon Dioxide 0.02
Oxygen 2.88
Nitrogen 5.35
Water 40,000.39
C-701 E-701 C-703 R-701 E-704 C-704 T-701 E-705 R-702 E-706 C-705 T-702 E-707 T-703 E-708
air inter air EO reactor blower EO reactor EO reactor blower EO distillation EO condenser
compressor cooler compressor reactor cooler absorber pre-heater reactor cooler absorber pre-cooler column
C-702 E-702 E-703 E-709 V-701 P-701 A/B
air inter reactor reboiler reflux reflux
compressor cooler pre-heater drum pump
E-704 E-706
C-704 C-705 27
20 21
12 13
fuel
cw cw 22 gas
24 26
23
15
process
mps 14 mps light
water
gases
34
16
T-702
R-701 R-702
E-705
32
hps
E-709 ethylene
18 oxide
T-701 19 cw
25
FIC
T-703 V-701 LIC
bfw bfw
cw
17 29 30 31
28
P-701A/B
E-707
LIC
2 8 9
11
ethylene
hps 33
E-708
hps waste
cw cw water
1 3 4 5 6 7 10
Compressors
C-701 C-704
carbon steel carbon steel
power = 19 MW power = 5.5 MW
80% adiabatic efficiency 80% adiabatic efficiency
C-702 C-705
carbon steel carbon steel
power = 23 MW power = 5.5 MW
80% adiabatic efficiency 80% adiabatic efficiency
C-703
carbon steel
power = 21.5 MW
80% adiabatic efficiency
Reactors
R-701 R-702
carbon steel, shell-and-tube packed bed carbon steel, shell-and-tube packed bed
spherical catalyst pellet, 9 mm diameter spherical catalyst pellet, 9 mm diameter
void fraction = 0.4 void fraction = 0.4
V = 202 m3 V = 202 m3
10 m tall, 7.38 cm diameter tubes 10 m tall, 9.33 cm diameter tubes
4722 tubes 2954 tubes
100% filled with active catalyst 100% filled with active catalyst
Q = 33,101 MJ/h Q = 26,179 MJ/h
mps made in shell mps made in shell
Other Equipment
P-701 A/B V-701
stainless steel stainless steel
power = 4 kW (actual) V = 12.7 m3
73% efficient
3) DESCRIPCIN DEL PROCESO
C2 H 4 0.5 O2 C2 H 4O (1)
C2 H 4 3 O2 2CO2 2H 2O (2)
C2 H 4O 2.5 O2 2CO2 2H 2O (3)
GASES
AGUA
COMBUSTIBLES
ABSORBEDORR
GASES
ABSORBEDORR
LIGEROS
REACCION REACCION
ETILENO EO EO
COLUMNA EO
AIRE
EO
(MAYORIA OXIDO DE
OXIGENO) ETILENO
AGUA
C2 H 4 3 O2 2CO2 2H 2O (2)
C2 H 4 0.5 O2 C2 H 4 O
200 kmol/h 100kmol/h 200kmol/h
Stream 3 4
Temp (C) 240.00 240.00
Pres (bar) 26.50 25.75
Vapor mole fraction 1.00 1.00
Flowrate (kg/h) 1,023,980.01 1,023,979.79
Flowrate (kmol/h) 35,639.59 35,539.42
Component Flowrates (kmol/h)
Ethylene 1047.91 838.67
Ethylene Oxide 6.47 206.79
Carbon Dioxide 31.71 49.56
Oxygen 6331.12 6204.19
Nitrogen 28,191.39 28,191.39
Water 30.98 48.82
Stream 4 5 7 6
Temp C 63.78 25.00 30.0851 52.26
Pres bar 30.15 30.00 30.00 30.00
Vapor mole fraction 1.00 0.00 1.00 0.00
Total kg/h 1,015,668.84 360,300.00 1,008,083.53 367,885.27
Total kmol/h 35,277.47 20,000.00 35094.76 20,182.72
Flowrates in kmol/h
Ethylene 670.64 670.08 0.57
Ethylene Oxide 175.83 12.96 162.88
Carbon Dioxide 63.44 63.43 0.01
Oxygen 6101.72 6100.28 1.43
Nitrogen 28,188.72 28,186.04 2.68
Water 77.13 20,000.00 61.96 20,015.15
- BALANCE COLUMNA (T-702):
Stream 6 10 11
Temp (C) 45.02 86.40 182.30
Pres (bar) 10.00 10.00 10.50
Vapor mole fraction 0.00 0.00 0.00
Flowrate (kg/h) 736,218.00 15,514.72 720,703.00
Flowrate (kmol/h) 40,354.95 352.39 40,002.57
Component Flowrates (kmol/h)
Ethylene 1.27
Ethylene Oxide 354.22 352.04 2.18
Carbon Dioxide 0.02
Oxygen 2.89
Nitrogen 5.35
Water 40,000.74 0.35 40,000.39
R-701 R-702
bfwhps bfwhps
13,673 kg/h 10,813 kg/h
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