Solucionario

a) 25 C 298 K
+ +
0
=
0
= 94.1 92.07 (124.29 26.4)
0
= 35.48 /

0
=
0
= 94.3 86.8 (111.4 32.8)
0
= 36.9 /

0

=

36.9

= 1.987103 298

= 1.1595 1027

+ +
0
=
0
= 68.3 92.07 (124.29 + 0)
0
= 36.08 /

0
=
0
= 56.7 86.8 (111.4 + 0)
0
= 32.1 /

0

=

32.1

= 1.987103 298

= 3.4973 1023

b) 150 C 423 K
+ +

/ 2 2
A 6.983 7.017 9.251 9.701 16.6 10.07
B 2.44 4.05
C -3.88 -0.58
25 - 100 C 100 - 200 C 25 - 100 C 100 - 200 C
 =

cp cal/mol*K Reaccin
A -4.262 -3.846
B 1.61 1.61
C 3.3 3.3
25 - 100 C 100 - 150 C

1
= + 0 = + + 0 = + 1
0 0 1 1

4.262 + 1.61 103 + 3.3 105 2
= 298
1
35.48
1000
1.61106 2
1 = 4.262 103 + 2
3.3 102 1 33.17 Solo sirve entre 25 100 C

373
4.262 + 1.61 103 + 3.3 105 2
2 =
298 1000

3.846 + 1.61 103 + 3.3 105 2
+ 35.48
373 1000
1.61106 2
2 = 3.846 103 + 2
3.3 102 1 33.33 Solo sirve entre 100 200 C

1.61 106 4232

423 = 3.846 103 423 + 3.3 102 4231 33.33
2
373 = 35.59 /