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TRACE ANALYSIS
Certified Reference Materials and High Purity
Reagents for Elemental Analysis
Zuzana Antalov
May 16, 2017
Cluj, Romania
Inorganic Trace Analysis
High-purity reagents and standards
manufactured to clear, guaranteed specifications
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CALIBRATION
Certified Reference Materials
TraceCERT
TraceCERT CRMs are high accuracy standards for instrument calibration and process
validation
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Certified Reference Materials
Certification process
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Certified Reference Materials
www.sigmaaldrich.com/tracecert
Inorganics for Spectroscopy
Custom standard for AAS and ICP using our online custom
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solutions standards platform
Inorganics for Spectroscopy
Multi-element mixes for ICP
Mix 2 for ICP (17 elements), # 41135 Alkaline Earth (100mg/L, #67288)
Mix 3 for ICP (16 elements), # 78334 Rare Earth (50mg/L, #67349)
Metalloid and non-metals (100mg/L,#55263)
A detailed and comprehensive certificate of up to four pages, in accordance with ISO Guide 31
Example:
ICP Platinum
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TraceCERT
Certification and Comprehensive Documentation
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TRACECERT CRMS
FOR IC
Certified Reference Materials
For Ion Chromatography www.sigmaaldrich.com/tracecert
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Inorganics for Spectroscopy
Cant find exactly what you need?
TraceCERT Custom
Standards are:
Wit High accuracy and
reliability of certified
concentrations
Traceable to NIST
standards and other
accepted references
Certified according to
ISO/ IEN 17025 and ISO
TraceCERT Custom Standard Solutions Guide 34 and supplied
with a CoA according to
ISO Guide 31
Elemental AAS, ICP Anions and Cations
Packaged specially to
for Ion Chromatography ensure maximum shelf life
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SAMPLING AND
SAMPLE
PREPARATION
HIGH PURITY
ACIDS & BASES
AND SALTS
High Purity Acids and Bases
Suprapur acids and bases | Ultrapur acids
Advantages
Choose your purity grade for instrumental trace analysis
Suprapur acids filled in borosilicate glass or extra pure HDPE material
Ultrapur acids filled in PFA bottles
Certificate of Analysis gives an extensive impurity profile
Quality grades
for your
individual needs
High Purity Acids and Bases
Different grades to meet your needs
Ultrapur acids
High purity acids, hydrogen peroxide
Highly sophisticated instrumental ultra-trace analysis, e.g. ICP-MS
Specified parameters in ppt range
Ultrapur acids are preferred for ultra-trace analysis in the pg/g (ppt)
range
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High Purity Acids and Bases
Suprapur acids and bases | Ultrapur acids
Suprapur acids and bases are suitable for trace Ultrapur acids are preferred for ultra-
analysis in the ng/g (ppb) range trace analysis in the pg/g (ppt) range
Suprapur acids are filled in borosilicate or extra pure PE bottles. Ultrapur reagents are produced by subboiling
The material minimizes any elemental impurity of the acid, so the distillation. The slowly distilled reagents subsequently
specification of the unopened bottle is kept during the minimum have the lowest possible trace-impurities. Ultrapur
shelf life. The bottles are cleaned and pre-conditioned before filling. reagents are exclusively filled in pre-conditioned PFA
Quality control is done after filling. This gives you the assurance (fluorpolymer) bottles. This material meets the
that the certified batch values are those values of the filled acid. highest demands of all users for ultratrace
Suprapur reagents are packed in a stable outer-box. instrumental analysis, e.g. ICP-MS. Ultrapur reagents
Hydrogen peroxide Suprapur is packed in a black bottle to protect are packed in a stable
it against light. The bottle is made of extra pure PE material to avoid outer-box.
any contamination. To make it more safe for you: hydrogen peroxide
bottles are closed with the SafetyCap. The SafetyCap with the PTFE
membrane releases the pressure, but avoids any contamination.
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High Purity Acids and Bases
Suprapur acids and bases | Ultrapur acids in a nutshell
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High Purity Acids and Bases
CoA
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High purity acids and bases - Suprapur
Product Range
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High purity acids and bases - Ultrapur
Product Range
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High Purity Acids and Bases
HDPE dosage bottle for hydrofluoric acid
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High Purity Acids and Bases
SafetyCap the intelligent closure
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AAS Auxiliaries
L-(+)-Ascorbic acid GR
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High purity salts - Suprapur
Improved flowability and chemical purity
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Inorganic Trace Analysis
Certified Eluent Concentrates for IC
The certified eluent concentrates for ion chromatography are traceable by potentiometric titration to NIST
Standard Reference Materials and certified in accordance with ISO Guide 31. All details about exact
content, uncertainty, traceability and expiry date are described in the certificate.
Single Concentrates
Binary Concentrates
the selection of well-characterized eluent concentrates, a novel group of binary concentrates (20-fold
concentration)
The key features are
1. Application tested using Metrohms Metrosep columns
2. Certificate according to ISO Guide 31
3. High-purity starting materials
4. All details about the exact content, specifications, and expiry date are described in the certificate
5. Packaging: 1 L and 2.5 L HDPE bottles with 45 mm screw thread
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Inorganic Trace Analysis
Water for IC
Specification
Organic traces 10 g/kg each: acetate, formiate, glycolate, oxalate
Cation traces
5 g/kg each: Al, Ba, Bi, Cd, Co, Cr, Cu, Fe, Li, Mg, Mn, Mo, Ni, Pb, Sr, Zn
10g/kg each: Ca, K, Na, NH4+
1 g/kg each: bromide, bromate, chlorate, chloride, chlorite, fluoride, iodide, nitrate, nitrite,
Anion traces
phosphate, sulfate
Conductivity 2 S/cm
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METHOD DEVELOPMENT
AND VALIDATION
Inorganic Trace Analysis
Matrix CRMs from the European Commissions Joint Research Centre
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Inorganic Trace Analysis
Qualification Kit for IC
The kit is intended for testing detection linearity, injector precision and injector carry-over
The 50 mg/kg standard is used for repeatability tests (injector precision) and the maximum
carry-over during injection is verified with the 1000 mg/kg standard.
The standards 5 to 100 mg/kg are used to prove the detector linearity
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Inorganic Trace Analysis
Proficiency Testing Process and Products