1

Case Name: IPA ACETATE.hsc

2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: 1. Column In Property Package: NRTL - Ideal
8
9
10
CONDITIONS
11 Overall Liquid Phase
12 Vapour / Phase Fraction 0.0000 1.0000
13 Temperature: (C) 45.00 * 45.00
14 Pressure: (bar_g) 0.5000 * 0.5000
15 Molar Flow (kgmole/h) 39.82 39.82
16 Mass Flow (kg/h) 4000 * 4000
17 Std Ideal Liq Vol Flow (m3/h) 4.537 4.537
18 Molar Enthalpy (kcal/kgmole) -1.217e+005 -1.217e+005
19 Molar Entropy (kJ/kgmole-C) -70.57 -70.57
20 Heat Flow (kcal/h) -4.848e+006 -4.848e+006
21 Liq Vol Flow @Std Cond (m3/h) 4.534 * 4.534
22
23
PROPERTIES
24 Overall Liquid Phase
25 Molecular Weight 100.5 100.5
26 Molar Density (kgmole/m3) 8.446 8.446
27 Mass Density (kg/m3) 848.4 848.4
28 Act. Volume Flow (m3/h) 4.714 4.714
29 Mass Enthalpy (kcal/kg) -1212 -1212
30 Mass Entropy (kJ/kg-C) -0.7025 -0.7025
31 Heat Capacity (kJ/kgmole-C) 194.7 194.7
32 Mass Heat Capacity (kJ/kg-C) 1.939 1.939
33 LHV Molar Basis (Std) (kcal/kgmole) 6.226e+005 6.226e+005
34 HHV Molar Basis (Std) (kcal/kgmole) 6.708e+005 6.708e+005
35 HHV Mass Basis (Std) (kcal/kg) 6678 6678
36 CO2 Loading --- ---
37 CO2 App ML Con (kgmole/m3) --- ---
38 CO2 App WT Con (kgmol/kg) --- ---
39 LHV Mass Basis (Std) (kcal/kg) 6198 6198
40 Phase Fraction [Vol. Basis] 0.0000 1.000
41 Phase Fraction [Mass Basis] 0.0000 1.000
42 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
43 Mass Exergy (kcal/kg) -7.238 ---
44 Partial Pressure of CO2 (bar_g) -1.013 ---
45 Cost Based on Flow (Cost/s) 0.0000 0.0000
46 Act. Gas Flow (ACT_m3/h) --- ---
47 Avg. Liq. Density (kgmole/m3) 8.778 8.778
48 Specific Heat (kJ/kgmole-C) 194.7 194.7
49 Std. Gas Flow (STD_m3/h) 941.5 941.5
50 Std. Ideal Liq. Mass Density (kg/m3) 881.7 881.7
51 Act. Liq. Flow (m3/s) 1.310e-003 1.310e-003
52 Z Factor 6.773e-003 6.773e-003
53 Watson K 9.814 9.814
54 User Property --- ---
55 Partial Pressure of H2S (bar_g) -1.013 ---
56 Cp/(Cp - R) 1.045 1.045
57 Cp/Cv 1.327 1.327
58 Heat of Vap. (kcal/kgmole) 7579 ---
59 Kinematic Viscosity (cSt) 0.5014 0.5014
60 Liq. Mass Density (Std. Cond) (kg/m3) 882.2 882.2
61 Liq. Vol. Flow (Std. Cond) (m3/h) 4.534 4.534
62 Liquid Fraction 1.000 1.000
63 Molar Volume (m3/kgmole) 0.1184 0.1184
64 Mass Heat of Vap. (kcal/kg) 75.45 ---
65 Phase Fraction [Molar Basis] 0.0000 1.0000
66 Surface Tension (dyne/cm) 32.90 32.90
67 Thermal Conductivity (W/m-K) 0.1351 0.1351
68 Viscosity (cP) 0.4254 0.4254
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 1 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: 1. Column In (continued) Property Package: NRTL - Ideal
8
9
10
PROPERTIES
11 Overall Liquid Phase
12 Cv (Semi-Ideal) (kJ/kgmole-C) 186.4 186.4
13 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.856 1.856
14 Cv (kJ/kgmole-C) 146.7 146.7
15 Mass Cv (kJ/kg-C) 1.461 1.461
16 Cv (Ent. Method) (kJ/kgmole-C) 1.589e+004 1.589e+004
17 Mass Cv (Ent. Method) (kJ/kg-C) 158.2 158.2
18 Cp/Cv (Ent. Method) 1.226e-002 1.226e-002
19 Reid VP at 37.8 C (bar_g) -0.8708 -0.8708
20 True VP at 37.8 C (bar_g) -0.8723 -0.8723
21 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 4.534 4.534
22 Viscosity Index -8.414 ---
23
24
COMPOSITION
25
26
Overall Phase Vapour Fraction 0.0000

27 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
28 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
29 i-P-Acetate 39.0241 * 0.9800 * 3985.6526 * 0.9964 * 4.5222 * 0.9968 *
30 H2O 0.7964 * 0.0200 * 14.3474 * 0.0036 * 0.0144 * 0.0032 *
31 Propene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
32 Total 39.8206 1.0000 4000.0000 1.0000 4.5366 1.0000
33
34
Liquid Phase Phase Fraction 1.000

35 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
36 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
37 i-P-Acetate 39.0241 0.9800 3985.6526 0.9964 4.5222 0.9968
38 H2O 0.7964 0.0200 14.3474 0.0036 0.0144 0.0032
39 Propene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 Total 39.8206 1.0000 4000.0000 1.0000 4.5366 1.0000
41
42
K VALUE
43 COMPONENTS MIXED LIGHT HEAVY
44 i-P-Acetate 0.0000 0.0000 ---
45 H2O 0.0000 0.0000 ---
46 Propene --- --- ---
47
48
UNIT OPERATIONS
49 FEED TO PRODUCT FROM LOGICAL CONNECTION
50
51
52
UTILITIES
53 ( No utilities reference this stream )
54
55
PROCESS UTILITY
56
57
58
DYNAMICS
59 Pressure Specification (Active): 0.5000 bar_g *
60 Flow Specification (Active) Molar: 39.82 kgmole/h Mass: 4000 kg/h * Std Ideal Liq Volume: 4.537 m3/h
61
62
User Variables
63
64
NOTES
65
66
67
Description
68
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 2 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: 2 Pure IPA Col Btm Property Package: NRTL - Ideal
8
9
10
CONDITIONS
11 Overall Liquid Phase
12 Vapour / Phase Fraction 0.0000 1.0000
13 Temperature: (C) 95.00 * 95.00
14 Pressure: (bar_g) 0.5000 * 0.5000
15 Molar Flow (kgmole/h) 19.58 19.58
16 Mass Flow (kg/h) 2000 * 2000
17 Std Ideal Liq Vol Flow (m3/h) 2.269 2.269
18 Molar Enthalpy (kcal/kgmole) -1.204e+005 -1.204e+005
19 Molar Entropy (kJ/kgmole-C) -28.43 -28.43
20 Heat Flow (kcal/h) -2.357e+006 -2.357e+006
21 Liq Vol Flow @Std Cond (m3/h) 2.269 * 2.269
22
23
PROPERTIES
24 Overall Liquid Phase
25 Molecular Weight 102.1 102.1
26 Molar Density (kgmole/m3) 7.705 7.705
27 Mass Density (kg/m3) 787.0 787.0
28 Act. Volume Flow (m3/h) 2.541 2.541
29 Mass Enthalpy (kcal/kg) -1178 -1178
30 Mass Entropy (kJ/kg-C) -0.2783 -0.2783
31 Heat Capacity (kJ/kgmole-C) 218.8 218.8
32 Mass Heat Capacity (kJ/kg-C) 2.142 2.142
33 LHV Molar Basis (Std) (kcal/kgmole) 6.353e+005 6.353e+005
34 HHV Molar Basis (Std) (kcal/kgmole) 6.843e+005 6.843e+005
35 HHV Mass Basis (Std) (kcal/kg) 6700 6700
36 CO2 Loading --- ---
37 CO2 App ML Con (kgmole/m3) --- ---
38 CO2 App WT Con (kgmol/kg) --- ---
39 LHV Mass Basis (Std) (kcal/kg) 6220 6220
40 Phase Fraction [Vol. Basis] 0.0000 1.000
41 Phase Fraction [Mass Basis] 0.0000 1.000
42 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
43 Mass Exergy (kcal/kg) -14.09 ---
44 Partial Pressure of CO2 (bar_g) -1.013 ---
45 Cost Based on Flow (Cost/s) 0.0000 0.0000
46 Act. Gas Flow (ACT_m3/h) --- ---
47 Avg. Liq. Density (kgmole/m3) 8.629 8.629
48 Specific Heat (kJ/kgmole-C) 218.8 218.8
49 Std. Gas Flow (STD_m3/h) 463.0 463.0
50 Std. Ideal Liq. Mass Density (kg/m3) 881.3 881.3
51 Act. Liq. Flow (m3/s) 7.060e-004 7.060e-004
52 Z Factor 6.416e-003 6.416e-003
53 Watson K 9.814 9.814
54 User Property --- ---
55 Partial Pressure of H2S (bar_g) -1.013 ---
56 Cp/(Cp - R) 1.040 1.040
57 Cp/Cv 1.329 1.329
58 Heat of Vap. (kcal/kgmole) 7536 ---
59 Kinematic Viscosity (cSt) 0.3222 0.3222
60 Liq. Mass Density (Std. Cond) (kg/m3) 881.4 881.4
61 Liq. Vol. Flow (Std. Cond) (m3/h) 2.269 2.269
62 Liquid Fraction 1.000 1.000
63 Molar Volume (m3/kgmole) 0.1298 0.1298
64 Mass Heat of Vap. (kcal/kg) 73.79 ---
65 Phase Fraction [Molar Basis] 0.0000 1.0000
66 Surface Tension (dyne/cm) 23.48 23.48
67 Thermal Conductivity (W/m-K) 0.1146 0.1146
68 Viscosity (cP) 0.2535 0.2535
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 3 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: 2 Pure IPA Col Btm (continued)
Property Package: NRTL - Ideal
8
9
10
PROPERTIES
11 Overall Liquid Phase
12 Cv (Semi-Ideal) (kJ/kgmole-C) 210.5 210.5
13 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.061 2.061
14 Cv (kJ/kgmole-C) 164.6 164.6
15 Mass Cv (kJ/kg-C) 1.612 1.612
16 Cv (Ent. Method) (kJ/kgmole-C) 1.408e+004 1.408e+004
17 Mass Cv (Ent. Method) (kJ/kg-C) 137.9 137.9
18 Cp/Cv (Ent. Method) 1.554e-002 1.554e-002
19 Reid VP at 37.8 C (bar_g) -0.8708 -0.8708
20 True VP at 37.8 C (bar_g) -0.8708 -0.8708
21 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 2.269 2.269
22 Viscosity Index -20.43 ---
23
24
COMPOSITION
25
26
Overall Phase Vapour Fraction 0.0000

27 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
28 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
29 i-P-Acetate 19.5823 * 1.0000 * 2000.0000 * 1.0000 * 2.2693 * 1.0000 *
30 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 Propene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
32 Total 19.5823 1.0000 2000.0000 1.0000 2.2693 1.0000
33
34
Liquid Phase Phase Fraction 1.000

35 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
36 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
37 i-P-Acetate 19.5823 1.0000 2000.0000 1.0000 2.2693 1.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 Propene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 Total 19.5823 1.0000 2000.0000 1.0000 2.2693 1.0000
41
42
K VALUE
43 COMPONENTS MIXED LIGHT HEAVY
44 i-P-Acetate 0.0000 0.0000 ---
45 H2O --- --- ---
46 Propene --- --- ---
47
48
UNIT OPERATIONS
49 FEED TO PRODUCT FROM LOGICAL CONNECTION
50
51
52
UTILITIES
53 ( No utilities reference this stream )
54
55
PROCESS UTILITY
56
57
58
DYNAMICS
59 Pressure Specification (Active): 0.5000 bar_g *
60 Flow Specification (Active) Molar: 19.58 kgmole/h Mass: 2000 kg/h * Std Ideal Liq Volume: 2.269 m3/h
61
62
User Variables
63
64
NOTES
65
66
67
Description
68
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 4 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: 3. Column O/H Property Package: NRTL - Ideal
8
9
10
CONDITIONS
11 Overall Vapour Phase Liquid Phase
12 Vapour / Phase Fraction 0.0178 0.0178 0.9822
13 Temperature: (C) 84.00 * 84.00 84.00
14 Pressure: (bar_g) 0.2500 * 0.2500 0.2500
15 Molar Flow (kgmole/h) 18.33 0.3254 18.00
16 Mass Flow (kg/h) 1500 * 22.67 1477
17 Std Ideal Liq Vol Flow (m3/h) 1.704 2.994e-002 1.674
18 Molar Enthalpy (kcal/kgmole) -1.062e+005 -5.997e+004 -1.070e+005
19 Molar Entropy (kJ/kgmole-C) -16.58 102.6 -18.73
20 Heat Flow (kcal/h) -1.945e+006 -1.951e+004 -1.926e+006
21 Liq Vol Flow @Std Cond (m3/h) 1.685 * 2.916e-002 1.656
22
23
PROPERTIES
24 Overall Vapour Phase Liquid Phase
25 Molecular Weight 81.85 69.67 82.08
26 Molar Density (kgmole/m3) 1.935 4.254e-002 9.889
27 Mass Density (kg/m3) 158.4 2.964 811.6
28 Act. Volume Flow (m3/h) 9.470 7.650 1.820
29 Mass Enthalpy (kcal/kg) -1297 -860.7 -1304
30 Mass Entropy (kJ/kg-C) -0.2025 1.473 -0.2282
31 Heat Capacity (kJ/kgmole-C) 179.3 110.2 180.6
32 Mass Heat Capacity (kJ/kg-C) 2.191 1.581 2.200
33 LHV Molar Basis (Std) (kcal/kgmole) 4.876e+005 5.014e+005 4.873e+005
34 HHV Molar Basis (Std) (kcal/kgmole) 5.273e+005 5.386e+005 5.271e+005
35 HHV Mass Basis (Std) (kcal/kg) 6442 7732 6422
36 CO2 Loading --- --- ---
37 CO2 App ML Con (kgmole/m3) --- --- ---
38 CO2 App WT Con (kgmol/kg) --- --- ---
39 LHV Mass Basis (Std) (kcal/kg) 5956 7197 5937
40 Phase Fraction [Vol. Basis] 1.757e-002 1.757e-002 0.9824
41 Phase Fraction [Mass Basis] 1.511e-002 1.511e-002 0.9849
42 Phase Fraction [Act. Vol. Basis] 0.8078 0.8078 0.1922
43 Mass Exergy (kcal/kg) -10.91 --- ---
44 Partial Pressure of CO2 (bar_g) -1.013 --- ---
45 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
46 Act. Gas Flow (ACT_m3/h) 7.650 7.650 ---
47 Avg. Liq. Density (kgmole/m3) 10.76 10.87 10.75
48 Specific Heat (kJ/kgmole-C) 179.3 110.2 180.6
49 Std. Gas Flow (STD_m3/h) 433.3 7.694 425.6
50 Std. Ideal Liq. Mass Density (kg/m3) 880.4 757.3 882.6
51 Act. Liq. Flow (m3/s) 5.056e-004 --- 5.056e-004
52 Z Factor --- 1.000 4.302e-003
53 Watson K 9.857 10.85 9.841
54 User Property --- --- ---
55 Partial Pressure of H2S (bar_g) -1.013 --- ---
56 Cp/(Cp - R) 1.049 1.082 1.048
57 Cp/Cv 1.001 1.082 1.048
58 Heat of Vap. (kcal/kgmole) 8990 --- ---
59 Kinematic Viscosity (cSt) --- 3.134 0.3707
60 Liq. Mass Density (Std. Cond) (kg/m3) 890.0 777.6 891.9
61 Liq. Vol. Flow (Std. Cond) (m3/h) 1.685 2.916e-002 1.656
62 Liquid Fraction 0.9822 0.0000 1.000
63 Molar Volume (m3/kgmole) 0.5168 23.51 0.1011
64 Mass Heat of Vap. (kcal/kg) 109.8 --- ---
65 Phase Fraction [Molar Basis] 0.0178 0.0178 0.9822
66 Surface Tension (dyne/cm) 33.36 --- 33.36
67 Thermal Conductivity (W/m-K) --- 1.855e-002 0.1933
68 Viscosity (cP) --- 9.288e-003 0.3008
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 5 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: 3. Column O/H (continued) Property Package: NRTL - Ideal
8
9
10
PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Cv (Semi-Ideal) (kJ/kgmole-C) 171.0 101.8 172.2
13 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.089 1.462 2.099
14 Cv (kJ/kgmole-C) 179.1 101.8 172.2
15 Mass Cv (kJ/kg-C) 2.188 1.462 2.099
16 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
17 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
18 Cp/Cv (Ent. Method) --- --- ---
19 Reid VP at 37.8 C (bar_g) -0.5655 5.166 -0.6731
20 True VP at 37.8 C (bar_g) -0.5873 5.299 -0.6937
21 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 1.686 2.916e-002 1.656
22 Viscosity Index -16.05 --- ---
23
24
COMPOSITION
25
26
Overall Phase Vapour Fraction 0.0178

27 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
28 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
29 i-P-Acetate 13.8055 * 0.7534 * 1410.0000 * 0.9400 * 1.5998 * 0.9390 *
30 H2O 4.1632 * 0.2272 * 75.0000 * 0.0500 * 0.0752 * 0.0441 *
31 Propene 0.3565 * 0.0195 * 15.0000 * 0.0100 * 0.0288 * 0.0169 *
32 Total 18.3252 1.0000 1500.0000 1.0000 1.7038 1.0000
33
34
Vapour Phase Phase Fraction 1.776e-002

35 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
36 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
37 i-P-Acetate 0.1627 0.4998 16.6127 0.7328 0.0188 0.6297
38 H2O 0.0329 0.1010 0.5920 0.0261 0.0006 0.0198
39 Propene 0.1299 0.3992 5.4663 0.2411 0.0105 0.3505
40 Total 0.3254 1.0000 22.6710 1.0000 0.0299 1.0000
41
42
Liquid Phase Phase Fraction 0.9822

43 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
44 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
45 i-P-Acetate 13.6429 0.7579 1393.3873 0.9432 1.5810 0.9445
46 H2O 4.1303 0.2295 74.4080 0.0504 0.0746 0.0445
47 Propene 0.2266 0.0126 9.5337 0.0065 0.0183 0.0109
48 Total 17.9997 1.0000 1477.3290 1.0000 1.6738 1.0000
49
50
K VALUE
51 COMPONENTS MIXED LIGHT HEAVY
52 i-P-Acetate 0.6595 0.6595 ---
53 H2O 0.4401 0.4401 ---
54 Propene 31.71 31.71 ---
55
56
UNIT OPERATIONS
57 FEED TO PRODUCT FROM LOGICAL CONNECTION
58
59
60
UTILITIES
61 ( No utilities reference this stream )
62
63
PROCESS UTILITY
64
65
66
DYNAMICS
67 Pressure Specification (Active): 0.2500 bar_g *
68 Flow Specification (Active) Molar: 18.33 kgmole/h Mass: 1500 kg/h * Std Ideal Liq Volume: 1.704 m3/h
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 6 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: 3. Column O/H (continued) Property Package: NRTL - Ideal
8
9
10
User Variables
11
12
NOTES
13
14
15
Description
16
17
Fluid Package: Basis-1
18 Material Stream: Safety Valve@0.4 barg & VF 1Property Package: NRTL - Ideal
19
20
21
CONDITIONS
22 Overall Vapour Phase Liquid Phase
23 Vapour / Phase Fraction 1.0000 * 1.0000 0.0000
24 Temperature: (C) 103.0 103.0 103.0
25 Pressure: (bar_g) 0.4000 * 0.4000 0.4000
26 Molar Flow (kgmole/h) 23.21 23.21 0.0000
27 Mass Flow (kg/h) 1900 * 1900 0.0000
28 Std Ideal Liq Vol Flow (m3/h) 2.158 2.158 0.0000
29 Molar Enthalpy (kcal/kgmole) -9.749e+004 -9.749e+004 -1.047e+005
30 Molar Entropy (kJ/kgmole-C) 82.52 82.52 -4.074
31 Heat Flow (kcal/h) -2.263e+006 -2.263e+006 0.0000
32 Liq Vol Flow @Std Cond (m3/h) 2.135 * 2.135 0.0000
33
34
PROPERTIES
35 Overall Vapour Phase Liquid Phase
36 Molecular Weight 81.85 81.85 78.12
37 Molar Density (kgmole/m3) 4.519e-002 4.519e-002 10.18
38 Mass Density (kg/m3) 3.699 3.699 795.4
39 Act. Volume Flow (m3/h) 513.6 513.6 0.0000
40 Mass Enthalpy (kcal/kg) -1191 -1191 -1340
41 Mass Entropy (kJ/kg-C) 1.008 1.008 -5.216e-002
42 Heat Capacity (kJ/kgmole-C) 131.2 131.2 180.5
43 Mass Heat Capacity (kJ/kg-C) 1.603 1.603 2.310
44 LHV Molar Basis (Std) (kcal/kgmole) 4.876e+005 4.876e+005 4.540e+005
45 HHV Molar Basis (Std) (kcal/kgmole) 5.273e+005 5.273e+005 4.918e+005
46 HHV Mass Basis (Std) (kcal/kg) 6442 6442 6296
47 CO2 Loading --- --- ---
48 CO2 App ML Con (kgmole/m3) --- --- ---
49 CO2 App WT Con (kgmol/kg) --- --- ---
50 LHV Mass Basis (Std) (kcal/kg) 5956 5956 5812
51 Phase Fraction [Vol. Basis] 1.000 1.000 ---
52 Phase Fraction [Mass Basis] 1.000 1.000 0.0000
53 Phase Fraction [Act. Vol. Basis] 1.000 1.000 0.0000
54 Mass Exergy (kcal/kg) 8.822 --- ---
55 Partial Pressure of CO2 (bar_g) -1.013 --- ---
56 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
57 Act. Gas Flow (ACT_m3/h) 513.6 513.6 ---
58 Avg. Liq. Density (kgmole/m3) 10.76 10.76 11.37
59 Specific Heat (kJ/kgmole-C) 131.2 131.2 180.5
60 Std. Gas Flow (STD_m3/h) 548.8 548.8 0.0000
61 Std. Ideal Liq. Mass Density (kg/m3) 880.4 880.4 888.0
62 Act. Liq. Flow (m3/s) --- --- ---
63 Z Factor --- 1.000 4.438e-003
64 Watson K 9.857 9.857 9.815
65 User Property --- --- ---
66 Partial Pressure of H2S (bar_g) -1.013 --- ---
67 Cp/(Cp - R) 1.068 1.068 1.048
68 Cp/Cv 1.068 1.068 1.048
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 7 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: Safety Valve@0.4 barg & VF 1Property
(continued)
Package: NRTL - Ideal
8
9
10
PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Heat of Vap. (kcal/kgmole) 8921 --- ---
13 Kinematic Viscosity (cSt) 2.469 2.469 0.3249
14 Liq. Mass Density (Std. Cond) (kg/m3) 890.0 890.0 899.5
15 Liq. Vol. Flow (Std. Cond) (m3/h) 2.135 2.135 0.0000
16 Liquid Fraction 0.0000 0.0000 1.000
17 Molar Volume (m3/kgmole) 22.13 22.13 9.821e-002
18 Mass Heat of Vap. (kcal/kg) 109.0 --- ---
19 Phase Fraction [Molar Basis] 1.0000 1.0000 0.0000
20 Surface Tension (dyne/cm) --- --- 32.37
21 Thermal Conductivity (W/m-K) 1.813e-002 1.813e-002 0.2117
22 Viscosity (cP) 9.133e-003 9.133e-003 0.2584
23 Cv (Semi-Ideal) (kJ/kgmole-C) 122.9 122.9 172.1
24 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.501 1.501 2.204
25 Cv (kJ/kgmole-C) 122.9 122.9 172.1
26 Mass Cv (kJ/kg-C) 1.501 1.501 2.204
27 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
28 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
29 Cp/Cv (Ent. Method) --- --- ---
30 Reid VP at 37.8 C (bar_g) -0.5655 -0.5655 -0.8625
31 True VP at 37.8 C (bar_g) -0.5873 -0.5873 -0.8851
32 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 2.135 2.135 0.0000
33 Viscosity Index -21.30 --- ---
34
35
COMPOSITION
36
37
Overall Phase Vapour Fraction 1.0000 *

38 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
39 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
40 i-P-Acetate 17.4870 * 0.7534 * 1786.0000 * 0.9400 * 2.0265 * 0.9390 *
41 H2O 5.2734 * 0.2272 * 95.0000 * 0.0500 * 0.0952 * 0.0441 *
42 Propene 0.4515 * 0.0195 * 19.0000 * 0.0100 * 0.0365 * 0.0169 *
43 Total 23.2119 1.0000 1900.0000 1.0000 2.1581 1.0000
44
45
Vapour Phase Phase Fraction 1.000

46 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
47 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
48 i-P-Acetate 17.4870 0.7534 1786.0000 0.9400 2.0265 0.9390
49 H2O 5.2734 0.2272 95.0000 0.0500 0.0952 0.0441
50 Propene 0.4515 0.0195 19.0000 0.0100 0.0365 0.0169
51 Total 23.2119 1.0000 1900.0000 1.0000 2.1581 1.0000
52
53
Liquid Phase Phase Fraction 0.0000

54 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
55 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
56 i-P-Acetate 0.0000 0.7143 0.0000 0.9340 0.0000 0.9410
57 H2O 0.0000 0.2852 0.0000 0.0658 0.0000 0.0585
58 Propene 0.0000 0.0005 0.0000 0.0003 0.0000 0.0005
59 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
60
61
K VALUE
62 COMPONENTS MIXED LIGHT HEAVY
63 i-P-Acetate 1.055 1.055 ---
64 H2O 0.7967 0.7967 ---
65 Propene 39.51 39.51 ---
66
67
68
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 8 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: Safety Valve@0.4 barg & VF 1Property
(continued)
Package: NRTL - Ideal
8
9
10
UNIT OPERATIONS
11 FEED TO PRODUCT FROM LOGICAL CONNECTION
12
13
14
UTILITIES
15 ( No utilities reference this stream )
16
17
PROCESS UTILITY
18
19
20
DYNAMICS
21 Pressure Specification (Active): 0.4000 bar_g *
22 Flow Specification (Active) Molar: 23.21 kgmole/h Mass: 1900 kg/h * Std Ideal Liq Volume: 2.158 m3/h
23
24
User Variables
25
26
NOTES
27
28
29
Description
30
31
Fluid Package: Basis-1
32 Material Stream: Safety Valve@0.4 barg-84 C Property Package: NRTL - Ideal
33
34
35
CONDITIONS
36 Overall Vapour Phase Liquid Phase
37 Vapour / Phase Fraction 0.0068 0.0068 0.9932
38 Temperature: (C) 84.00 * 84.00 84.00
39 Pressure: (bar_g) 0.4000 * 0.4000 0.4000
40 Molar Flow (kgmole/h) 23.21 0.1579 23.05
41 Mass Flow (kg/h) 1900 * 10.53 1889
42 Std Ideal Liq Vol Flow (m3/h) 2.158 1.433e-002 2.144
43 Molar Enthalpy (kcal/kgmole) -1.062e+005 -5.277e+004 -1.066e+005
44 Molar Entropy (kJ/kgmole-C) -16.59 106.4 -17.43
45 Heat Flow (kcal/h) -2.466e+006 -8332 -2.458e+006
46 Liq Vol Flow @Std Cond (m3/h) 2.135 * 1.393e-002 2.121
47
48
PROPERTIES
49 Overall Vapour Phase Liquid Phase
50 Molecular Weight 81.85 66.66 81.96
51 Molar Density (kgmole/m3) 4.109 4.759e-002 9.889
52 Mass Density (kg/m3) 336.4 3.173 810.5
53 Act. Volume Flow (m3/h) 5.649 3.317 2.331
54 Mass Enthalpy (kcal/kg) -1298 -791.6 -1301
55 Mass Entropy (kJ/kg-C) -0.2026 1.597 -0.2126
56 Heat Capacity (kJ/kgmole-C) 179.8 106.2 180.3
57 Mass Heat Capacity (kJ/kg-C) 2.196 1.593 2.199
58 LHV Molar Basis (Std) (kcal/kgmole) 4.876e+005 4.971e+005 4.875e+005
59 HHV Molar Basis (Std) (kcal/kgmole) 5.273e+005 5.335e+005 5.272e+005
60 HHV Mass Basis (Std) (kcal/kg) 6442 8002 6433
61 CO2 Loading --- --- ---
62 CO2 App ML Con (kgmole/m3) --- --- ---
63 CO2 App WT Con (kgmol/kg) --- --- ---
64 LHV Mass Basis (Std) (kcal/kg) 5956 7456 5948
65 Phase Fraction [Vol. Basis] 6.641e-003 6.641e-003 0.9934
66 Phase Fraction [Mass Basis] 5.540e-003 5.540e-003 0.9945
67 Phase Fraction [Act. Vol. Basis] 0.5873 0.5873 0.4127
68 Mass Exergy (kcal/kg) -11.76 --- ---
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 9 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: Safety Valve@0.4 barg-84 C (continued)
Property Package: NRTL - Ideal
8
9
10
PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Partial Pressure of CO2 (bar_g) -1.013 --- ---
13 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
14 Act. Gas Flow (ACT_m3/h) 3.317 3.317 ---
15 Avg. Liq. Density (kgmole/m3) 10.76 11.02 10.75
16 Specific Heat (kJ/kgmole-C) 179.8 106.2 180.3
17 Std. Gas Flow (STD_m3/h) 548.8 3.733 545.1
18 Std. Ideal Liq. Mass Density (kg/m3) 880.4 734.3 881.4
19 Act. Liq. Flow (m3/s) 6.476e-004 --- 6.476e-004
20 Z Factor --- 1.000 4.813e-003
21 Watson K 9.857 11.08 9.850
22 User Property --- --- ---
23 Partial Pressure of H2S (bar_g) -1.013 --- ---
24 Cp/(Cp - R) 1.048 1.085 1.048
25 Cp/Cv 1.001 1.085 1.048
26 Heat of Vap. (kcal/kgmole) 8921 --- ---
27 Kinematic Viscosity (cSt) --- 2.975 0.3695
28 Liq. Mass Density (Std. Cond) (kg/m3) 890.0 755.4 890.8
29 Liq. Vol. Flow (Std. Cond) (m3/h) 2.135 1.393e-002 2.121
30 Liquid Fraction 0.9932 0.0000 1.000
31 Molar Volume (m3/kgmole) 0.2434 21.01 0.1011
32 Mass Heat of Vap. (kcal/kg) 109.0 --- ---
33 Phase Fraction [Molar Basis] 0.0068 0.0068 0.9932
34 Surface Tension (dyne/cm) 33.21 --- 33.21
35 Thermal Conductivity (W/m-K) --- 1.900e-002 0.1925
36 Viscosity (cP) --- 9.438e-003 0.2994
37 Cv (Semi-Ideal) (kJ/kgmole-C) 171.4 97.88 171.9
38 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.094 1.468 2.098
39 Cv (kJ/kgmole-C) 179.6 97.88 171.9
40 Mass Cv (kJ/kg-C) 2.195 1.468 2.098
41 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
42 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
43 Cp/Cv (Ent. Method) --- --- ---
44 Reid VP at 37.8 C (bar_g) -0.5655 6.195 -0.6134
45 True VP at 37.8 C (bar_g) -0.5873 6.317 -0.6345
46 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 2.135 1.393e-002 2.121
47 Viscosity Index -16.05 --- ---
48
49
COMPOSITION
50
51
Overall Phase Vapour Fraction 0.0068

52 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
53 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
54 i-P-Acetate 17.4870 * 0.7534 * 1786.0000 * 0.9400 * 2.0265 * 0.9390 *
55 H2O 5.2734 * 0.2272 * 95.0000 * 0.0500 * 0.0952 * 0.0441 *
56 Propene 0.4515 * 0.0195 * 19.0000 * 0.0100 * 0.0365 * 0.0169 *
57 Total 23.2119 1.0000 1900.0000 1.0000 2.1581 1.0000
58
59
Vapour Phase Phase Fraction 6.802e-003

60 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
61 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
62 i-P-Acetate 0.0703 0.4453 7.1811 0.6823 0.0081 0.5685
63 H2O 0.0142 0.0897 0.2553 0.0243 0.0003 0.0178
64 Propene 0.0734 0.4649 3.0890 0.2935 0.0059 0.4137
65 Total 0.1579 1.0000 10.5253 1.0000 0.0143 1.0000
66
67
68
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 10 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: Safety Valve@0.4 barg-84 C (continued)
Property Package: NRTL - Ideal
8
9
10
COMPOSITION
11
12
Liquid Phase Phase Fraction 0.9932

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 i-P-Acetate 17.4167 0.7555 1778.8189 0.9414 2.0183 0.9415
16 H2O 5.2592 0.2281 94.7447 0.0501 0.0949 0.0443
17 Propene 0.3781 0.0164 15.9110 0.0084 0.0305 0.0142
18 Total 23.0540 1.0000 1889.4747 1.0000 2.1438 1.0000
19
20
K VALUE
21 COMPONENTS MIXED LIGHT HEAVY
22 i-P-Acetate 0.5895 0.5895 ---
23 H2O 0.3934 0.3934 ---
24 Propene 28.35 28.35 ---
25
26
UNIT OPERATIONS
27 FEED TO PRODUCT FROM LOGICAL CONNECTION
28
29
30
UTILITIES
31 ( No utilities reference this stream )
32
33
PROCESS UTILITY
34
35
36
DYNAMICS
37 Pressure Specification (Active): 0.4000 bar_g *
38 Flow Specification (Active) Molar: 23.21 kgmole/h Mass: 1900 kg/h * Std Ideal Liq Volume: 2.158 m3/h
39
40
User Variables
41
42
NOTES
43
44
45
Description
46
47
Fluid Package: Basis-1
48 Material Stream: Pure IPAc at 0.25 barg C Property Package: NRTL - Ideal
49
50
51
CONDITIONS
52 Overall Liquid Phase
53 Vapour / Phase Fraction 0.0000 1.0000
54 Temperature: (C) 45.00 * 45.00
55 Pressure: (bar_g) 0.2500 * 0.2500
56 Molar Flow (kgmole/h) 39.16 39.16
57 Mass Flow (kg/h) 4000 * 4000
58 Std Ideal Liq Vol Flow (m3/h) 4.539 4.539
59 Molar Enthalpy (kcal/kgmole) -1.228e+005 -1.228e+005
60 Molar Entropy (kJ/kgmole-C) -74.57 -74.57
61 Heat Flow (kcal/h) -4.811e+006 -4.811e+006
62 Liq Vol Flow @Std Cond (m3/h) 4.538 * 4.538
63
64
PROPERTIES
65 Overall Liquid Phase
66 Molecular Weight 102.1 102.1
67 Molar Density (kgmole/m3) 8.298 8.298
68 Mass Density (kg/m3) 847.5 847.5
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 11 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: Pure IPAc at 0.25 barg C (continued)
Property Package: NRTL - Ideal
8
9
10
PROPERTIES
11 Overall Liquid Phase
12 Act. Volume Flow (m3/h) 4.720 4.720
13 Mass Enthalpy (kcal/kg) -1203 -1203
14 Mass Entropy (kJ/kg-C) -0.7302 -0.7302
15 Heat Capacity (kJ/kgmole-C) 197.2 197.2
16 Mass Heat Capacity (kJ/kg-C) 1.930 1.930
17 LHV Molar Basis (Std) (kcal/kgmole) 6.353e+005 6.353e+005
18 HHV Molar Basis (Std) (kcal/kgmole) 6.843e+005 6.843e+005
19 HHV Mass Basis (Std) (kcal/kg) 6700 6700
20 CO2 Loading --- ---
21 CO2 App ML Con (kgmole/m3) --- ---
22 CO2 App WT Con (kgmol/kg) --- ---
23 LHV Mass Basis (Std) (kcal/kg) 6220 6220
24 Phase Fraction [Vol. Basis] 0.0000 1.000
25 Phase Fraction [Mass Basis] 0.0000 1.000
26 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
27 Mass Exergy (kcal/kg) -6.219 ---
28 Partial Pressure of CO2 (bar_g) -1.013 ---
29 Cost Based on Flow (Cost/s) 0.0000 0.0000
30 Act. Gas Flow (ACT_m3/h) --- ---
31 Avg. Liq. Density (kgmole/m3) 8.629 8.629
32 Specific Heat (kJ/kgmole-C) 197.2 197.2
33 Std. Gas Flow (STD_m3/h) 926.0 926.0
34 Std. Ideal Liq. Mass Density (kg/m3) 881.3 881.3
35 Act. Liq. Flow (m3/s) 1.311e-003 1.311e-003
36 Z Factor 5.755e-003 5.755e-003
37 Watson K 9.814 9.814
38 User Property --- ---
39 Partial Pressure of H2S (bar_g) -1.013 ---
40 Cp/(Cp - R) 1.044 1.044
41 Cp/Cv 1.338 1.338
42 Heat of Vap. (kcal/kgmole) 7625 ---
43 Kinematic Viscosity (cSt) 0.4980 0.4980
44 Liq. Mass Density (Std. Cond) (kg/m3) 881.4 881.4
45 Liq. Vol. Flow (Std. Cond) (m3/h) 4.538 4.538
46 Liquid Fraction 1.000 1.000
47 Molar Volume (m3/kgmole) 0.1205 0.1205
48 Mass Heat of Vap. (kcal/kg) 74.66 ---
49 Phase Fraction [Molar Basis] 0.0000 1.0000
50 Surface Tension (dyne/cm) 32.17 32.17
51 Thermal Conductivity (W/m-K) 0.1296 0.1296
52 Viscosity (cP) 0.4220 0.4220
53 Cv (Semi-Ideal) (kJ/kgmole-C) 188.8 188.8
54 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.849 1.849
55 Cv (kJ/kgmole-C) 147.4 147.4
56 Mass Cv (kJ/kg-C) 1.443 1.443
57 Cv (Ent. Method) (kJ/kgmole-C) 1.955e+004 1.955e+004
58 Mass Cv (Ent. Method) (kJ/kg-C) 191.4 191.4
59 Cp/Cv (Ent. Method) 1.009e-002 1.009e-002
60 Reid VP at 37.8 C (bar_g) -0.8708 -0.8708
61 True VP at 37.8 C (bar_g) -0.8708 -0.8708
62 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 4.538 4.538
63 Viscosity Index -8.561 ---
64
65
66
67
68
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 12 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: Pure IPAc at 0.25 barg C (continued)
Property Package: NRTL - Ideal
8
9
10
COMPOSITION
11
12
Overall Phase Vapour Fraction 0.0000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 i-P-Acetate 39.1646 * 1.0000 * 4000.0000 * 1.0000 * 4.5385 * 1.0000 *
16 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
17 Propene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
18 Total 39.1646 1.0000 4000.0000 1.0000 4.5385 1.0000
19
20
Liquid Phase Phase Fraction 1.000

21 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
22 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
23 i-P-Acetate 39.1646 1.0000 4000.0000 1.0000 4.5385 1.0000
24 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
25 Propene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
26 Total 39.1646 1.0000 4000.0000 1.0000 4.5385 1.0000
27
28
K VALUE
29 COMPONENTS MIXED LIGHT HEAVY
30 i-P-Acetate 0.0000 0.0000 ---
31 H2O --- --- ---
32 Propene --- --- ---
33
34
UNIT OPERATIONS
35 FEED TO PRODUCT FROM LOGICAL CONNECTION
36
37
38
UTILITIES
39 ( No utilities reference this stream )
40
41
PROCESS UTILITY
42
43
44
DYNAMICS
45 Pressure Specification (Active): 0.2500 bar_g *
46 Flow Specification (Active) Molar: 39.16 kgmole/h Mass: 4000 kg/h * Std Ideal Liq Volume: 4.539 m3/h
47
48
User Variables
49
50
NOTES
51
52
53
Description
54
55
Fluid Package: Basis-1
56 Material Stream: Pure IPA @ 0.5 barg 45C Property Package: NRTL - Ideal
57
58
59
CONDITIONS
60 Overall Liquid Phase
61 Vapour / Phase Fraction 0.0000 1.0000
62 Temperature: (C) 45.00 * 45.00
63 Pressure: (bar_g) 0.5000 * 0.5000
64 Molar Flow (kgmole/h) 39.16 39.16
65 Mass Flow (kg/h) 4000 * 4000
66 Std Ideal Liq Vol Flow (m3/h) 4.539 4.539
67 Molar Enthalpy (kcal/kgmole) -1.228e+005 -1.228e+005
68 Molar Entropy (kJ/kgmole-C) -73.07 -73.07
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 13 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: Pure IPA @ 0.5 barg 45C (continued)
Property Package: NRTL - Ideal
8
9
10
CONDITIONS
11 Overall Liquid Phase
12 Heat Flow (kcal/h) -4.811e+006 -4.811e+006
13 Liq Vol Flow @Std Cond (m3/h) 4.538 * 4.538
14
15
PROPERTIES
16 Overall Liquid Phase
17 Molecular Weight 102.1 102.1
18 Molar Density (kgmole/m3) 8.298 8.298
19 Mass Density (kg/m3) 847.5 847.5
20 Act. Volume Flow (m3/h) 4.719 4.719
21 Mass Enthalpy (kcal/kg) -1203 -1203
22 Mass Entropy (kJ/kg-C) -0.7155 -0.7155
23 Heat Capacity (kJ/kgmole-C) 197.2 197.2
24 Mass Heat Capacity (kJ/kg-C) 1.930 1.930
25 LHV Molar Basis (Std) (kcal/kgmole) 6.353e+005 6.353e+005
26 HHV Molar Basis (Std) (kcal/kgmole) 6.843e+005 6.843e+005
27 HHV Mass Basis (Std) (kcal/kg) 6700 6700
28 CO2 Loading --- ---
29 CO2 App ML Con (kgmole/m3) --- ---
30 CO2 App WT Con (kgmol/kg) --- ---
31 LHV Mass Basis (Std) (kcal/kg) 6220 6220
32 Phase Fraction [Vol. Basis] 0.0000 1.000
33 Phase Fraction [Mass Basis] 0.0000 1.000
34 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
35 Mass Exergy (kcal/kg) -7.267 ---
36 Partial Pressure of CO2 (bar_g) -1.013 ---
37 Cost Based on Flow (Cost/s) 0.0000 0.0000
38 Act. Gas Flow (ACT_m3/h) --- ---
39 Avg. Liq. Density (kgmole/m3) 8.629 8.629
40 Specific Heat (kJ/kgmole-C) 197.2 197.2
41 Std. Gas Flow (STD_m3/h) 926.0 926.0
42 Std. Ideal Liq. Mass Density (kg/m3) 881.3 881.3
43 Act. Liq. Flow (m3/s) 1.311e-003 1.311e-003
44 Z Factor 6.894e-003 6.894e-003
45 Watson K 9.814 9.814
46 User Property --- ---
47 Partial Pressure of H2S (bar_g) -1.013 ---
48 Cp/(Cp - R) 1.044 1.044
49 Cp/Cv 1.338 1.338
50 Heat of Vap. (kcal/kgmole) 7536 ---
51 Kinematic Viscosity (cSt) 0.4980 0.4980
52 Liq. Mass Density (Std. Cond) (kg/m3) 881.4 881.4
53 Liq. Vol. Flow (Std. Cond) (m3/h) 4.538 4.538
54 Liquid Fraction 1.000 1.000
55 Molar Volume (m3/kgmole) 0.1205 0.1205
56 Mass Heat of Vap. (kcal/kg) 73.79 ---
57 Phase Fraction [Molar Basis] 0.0000 1.0000
58 Surface Tension (dyne/cm) 32.17 32.17
59 Thermal Conductivity (W/m-K) 0.1296 0.1296
60 Viscosity (cP) 0.4220 0.4220
61 Cv (Semi-Ideal) (kJ/kgmole-C) 188.8 188.8
62 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.849 1.849
63 Cv (kJ/kgmole-C) 147.4 147.4
64 Mass Cv (kJ/kg-C) 1.443 1.443
65 Cv (Ent. Method) (kJ/kgmole-C) 1.646e+004 1.646e+004
66 Mass Cv (Ent. Method) (kJ/kg-C) 161.2 161.2
67 Cp/Cv (Ent. Method) 1.197e-002 1.197e-002
68 Reid VP at 37.8 C (bar_g) -0.8708 -0.8708
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 14 of 15
Licensed to: MOTT MACDONALD * Specified by user.
1
Case Name: IPA ACETATE.hsc
2 MOTT MACDONALD
3 Burlington, MA Unit Set: ACPA
4 USA
Date/Time: Thu Nov 10 18:50:18 2016
5
6
Fluid Package: Basis-1
7 Material Stream: Pure IPA @ 0.5 barg 45C (continued)
Property Package: NRTL - Ideal
8
9
10
PROPERTIES
11 Overall Liquid Phase
12 True VP at 37.8 C (bar_g) -0.8708 -0.8708
13 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 4.538 4.538
14 Viscosity Index -8.561 ---
15
16
COMPOSITION
17
18
Overall Phase Vapour Fraction 0.0000

19 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
20 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
21 i-P-Acetate 39.1646 * 1.0000 * 4000.0000 * 1.0000 * 4.5385 * 1.0000 *
22 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
23 Propene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
24 Total 39.1646 1.0000 4000.0000 1.0000 4.5385 1.0000
25
26
Liquid Phase Phase Fraction 1.000

27 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
28 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
29 i-P-Acetate 39.1646 1.0000 4000.0000 1.0000 4.5385 1.0000
30 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
31 Propene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
32 Total 39.1646 1.0000 4000.0000 1.0000 4.5385 1.0000
33
34
K VALUE
35 COMPONENTS MIXED LIGHT HEAVY
36 i-P-Acetate 0.0000 0.0000 ---
37 H2O --- --- ---
38 Propene --- --- ---
39
40
UNIT OPERATIONS
41 FEED TO PRODUCT FROM LOGICAL CONNECTION
42
43
44
UTILITIES
45 ( No utilities reference this stream )
46
47
PROCESS UTILITY
48
49
50
DYNAMICS
51 Pressure Specification (Active): 0.5000 bar_g *
52 Flow Specification (Active) Molar: 39.16 kgmole/h Mass: 4000 kg/h * Std Ideal Liq Volume: 4.539 m3/h
53
54
User Variables
55
56
NOTES
57
58
59
Description
60
61
62
63
64
65
66
67
68
69 Aspen Technology Inc. Aspen HYSYS Version 8.6 (32.0.0.8628) Page 15 of 15
Licensed to: MOTT MACDONALD * Specified by user.