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SINCOR, C.A.
UPSTREAM SURFACE FACILITIES PROJECT
REVISION INDEX:
APPROVAL REGISTER
CONTENTS
SECTION N PAGE
1. SCOPE 4
3. DEFINITIONS 4
4. ELECTROCHEMICAL CORROSION 5
5.1. Pipelines 6
5.2. Aboveground Storage Tank Bottoms 7
5.3. Well Casings 8
8. COATING SELECTION 12
9. RECTIFIERS 14
1. SCOPE
This document describes and specify the Cathodic Protection Basis and Design Criteria
involved in the corrosion control through the use of coatings and cathodic protection on oil
production, above ground storage tanks, pipelines etc. to be used in the design of the
SINCOR UPSTREAM SURFACE FACILITIES.
The following codes and standards will be used for the Cathodic Protection designs.
3. DEFINITIONS
Corrosion of a buried or submerged metallic structure, in this case steel, occurs when
several components exist forming the basic corrosion circuit, with an anode or part of the
structure (where there is loss of steel into the electrolyte, corrosion), a cathode (where no
corrosion occurs), an electrolyte in which both the anode and cathode are located, and an
electrical pass for the electrons involved in the corrosion circuit to go from the anodic
areas to the cathodic ones. Basically if one or more of these components are missing no
corrosion will occur.
steel sheetpile, etc.). These elements themselves form part of a similar system, consisting
of anodic and cathodic areas, electrolyte and collecting conductors (copper wires, steel of
the structure, etc..). When a CP system is properly designed and installed, all portions of
the protected structure collect current from the surrounding electrolyte and the entire
exposed surface becomes one large cathodic area. CP current is the type denominated
direct current, such as found in a battery.
CP is applicable only to control the corrosion resulting from flow of measurable direct
currents from portions of a structure (anodic areas), through an electrolyte to other parts of
the same structure (cathodic areas). This type of corrosion is called electrochemical
corrosion, and where current is discharged from the anodic areas, metal loss or corrosion
will occur; conversely, the cathodic areas will collect the current and no corrosion will occur
at that part of the structure, i.e. it is cathodically protected.
4. ELECTROCHEMICAL CORROSION
Electrochemical corrosion can occur naturally or artificially. The first case was discussed
previously and the second is referred to as Electrolysis or Interference. This term is
sometimes erroneously used to refer to both types of corrosion. Electrolysis or
interference results when direct current is discharged into the soil or water, the electrolyte.
These currents are also known as stray or erratic currents. Seifert1 defines Interference
Currents as manmade electrical currents, performing work on one grounded plant, which
flow on other grounded plant(s) using electrolytic paths of earth for interconnection. These
manmade currents can be separated into two main categories, static, generated in
foreign CP systems, electrolytic cells, or dynamic, continuously varying in amplitude and/or
continually changing their geographic paths, such as in DC generating equipment in
underground mines and electrical railway generating equipment (Subways).
When these currents are picked up from the electrolyte on areas of a structure, not
connected to the CP system, and discharged in other areas of the same structure,
corrosion occurs in the discharge zones and some cathodic protection results at the
collecting areas of the structure. This type of corrosion can be found widely where
pipelines cross each other, or there are several pipes paralleling at short separations in
the same corridor, some protected and others not. This phenomenon is also found in
underground structures in industrial plants, with CP systems for some structures, and in
cities along the Metro or Subway lines, specifically near the Stations.
1
PRACTICAL INTERFERENCE CURRENT TESTING ON UNDERGROUND METALLIC STRUCTURES, RICHARD L. SEIFERT.
SINCOR
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5.1. Pipelines
When cathodically protected well coated lines with a high electrical resistance to
soil arrive at an industrial plant it has been proven that their potentials suffer a large
fall, due to the connection of the lines with a large amount of unprotected steel and
other metals, with a very low resistance to soil. NACE RP0286 and other
Standards indicate that the proper way to avoid this loss of protection is by
isolating these pipes at the point of entrance to the plants.
SINCOR
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Due to the high resistivity of the soils in that part of the country, impressed
current CP systems with conventional anode groundbeds distributed
around the tank perimeter will not work properly. Other anode configuration
and types should be considered in this case, e.g. distributed titanium
ribbon in a grid or MMO anodes located immediately below the tank
separated around one foot from the steel plates is a proper solution to
control the corrosion of the bottoms. Electrical isolation of the tanks at
incoming and outgoing pipes should be analyzed.
First of all information should be recollected to find out if corrosion has occurred in
well casings in that part of the country where the installations will be located. If no
reports are available concerning this matter, oil production engineers or well
operators should be contacted, working in the area or other states in the east of
Venezuela, with similar formations, such as Monagas.
The case of well casings can be of interest when CP systems are designed in oil
fields, where there are flow- and trunklines and pipeline corridors going towards
other installations. In many cases these casings suffer corrosion processes and
one of the forms of preventing this phenomenon is by impressed current CP
installations. To determine their effectively the behavior of the well casing potential
should be known when going downwards, to determine in this way the most
adequate current demand.
In countries like the States and Canada this problem has been detected and
studied, and there is literature about the ways to measure the potentials downhole
and the actions that have been taken to control the problem.
External corrosion of the well casing can result in the loss of a well, the loss of
production, environmental dangers and human safety considerations. The only way
to prevent external corrosion of the casings effectively is by means of cathodic
protection.
CP does not necessarily eliminate all the corrosion, but transfers it from the structure to be
protected and concentrates it on another structures, such as galvanic or inert anodes
which will be consumed instead of the structure itself. Proper design procedures and
selection of the right material will give these anodes a long life and easy replacement.
CP is only of value to the surface of the metal exposed to the same electrolyte (soil or
water) as the anode.
Coating buried structures and applying cathodic protection is the proper approach to
corrosion control.
Pipe to soil potentials is one of the most important measurements in Corrosion Control
and Cathodic Protection as the value of this parameter indicates if there is active
corrosion going on, the magnitude of it and also if CP has been achieved according to the
Criteria given in NACE RP0169, Section 6, Criteria and other Considerations for
Cathodic Protection. Section on SURVEY METHODS USED IN CATHODIC
PROTECTION WORK, elaborates on the different ways to measure structure to soil
potentials, and the equipment used for this purpose.
This section will list criteria and other considerations that will indicate, when used either
separately or in combination, whether adequate cathodic protection of a metallic structure
(buried piping system, aboveground or underground storage tank) has been achieved.
Sound engineering practices shall be used to determine the methods and frequency of
testing required to satisfy these criteria.
It is not intended that persons responsible for corrosion control be limited to the criteria
listed below. Criteria that have been successfully applied on existing piping systems can
continue to be used on those piping systems. Any other criteria used must achieve
corrosion control comparable to that attained with the criteria herein. The criteria in more
common use involve measurements of voltage (differences in potential) between the
protected structure and the electrolyte.
The most widely used criterion in the oil business involves the use of a copper/copper
sulfate electrode as a reference half cell. The electrode consists of a copper rod
immersed in a saturated copper sulfate solution, both housed in a plastic cylinder with a
porous plug (wood or ceramic) on the bottom end, to make contact with the soil, and the
copper rod extending out of the top (for connection to the measuring high-resistance
voltmeter or multimeter). The means to measure this potential shall be designed, so as to
be able to compare the values with those given in NACE RP0169-96, Section 6. All
potential mentioned are measured with respect to a saturated copper/copper sulfate
(stable) electrode (Cu/CuSO4 ) in contact with the electrolyte.
Normal values of potentials for buried steel without any CP applied and not receiving any
stray currents is in the order of -500 to -600 mV Cu/CuSO4 . This potential is called Native
Potential (Pnat).
2
Cathodic polarization: The change of electrode potential in the electronegative direction resulting from the flow of current between the
electrolyte and electrode.
SINCOR
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When a pipeline is buried in dry or aerated high resistivity soil, values less negative than
the criteria listed above may be sufficient.
In general the maximum protection for well coated pipes shall be Pact = -2.000 mV
Cu/CuSO4
Situations involving stray currents and stray electrical gradients may exist that require
special analysis.
Where experience has shown that a certain current density has been effective in
protecting steel in a given relatively uniform environment, this current density, applied
uniformly, may be considered an indirect protection criterion. A value used commonly for
protection of bare steel pipe is a current density of 1 mA/sqft. This value will be higher for
structures in sea water or for special considerations in buried steel, such as the case of
presence of SRB (Sulfate Reducing Bacteria), where the current density might be as high
as 25 mA/sqft. When the CP are functioning continuously, polarization and ampere -hour
effects tend to reduce the current demand required for protection of the same structure.
The reduction in this current density will depend on the type of electrolyte and the
magnitude of the current amperage.
In the case of external tank bottoms, a current density of around 3 mA/sqft has been
regarded as, specially when the rebars in the ring foundation might accidentally contact
the steel bottom, and to take account of the loss of protective current towards the
grounding rebars or bare copper wire.
SINCOR
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8. COATING SELECTION
According to the general practice nowadays and also to standards concerning pipelines,
all new buried pipes, conducting products such as oil or diluent will be coated. No bare
pipe is considered in the project for its corrosion control.
The fundamental role of a protective pipe line coating is to provide and electrical and
electrochemical barrier isolating steel from the corrosive soil, halting corrosion by
breaking the continuity of the electrical circuit by insulating anode and cathode areas. It
follows that a coatings fundamental property must be moisture uptake resistance,
guarding against further disbondment promoted by moisture penetration to the steel-
coating interface.
The coatings moisture resistance is one of the properties that really matters Moisture
uptake can markedly reduce coating mechanical properties, making it much easier for soil
stresses to damage the coating.
Coating defects determine CP need and it is the distribution of defect sizes and locations
that determines the potential profile along a pipe line. Interaction between the competing
processes of corrosion to dissolve metal and CP to prevent metal dissolution results in the
steel surface exposed at organic coating defects being covered with a layer of corrosion
products that provides a form of protection. This corrosion-product layer is called the
inorganic coating.
Fault causes in a buried pipe lines protective coating are mainly the following:
SINCOR
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Soil stress effects assisted by high operating temperatures and moisture uptake by
the coating.
For a 20 year design life of the CP system, a current density of 1 mA/sqft will be adopted,
applied on an estimated 4 % percentage of the whole outer surface of the pipe. This value
also takes into account future damages due to aging of the coating, taken from the
technical literature and accumulated experience in other pipelines CP designs. Thus for
the design a density current of 0,04 mA/sqft of the total external surface shall be applied to
the total external surface of the pipes.
Electric isolation of the pipeline steel surface and soil surrounding it shall be achieved with
a coating of optimum quality such as FBE (Fusion Bonded Epoxy) or similar, applied in
Plant with a controlled procedure and inspected through several methods in all its steps,
through several methods, by Holiday Detection, in the field before laying the pipe in the
trench, and backfilling it. Experience from other pipelines for projects in areas in the
eastern part of the country with similar conditions (Monagas and Anzotegui States) have
been considered for the coating selection. However literature has indicated that FBE can
absorb water with the aging of the coating.
Another excellent coating is Coal Tar Urethane 1, a 100% solid high structure, auto -
adhesive and of high effectivity has a rapid curing time, excellent resistance to corrosion
and abrasion, and can be buried or covered in a short time after its application. It can be
applied in plant, field and also on the welds, being compatible with FBE and Trilayer FBE
system with polyethylene or polypropylene on the outside.
Other coatings such as Polyethylene tape/butyl adhesive coatings have been proposed for
buried pipelines, however the application of these tapes should be inspected thoroughly,
and done with machines. Moisture resistance of these coatings is determined by the tape
application procedure and the type and amount of adhesive mastic used to stick the tape
SINCOR
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to the pipe. In the case of expansive clays, special types of adhesive tapes should be
applied. Tree root penetration has a larger probability to occur than in the case of the thin
film epoxy coatings.
Sufficiency shall be considered for possible protection current loss to other existing or
future pipelines, of different diameters and older, buried in corridors to be shared or which
will be crossed, increasing the areas to be protected or the rectifier capacity.
Information should be recollected regarding the characteristics of the soil, such as pH,
Chloride Content, soil stresses (presence of expansive clays), and presence of Sulfate
Reducing Bacteria along the route, for the coating selection.
To evaluate the pipe coating behavior, -specially for critical pipes due to their high
pressure, or passing through different resistivity zones-, IR Drop Stations shall be
designed to measure the coating resistance and its behavior over the time. When several
pipelines parallel each other, the most critical shall be considered for the IR Drop station
installation. These IR Drop stations shall be designed at 3 to 5 mile distance between
each other.
9. RECTIFIERS
The selection of the transformer rectifier (T/R) or rectifier will be based on the current
demand required to protect the pipelines, with and adequate margin for pipe coating
damaging, during handling, transportation, laying in the trench, backfilling with excavation
material, the natural aging of the coating and future enlargement of the pipe systems.
Rectifiers shall meet the latest applicable NEMA, ANSI, NFPA, Mil-C-456662 and T-M
Standards. Rectifiers shall be designed to operate continuously with a variation in DC
current and voltage output, to adapt to the deviations of the subsoil humidity, addition
protection current requirement, and maintaining the CP potentials. This is normally
achieved with the full rated DC output voltage by not less than 20 equal steps or with
proper dimensioned rheostats.
Rectifiers shall be air-cooled, Wayne Broyles, Good-All or similar, single or three phase,
manually adjustable with tap studs and link bars, 120/240 AC V input, with sufficiency in
DC current and tension for the CP systems.
SINCOR
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Similar rectifiers have been used for many years with good results for the Oil Industry
installations in the country.
The output ranges should permit, by simple adjustment means, an efficient equipment
operation, according to the yearly seasons and the anode beds resistance variations.
The CP design should be done, locating the required rectifiers, when possible, near the
zones of electrical energy availability o with nearby electrical lines, e.g. in the existing or
projected Plants.
The project pipelines can accidentally come in contact with other existing lines, some
quite old, with regular coating, while the new pipe would be well protected, e.g. in the
connection at the existing Plants. This should be considered to design isolation between
the different pipes.
The impressed current groundbeds selected to protect the project buried pipelines,
must correspond to a type of design wherein the header or positive cable of the
rectifier arrives at a junction box where the output current is distributed through a
common copper bus bar to an individual cable per pair or group of anodes, till their
location in the terrain. This consists in a layout where there is a positive (+) cable
coming from the rectifier to the box. Anodes are separated between 15 ft (5 m) to
22 ft (7 m) one from the other. During the design the position of the groundbeds
and anode separations will be defined. In the case of groundbeds with few anodes,
each anode will be connected to an individual cable.
The anode beds will be designed in a perpendicular position to the axis of the
pipeline, with the first anode separated 330 ft (100 m) from the first pipe
encountered in the corridor. This distance may change during the design, if
difficulties are found due to conditions and terrain characteristics or other
particularities. If there exist conditions that should require it, the groundbeds could
be designed in an angle with the pipeline axis or in a T distribution, parallel to the
pipe.
SINCOR
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The beds will be designed in such a way to locate them in zones with lower
resistivities, and thus during the fieldwork possible locations for the groundbeds will
be pre-selected, to take resistivity measurements a higher depths [up to 25 ft (8
m))] in a grid of 66 ft by 66 ft (20 m x 20 m).
In some cases in the area, such as Monagas, the soils have very high resistivities
and lower values are found at depths of up to 50 or 60 ft, and measurements
should be taken up to that depth, at separations of 6 ft (2 m), in order to determine
the resistivities by the Layer or Barnes Method. As the area of Zuata seems to be
similar to Monagas, possibly anode groundbeds might have to be designed up to
that depth.
In the case of soils with very variable resistivities, with some very high values,
where the highest resistivities can be a 100 or more times the lowest ones, the
groundbeds shouldnt however be located in the sites with very low resistivities,
because it might be very difficult to get an adequate distribution of the current
towards the pipes in the highest resistivities soils.
The design shall meet the general Criteria of designing the anode beds with a
minimum of eight (8) and a maximum of thirty (30) anodes, trying to obtain low bed
resistance.
According to the design results, sufficient capacity shunts and a variable resistor
shall be designed in the junction boxes, to permit the calibration of the output
current of each individual anode or group of anodes. The advantage of a design
with a variable resistor is that it permits control of each individual anode or group of
anodes output current, achieving a uniform attenuation curve along the header
cable and the adjustment of the current output per anode.
High Silicon Cast Iron 3 anodes will be designed for a maximum current output
of 5 A/anode, with a 1,2 A/sqft density current. For 2 the output will be less,
around 3 A/anode, with a 1,1 A/sqft discharge. In the case of MMO anodes a
higher output is permitted, according to the manufacturers technical sheets.
The anodes will be designed for vertical installation in a low value metallurgical
coke breeze column, not larger than 25 Ohm-cm, guaranteeing a good current
drainage. However as the national metallurgical coke breeze has some impurities,
it is wise to use imported coke breeze, of low resistivity, of the fluidified petroleum.
In the case where particular conditions so requires, the anode beds shall be
designed with the anodes installed in a horizontal way in a coke breeze bed.
SINCOR
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Where the soil is of very high resistivities, beds will be designed with petroleum or
metallurgical coke breeze of very low resistivities (1 Ohm-cm) and/or with treatment
around the anodes with low resistivity electrolytic mixes to reduce the groundbed-
to-soil resistance.
Due to the high existing resistivities in the area, only in extreme cases sacrificial
Magnesium (Magnesium) anode beds will be adopted, to protect very short pipe
lengths buried in the Plants and road crossings, where the pipe length in contact
with the soil is 150 ft (50 m.) or less.
The Magnesium anode beds will be designed with the negative cable welded to
the pipe arriving at a box or test point, where the anode cable is connected,
intercalating a shunt to measure the current output and permit the calculation of the
remaining anode life. The cable terminals and the shunt will be fixed on a bakelite
sheet, to isolate them from the metallic box, unless weather resistant plastic test
points are designed. The number of anodes per bed will depend on the amount of
current output required.
Anode beds will be designed in a perpendicular position to the pipe axis, with the
first anode separated 10 ft (3 m.) from the pipe. This distance might be
reconsidered during the design, if difficulties are encountered due to the terrain
conditions or characteristics or other particularities. In the case of conditions found
that thus require it, the anode beds could be designed in a position slanting to the
pipe axis or in a T form, parallel to the pipe.
The beds will be designed in such a way to locate them in the zones of lower
resistivities (up to 10.000 Ohm-cm), and thus during the fieldwork possible sites for
the anodes will be preselected, in order to take resistivity measurements at depths
of 1 to 2 m.
This anode selection will be implemented, designing a shunt of 0,1 Ohm and 2 A
capacity (MCM Miller, Cott Mfg.) or similar characteristics in the test point, to
measure the small current output of the sacrificial anodes.
The current output of the anodes will be calculated as a function of the soil
resistivities, the geometric characteristics of the anode and the desired potential of
the pipe (-900 mV -1000 mV Cu/CuSO4 ).
SINCOR
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The positive, negative and bonding cables shall be selected of stranded copper, Class B,
Type HMWPE (CP cable, High Molecular Weight Polyethylene) or TTU (Polyethylene
covered with PVC) for direct burial.
The cable gages will be selected for the maximum current capacity, e.g. # 8 AWG (max.
cap. 45 A DC) for the anode cables. The bonding cables between pipes will be Type
HMWPE or TTU # 8 AWG (max. cap. 45 A DC) for mechanical resistance.
The negative copper cables shall be HMWPE or TTU # 2 AWG (max. cap. 115 A DC). In
the case of parallel pipes in corridors, or joint systems, the negative cables will be taken to
a common copper bus bar in the junction box for negative cables, were adjustable power
resistors or rheostats, rated for the respective cable current will be inserted. From this
place a single # 2 AWG THW will connect the bar to the rectifier negative terminal.
Some cables for the monitoring system will be stranded Class B copper THW, properly
rated for each situation as detailed in the Project drawings.
The CP system shall be designed restricting the current on the project pipe stretches and
trying as much as possible to avoid current loss towards other structures connected
mechanically to them, such as the arrival or outgoing of the pipes at Plants or any lateral
pipe. In the project the pipes will be isolated at the Wellheads, Main Plant and Zuata.
This purpose will be achieved designing monolithic joints or isolating flanges at these
points, to avoid the passing of the current further on from the pipe. In order to protect the
insulating components of those isolation flange kits or monolithic joints from possible
atmospheric electric discharges that could fall on the pipeline aboveground parts or
valves, polarization cells shall be designed of the type consisting of plastic containers with
pure Nickel plates in KOH solution, or direct current isolation capacitors, located in
outdoors steel enclosures near the joints.
SINCOR
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Contacts will be avoided as much as possible, between the reinforcing bars of concrete
pipe supports or crossing elements and the pipe or casings under road crossings.
All pipeline that should appear during the construction and that was not detected
beforehand or during the field work, of 8 size or larger should be electrically bonded.
When lesser diameter gas lines or high pressure lines are found, the need for their bond
should be studied during the Commissioning of the CP, based on the pipe to soil potential
measurements. Under no circumstances direct burial pipe crossings will be permitted,
without a test point, even if the bond is identified.
Soil resistivity or the resistance of the earth to current passing through it, is
very important to obtain values which will indicate the aggressiveness of
SINCOR
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the electrolyte. Soils with low resistivities will be corrosive to buried steel,
but will also be adequate to design corrosion control procedures. Soils with
high resistivities will not be corrosive, but at the same time offer a high
resistance to pass current through them for any CP system to be designed.
Even though high soil resistivities are not corrosive, the presence along a
pipeline of areas with low and high resistivities might generate corrosion
currents, that have to be taken into account. The same might happen under
tank bottoms with soils of different resistivities in contact with the steel
plates.
Soil resistivity values are important for CP designs in the case of buried
structures as they will give values to design the sacrificial anode system or
where to select the most adequate location for the impressed current
ground beds.
3
CORROSION AND CATHODIC PROTECTION OF UNDERGROUND METALLIC WATER PIPING SYSTEMS, R.A. Gummow, presented at the
A.W.W.A., ONTARIO SECTION MEETING, HAMILTON, ONTARIO, MAY 30th, 1979
SINCOR
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TABLE I
ANTICIPATED CORROSION OF STEEL EXPOSED TO SOILS
IN VARYING RESISTIVITY
15.1.2.Potential Measurements
TABLE II
GALVANIC SERIES
METAL Millivolts
MAGNESIUM (COMMERCIALLY PURE) -1750 - active
ZINC
ALUMINUM ALLOY (5% ZINC) -1100
COMMERCIALLY PURE ALUMINUM -1050
MILD STEEL (CLEAN AND SHINY) -800
MILD STEEL (RUSTED) -500 to -800
CAST IRON (NOT GRAPHITIZED) -200 to -500
LEAD -500
MILD STEEL IN CONCRETE -500
COPPER, BRASS, BRONZE -200
HIGH SILICON CAST IRON -200
MILL SCALE ON STEEL -200
CARBON, GRAPHITE, COKE -200
+400 - noble
The meaning of structure is any steel buried or in contact with the soil or
immersed in water. In general the structures referred to in this document
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In high resistivity soils, such as the probable case of the pipelines between
Main Station and Zuata, some measuring stations with buried probes
and/or permanent reference electrodes will be designed, to eliminate IR
drops in the P/S potentials. Permanent copper/copper sulfate electrodes
for 15 years or of the gel type for a longer life are desirable. Nowadays
electrodes of the copper sulfate gel type for a long life are available with a
guaranteed thirty (30) years of operation.
with the Cu/CuSO4 half cell, and in absence of stray currents, the polarity
will not be of a large concern, as the potentials will in general have a
negative value. However, when a zinc reference cell is used, as in the case
of permanent electrodes, and measurements are done in sea water, the
polarity of the potential is of utmost importance, as the result has to be
converted into Cu/CuSO4 values, for comparison with standardized
potentials.
The direction of the flow of direct current involved in corrosion and CP,
specially in the case of pipelines, can be determined using a multimeter. In
the case of a pipeline without any CP applied, the area or location where
current flows from the structure to the earth indicates an anodic zone where
corrosion is occurring. This can be detected by noting direction and
magnitude of current flow in the pipe. The point along the pipe, where the
value reaches its maximum and reverses the direction of flow is the point
where corrosion is occurring.
Because the same current flowing along the pipe must also be flowing in
the adjacent soil, where the larger soil resistance produces millivolt
readings of greater magnitude than in the pipe, the measuring procedure is
usually modified. This is called the surface potential or two electrode
survey, requiring a multimeter (or high resistance voltmeter) with polarity
reversal indication, two Cu/CuSO4 electrodes, and suitable test leads
connected to the instrument. For more accurate results, the crew should
SINCOR
Project Title: SINCOR, C. A. Document: CA04-04-33-P-SP-030
UPSTREAM SURFACE FACILITIES PROJECT Page /File: 26/CA04-04-33-P-SP-030_X2.doc
Rev./Date: X2 / Oct,10-05
The two electrodes, calibrated to read within two milliVolts of each other,
are placed over the pipe at a suitable distance apart, usually 20 ft and the
potential difference and electrode polarity is read on the multimeter and
recorded. The electrodes are then leapfrogged down the line maintaining
the same separation, and the millivolt readings and polarity recorded over
the full length of the line under survey. Pipe-to-soil potentials are not
necessary, but it may be desirable to have their values.
Anodic and cathodic areas on the unprotected pipe are identified as points
of potential reversal. The anodic areas are identified during the survey, and
soil resistivities are measured at those locations. Direct current volt
gradients, also called side drains with the two electrodes positioned
perpendicularly to the pipeline are obtained at these spots and also on
cathodic areas.
The corrosion engineer will analyze the different results and use them for
the CP designs, with sacrificial or impressed current anodes.
The bottoms of the above ground storage tanks (ASTs) shall be bare
metal in contact with the electrolyte, as very seldom the underpart of the
steel tank plates are coated before erecting the tank. All pipes carrying
products will be coated with an appropriate dielectric revetment.
In most of the cases when new installations are considered, the corrosion
engineer will have to use his best judgment to select the current density
during his design to dimension the cathodic protection system. When
cathodic protection has to be designed for existing steel structures, such
as bare or coated pipelines, or tank bottoms, it is advisable to install a
temporary cathodic protection system and measure potentials till the
structure has been protected according to NACE standards. This
temporary installation consists of a current source, impressing current
through temporary anodes, and positive and negative cables. If possible in
existing installations the structure being studied should be isolated
temporary, so as to restrict the protective current on its surface. If this is not
possible, measurements should be taken to determine the spread or loss
of cathodic protection current towards other structures.
The current source used might be a battery for small amounts of currents, a
generator or welding machine, or an existing rectifier, for larger amounts of
current (up to 100 A DC). The temporary anodes should be located
strategically, around or near the structure to be protected. The anodes
might be steel rods or steel pipes (carbon or galvanized) driven in the soil,
abandoned lines or well casings, the vertical pipes of cyclone fences driven
in the soil, and even aluminum foil has been used, covered with earth to get
a better contact. A good practice is to wet the soil around the temporary
anodes, and in some cases add some salt, to lower the resistance of the
anode to soil. If the location for the anode beds has been predetermined, it
is advisable to locate the temporary anodes near these places.
Before applying the test current P/S natural potentials should be measured,
and afterwards when the current has been applied for a certain time, about
2 to 4 hours, depending on the characteristics of the electrolyte (soil or
water). In sea water the polarization of the protected structures can be
observed in a short time, but in high resistivity soils, the current should
sometimes be applied for a whole night prior to making the final
measurements. The time of all measurement should be recorded to
appreciate the electrical polarization of the structure. Besides de Pnat
measured before the test, active potentials (Pact) should be measured at
SINCOR
Project Title: SINCOR, C. A. Document: CA04-04-33-P-SP-030
UPSTREAM SURFACE FACILITIES PROJECT Page /File: 28/CA04-04-33-P-SP-030_X2.doc
Rev./Date: X2 / Oct,10-05
If The only measurements that can be taken are those of the circumference,
than other approaches should be used to estimate the T/S potentials
towards the center of the tank.
If its not possible to obtain full cathodic protection, the measured values of
potentials and the DC current output can be used to estimate the values of
the electrical parameters, such as amperage and voltage of the rectifier or
the number of galvanic anodes if the current demand is low.
SINCOR
Project Title: SINCOR, C. A. Document: CA04-04-33-P-SP-030
UPSTREAM SURFACE FACILITIES PROJECT Page /File: 29/CA04-04-33-P-SP-030_X2.doc
Rev./Date: X2 / Oct,10-05
The calculation and design of the CP Systems will cover the following subjects:
Analysis of the resistivity values along the routes of the different sections of the project
pipes.
Current demand calculated with the data of the different sections of the project pipes.
Interpretation of the P/S potential data of existing pipeline (with test points and
available), that cross or go parallel to the project pipelines.
Analysis of the behavior of the existing CP systems along the proposed pipe routes.
Analysis of the current demand and the CP levels achieved by other existing pipelines
crossing or paralleling the project lines. The current demand should consider a certain
amount of current that might be lost to other structures in the vicinity, if accidental b onds
might occur during construction of the installations (grounding systems attached to
tanks, pumps connected to pipelines, etc..).
Rectifier dimensioning.
CP groundbed designs with tubular Mixed Metal Oxide (MMO), cylindrical High
Chromium Cast Iron (FeSiCr) or other proven type of anodes for the pipelines between
the Main Station and Petrozuata.
CP groundbed designs for the tank bottoms, taking into account the probable high
resistivity of the soil in the area, to select a system with ribbon titanium anodes and
conductor bars located underneath the tank bottoms in the fill of the foundation.
Dimensioning of the positive and negative cables, and variable resistors in the junction
boxes.
Calculation of the electrical grounds for the CP equipment, rectifier and junction boxes.
Calculation of Polarization Cells in places where the towers of the HVL are at less than
30 m away from the project pipelines, and where the pipelines parallel the electrical
transmission lines.
The criteria for CP monitoring is based on the need to know if the CP systems are
working properly or not, if CP has been met according to NACE RP0169-96 or other
applicable Standards, and the necessity of their continuous operation and maintenance.
For this reason the following CP monitoring controls have been designed for the buried
sections of the project, pipelines or tank bottoms of the ASTs:
Standard Pipe to Soil (P/S) potential test points (N) along the pipe route.
Critical Areas P/S potential test points (ACR), at sites such as asphalt covered roads,
rivers, mayor creeks or sudden changes of the terrain topography or geology, along the
proposed pipe route.
P/S potential test points, at other pipe crossings or where the pipes parallel foreign
lines along the proposed route.
P/S potential test points, with buried probes and/or coupons, where the pipes parallel
other lines in corridors, specially in high resistivity soils.
P/S potential and sacrificial (magnesium) anodes test points, where special conditions
might require this type of anode, and the resistivity of the soil permits their use.
P/S potential test points, at monolithic isolation joints or insulating flanges, at both ends
of the different pipes (Main Station and Zuata), to observe the behavior of this electric
parameter on both sides of the isolating piece.
Inclusion in the distribution or junction boxes of shunts to measure current output going
to the CP impressed current system anodes and variable resistors to adjust this current
output if required. This will be used both on the CP systems for the buried pipelines as
well as for the anodes underneath the tank bottoms.
IR drop test stations for the pipe lines, to monitor coating and resistance to soil.
For the Monitoring and Commissioning Phase, as well as for the Operation and
Maintenance, a Manual should be prepared at the Detailed Engineering Level for the
pipelines and tankbottoms cathodic protection.