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APPENDIX 5B

Shah Deniz 2 Project


Composition and Function of Key SD2 Chemicals with Potential for
Discharge
Shah Deniz 2 Project Appendix 5B
Environmental & Socio-Economic Impact Assessment

The tables in this Appendix provide a list of the product name, chemical composition, function,
and usage of key products which will, or could potentially, be discharged to sea during all
phases of the Shah Deniz (SD) 2 Project. The tables also indicate the environmental rating of
each product.

Chemicals with the most favourable available environmental rating have been selected for the
project, with the aim of minimising the environmental impact of any unavoidable discharges.
The composition and chemistry of each planned or potential discharge has been fully taken
into account in the impact assessment process.

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Final
Shah Deniz 2 Project Appendix 5B
Environmental and Socio-Economic Impact Assessment

Table 1: Drilling Chemicals

Total Worst Case Discharge


Product Composition Function Rating Activity Application
Volume per Hole (Tonnes)
Pilot Hole Drilling (Seawater / PHB
Barite Barium sulphate Weighting Agent 648 E Drilling
Sweeps/ WBM)
Pilot Hole Drilling (Seawater / PHB
Bentonite Bentonite Viscosifier 30 E Drilling
Sweeps/ WBM)
Pilot Hole Drilling (Seawater / PHB
Soda Ash Soda Ash Alkalinity Control 3 E Drilling
Sweeps/ WBM)
Poly Anionic Water Soluble Polymer
Polypac UL 6 E Drilling Pilot Hole Drilling (WBM)
Cellulose Designed to Control Fluid Loss
Duovis Xanthan Gum Viscosifier 4 E Drilling Pilot Hole Drilling (WBM)
Nut Plug Nut Shells LCM /Pipe Scouring 3 E Drilling Pilot Hole Drilling (WBM)
Geotechnical Hole (Seawater / PHB
Barite Barite Weighting Agent 1200 E Drilling
Sweeps/ WBM)
Geotechnical Hole (Seawater / PHB
Bentonite Bentonite Viscosifier 90 E Drilling
Sweeps/ WBM)
Geotechnical Hole (Seawater / PHB
Soda Ash Soda Ash Alkalinity Control 7 E Drilling
Sweeps/ WBM)
Poly Anionic Water Soluble Polymer
Polypac UL 12 E Drilling Geotechnical Hole (WBM)
Cellulose Designed to Control Fluid Loss
Duovis Xanthan Gum Viscosifier 6 E Drilling Geotechnical Hole (WBM)
Nut Plug Nut Shells LCM /Pipe Scouring 3 E Drilling Geotechnical Hole (WBM)
42 Section (Seawater / PHB Sweeps/
Barite Barite Weighting Agent 116 E Drilling
WBM)
42 Section (Seawater / PHB Sweeps/
Bentonite Bentonite Viscosifier 35 E Drilling
WBM)
42 Section (Seawater / PHB Sweeps/
Soda Ash Soda Ash Alkalinity Control 1 E Drilling
WBM)
Poly Anionic Water Soluble Polymer
Polypac UL 2.1 E Drilling 42 Section (WBM)
Cellulose Designed to Control Fluid Loss
Duovis Xanthan Gum Viscosifier 0.35 E Drilling 42 Section (WBM)
Nut Plug Nut Shells LCM /Pipe Scouring 0.7 E Drilling 42 Section (WBM)

November 2013 5B/2


Final
Shah Deniz 2 Project Appendix 5B
Environmental and Socio-Economic Impact Assessment

Total Worst Case Discharge


Product Composition Function Rating Activity Application
Volume per Hole (Tonnes)
Magnesium oxide Magnesium oxide pH control 3 E Drilling 42 Section (WBM)
32 Section (Seawater / PHB Sweeps/
Barite Barite Weighting Agent 289 E Drilling
WBM)
32 Section (Seawater / PHB Sweeps/
Bentonite Bentonite Viscosifier 54 E Drilling
WBM)
32 Section (Seawater / PHB Sweeps/
Soda Ash Soda Ash Alkalinity Control 0.7 E Drilling
WBM)
Poly Anionic Water Soluble Polymer
Polypac UL 3.5 E Drilling 32 Section (WBM)
Cellulose Designed to Control Fluid Loss
Duovis Xanthan Gum Viscosifier 0.85 E Drilling 32 Section (WBM)
Nut Plug Nut Shells LCM /Pipe Scouring 1.4 E Drilling 32 Section (WBM)
Magnesium oxide Magnesium oxide pH control 3 E Drilling 32 Section (WBM)
28 Section (Seawater / PHB Sweeps/
Barite Barite Weighting Agent 1826 E Drilling
WBM)
28 Section (Seawater / PHB Sweeps/
Soda Ash Soda Ash Alkalinity Control 2 E Drilling
WBM)
Poly Anionic Water Soluble Polymer
Polypac UL 19 E Drilling 28 Section (WBM)
Cellulose Designed to Control Fluid Loss
Duovis Xanthan Gum Viscosifier 5 E Drilling 28 Section (WBM)
Borehole Stabiliser/Shale
Potassium Chloride Salts (KCI) 325 E Drilling 28 Section (WBM)
Inhibitor

Poly Ether
Amine/Poly Ether
Ultrahib Shale Inhibitor 96 GOLD Drilling 28 Section (WBM)
Amine Acetate
Blend

Aliphatic
Ultracap Anti-Accretion Additive 7 GOLD Drilling 28 Section (WBM)
Terpolymer
Ester/Alkenes
Ultrafree Shale Encapsulator 92 GOLD Drilling 28 Section (WBM)
C15-C18 Blend
Polyproplene
Super Sweep Hole Cleaning Agent 2 GOLD Drilling 28 Section (WBM)
Fibres
Oil well chemical
STARCARB Sealing/Bridging Agent 15 E Drilling Drilling Contingency Chemical (WBM)
containing quarts

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Final
Shah Deniz 2 Project Appendix 5B
Environmental and Socio-Economic Impact Assessment

Total Worst Case Discharge


Product Composition Function Rating Activity Application
Volume per Hole (Tonnes)
Calcined
STEELSEAL Sealing/Bridging Agent 15 E Drilling Drilling Contingency Chemical (WBM)
petroleum coke

Not
Currently
Listed
Into UK
EZ SPOT Pipe freeing agent Spotting Fluid 2.3 OCNS Drilling Drilling Contingency Chemical (WBM)
Ranked
Lists of
Notified
Products

N,N-methylene-
STARCIDE bis(5- Biocide 1.3 GOLD Drilling Drilling Contingency Chemical (WBM)
methyloxazolidine)

OXYGON:
OXYGON Oxygen Scavenger 0.3 GOLD Drilling Drilling Contingency Chemical (WBM)
granulate / powder
Synthetic chemical
SOURSCAV H2S Scavenger 1.9 GOLD Drilling Drilling Contingency Chemical (WBM)
compound
Bentonite Bentonite Viscosifier 5 E Drilling Drilling Contingency Chemical (WBM)
Sodium
Sodium Bicarbonate Alkalinity Control 1 E Drilling Drilling Contingency Chemical (WBM)
Bicarbonate
Magnesium Oxide Magnesium Oxide pH Control 6 E Drilling Drilling Contingency Chemical (WBM)

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Final
Shah Deniz 2 Project Appendix 5B
Environmental and Socio-Economic Impact Assessment

Table 2: Cementing Chemicals

Total Worst Case Discharge


Product Composition Function Rating Activity Application
Volume per Hole (Tonnes)

Cement Class G MODU


Cement Cement 151 E Section Casing Cementing
D907 Cementing
Dimethyl
Antifoaming Agent Siloxanes, MODU
Antifoam Agent 0.77 Gold Section Casing Cementing
D206 Silicones And Cementing
Sorbitan Stearate
Silicate Additive Silicic Acid, MODU
Cement Additive 0.91 E Section Casing Cementing
D075 Sodium Salt Cementing
Hematite Weighting MODU
Hematite Weighting Agent 1 E Section Casing Cementing
Agent D076 Cementing
Liquid Accelerator MODU
Calcium Chloride Accelerator 0.3 E Section Casing Cementing
D077 Cementing
Not
Currently
Listed Into
SALTBOND II Solution Of UK OCNS MODU
Dispersant 0.25 Section Casing Cementing
Additive D080A Aromatic Polymer Ranked Cementing
Lists of
Notified
Products
Liquid Retarder MODU
Lignosulfonate Low Temperature Retarder 0.4 E Section Casing Cementing
D081 Cementing
D095 Cement MODU
Glass Fiber Cement Additive 0.28 E Section Casing Cementing
Additive Cementing
MODU
Litefil D124 extender Aluminium silicate Solid Extender, cement additive. 19 E Section Casing Cementing
Cementing

Low Temperature Sulfonated


MODU
Liquid Dispersant Melamine- Dispersant 0.97 Gold Section Casing Cementing
Cementing
D145A Formaldehyde

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Final
Shah Deniz 2 Project Appendix 5B
Environmental and Socio-Economic Impact Assessment

Total Worst Case Discharge


Product Composition Function Rating Activity Application
Volume per Hole (Tonnes)

Not
Currently
Listed Into
UK OCNS MODU
Retarder D177 Organic Salts Mid Temperature Retarder 1.365 Section Casing Cementing
Ranked Cementing
Lists of
Notified
Products
Low Temperature Polycarboxylic MODU
Low Temperature Dispersant 0.35 Gold Section Casing Cementing
Dispersant D185 Polymer Cementing

Low Temperature
MODU
Cement Set Accelerator Cement or Cement Additive 0.1 Gold Section Casing Cementing
Cementing
Enhancer D186

MODU
Ultralite D188 Glass Extender 4 E Section Casing Cementing
Cementing
Fluid Loss Control MODU
Polymer Aqueous Fluid Loss Agent 2.7 Gold Section Casing Cementing
Additive D193 Cementing
MODU
Losseal W D199 Losseal W D199 Lost Circulation Material 0.9 Gold Section Casing Cementing
Cementing
Polymeric MODU
GASBLOK LT D500 Cement or Cement Additive 6.18 Gold Section Casing Cementing
Microgels Cementing

D600 GASBLOK
Latex Particles, MODU
Gas Migration Cement or Cement Additive 5.4 Gold Section Casing Cementing
Surfactant Cementing
Control Additive

Mid-Temp Retarder- Lignosulfonate MODU


Cement or Cement Additive 0.3 E Section Casing Cementing
LD Retarder Cementing
Sulfonated
MUD PUSH II Organic Polymer, MODU
Cement or Cement Additive 0.77 Gold Section Casing Cementing
Spacer D182 Glucoside Cementing
Polymer
Fluid Loss Control MODU
D168 Fluid Loss Control Additive 3.4 Gold Section Casing Cementing
Additive Cementing
MODU
D209 Extender Extender Cement or Cement Additive 4 E Section Casing Cementing
Cementing
Cement Class G MODU
Cement Cement 16 E Cement Unit Washing
D907 Cementing

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Final
Shah Deniz 2 Project Appendix 5B
Environmental and Socio-Economic Impact Assessment

Table 3: Blow Out Preventer Fluid Chemicals

Total Worst Case Discharge Volume (Litres), per


Chemical Activity Application
Well for Two Pods Testing

Propylene Glycol 513 Drilling BOP Testing


Ethylene glycol 30.78 Drilling BOP Testing
Monoethanolamine 10.26 Drilling BOP Testing
Triazine 5.13 Drilling BOP Testing
Triethanolamine 10.26 Drilling BOP Testing

Table 4: Commissioning and Operations Chemicals

Total Worst Case Concentration in


Product Composition Function Discharge Volume Rating Activity Application Discharge/Dosing
3
(m ) Regime

Combined Biocide,
Hydrosure Treat seawater used for
Corrosion Inhibitor and 0.75 Gold Jacket Installation Jacket Ballasting 1000ppm
HD50000 hydrotesting
Oxygen Scavenger
Tros Seadye Tros Seadye Dye 0.075 Gold Jacket Installation Jacket Ballasting 100ppm
Combined Biocide,
Hydrosure Treat seawater used for Subsea Export Pipeline Pre
Corrosion Inhibitor and 455 Gold 1000ppm
HD50000 hydrotesting Pipelines Commissioning
Oxygen Scavenger
Subsea Export Pipeline Pre
Tros Seadye Tros Seadye Dye 45 Gold 100ppm
Pipelines Commissioning
Combined Biocide,
Hydrosure Treat seawater used for Infield Subsea Flowlines Pre
Corrosion Inhibitor and 33 Gold 1000ppm
HD50000 hydrotesting Flowlines Commissioning
Oxygen Scavenger
Infield Subsea Flowlines Pre
Tros Seadye Tros Seadye Dye 3.3 Gold 100ppm
Flowlines Commissioning
Mono Ethylene MEG used to pre-fill Subsea Subsea Infrastructure
MEG 63 E n/a
Glycol (MEG) subsea components Infrastructure Installation
Subsea
MEG used to pre-fill Production Tree
MEG MEG 33.8 E Infrastructure n/a
subsea components Replacement
Intervention
Castrol Transqua Water Based Control Subsea control system Valve Operations
286.3 D Subsea Operations n/a
HC10 Fluid fluid and Discharge
Note: Volume of Castrol Transqua HC10 per discharged varies between approximately 4.5 litres per thousand barrel of condensate produced (plateau) to 0.2 litres per thousand barrel of
condensate produced (end of PSA)

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Final