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ETOOS & MOTION

JEE MAIN
TARGET IIT - JEE - 2017

Duration :3 Hours Max. Marks : 360

_________________________________________________________________________________________

INSTRUCTIONS

In each part of the paper, each section contains 30 questions. Total number of pages are 17. Please ensure that the

Questions paper you have received contains ALL THE QUESTIONS in each section and PAGES.

SECTION - C

1. Q.1 to Q.30 has four choices (A), (B), (C), (D) out of which only one is correct & carry 4 marks each. 1 mark will be

deducted for each wrong answer.

NOTE : GENERAL INSTRUCTION FOR FILLING THE OMR ARE GIVEN BELOW.

1. Use only HB pencil or blue/black pen (avoid gel pen) for darkening the bubble.

2. Indicate the correct answer for each question by filling appropriate bubble in your OMR answer sheet.

3. The Answer sheet will be checked through computer hence, the answer of the question must be marked by shading the

circles against the question by dark HB pencil or blue/black pen.

4. While filling the bubbles please be careful about SECTIONS.[i.e. Section-A (include single correct)]

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Page # 13 JEE MAIN

PART - III [CHEMISTRY]


Use Data : 1H1, 2He4, 3Li7, 4Be9, 5B10, 6C12, 7N14, 8O16, 9F19, 11Na23, 12Mg24, 13Al27,
16
S32, 15P31, 17Cl35.5, 19K39, 20Ca40, 26Fe 56, 29Cu63.5, 30Zn65, 24Cr52, 23V51
5. Calculate EAN for
SECTION - C (i) Fe2(CO)9 (ii) Fe3(CO)12
[STRAIGHT OBJECTIVE TYPE] (iii) Mn2(CO)10 (iv) Ir4(CO)12
Q.1 to Q.30 has four choices (A), (B), (C), (D) out (A) 36 36 36 86 (B) 36 36 34 86
of which ONLY ONE is correct (C) 36 36 34 84 (D) 36 36 36 84
1. One element has atomic weight 39. Its
electronic configuration is 1 s2, 2s2, 2p6, 3s2,
3p6,4s1. The true statement for that element is:
(A) High value of IE 6.
(B) Transition element
(C) Isotone with 18Ar38 For this structure of double chain silicates
(D) None
the number of oxygen shared per tetra hydra
2. Identify the correct order of acidic strengths is
of CO2, CuO, CaO, H2O : (A) 5/2 (B) 7/3
(A) CaO < CuO < H2O < CO2 (C) 9/4 (D) 4/5
(B) H2O < CuO < CaO < CO2
(C) CaO < H2O < CuO < CO2
(D) H2O < CO2 < CaO < CuO 7. Hybridisation of [Cu(NH3)4] SO4 is
(A) SP3 (B) dSP2
3. Among the following, the paramagnetic 2
(C) sp d (D) None
compound is
(A) Na2O2 (B) O3 8. The compound(s) that exhibit (s) geometrical
(C) N2O (D) KO2
isomerism is (are)
4. Statement-1 : In water, orthoboric acid (A) [Pt(en)Cl2] (B) [Pt(en)2]Cl2
behaves as a weak monobasic acid. (C) [Pt(en)2Cl2]Cl2 (D) None
Statement-2 : In water, orthoboric acid acts
as a proton donor. 9. Extraction for zinc from zinc blende is
(A) Statement-1 is True, Statement-2 is True ;
Statement-2 is a correct explanation for achieved by :
Statement-1 (A) electrolytic reduction
(B) Statement-1 is True, Statement-2 is True (B) roasting followed by reduction with carbon
; Statement-2 is NOT a correct explanation (C) roasting followed by reduction with
for Statement-1 another metal
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True. (D) roasting followed by selfreduction

(SPACE FOR ROUGH WORK)

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Page # 14 JEE MAIN

10. Oxidation states of the metal in the minerals 14. The crystalline structure of a solid is CCP for
haematite and magnetite, respectively, are 'X' atoms. If 'Y' atoms occupy all the
(A) II, III in haematite and III in magnetite octahedral voids and 'Z' atoms occupy all
(B) II, III in haematite and II in magnetite the tetrahedral voids, without any distortion
(C) II in haematite and II, III in magnetite in the CCP arrangement of 'X' atoms, then
(D) III in haematite and II, III in magnetite the fraction of body diagonal not covered by
11. Which kind of defects is introduced by doping the atoms is
in silicon crystal? (A) 0.26 (B) 0.24
(A) Dislocation defect (B) Schottky defect (C) 0.76 (D) 0.81
(C) Frenkel defect (D) Electronic defect
15. If the unit cell length of sodium chloride crystal
is 600 pm, then its density will be
12. A ferromagnetic substance becomes a
(A) 2.165 g/cm3 (B) 3.247 g/cm3
permanent magnet when it is placed in a
(C) 1.79 g/cm 3
(D) 1.082 g/cm3
magnetic field because
(A) All the domains get oriented in the
16. The inter-metallic compound LiAg crystallizes
direction of magnetic field.
in cubic lattice in which both Li and Ag have
(B) All the domains get oriented in the direction
Co-ordination number of 8. The class of
opposite to the direction of magnetic field crystal is
(C) Domains get oriented randomly. (A) Simple cubic (B) BCC
(D) Domains are not affected by magnetic (C) FCC (D) End centred cubic
field.
17. A mineral having the formula AB2 crystallizes
13. Give the correct order of initials T (true) or F in the CCP lattice, with the A atoms occupying
(false) for following statements: the lattice points. What is the coordination
I. In an anti-fluorite structure, anions form number of the B atoms?
FCC and cation occupy all the tetrahedral (A) 4 (B) 6
voids. (C) 8 (D) 12
II. If the radius of cation and anions is 20
and 95 pm, then the coordination number of 18. In a cubic closest packed structure of mixed
cation in the crystal is 4. oxides, the lattice is made up of oxide ions.
III. An atom or ion is transferred from a lattice Tetrahedral voids are occupied by divalent
site to an interstitial position in Frenkel defect. X2+ ions and octahedral voids are occupied
IV. Density of crystal always increases due by trivalent Y3+ ions. If only 50% of the
to substitutional impurity defect. octahedral voids are occupied, then the
(A) TTTT (B) FFFF percentage of tetrahedral voids occupied is
(C) FFTT (D) TFTF (A) 50 % (B) 12.5 %
(C) 25 % (D) 40 %

(SPACE FOR ROUGH WORK)

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Page # 15 JEE MAIN

19. The densities of ice and water at 0C and 1


bar are 0.96 and 0.99 g/cm3, respectively. If
OH O
the percentage of occupied space in ice is x, 22. SOCl2
Mg,

P yridine Et O +
then the percentage of empty space in water O
2
H3O
is
Product of reaction is :
32 33 OH
(A) x (B) x (A)
33 32 O

33 32 O CH3
(C) 100 x (D) 100 x
32 33 (B) CH C
O CH 3
20. Pac ki ng fract i on i n 2D he xagonal
arrangement of identical spheres is
CH3

(A) (B) (C) O CH2 C CH2 OH
3 2 3 3
CH3
(C) (D)
2 3 6 OH
(D)
O CH2 CH 2 C CH 3
21. Find the product of the following reaction
CH3
Et2O HBr, hv
H2CCHCH2Br+Mg A B
Benzoyl Peroxide O
O
PhMgBr
23. CH 3 CH2 C H Products
Find out 'B' : H3 O
(A) HOH2CCH2CH2Br Products obtained in the reaction are :

Br (A) Meso
(B) HOCH 2CHCH 3 (B) Racemic
(C) HOH2CCH=CH2 (C) Homomer

(D) Diastereomer
(D) Br Mg C H2CH=CH 2

(SPACE FOR ROUGH WORK)

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Page # 16 JEE MAIN

24. In the following reaction the most probable CH3


product will be :
NBS KCN(alc.)
26. A B;
Br (2 equ.) (1 equ.)

H CH3 OH
H3C H CH2CH3
SN 2
C 2H 5
Prodcut B is
OH CH3 Br
OH CN
H CH3 H
(A) (B) H C H
H3C H 3

C2H5 C2H5
(A) (B)

C2H5 CH3
H CH3 HO H Br Br
(C) H3C H (D) H3C H Br Br
OH C2H5

25. Correct order of rate of SN2 reaction : (C) (D)

Br Br Br Br CN

27. Consider the following nucleophiles :

O O O

OCH 3 CH 3 NO2 CF3 S O, Ph S O, Ph O, CH3 C O
(P) (Q) (R) (S)
O O
(I) (II) (III) (IV)

(A) Q > R > P > S when attached to sp3-hybridized carbon, their


(B) R> Q > S > P leaving group ability in nucleophilic substitu-
tion reactions decreases in the order
(C) P > Q > R > S (A) I > II > III > IV (B) I > II > IV > III
(C) IV > I > II > III (D) IV > III > II > I
(D) S > P > R > Q
(SPACE FOR ROUGH WORK)

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Page # 17 JEE MAIN

28. Arrange the following in decreasing order of


E2 reaction

(A) X > Y > Z (B) X > Z > Y


(C) Z > X > Y (D) Y > X > Z

Me
Me
+
N

O
29. Major product

CH3

(A) (B)

(C) (D) None of these

KOH(alc.)
30. PhCH2CHCH3 PhCH=CH CH3
Br
path of reaction which is followed mainly
(A) E1 (B) E2
(C) Ei (D) E1CB

(SPACE FOR ROUGH WORK)

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