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30 No\EMBER1999 PHYSICS
ToDAY o teeeAocntu l^nnu. ol P6Iis. s
FrcuRr 1. FRIEDMLAT cRoss sEcTroNs.
The two conpurersimularioncotrrour
m-apsare tor a geomerfica y ideaiizeddisk
or ma! Jt rhe end offryins. The rop prnel
's s,mptl a remperaru.e prolite.Is .enrrJ
bluemdicrre\the defted finJt core,emoer
-
ature, and rhe outs-rd progression to
greenmd ye ow ind;caiesiisher remoera,
ruresne:rerthe trying 'u,f-e1 1Tn. rco
surt*e hs cooledsincen -r h,t on rh.
pan.)The niddie panelis a orofile of the
exponenrial rhernal vdabl; Z. intesrared
avpr the cookins!ins. (Seefrqure2 fir the
Midl .oro, scate.) Thd n r herie.,ndnror of the
rhernal history of the proces and ns
ettectson rhe mearprorins.Ir nore ctose-
1y tesemblesthe numced iofornation :
cook getshom the actualcoior proflleof a
Mi.U cookedsteak (botton pael).
No\EMBER1999 pHystcsToDAy 31
oven.i., uro.ced 175.c (350.F) 20 165 l
oven tr, forced17s'c s0 'I) 165 2A
lrring oil, unJ6.ed 175'C (r50 'F) 165
lrritrg oil, fored 17s'c (350'D 165 320
,i/ntr belov bonea"c (2a0"4 80 160
100'c 10000
T I
Saturated$ern 100'C (212 20000 2000
I I
!m f.rins 175"C Pso "F) 100 50
100'c 100 290
'0
I I,l!o
Glovinscoals1000"c (1900 990
50 290 15
T
Oren v:lL md ai. :r00 'C (575 'F) 290
boiling point, all the \rater in that pofiion has to boii away polyiers of amino acids that arc folded and held in par-
first. So even ilthe very suface ofthe meat drieE out and ticular three-dimensionalshapesby heans of inbamolec-
clinbs above the boiling point, jNt below it tu a layer that ular bonds. In muscle, these pob'rners reach molecular
is still moist ard the.efore still boilins off water. The inte- weights as high as 106amu. The proteirs are ananged in
or bulk of the meat thus experiences temperatue two kinds of stroctues. The first are the contractile ffbers
chmg$ as if it were srmouded Dot by hot coals, but by md associated enzlnes, which peform the work of mov-
boiline water. ins the mimal. The second ae the thin sheaths of con-
In cookins methods that allow surface moistue to nective tissue (larsely the pmtein caled collagen) that
evaporate-such as masting, erilling, and fiying-ihe Bmound each muscte cell and each bundle of cells. These
water also slows the initial heating of the sudace to the sheaths contain. reinforce. and harness the fibers.
boilins point. This etrect is esseDtially the reve$e of con- Wlen meat iB heated to arcurd 50 'C (120 'F),
densation, wherein the phase chDge of steaE to liquid incrcased molecular motion besins to break intrdolecu-
water rcleases a bemendous amount of heat to the meat lar bonds and undo the native folded structure of the pro
E!r{ace. The liquid water on a moist meat Bur{ace absolbs teins. Thus the proteins Iose their tunctional activity and
l h e s d D e l r c m p D d o u sm o u l o l L e a l w h c n i l v a p o f l z e s , are said to be denatured. Unfoldins also exposes reactive
and thus leaves less heat behind to raise the temperature regions of the protein nolecules, which are then free to
of the neat. In an oven just at the boiling point, the Bu- DarticiDate in the formation of tntrmolecular bonds.
face tmperature of a perspiring roast will rcmain below Th; denatued proteins thus form solid assresates
75 'C (170 "I') for houis. with a reduced capacity for retaidns water The meat
becomesfirmer ir 1ex1ure,sd lrshrer and Do.e opaquein
Denrturing protein appeannce. At eoud 60 "C (140 "F), the comective tis-
The most comon cuts of meat come ftom the skeletal sue sheaths collapse and shrink, thE exer-ting prese]lre on
musclesof animals. They can be thought of as a matrix of the free water in the muscle cel]s. The water flovs out the
pmtin molecules and water.r ProteinB a.e long linear ends of t}le muscle fibers, dd the meat seems, for the
4*r=too'c
FIGTIRE2. SIMUI-ATEDDONENESS PlG
B!ry
{il files and cooking tines for neardisks of
various thickressesimnersed in hot Liquid
(at 80 "c or 100'C) andcookedto 60 "c
at the center. In eachcse the staning ten-
10 12 14 16 13
cooKING TIME (ninuF,
{l the time scaleshov rhe :5 "C tolerance
32 NoVEMBER
1999 PHYsrcs
ToDAY
? d d J = 1 0" c
o r00
424 2A
345678910 0
'm,IE
(niftres)
120
moment, wondeffi y juicl But once rhe juice flows fiom Computermodelsfor immersionand frying
t h F o e a l i r - g o n p :a n d i I r h e r F r p c r e t L U - p g a r s m L . h The starting point
a b o ! ? / 0 " C r 6 0 " F , . r \ e m " a r o e c o m " sv e , 1 o r 1 r d e e o . for the analysis of conductive heat
l l s i n r h s s m pr F m p e r aur . p r s n g e r n " r t h e p r g m " n r transier iB the 1807 Fouier heat equation:
m \ o s l o b i n w h ' c h i . h b a r m a k 's r d s m F a r o o kr e d d " n a _ Q = h A dT /dr.
i r r e . a n d r L r . s C r a y i " nb r o q . T h s r q $ b y n e " r d o n p n e q s
It Btatesthat the rate ofone dinensional heat flow. e, is
i 3 u . u a l l y . u d g " d h ) c o l o r :a d a r i r p d i n r F n o r i FS F t - t . k pE, pmporiional
U s l I r F d i r r " r o . s f i m e r s n d j J i c r e " ,a n d a d u l l i n r " . i o r to the ooss-sectionalareaA and the tenper-
a t u r p g ' s d i e n t . T r e c o n s r a n ro l p r o p o , r r o r a l i r \*. . i s l l p
i s h r m e r . L i l l e d d D . I n e e n F r a l .L h eo n J r . , e b b k n o s e
materur s therral conductivitv.
nleiors d"e 'llenr:o d'y hFar"dDa.r 70 "C d.p rough
I n v o k i r g e n " r g y c o n s F r u a r i o ra n d g e n p " a t r z i n gr o
culs uhosp abu.rdaDlolnec' \p I s-,p.ottdCpnmLsr br
t h . e p d ' m F n so r s . o n e g F r . t h F d i t T u " . o nequaLion
thoroughly dismantled.
But cooks routinely erpose meat extedors to temper- V ( k v ' I ) = p C d'I/dt,
a t u . e s w e l l a b o v c t 0 0 . c n a r d e r r o d e l e t o pa d r j . t u s l where p is
the matedal's density and C is its heat
a n d r h " " i r h f l d v o r sa n d d s r k c o t o r . h a r r p ; L t r f r o m s o
c a l e d M ' i l a . d r c d r i o n .d l d B h l F m p p . s r u r e $ r h " n h e d l ft deternine the time evolution of the mear rempera
r q l n u s d D p | l F df r o m g t o \ f f S , n a t s0 r d v e h ] o r p a n , 8 u o i L r e n q l i r p .
l h c s o l u ro n o l l h i . p a n i a t o i l e r e r t i a l ; q u s -
suda@ resions of the meat necessadty spend tim; at high rion.MLh lhF
iemperatures that dry the fibeIS out. A sreak gdled to 60 radialive boundary " p p r o D i s i ec . o d u c r i v e..o l v e . t i \ e , a r d
conditions. This car be dore anarpr
" ( - I 4 0 " F l d r t b e c p . t e r$ . h a v e a r e m p e r a r ; F o ^ t 0 0 " C c d - v l o " o n r
l h e s m p l p s r c a s p s .F o r c p o n p l r , p s a n d
s r r h " s u ' f a c e .a n o w s p a D h a r r - r p e " " r r r c , s n g e ; n b o u d d " t ,
c o n dr i o n . t w i . a r o . r ] e a r c o o k j ; c ,r r p d i f t u . i o n
equation hust be solved nme calb This is t)"icslly
F o " t h o s es h o F n j o yb o l h j r i . \ a r d d r v p o - r i o n b1 a done by
. . c Lo i t i l e . discretizins the equation witil tinite volu;e eie-
" r l F b : L r h i " d o - e n F 6 " e - s d i e nrr" a D r e a ; a ;
s ment-B and frnite tempemture ditrerences. The resnlrins
B u l o r l h o s F. h o r v E n rb o t h a f l a v o r f l . r r a c p d n d r h e set of alsebraic
ju:cies.Dosqible equations can then sotved nmericatty. i
i n , e n o r r h e e r a d p r r o o q e sa , h a . n s e : vdiety of software packases
are available fo. this task.
H o $ . d l h ec o o \D n r n z p t b e . r a r l i o i o f r h p ; n L e r o r L h a l We have used one such program, r,lexpDE, ftorn pDE
rises abovea dryins 70 "C (160 .F)?
S o l L , i o n s l. - c . A ! F r " i o Do f r h i . p . o s , s m .t : D p d l o r w o -
Another chalense for the exacrine cook is that it d mer.ional p.oblems, car be do*lrjosdFd .ior r\e com-
takeB only a minute or two for rneat io so fron srccuieni
qanyn Web site for educationat uBe.8)An input fite for
L a d e s r c d r F d b e r a " s e r h p . " ' r " r r e m p ; . ! r u r e n c r e a s e s FlexPDE
inciudes the problem seomerrt. relev;t themal
\ p r y r a p , d y i n r F p n s . r o L $ , . d o ; o " d c c F p l d o , t i r yprcpedies
of the modeled material, initial and bouda{r
between55 and 70 "C (130 160 "F). In a steal or ahop,the c o n d , r i o n - .
d n d r h p s o v e r n i n sd i f f u . o n e q u s | o n . T h e p r c -
rate ofcenhal temperaturc indease caD exceed10 .-Cper
minute. In a roasting chicken, it's a much nore teisur;ly e r a m d ) r a n r i c a U yd r v i d e -r h p l o d e l F dv o t u D ei n r o a t , d
o f d o p r o D r i a F l ys i z e dc e u sd o a d j u s r su r e u m * s , c p . r z e
1.5'C per minute. l o k p e pc o r p u i a i o n a l e m o r sw i t h i n d . c a p l a b . F e i l s
W]iat can cooks do to minimize the unavoidabte over- F ^ r o u . i r m F r i c " .e r T e r m e n r s ,$ e ; b r a i n e d r h e r n a
cookins of the outer podions of mear? And how can rhey properties
and heat transfer coefficients from rhe litera-
malimize the window oltime in rhich the ceDter is ctose tue, and chose
{epresentative dimensions for a modet
r o L h pd e s i r e dd o n p r F s s T r r F s es e r n p q u e q r r ob, . e 1 d \ e hamburyer-a disk 10 cm h diameter
tned to addrcss and 2 cm thick.
F{,.ins and total imme$ion of the hamburser shape were
NoWMBER1999 PHysrcsToDAy 33
1,20 124
O 1oo 6roo
880
5 5
960
a
Er10 840
F,.
0
0 1 2 3 4 t 6 7 8 91arr12 01 2 3 4 5 6 7 8 9 1 0 1 11 2
120
o r'- 100
FIGURT4. EFFTCTOF ILI?PING
frequdc). on rhe sinulated renferaruie F
evolurior dd final donenes profile of a
2 cm thick meat disL cooLedto 60 oC at fr
the cdter. Eachsimulatioq startsat
10 "C, with the iDd;catedfli! inrerals,
E
F
fron 6 ninutes down to 15 seconds.
0;
4 5 L 7 S 9141112 4 5 6 7 I91A1rt2
TIME (miruE
beated as two-dimenBional problems, the geomehy being 10 "C rise in tempemture. Rather than trying to define a
ais)mmetric. We ignored dimensional chang$ and mass denaturation mte, ia'e simulate a mte etrect in our models
ad heat hansfer caused by fluid movement vithin and by defining m etrective exponential thermal variable ?',
otrt of t}Ie meat. Ard we made simplifyins asstrmptions which vmishes abnptly below 55 'C. Alove this tlresh-
based on the fact that the meat's water content sets an old, it is siven by
etrective mdimum cooking temperatue of 100 "C.
Ta=ft1o tn T>55'C.
Ior the frying model, we simulated flipping a ham-
buser by exposing one side to a cookins sudace at 100 'C where ? tu the temperature in centisrade. Thus defned,
for a given time interval, while the other side lost heat by ?' dollbles with every 10 "C Iise ir temperaturc above the
conduction and convection. In aI cases. we ran the simu- 55 'C denatuing thrcshold. We then integated ?" over
latioD util the meat center reached a teDperature of the cooking time at each of 200 points in the meat's cenhal
60 "C (140 "I'), ihe equivalent of'medim rare." The sener- transve$e plme and plotted these inte$als in contou
al validity of the models was con$med i4 several kitchen maps t}Iat show the rclative donenesB of diFerent reeions
expedmenk uBing sli@B of beef eye of.ound and a disital in the meat. The difference behveen such a map and a
themometer with a themo@uple plobe 1 bm in diametr stmdard temperature map is most evident in the case of
fting, where the cooling of the otr-heat side dissrises its
The key parameter:
time at temperature thermal history (See figue 1).
For the gaphical rcFesentation of our reBults, we devel A contou map of relative doneness has the vidue of
oped a fomat sussested by the actual expedence of cook- r$emblins the visual inlomation provided to the cook by
ins meat. A siDple map of the temperatue distibution the ooss section of a real piece of meat. But it otrers ody
aooss a slice ofmeat is not the most relevant display for a qualitative basis for comparing the etrects of ditrerent
the cook, because it rcpresents only one instant in the cooking rcgimes. We the.eforc srmDed the 200 individual
cooking pFocess.Doneness and cooked quality is a functioD integrals of ?' over time for each simulation e4 for con-
of the meat's therlnal history in particuls its cuquEuve venience, divided by 106 to obtain an overalt 'doneness
exposure to the proteia-denatuins dd dehydrating tem- indel' for each meat disk.
peraturcs above 55 'C (130 "F). The Deat proteins, includ- This srn k a simple nmedcl indicator of the meat
ing the pigment, are $sentialy molecular sensors that disk's total exposure to denatu ng temperatuies. Becaue
register their clnllative temperature exposue. The color ail simulations werc rur to the same endpoint tempera
gadient acrGs e slice of meat is thus a reFesentation of turc, 60 "C (140 'F) at the centr, a relatively low doneness
the integal oftemperatue exposure over time. We there- index reflecb less overcooking of the outer reaches and
fo.e chose to display our results in a contou map ofa such thereforc a moistex more tender outcome.
We decided asainst using a Eimple tiDe intesal of Immersion: cut thin and don't boil
temperaturc it"self, because such an splession neglects We besM with the simple case of immenins the meat dtuk
the important effect of tempemtue on the rate of protein in hot Iiquid that instantly raises the entire meat surface
denatuation, dd thus of changes in meat textue and to the liqldd temperature and maintains it therc.
color. Fint-order chenical reaction rates ue observed to Althoueh few cooks would actually boil a hamburgr, this
fo ow an Arhenius relation of the fom case does appronmat the conditione for simerine stew
meats and poaching tuh, as well as the double sided 6y,
R= R^e'p(-E/kT),
ins ofhamburse$ practiced in some fast-food restaurants
where , is the averase themal eneryy requhed to initiate Dd offercd by specialized hamburger appliances for the
the rcaction. Reaction mts tJ,"ically double with each home kitchen. We varied two Darameters-the thickness