Se dispone de los datos siguientes para un gas monoatmico, uno diatmico y uno triatmico a 0C:

a) Representar PV frente a P. Son ideales los gases?

b) Utilizar las tres series de datos para obtener el valor de la constante de los gases, R.
c) Calcular el segundo coeficiente del virial para cada gas y discutir si predominan las interacciones atractivas
o las repulsivas en el intervalo de presiones medidas.

Ne O2 CO2
PVm(atmL/mol PVm(atmL/mol
P / atm Vm / L/mol ) P / atm Vm / L/mol ) P / atm Vm / L/mol
1.0000 22.4280 22.4280 1.0000 22.3939 22.3939 1.0000 22.2643
0.6667 33.6360 22.4251 0.7500 29.8649 22.3987 0.6667 33.4722
0.3333 67.2567 22.4167 0.5000 44.8090 22.4045 0.5000 44.6794
0.2500 89.6384 22.4096 0.3333 67.0962
0.2500 89.5100

a= 22.4119182 a= 22.4149 a= 22.4142964

b= 0.0170124 b= -0.02117 b= -0.1494192
R = 0.92528094 R = 0.99868838 R = 0.99950127

22.4500

f(x) = 0.0170124031x + 22.411918168

22.4000 R = 0.9252809402
f(x) = - 0.02117x + 22.4149
R = 0.9986883785
f(x) = - 0.1494192211x + 22.4142964116
22.3500 R = 0.9995012734
PVm(atmL/mol)

22.3000

22.2500

22.2000

22.1500
0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000 1.1000

P (atmL)

Ne Linear (Ne) O2 Linear (O2)

CO2 Linear (CO2) Linear (CO2)
 Ne O2 CO2
a= 22.4119182 a= 22.4149 a= 22.4142964
R= 0.08209494 R= 0.08210586 R= 0.08210365

Prom. 0.08210148

22.4500

f(x) = 0.0170124031x + 22.411918168

22.4000 R
f(x)= =0.9252809402
- 0.02117x + 22.4149
R = 0.9986883785
f(x) = - 0.1494192211x + 22.4142964116
R = 0.9995012734
22.3500
PVm(atmL/mol)

22.3000

22.2500

22.2000

22.1500
0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000 1.1000

P (atmL)

Ne Linear (Ne) O2 Linear (O2) CO2 Linear (CO2)

22.4500

f(x) = 0.0170124031x + 22.411918168

22.4000 R
f(x)= =0.9252809402
- 0.02117x + 22.4149
R = 0.9986883785
f(x) = - 0.1494192211x + 22.4142964116
R = 0.9995012734
22.3500
PVm(atmL/mol)

22.3000

22.2500

22.2000
PVm(atmL/mol)
22.3000

22.2500

22.2000

22.1500
0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000 1.1000

P (atmL)

Ne Linear (Ne) O2 Linear (O2) CO2 Linear (CO2)

tmico a 0C:

interacciones atractivas

CO2
PVm(atmL/mol
)
22.2643
22.3159
22.3397
22.3632
22.3775

000 1.0000 1.1000

000 1.0000 1.1000

ar (CO2)
000 1.0000 1.1000

ar (CO2)
 30.0

25.0

20.0
P (bar)

15.0

10.0

5.0

0.0
0.00 2.00 4.00 6.00 8.00 10.00 12.00

Vm (L/mol)

Gas Ideal Gas VdW Gas VdW Gas VdW

b=0 a=0
2. Construir una hoja de clculo que permita representar en un mismo grfico las curvas P vs V m
para la expansin isotrmica reversible desde 1.0 a 10 dm 3/mol a 298 K de:
a) Un gas perfecto.
b) Un gas de Van der Waals con a=4.2 dm6 bar/mol2 y b=0
c) Un gas de Van der Waals con a=0 y b=5.10510-2 dm3/mol
Explorar la importancia de a (el trmino atractivo) y b (el trmino repulsivo) en la modificacin del rea bajo la isoterma y por c

a
P 2 Vm b R T
T (K) 298 Vm
a (L2 bar/mol2) 4.2
b (L/mol) 5.105E-02 0
R (barL/Kmol) 8.31000E-02

Gas Ideal Gas VdW Gas VdW

b=0

Vm PEXT PEXT PEXT

(L/mol) (bar) (bar) (bar)
1.00 24.7638 21.8960 20.5638
1.02 24.2782 21.5204 20.2413
1.04 23.8113 21.1574 19.9282
1.06 23.3621 20.8061 19.6241
1.08 22.9294 20.4662 19.3286
1.10 22.5125 20.1371 19.0415
1.12 22.1105 19.8183 18.7623
1.14 21.7226 19.5092 18.4909
1.16 21.3481 19.2096 18.2268
1.18 20.9863 18.9189 17.9699
1.20 20.6365 18.6368 Chart Title
17.7198
1.22 20.2982 18.3628 17.4764
1.24 19.9708 30.0000 18.0968 17.2393
1.26 19.6538 17.8382 17.0083
25.0000
1.28 19.3467 17.5869 16.7832
1.30 19.0491 20.0000 17.3425 16.5639
1.32 18.7605 17.1047 16.3500
1.34 18.4804 15.0000 16.8733 16.1414
1.36 18.2087 16.6481 15.9379
1.38 17.9448 10.0000 16.4287 15.7394
1.40 17.6884 16.2150 15.5456
5.0000
1.42 17.4393 16.0067 15.3564
1.44 17.1971 0.0000
15.8037 15.1716
1.46 16.9615 0.00 15.60572.00 4.00 6.00
14.9912 8.00 10.00 12.00
1.48 16.7323 15.4126
Col umn B 14.8148
Col umn C Col umn D Col umn E
1.50 16.5092 15.2242 14.6425
1.52 16.2920 15.0403 14.4741
1.54 16.0804 14.8608 14.3094
1.56 15.8742 14.6854 14.1484
1.58 15.6733 14.5142 13.9909
1.60 15.4774 14.3469 13.8368
1.62 15.2863 14.1833 13.6859
1.64 15.0999 14.0234 13.5383
1.66 14.9180 13.8671 13.3938
1.68 14.7404 13.7142 13.2523
1.70 14.5669 13.5646 13.1137
1.72 14.3976 13.4183 12.9779
1.74 14.2321 13.2750 12.8448
1.76 14.0703 13.1348 12.7145
1.78 13.9122 12.9974 12.5867
1.80 13.7577 12.8629 12.4614
1.82 13.6065 12.7312 12.3385
1.84 13.4586 12.6021 12.2180
1.86 13.3139 12.4756 12.0999
1.88 13.1722 12.3516 11.9839
1.90 13.0336 12.2300 11.8701
1.92 12.8978 12.1108 11.7585
1.94 12.7648 11.9939 11.6489
1.96 12.6346 11.8792 11.5413
1.98 12.5070 11.7666 11.4357
2.00 12.3819 11.6562 11.3319
2.02 12.2593 11.5478 11.2300
2.04 12.1391 11.4415 11.1299
2.06 12.0213 11.3370 11.0315
2.08 11.9057 11.2344 10.9349
2.10 11.7923 11.1337 10.8399
2.12 11.6810 11.0348 10.7465
2.14 11.5719 10.9376 10.6548
2.16 11.4647 10.8420 10.5645
2.18 11.3595 10.7482 10.4758
2.20 11.2563 10.6559 10.3885
2.22 11.1549 10.5652 10.3027
2.24 11.0553 10.4760 10.2182
2.26 10.9574 10.3884 10.1351
2.28 10.8613 10.3021 10.0534
2.30 10.7669 10.2173 9.9729
2.32 10.6741 10.1339 9.8937
2.34 10.5828 10.0518 9.8158
2.36 10.4931 9.9710 9.7390
2.38 10.4050 9.8916 9.6635
2.40 10.3183 9.8133 9.5891
2.42 10.2330 9.7363 9.5158
2.44 10.1491 9.6605 9.4436
2.46 10.0666 9.5859 9.3726
2.48 9.9854 9.5124 9.3025
2.50 9.9055 9.4400 9.2335
2.52 9.8269 9.3687 9.1655
2.54 9.7495 9.2985 9.0985
2.56 9.6734 9.2293 9.0325
2.58 9.5984 9.1612 8.9674
2.60 9.5245 9.0940 8.9032
2.62 9.4518 9.0278 8.8400
2.64 9.3802 8.9626 8.7776
2.66 9.3097 8.8983 8.7161
2.68 9.2402 8.8349 8.6555
2.70 9.1718 8.7724 8.5956
2.72 9.1043 8.7108 8.5366
2.74 9.0379 8.6500 8.4785
2.76 8.9724 8.5901 8.4210
2.78 8.9078 8.5310 8.3644
2.80 8.8442 8.4727 8.3085
2.82 8.7815 8.4152 8.2533
2.84 8.7196 8.3585 8.1989
2.86 8.6587 8.3026 8.1452
2.88 8.5985 8.2473 8.0922
2.90 8.5392 8.1928 8.0398
2.92 8.4808 8.1391 7.9882
2.94 8.4231 8.0860 7.9372
2.96 8.3661 8.0336 7.8868
2.98 8.3100 7.9819 7.8370
3.00 8.2546 7.9308 7.7879
3.02 8.1999 7.8804 7.7394
3.04 8.1460 7.8307 7.6915
3.06 8.0927 7.7815 7.6442
3.08 8.0402 7.7330 7.5975
3.10 7.9883 7.6850 7.5513
3.12 7.9371 7.6377 7.5057
3.14 7.8866 7.5909 7.4606
3.16 7.8366 7.5447 7.4160
3.18 7.7874 7.4991 7.3720
3.20 7.7387 7.4540 7.3285
3.22 7.6906 7.4094 7.2855
3.24 7.6431 7.3654 7.2431
3.26 7.5963 7.3219 7.2011
3.28 7.5499 7.2789 7.1595
3.30 7.5042 7.2364 7.1185
3.32 7.4590 7.1944 7.0779
3.34 7.4143 7.1529 7.0378
3.36 7.3702 7.1119 6.9982
3.38 7.3266 7.0713 6.9589
3.40 7.2835 7.0312 6.9201
3.42 7.2409 6.9915 6.8818
3.44 7.1988 6.9523 6.8439
3.46 7.1572 6.9135 6.8063
3.48 7.1160 6.8752 6.7692
3.50 7.0754 6.8372 6.7325
3.52 7.0352 6.7997 6.6962
3.54 6.9954 6.7626 6.6603
3.56 6.9561 6.7259 6.6247
3.58 6.9173 6.6896 6.5896
3.60 6.8788 6.6537 6.5548
3.62 6.8408 6.6182 6.5203
3.64 6.8032 6.5830 6.4863
3.66 6.7661 6.5482 6.4525
3.68 6.7293 6.5138 6.4192
3.70 6.6929 6.4798 6.3861
3.72 6.6569 6.4461 6.3534
3.74 6.6213 6.4127 6.3211
3.76 6.5861 6.3797 6.2890
3.78 6.5513 6.3470 6.2573
3.80 6.5168 6.3147 6.2259
3.82 6.4827 6.2827 6.1948
3.84 6.4489 6.2510 6.1641
3.86 6.4155 6.2196 6.1336
3.88 6.3824 6.1885 6.1034
3.90 6.3497 6.1578 6.0736
3.92 6.3173 6.1273 6.0440
3.94 6.2852 6.0972 6.0147
3.96 6.2535 6.0673 5.9857
3.98 6.2221 6.0378 5.9569
4.00 6.1910 6.0085 5.9285
4.02 6.1601 5.9795 5.9003
4.04 6.1297 5.9508 5.8723
4.06 6.0995 5.9223 5.8447
4.08 6.0696 5.8942 5.8173
4.10 6.0400 5.8663 5.7901
4.12 6.0106 5.8386 5.7632
4.14 5.9816 5.8112 5.7365
4.16 5.9528 5.7841 5.7101
4.18 5.9244 5.7572 5.6840
4.20 5.8961 5.7306 5.6580
4.22 5.8682 5.7042 5.6324
4.24 5.8405 5.6781 5.6069
4.26 5.8131 5.6522 5.5817
4.28 5.7859 5.6265 5.5567
4.30 5.7590 5.6011 5.5319
4.32 5.7324 5.5759 5.5073
4.34 5.7059 5.5509 5.4830
4.36 5.6798 5.5261 5.4588
4.38 5.6538 5.5016 5.4349
4.40 5.6281 5.4773 5.4112
4.42 5.6027 5.4532 5.3877
4.44 5.5774 5.4293 5.3644
4.46 5.5524 5.4056 5.3413
4.48 5.5276 5.3821 5.3184
4.50 5.5031 5.3588 5.2957
4.52 5.4787 5.3357 5.2731
4.54 5.4546 5.3128 5.2508
4.56 5.4307 5.2902 5.2287
4.58 5.4069 5.2677 5.2067
4.60 5.3834 5.2454 5.1849
4.62 5.3601 5.2232 5.1634
4.64 5.3370 5.2013 5.1419
4.66 5.3141 5.1796 5.1207
4.68 5.2914 5.1580 5.0997
4.70 5.2689 5.1366 5.0788
4.72 5.2466 5.1154 5.0580
4.74 5.2244 5.0944 5.0375
4.76 5.2025 5.0735 5.0171
4.78 5.1807 5.0528 4.9969
4.80 5.1591 5.0323 4.9768
4.82 5.1377 5.0119 4.9569
4.84 5.1165 4.9917 4.9372
4.86 5.0954 4.9717 4.9176
4.88 5.0745 4.9518 4.8982
4.90 5.0538 4.9321 4.8789
4.92 5.0333 4.9126 4.8598
4.94 5.0129 4.8932 4.8408
4.96 4.9927 4.8739 4.8220
4.98 4.9727 4.8548 4.8033
5.00 4.9528 4.8358 4.7848
5.02 4.9330 4.8170 4.7664
5.04 4.9135 4.7984 4.7481
5.06 4.8940 4.7799 4.7300
5.08 4.8748 4.7615 4.7120
5.10 4.8556 4.7433 4.6942
5.12 4.8367 4.7252 4.6765
5.14 4.8179 4.7072 4.6589
5.16 4.7992 4.6894 4.6414
5.18 4.7807 4.6717 4.6241
5.20 4.7623 4.6542 4.6069
5.22 4.7440 4.6367 4.5899
5.24 4.7259 4.6194 4.5730
5.26 4.7079 4.6023 4.5561
5.28 4.6901 4.5852 4.5395
5.30 4.6724 4.5683 4.5229
5.32 4.6548 4.5516 4.5065
5.34 4.6374 4.5349 4.4901
5.36 4.6201 4.5183 4.4739
5.38 4.6029 4.5019 4.4578
5.40 4.5859 4.4856 4.4419
5.42 4.5690 4.4694 4.4260
5.44 4.5522 4.4534 4.4102
5.46 4.5355 4.4374 4.3946
5.48 4.5189 4.4216 4.3791
5.50 4.5025 4.4058 4.3637
5.52 4.4862 4.3902 4.3484
5.54 4.4700 4.3747 4.3332
5.56 4.4539 4.3593 4.3181
5.58 4.4380 4.3440 4.3031
5.60 4.4221 4.3289 4.2882
5.62 4.4064 4.3138 4.2734
5.64 4.3907 4.2988 4.2587
5.66 4.3752 4.2839 4.2441
5.68 4.3598 4.2692 4.2296
5.70 4.3445 4.2545 4.2153
5.72 4.3293 4.2400 4.2010
5.74 4.3143 4.2255 4.1868
5.76 4.2993 4.2111 4.1727
5.78 4.2844 4.1969 4.1587
5.80 4.2696 4.1827 4.1448
5.82 4.2549 4.1686 4.1310
5.84 4.2404 4.1546 4.1172
5.86 4.2259 4.1407 4.1036
5.88 4.2115 4.1269 4.0901
5.90 4.1973 4.1132 4.0766
5.92 4.1831 4.0996 4.0632
5.94 4.1690 4.0861 4.0500
5.96 4.1550 4.0727 4.0368
5.98 4.1411 4.0593 4.0237
6.00 4.1273 4.0461 4.0106
6.02 4.1136 4.0329 3.9977
6.04 4.1000 4.0198 3.9848
6.06 4.0864 4.0068 3.9721
6.08 4.0730 3.9939 3.9594
6.10 4.0596 3.9810 3.9468
6.12 4.0464 3.9683 3.9342
6.14 4.0332 3.9556 3.9218
6.16 4.0201 3.9430 3.9094
6.18 4.0071 3.9305 3.8971
6.20 3.9942 3.9181 3.8849
6.22 3.9813 3.9057 3.8728
6.24 3.9686 3.8934 3.8607
6.26 3.9559 3.8812 3.8487
6.28 3.9433 3.8691 3.8368
6.30 3.9308 3.8571 3.8249
6.32 3.9183 3.8451 3.8132
6.34 3.9060 3.8332 3.8015
6.36 3.8937 3.8214 3.7898
6.38 3.8815 3.8096 3.7783
6.40 3.8693 3.7979 3.7668
6.42 3.8573 3.7863 3.7554
6.44 3.8453 3.7748 3.7440
6.46 3.8334 3.7633 3.7328
6.48 3.8216 3.7519 3.7216
6.50 3.8098 3.7406 3.7104
6.52 3.7981 3.7293 3.6993
6.54 3.7865 3.7181 3.6883
6.56 3.7750 3.7070 3.6774
6.58 3.7635 3.6959 3.6665
6.60 3.7521 3.6849 3.6557
6.62 3.7408 3.6740 3.6449
6.64 3.7295 3.6631 3.6342
6.66 3.7183 3.6523 3.6236
6.68 3.7072 3.6416 3.6130
6.70 3.6961 3.6309 3.6025
6.72 3.6851 3.6203 3.5921
6.74 3.6742 3.6097 3.5817
6.76 3.6633 3.5993 3.5714
6.78 3.6525 3.5888 3.5611
6.80 3.6417 3.5785 3.5509
6.82 3.6311 3.5681 3.5408
6.84 3.6204 3.5579 3.5307
6.86 3.6099 3.5477 3.5206
6.88 3.5994 3.5376 3.5107
6.90 3.5890 3.5275 3.5007
6.92 3.5786 3.5175 3.4909
6.94 3.5683 3.5075 3.4811
6.96 3.5580 3.4976 3.4713
6.98 3.5478 3.4878 3.4616
7.00 3.5377 3.4780 3.4520
7.02 3.5276 3.4682 3.4424
7.04 3.5176 3.4585 3.4328
7.06 3.5076 3.4489 3.4234
7.08 3.4977 3.4393 3.4139
7.10 3.4879 3.4298 3.4045
7.12 3.4781 3.4203 3.3952
7.14 3.4683 3.4109 3.3859
7.16 3.4586 3.4015 3.3767
7.18 3.4490 3.3922 3.3675
7.20 3.4394 3.3830 3.3584
7.22 3.4299 3.3737 3.3493
7.24 3.4204 3.3646 3.3403
7.26 3.4110 3.3555 3.3313
7.28 3.4016 3.3464 3.3224
7.30 3.3923 3.3374 3.3135
7.32 3.3830 3.3284 3.3046
7.34 3.3738 3.3195 3.2959
7.36 3.3646 3.3106 3.2871
7.38 3.3555 3.3018 3.2784
7.40 3.3465 3.2930 3.2698
7.42 3.3374 3.2843 3.2612
7.44 3.3285 3.2756 3.2526
7.46 3.3195 3.2669 3.2441
7.48 3.3107 3.2584 3.2356
7.50 3.3018 3.2498 3.2272
7.52 3.2931 3.2413 3.2188
7.54 3.2843 3.2328 3.2104
7.56 3.2756 3.2244 3.2021
7.58 3.2670 3.2160 3.1939
7.60 3.2584 3.2077 3.1857
7.62 3.2498 3.1994 3.1775
7.64 3.2413 3.1912 3.1694
7.66 3.2329 3.1830 3.1613
7.68 3.2245 3.1748 3.1532
7.70 3.2161 3.1667 3.1452
7.72 3.2077 3.1586 3.1373
7.74 3.1995 3.1506 3.1293
7.76 3.1912 3.1426 3.1215
7.78 3.1830 3.1346 3.1136
7.80 3.1748 3.1267 3.1058
7.82 3.1667 3.1189 3.0980
7.84 3.1586 3.1110 3.0903
7.86 3.1506 3.1032 3.0826
7.88 3.1426 3.0955 3.0750
7.90 3.1347 3.0877 3.0674
7.92 3.1267 3.0801 3.0598
7.94 3.1189 3.0724 3.0522
7.96 3.1110 3.0648 3.0447
7.98 3.1032 3.0573 3.0373
8.00 3.0955 3.0497 3.0299
8.02 3.0878 3.0422 3.0225
8.04 3.0801 3.0348 3.0151
8.06 3.0724 3.0274 3.0078
8.08 3.0648 3.0200 3.0005
8.10 3.0573 3.0126 2.9932
8.12 3.0497 3.0053 2.9860
8.14 3.0422 2.9980 2.9788
8.16 3.0348 2.9908 2.9717
8.18 3.0274 2.9836 2.9646
8.20 3.0200 2.9764 2.9575
8.22 3.0126 2.9693 2.9505
8.24 3.0053 2.9622 2.9435
8.26 2.9980 2.9551 2.9365
8.28 2.9908 2.9481 2.9295
8.30 2.9836 2.9411 2.9226
8.32 2.9764 2.9341 2.9157
8.34 2.9693 2.9272 2.9089
8.36 2.9622 2.9203 2.9021
8.38 2.9551 2.9134 2.8953
8.40 2.9481 2.9066 2.8885
8.42 2.9411 2.8998 2.8818
8.44 2.9341 2.8930 2.8751
8.46 2.9272 2.8863 2.8685
8.48 2.9203 2.8795 2.8619
8.50 2.9134 2.8729 2.8553
8.52 2.9065 2.8662 2.8487
8.54 2.8997 2.8596 2.8422
8.56 2.8930 2.8530 2.8356
8.58 2.8862 2.8464 2.8292
8.60 2.8795 2.8399 2.8227
8.62 2.8728 2.8334 2.8163
8.64 2.8662 2.8270 2.8099
8.66 2.8596 2.8205 2.8036
8.68 2.8530 2.8141 2.7972
8.70 2.8464 2.8077 2.7909
8.72 2.8399 2.8014 2.7847
8.74 2.8334 2.7951 2.7784
8.76 2.8269 2.7888 2.7722
8.78 2.8205 2.7825 2.7660
8.80 2.8141 2.7763 2.7598
8.82 2.8077 2.7700 2.7537
8.84 2.8013 2.7639 2.7476
8.86 2.7950 2.7577 2.7415
8.88 2.7887 2.7516 2.7355
8.90 2.7824 2.7455 2.7294
8.92 2.7762 2.7394 2.7234
8.94 2.7700 2.7334 2.7174
8.96 2.7638 2.7273 2.7115
8.98 2.7577 2.7213 2.7056
9.00 2.7515 2.7154 2.6997
9.02 2.7454 2.7094 2.6938
9.04 2.7394 2.7035 2.6880
9.06 2.7333 2.6976 2.6821
9.08 2.7273 2.6918 2.6763
9.10 2.7213 2.6859 2.6706
9.12 2.7153 2.6801 2.6648
9.14 2.7094 2.6743 2.6591
9.16 2.7035 2.6686 2.6534
9.18 2.6976 2.6628 2.6477
9.20 2.6917 2.6571 2.6421
9.22 2.6859 2.6514 2.6365
9.24 2.6801 2.6458 2.6309
9.26 2.6743 2.6401 2.6253
9.28 2.6685 2.6345 2.6197
9.30 2.6628 2.6289 2.6142
9.32 2.6571 2.6233 2.6087
9.34 2.6514 2.6178 2.6032
9.36 2.6457 2.6123 2.5978
9.38 2.6401 2.6068 2.5923
9.40 2.6344 2.6013 2.5869
9.42 2.6289 2.5958 2.5815
9.44 2.6233 2.5904 2.5762
9.46 2.6177 2.5850 2.5708
9.48 2.6122 2.5796 2.5655
9.50 2.6067 2.5743 2.5602
9.52 2.6012 2.5689 2.5549
9.54 2.5958 2.5636 2.5496
9.56 2.5904 2.5583 2.5444
9.58 2.5849 2.5530 2.5392
 9.60 2.5796 2.5478 2.5340
9.62 2.5742 2.5425 2.5288
9.64 2.5689 2.5373 2.5237
9.66 2.5635 2.5322 2.5185
9.68 2.5582 2.5270 2.5134
9.70 2.5530 2.5218 2.5083
9.72 2.5477 2.5167 2.5033
9.74 2.5425 2.5116 2.4982
9.76 2.5373 2.5065 2.4932
9.78 2.5321 2.5015 2.4882
9.80 2.5269 2.4964 2.4832
9.82 2.5218 2.4914 2.4782
9.84 2.5166 2.4864 2.4733
9.86 2.5115 2.4814 2.4683
9.88 2.5065 2.4764 2.4634
9.90 2.5014 2.4715 2.4585
9.92 2.4964 2.4666 2.4537
9.94 2.4913 2.4617 2.4488
9.96 2.4863 2.4568 2.4440
9.98 2.4813 2.4519 2.4392
10.00 2.4764 2.4471 2.4344
as curvas P vs V m

a modificacin del rea bajo la isoterma y por consiguiente del trabajo.

PV=
b R T
P_=
0

Gas VdW
a=0

PEXT
(bar)
26.0960
25.5574 25.5573559
25.0405 25.0404975
24.5441 24.54413004
24.0671 24.06705865
23.6082
23.1665
22.7410
22.3309
21.9352
t Title 21.5534
21.1847
20.8283
PEXT
20.4837
20.1504 (bar)
19.8277 30.0000
19.5152
25.0000
19.2124
18.9188 20.0000
PEXT
Axis Title

18.6341
15.0000 (bar)
18.3578
18.0896 10.0000
17.8292
6.00 8.00 10.00
17.5761 12.00 5.0000

Col umn D 17.3301

Col umn E 0.0000
17.0909 0.00 2.00 4.00 6.00 8.00 10.00 12.00
16.8582 Axis Title
16.6317
16.4113
16.1966
30.0000

25.0000

20.0000
ar)

Gas Idea l
15.9875 30.0000
15.7837
15.5850 25.0000
15.3913
15.2023 20.0000
15.0179

PEXT (bar)
Gas Idea l
14.8380 15.0000 Gas VdW
14.6622
Gas VdW
14.4907 10.0000 b=0
14.3230 Gas VdW
14.1592 a =0
5.0000
13.9992
13.8426
0.0000
13.6896 0.00 2.00 4.00 6.00 8.00 10.00 12.00
13.5399
Axis Title
13.3934
13.2501
13.1098
12.9725
12.8380
12.7062
12.5772
12.4507
12.3267
12.2052
12.0861
11.9693
11.8547
11.7422
11.6319
11.5237
11.4174
11.3131
11.2107
11.1101
11.0113
10.9142
10.8188
10.7251
10.6330
10.5425
10.4535
10.3660
10.2799
10.1953
10.1120
10.0301
9.9495
9.8702
9.7921
9.7153
9.6397
9.5652
9.4919
9.4197
9.3485
9.2785
9.2095
9.1415
9.0745
9.0085
8.9434
8.8793
8.8160
8.7537
8.6923
8.6317
8.5719
8.5130
8.4548
8.3975
8.3409
8.2851
8.2300
8.1757
8.1221
8.0691
8.0169
7.9653
7.9144
7.8641
7.8145
7.7655
7.7171
7.6693
7.6221
7.5755
7.5294
7.4839
7.4389
7.3945
7.3506
7.3072
7.2643
7.2220
7.1801
7.1387
7.0978
7.0573
7.0173
6.9778
6.9387
6.9000
6.8618
6.8240
6.7866
6.7496
6.7130
6.6768
6.6410
6.6055
6.5705
6.5358
6.5015
6.4675
6.4339
6.4007
6.3677
6.3352
6.3029
6.2710
6.2394
6.2081
6.1771
6.1465
6.1161
6.0860
6.0563
6.0268 30.0000
5.9976
5.9687
25.0000
5.9401
5.9117
5.8836 20.0000
5.8558
5.8282 15.0000
5.8009
5.7739
5.7471 10.0000
5.7205
5.6942 5.0000
5.6681
5.6423
5.6167 0.0000
0.00 2.00 4.00 6.00 8.00 10
5.5913
5.5662
5.5413
5.5166
5.4921
5.4679
5.4438
5.4200
5.3964
5.3730
5.3498
5.3268
5.3039
5.2813
5.2589
5.2366
5.2146
5.1927
5.1710
5.1495
5.1282
5.1070
5.0861
5.0653
5.0446
5.0242
5.0038
4.9837
4.9637
4.9439
4.9242
4.9047
4.8854
4.8662
4.8471
4.8282
4.8095
4.7909
4.7724
4.7541
4.7359
4.7179
4.6999
4.6822
4.6645
4.6470
4.6297
4.6124
4.5953
4.5783
4.5614
4.5447
4.5281
4.5116
4.4952
4.4789
4.4628
4.4468
4.4309
4.4151
4.3994
4.3838
4.3683
4.3530
4.3377
4.3226
4.3075
4.2926
4.2778
4.2630
4.2484
4.2339
4.2195
4.2051
4.1909
4.1768
4.1627
4.1488
4.1349
4.1212
4.1075
4.0939
4.0804
4.0670
4.0537
4.0405
4.0273
4.0143
4.0013
3.9884
3.9756
3.9629
3.9502
3.9377
3.9252
3.9128
3.9005
3.8882
3.8760
3.8639
3.8519
3.8400
3.8281
3.8163
3.8046
3.7929
3.7813
3.7698
3.7584
3.7470
3.7357
3.7245
3.7133
3.7022
3.6912
3.6802
3.6693
3.6584
3.6477
3.6369
3.6263
3.6157
3.6052
3.5947
3.5843
3.5740
3.5637
3.5534
3.5433
3.5332
3.5231
3.5131
3.5032
3.4933
3.4835
3.4737
3.4640
3.4543
3.4447
3.4351
3.4256
3.4162
3.4068
3.3974
3.3881
3.3789
3.3697
3.3606
3.3515
3.3424
3.3334
3.3245
3.3156
3.3067
3.2979
3.2891
3.2804
3.2718
3.2631
3.2546
3.2460
3.2375
3.2291
3.2207
3.2123
3.2040
3.1958
3.1875
3.1794
3.1712
3.1631
3.1550
3.1470
3.1390
3.1311
3.1232
3.1154
3.1075
3.0998
3.0920
3.0843
3.0766
3.0690
3.0614
3.0539
3.0464
3.0389
3.0315
3.0241
3.0167
3.0094
3.0021
2.9948
2.9876
2.9804
2.9732
2.9661
2.9590
2.9520
2.9449
2.9379
2.9310
2.9241
2.9172
2.9103
2.9035
2.8967
2.8899
2.8832
2.8765
2.8699
2.8632
2.8566
2.8500
2.8435
2.8370
2.8305
2.8240
2.8176
2.8112
2.8048
2.7985
2.7922
2.7859
2.7797
2.7734
2.7672
2.7611
2.7549
2.7488
2.7427
2.7366
2.7306
2.7246
2.7186
2.7127
2.7067
2.7008
2.6950
2.6891
2.6833
2.6775
2.6717
2.6659
2.6602
2.6545
2.6488
2.6432
2.6375
2.6319
2.6264
2.6208
2.6153
2.6098
2.6043
2.5988
2.5934
2.5879
2.5825
2.5772
2.5718
2.5665
2.5612
2.5559
2.5506
2.5454
2.5402
2.5350
2.5298
2.5246
2.5195
2.5144
2.5093
2.5042
2.4991
2.4941
2.4891
 PEXT
(bar)

12.00

Gas Idea l
 Gas Idea l
Gas VdW
Gas VdW
b=0
Gas VdW
a =0

12.00
 PEXT
(bar)
PEXT
(bar)
PEXT
(bar)
PEXT
(bar)

.00 6.00 8.00 10.00 12.00

 30

25

20
P (bar)

15

10

0
0 1 2 3 4 5 6 7 8 9 10
Vm (L/mol)

Gas Ideal Gas vdw Gas vdw b 0 Gas vdw a 0

DATOS EXPERIMENTALES

30 30
ESTIMACIN POLINOMIAL 29.5 29.5 f(x) = - 2.33333333333336E-06x^2
f(x) = - 2.33333333333336E-06x^2 + 0.00675595
R = 0.9736216075
R = 0.9736216075
29 29
T/K Cvm/JK-1mol-1
400 26.99 n= 2.45 mol 28.5 28.5
600 28.29 a= 2.484E+01
800 28.89 b= 6.756E-03 28 28
1000 29.19 c= -2.333E-06 27.5 27.5
1200 29.42 R2 = 0.9736
1400 29.69 27 27
1600 29.78 26.5 26.5
26 26
25.5
q= 78000.84 J 200 25.5 400 600 800 1000 1200
200 400 600 800 1000

SOLVER
c
CVm a bT
T2
T/K Cvm/JK-1mol-1 Cvm calc D D2 n= 2.45
400 26.99 26.96523643 0.024763572 0.000613235 a 28.92313182
600 28.29 28.3217054 -0.0317054 0.001005232 b 0.000636512
800 28.89 28.87921603 0.010783967 0.000116294 c 354000
1000 29.19 29.20564334 -0.01564334 0.000244714
1200 29.42 29.4411123 -0.0211123 0.000445729
1400 29.69 29.6336357 0.056364304 0.003176935
1600 29.78 29.80326899 -0.02326899 0.000541446 Ch
S 0.006143585 30.5
30
q = Err:509 J
29.5
29
28.5
28
27.5
27
U qw 26.5

Si V cte w 0 26
25.5
Por tanto 200 400 600 800

U q
q n C V dT
1600
q n C V dT
 27
U qw 26.5

Si V cte w 0 26
25.5
Por tanto 200 400 600 800

U q
q n C V dT
1600
q n C
400
V dT

Si C V a b T c T 2
1600

a b T c T dT
2
q n
400

1 1
q n a T2 T1 T22 T12 c
b
2 T2 T1
1
q n a1600 400 1600 2 400 2 c
b 1

2 1600 400
 U qw
Si V cte w 0
Por tanto
f(x) = - 2.33333333333336E-06x^2
2.33333333333336E-06x^2 + 0.0067559524x
+ 0.0067559524x + 24.8435714286+ 24.8435714286
736216075
R = 0.9736216075 U q
q n C V dT
1600
q n C
400
V dT

Si C V a b T c T 2
1600
q n a b T c T dT
2

400

q n a T2 T1 T22 T12 T23

b c
600 800 1000 1200 1400 1600 1800
00 600 800 1000 1200 1400 1600 1800 2 3

q n a 1600 400 1600 2 400

b
2

30.5
30
29.5
mol
28.92313182 29
28.9234
0.000636512 28.50.0006
354000 3.540E+05
28 Column B
Column C
27.5

Chart Title 27

5 26.5
0 26
5 25.5
30.5
9 200 400 600 800 1000 1200 1400 1600 1800
30
5
8 29.5
5 29
7 28.5
5
28
6
27.5
5
200 400 600 800 1000 27 1200 1400 1600 1800

26.5
26
25.5
200 400 600 800 1000 1200 1400 1600 1800
7 28.5
5
28
6
27.5
5
200 400 600 800 1000 27 1200 1400 1600 1800

26.5
26
25.5
200 400 600 800 1000 1200 1400 1600 1800
 w0

T/K 400 600 800 1000 1200

T Cvm/JK-1mol-1 26.99 28.29 28.89 29.19 29.42

dT

b T c T 2

b T c T 2 dT

T22 T12 T23 T13

b c
T1
2 3

1600 2 400 2 1600 3 400 3

b c
00 400
2 3

Column B
Column C

00 1800

1400 1600 1800

1400 1600 1800
 1400 1600
29.69 29.78
DATOS EXPERIMENTALES

ESTIMACIN POLINOMIAL

T/K Cvm/JK-1mol-1
400 26.99
600 28.29 a= 24.8440
800 28.89 b= 0.0068
1000 29.19 c= -2.333E-06
1200 29.42 R2 = 0.9736
1400 29.69
1600 29.78

Polinomial
T Cvm/JK-1mol-1 DT DCvm DT x DCvm S Acumulada
400 27.173072 0
420 27.26992588 20 27.22149894 544.4 544.4
440 27.36491312 20 27.3174195 546.3 1090.8
460 27.45803372 20 27.41147342 548.2 1639.0
480 27.54928768 20 27.5036607 550.1 2189.1
500 27.638675 20 27.59398134 551.9 2741.0
520 27.72619568 20 27.68243534 553.6 3294.6
540 27.81184972 20 27.7690227 555.4 3850.0
560 27.89563712 20 27.85374342 557.1 4407.1
580 27.97755788 20 27.9365975 558.7 4965.8
600 28.057612 20 28.01758494 560.4 5526.1
620 28.13579948 20 28.09670574 561.9 6088.1
640 28.21212032 20 28.1739599 563.5 6651.6
660 28.28657452 20 28.24934742 565.0 7216.5
680 28.35916208 20 28.3228683 566.5 7783.0
700 28.429883 20 28.39452254 567.9 8350.9
720 28.49873728 20 28.46431014 569.3 8920.2
740 28.56572492 20 28.5322311 570.6 9490.8
760 28.63084592 20 28.59828542 572.0 10062.8
780 28.69410028 20 28.6624731 573.2 10636.0
800 28.755488 20 28.72479414 574.5 11210.5
820 28.81500908 20 28.78524854 575.7 11786.2
840 28.87266352 20 28.8438363 576.9 12363.1
860 28.92845132 20 28.90055742 578.0 12941.1
880 28.98237248 20 28.9554119 579.1 13520.2
900 29.034427 20 29.00839974 580.2 14100.4
920 29.08461488 20 29.05952094 581.2 14681.6
940 29.13293612 20 29.1087755 582.2 15263.8
960 29.17939072 20 29.15616342 583.1 15846.9
 980 29.22397868 20 29.2016847 584.0 16430.9
1000 29.2667 20 29.24533934 584.9 17015.8
1020 29.30755468 20 29.28712734 585.7 17601.6
1040 29.34654272 20 29.3270487 586.5 18188.1
1060 29.38366412 20 29.36510342 587.3 18775.4
1080 29.41891888 20 29.4012915 588.0 19363.4
1100 29.452307 20 29.43561294 588.7 19952.2
1120 29.48382848 20 29.46806774 589.4 20541.5
1140 29.51348332 20 29.4986559 590.0 21131.5
1160 29.54127152 20 29.52737742 590.5 21722.0
1180 29.56719308 20 29.5542323 591.1 22313.1
1200 29.591248 20 29.57922054 591.6 22904.7
1220 29.61343628 20 29.60234214 592.0 23496.8
1240 29.63375792 20 29.6235971 592.5 24089.2
1260 29.65221292 20 29.64298542 592.9 24682.1
1280 29.66880128 20 29.6605071 593.2 25275.3
1300 29.683523 20 29.67616214 593.5 25868.8
1320 29.69637808 20 29.68995054 593.8 26462.6
1340 29.70736652 20 29.7018723 594.0 27056.7
1360 29.71648832 20 29.71192742 594.2 27650.9
1380 29.72374348 20 29.7201159 594.4 28245.3
1400 29.729132 20 29.72643774 594.5 28839.8
1420 29.73265388 20 29.73089294 594.6 29434.4
1440 29.73430912 20 29.7334815 594.7 30029.1
1460 29.73409772 20 29.73420342 594.7 30623.8
1480 29.73201968 20 29.7330587 594.7 31218.5
1500 29.728075 20 29.73004734 594.6 31813.1
1520 29.72226368 20 29.72516934 594.5 32407.6
1540 29.71458572 20 29.7184247 594.4 33001.9
1560 29.70504112 20 29.70981342 594.2 33596.1
1580 29.69362988 20 29.6993355 594.0 34190.1
1600 29.680352 20 29.68699094 593.7 34783.9 85220.45243

q numrico = 85220.45 J
q analtico = 78012.60 J
e= 7207.85
%e = 9.24 %
 30
29.5
29
28.5
28
27.5
27
26.5
26
25.5
200 400 600 800 1000

Simpson 1/3

y n 2 4 y n 1 y n Dx y 4y y S acumulada
DT n 2 n 1 n
3 3
27.173
27.270 20 0 0
27.365 20 54.53922955 1090.784591 1090.78
27.458 20 0 1090.78
27.549 20 54.91544523 1098.308905 2189.09
27.639 20 0 2189.09
27.726 20 55.27672779 1105.534556 3294.63
27.812 20 0 3294.63
27.896 20 55.62307723 1112.461545 4407.09
27.978 20 0 4407.09
28.058 20 55.95449355 1119.089871 5526.18
28.136 20 0 5526.18
28.212 20 56.27097675 1125.419535 6651.60
28.287 20 0 6651.60
28.359 20 56.57252683 1131.450537 7783.05
28.430 20 0 7783.05
20 56.85914379 1137.182876 8920.23
20 0 8920.23
20 57.13082763 1142.616553 10062.85
20 0 10062.85
20 57.38757835 1147.751567 11210.60
20 0 11210.60
20 57.62939595 1152.587919 12363.19
20 0 12363.19
20 57.85628043 1157.125609 13520.31
20 0 13520.31
20 58.06823179 1161.364636 14681.68
20 0 14681.68
20 58.26525003 1165.305001 15846.98
20 0 15846.98
20 58.44733515 1168.946703 17015.93
20 0 17015.93
20 58.61448715 1172.289743 18188.22
20 0 18188.22
20 58.76670603 1175.334121 19363.55
20 0 19363.55
20 58.90399179 1178.079836 20541.63
20 0 20541.63
20 59.02634443 1180.526889 21722.16
20 0 21722.16
20 59.13376395 1182.675279 22904.84
20 0 22904.84
20 59.22625035 1184.525007 24089.36
20 0 24089.36
20 59.30380363 1186.076073 25275.44
20 0 25275.44
20 59.36642379 1187.328476 26462.77
20 0 26462.77
20 59.41411083 1188.282217 27651.05
20 0 27651.05
20 59.44686475 1188.937295 28839.99
20 0 28839.99
20 59.46468555 1189.293711 30029.28
20 0 30029.28
20 59.46757323 1189.351465 31218.63
20 0 31218.63
20 59.45552779 1189.110556 32407.74
20 0 32407.74
20 59.42854923 1188.570985 33596.31
20 0 33596.31
20 59.38663755 1187.732751 34784.04
 30
29.5
29
28.5
28
27.5
27
26.5
26
25.5
200 400 600 800 1000 1200 1400 1600 1800
85220.90976
DATOS EXPERIMENTALES

30.5
30
ESTIMACIN POLINOMIAL
29.5
T/K Cvm/JK-1mol-1 29
400 26.99 28.5
600 28.29 a= 28.9234
800 28.89 b= 0.0006 28
1000 29.19 c= 3.540E+05 27.5
1200 29.42 27
1400 29.69
26.5
1600 29.78
26
25.5
200 400 600 800 10

T Cvm/JK-1mol-1 DT DCvm DT x DCvm S Acumulada

400 26.9650492664 0
420 27.18349715 20 27.07427321 541.5 541.5
440 27.3745342529 20 27.2790157 545.6 1087.1
460 27.5428223885 20 27.45867832 549.2 1636.2
480 27.6920728644 20 27.61744763 552.3 2188.6
500 27.825269902 20 27.75867138 555.2 2743.8
520 27.9448351059 20 27.8850525 557.7 3301.5
540 28.0527501091 20 27.99879261 560.0 3861.4
560 28.150649125 20 28.10169962 562.0 4423.5
580 28.2398895557 20 28.19526934 563.9 4987.4
600 28.3216064087 20 28.28074798 565.6 5553.0
620 28.3967546304 20 28.35918052 567.2 6120.2
640 28.4661423278 20 28.43144848 568.6 6688.8
660 28.5304570528 20 28.49829969 570.0 7258.8
680 28.5902867577 20 28.56037191 571.2 7830.0
700 28.6461366196 20 28.61821169 572.4 8402.3
720 28.6984426413 20 28.67228963 573.4 8975.8
740 28.7475827142 20 28.72301268 574.5 9550.2
760 28.7938856704 20 28.77073419 575.4 10125.7
780 28.8376387321 20 28.8157622 576.3 10702.0
800 28.8790936733 20 28.8583662 577.2 11279.1
820 28.9184719433 20 28.89878281 578.0 11857.1
840 28.9559689463 20 28.93722044 578.7 12435.9
860 28.9917576322 20 28.97386329 579.5 13015.3
880 29.025991524 20 29.00887458 580.2 13595.5
900 29.058807278 20 29.0423994 580.8 14176.4
920 29.0903268599 20 29.07456707 581.5 14757.9
940 29.1206594002 20 29.10549313 582.1 15340.0
960 29.1499027809 20 29.13528109 582.7 15922.7
 980 29.1781449995 20 29.16402389 583.3 16506.0
1000 29.2054653424 20 29.19180517 583.8 17089.8
1020 29.2319353999 20 29.21870037 584.4 17674.2
1040 29.2576199454 20 29.24477767 584.9 18259.1
1060 29.2825777 20 29.27009882 585.4 18844.5
1080 29.3068619982 20 29.29471985 585.9 19430.4
1100 29.3305213708 20 29.31869168 586.4 20016.7
1120 29.3536000543 20 29.34206071 586.8 20603.6
1140 29.376138439 20 29.36486925 587.3 21190.9
1160 29.398173464 20 29.38715595 587.7 21778.6
1180 29.4197389643 20 29.40895621 588.2 22366.8
1200 29.4408659793 20 29.43030247 588.6 22955.4
1220 29.461583025 20 29.4512245 589.0 23544.4
1240 29.4819163367 20 29.47174968 589.4 24133.9
1260 29.501890084 20 29.49190321 589.8 24723.7
1280 29.5215265631 20 29.51170832 590.2 25313.9
1300 29.5408463685 20 29.53118647 590.6 25904.6
1320 29.5598685464 20 29.55035746 591.0 26495.6
1340 29.5786107323 20 29.56923964 591.4 27086.9
1360 29.5970892746 20 29.58785 591.8 27678.7
1380 29.6153193458 20 29.60620431 592.1 28270.8
1400 29.6333150422 20 29.62431719 592.5 28863.3
1420 29.6510894746 20 29.64220226 592.8 29456.2
1440 29.6686548496 20 29.65987216 593.2 30049.4
1460 29.6860225438 20 29.6773387 593.5 30642.9
1480 29.7032031699 20 29.69461286 593.9 31236.8
1500 29.7202066381 20 29.7117049 594.2 31831.0
1520 29.737042211 20 29.72862442 594.6 32425.6
1540 29.7537185534 20 29.74538038 594.9 33020.5
1560 29.7702437784 20 29.76198117 595.2 33615.7
1580 29.786625489 20 29.77843463 595.6 34211.3
1600 29.8028708158 20 29.79474815 595.9 34807.2 85277.66988

q numrico = 85277.67 J
q analtico = 87148.68 J
e= 1871.01
%e = 2.15 %
 Ecuacin Mtodo Integra q analtico q numrico e %e
Polinmica Trapecios 78513.4 85220.45 -6707.09 -8.54
Simpson 1/3 78513.4 #REF! #REF! #REF!
No lineal Trapecios 90604.0 85277.67 5326.36 5.88
Simpson 1/3 90604.0 #REF! #REF! #REF!

q= J

q= J
 30.5
30
29.5
29
28.5
28
27.5
27
400 600 800 1000 1200 1400 1600 180026.5

26
25.5
200 400 600 800 1000 1200 1400 1600 180

y n 2 4 y n 1 y n Dx
DT y n2 4y n1 y n
3 3
26.96504927
27.18349715 20 0
27.37453425 20 54.35785737 1087.157147
27.54282239 20 0
27.69207286 20 55.07929889 1101.585978
27.8252699 20 0
27.94483511 20 55.64599586 1112.919917
28.05275011 20 0
28.15064913 20 56.10216156 1122.043231
28.23988956 20 0
28.32160641 20 56.47727125 1129.545425
28.39675463 20 0
20 56.79158909 1135.831782
20 0
20 57.0594191 1141.188382
20 0
20 57.29109196 1145.821839
20 0
20 57.49421972 1149.884394
20 0
20 57.67451142 1153.490228
20 0
20 57.8363168 1156.726336
20 0
20 57.982997 1159.65994
20 0
20 58.1171825 1162.34365
20 0
20 58.24095575 1164.819115
 20 0
20 58.35598271 1167.119654
20 0
20 58.46360896 1169.272179
20 0
20 58.56493091 1171.298618
20 0
20 58.66084918 1173.216984
20 0
20 58.75210909 1175.042182
20 0
20 58.83933177 1176.786635
20 0
20 58.92303814 1178.460763
20 0
20 59.00366775 1180.073355
20 0
20 59.08159353 1181.631871
20 0
20 59.15713358 1183.142672
20 0
20 59.23056057 1184.611211
20 0
20 59.30210926 1186.042185
20 0
20 59.37198273 1187.439655
20 0
20 59.44035731 1188.807146
20 0
20 59.50738673 1190.147735
20 0
20 59.57320552 1191.46411

85278.56 J
87148.68 J
1870.12
2.15 %
 Column B
Column B

00 1000 1200 1400 1600 1800

Dx
y n 2 4y n1 y n S acumulada
3

0.0
1087.2
1087.2
2188.7
2188.7
3301.7
3301.7
4423.7
4423.7
5553.3
5553.3
6689.1
6689.1
7830.3
7830.3
8976.1
8976.1
10126.0
10126.0
11279.5
11279.5
12436.2
12436.2
13595.9
13595.9
14758.2
14758.2
15923.0
15923.0
17090.1
17090.1
18259.4
18259.4
19430.7
19430.7
20603.9
20603.9
21779.0
21779.0
22955.8
22955.8
24134.2
24134.2
25314.3
25314.3
26495.9
26495.9
27679.1
27679.1
28863.7
28863.7
30049.7
30049.7
31237.2
31237.2
32426.0
32426.0
33616.1
33616.1
34807.6 85278.6
1. Representar Z frente a la presin reducida Pr para el etano a 247 K y el argn a 500 K.
Vc/Lmol-1 Pc/bar Tc/K
Etano 0.148 48.714 305.34
Argn 0.0753 49.288 150.95
a) Se cumple la ley de los estados correspondientes?
a) Utilizar los datos P-Vm del etano para calcular,
mediante regresin no lineal, los valores de las constantes de Van der Waals para este gas.

Tr 0.8089343 Tr 3.31235508
P V (C2H6) Pr Z V (Ar) Pr Z
(bar) (L/mol) (L/mol)
0.5 83 0.01026 2.02265051 41 0.01014 0.48718239 3.5
2 21 0.04106 2.01817066 10 0.04058 0.48619614
10 4 0.20528 1.99888785 2 0.20289 0.48085597 3
20 2 0.41056 1.9750278 0.9857 0.40578 0.47421684
40 0.9907 0.82112 1.92964501 0.4795 0.81156 0.46137156 2.5
60 0.6461 1.23168 1.8876708 0.3114 1.21733 0.44944036
80 0.475 1.64224 1.85037121 0.2279 1.62311 0.43856758
2
100 0.3734 2.05280 1.81823319 0.1785 2.02889 0.42937864
120 0.3068 2.46336 1.79271754 0.1462 2.43467 0.42201786
1.5
160 0.2265 3.28448 1.76466981 0.1076 3.24623 0.41412788
200 0.1819 4.10560 1.77148697 0.0863 4.05778 0.41518629
1
240 0.1548 4.92672 1.80907872 0.07348 4.86934 0.42421166
300 0.1303 6.15839 1.90344765 0.06208 6.08667 0.44799707
350 0.1175 7.18479 2.0025399 0.05626 7.10112 0.47366357 0.5
400 0.1085 8.21119 2.1133187 0.05219 8.11557 0.50216854
450 0.1019 9.23759 2.23286242 0.04919 9.13001 0.5324656 0
500 0.09676 10.26399 2.35581472 0.04687 10.14446 0.56372484 0.00000 5.00000
600 0.08937 12.31679 2.61106856 0.04348 12.17335 0.62754229
700 0.08421 14.36959 2.870364 0.04108 14.20224 0.69172057

a
P 2 Vm b R
T 247 K
R 0.0831434 bar L/mol K
a -4.3641312 V
V (C2H6) P
b
pcalc
-9.8008E-08
m
(L/mol) (bar) 1000
83 0.5 0.25 -0.25 0.06358833
21 2 1.00 -0.9988412 0.99768379 900
4 10 5.26 -4.7382351 22.4508715
800
2 20 11.19 -8.8124471 77.659224
0.9907 40 25.18 -14.82435 219.761355 700
0.6461 60 42.24 -17.760421 315.432546
0.475 80 62.58 -17.423031 303.562014 600
0.3734 100 86.30 -13.70122 187.723425
0.3068 120 113.30 -6.6978774 44.8615611 500
0.2265 160 175.74 15.7355336 247.607018
0.1819 200 244.80 44.795679 2006.65285 400
0.1548 240 314.78 74.7833905 5592.5555
300

200

100
 500

400

300
0.1303 300 414.65 114.653515 13145.4285
0.1175 350 490.88 140.876126 19846.083 200
0.1085 400 559.99 159.98902 25596.4866
0.1019 450 621.83 171.825201 29523.8996 100
0.09676 500 678.37 178.369538 31815.6922
0.08937 600 776.20 176.195247 31044.7651 0
0.08421 700 859.29 159.289608 25373.1792 0 10

1420.11929
 P V (C2H6)
(bar) (L/mol)
3.5 0.5 83
2 21
3 10 4
20 2
2.5 40 0.9907
60 0.6461
80 0.475
2
100 0.3734
Etano
120 0.3068
1.5 Argn
160 0.2265
200 0.1819
1
240 0.1548
300 0.1303
0.5 350 0.1175
400 0.1085
0 450 0.1019
0.00000 5.00000 10.00000 15.00000 20.00000 500 0.09676
600 0.08937
700 0.08421

Vm b R T

1000

900

800

700

600

500

400

300

200

100
500

400

300

200

100

0
0 10 20 30 40 50 60 70 80
V (Ar)
(L/mol)
41
10
2
2.3.1. Correlaciones generalizadas de dos constant
0.9857
0.4795
0.3114 Factor de compresibilidad, z: "Relacin entre el vol
molar de un gas y el volumen molar del gas supuest
0.2279
0.1785
0.1462
0.1076 las mismas condiciones de presin y de temperatur
0.0863

Vm P Vm
0.07348

z ig
0.06208
0.05626
0.05219
0.04919 Vm R T
0.04687
0.04348
0.04108
gas ideal: z=1
gas superperfecto: z > 1
gas subperfecto: z < 1 Valor normal excepto para gases a
y T muy elevada. Siempre para lquidos.
70 80 90
de dos constantes (Pc,Tc)
cin entre el volumen
del gas supuesto ideal a
y de temperatura
P Vm

RT

mal excepto para gases a P