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~f" and ‘tho second term on the let-hand side is analytic in the half-plane Re(s) < ‘Tho fist term on tho loft-hand side remains auelytie only inthe stip Zain < Ro(s) < A. We now write g,(e}/r(s) a8 a Cauchy integral, viz. ater H3)—O-(), (a) where OH) = for ee ay G+(s) is anslytic in the half-plane Re(s)<# snd G(s) in the half-plane Re(s) > —/". This decomposition is posiblesineo g,(u)/r4(a) ~ Ola) and aence the integrals exist ‘Finally, then, (42) becomes: (o—Eaia) (0). (40) ‘common region af analyti- city. We may conclude, therefore, by Liowville's theorem, thet the functions on theright- and left-hand sides are analytic continuations of one another. Examine- tion of tho behaviour of (45) a |s| + oo indicates that we may set + (Sin) -) = Op, (40) ‘where Cis a oonstant, ‘Wo obtain Cy by impasing the condition that (2) goes to aero at least as {ast as oxp(—miat). This is equivalent to setting the enefficients of «and. 5°? to 2or0 in an asymptotic expansion of (a) in powers of «, Thus we find y= —Snua@-(0), and in edition @-(0) = Bmx™(0) ‘To evaluste G(s) itis only necessary to invert the orders of the w and (6,1) integrations in (44). Wo then obtain “nore fant owe e%em.0). (47) ‘p* contains the unlenown funetions Ay/2Ky and p(c,~ 1,0). Thus using the con- dition derived above that (/-(0) = Zqin@~{0) we find from (47) that BE nm7 0-9 p [acetone ("ger (22) wtp = eet apy acoere[ aye (22) 40-12) 014 mated) a Bi [fn (FE)mn ered -noy14 BEAL, Williams ‘where we have used a relationship involving the function 7_(s) which is given in appendix Ay/2Ky is by definition the slip coeflicient, but before it can be evaluated it will be necessuzy to obtain the equation for ple, ~ 0). Integration of (32) leads to the relation red e2) 49) for n> 0. Lf we now insert the value of Q, into (48) ond then use (40), the equation for ple, 0) becomes stale = ay pee (22) Tp,PO 0 = 270) + Sand) of ier ene 2) x pene. HH MAGE A=W 2—Me HEAL —p. (50) Thus, together, (48) and (50) yield the slip coefficient £ and the quantity Ale, =H,0){2K,. To obtain the value of the velocity at the suxface, 2{0), it is ‘uly novessary to insert ple, ~ 1,0) in (25). For thespatial haviour of the molecular distribution function tis convenient to rebum to (88). Then we find 40) =f shore C is. line lying to the right ofall singularitis ofthe integrand. Knowing, ®(e), the complete distribution fametion may be reconstructed by integrating, the frst order equation (32). ‘The complete inversion of (51) is represented by a rather complex function, ‘The genocal form of the solution, however, may he written 9s we, Vay 1) KG) (2) = [2 acnesan (ey Thus) becomes Fea) =240-[7 Boemdn (53) ‘The form of this solution ia sketched in figure 2 and we note that it consists of ‘two welllefined ports: tho asymptotic (»-+£) anda spatial transient. In practice, ‘the magnitude of the spatial transient is of some importance for it governs the applicability of the conventional hydrodynamie equations ¢o problems af this type. The form ofthe transient given by (58) indicates that t should he negligible tabout one maximum mean free path from the interfave (ie. Zz). Calonlations for the analogous Aline problem in neutron transport theory show this tobe true, ‘This suggests, therefore, that we may use the hydzodynamiv equations with the Kinetic theory of oases, I. Sip flow 155 appropriate slip boundary condition in regions whieh are no neater thax Bik, From a surface, Beforo accopting this us a fact, however, it sould. be bore it aaind that we have approsimated the sattering kernel and have theroby altered the form of the transiont solution. Tt is also worth noting that the constant collision ato approsimation implies Zn = 0. In this easo the transient may be important up to a substantial distance from the boundary. Toweves,m- rerio work by Loyal & Periger (1007) hasshown that this effet fs uot very serious. -— : ‘Frovne 2. Mean ow velocity in =ieation ox function of isance fom the bouslary £n tho slip eooiint, A more fundamental study of the Boltzmann equation (Williams 1966) shows that, in general, the equation for g(, 2) admits solutions of the form For our simple model it was shown thet only double, discrete eigenvalue at = Ocxisted, together with a continuous spectrum extending from y = Emin to 1 =2o, The double zoro gives vis to the asymptotic part af the solution and the continuum to tho intogral torm. In practic, thero may exist other diserete eigenvalues »,(j=1,2,...) which would contsiiute additional terms of the form Asexp (—142) to (53). "These r, ate less than Pain and hence their contribution to ‘the non-asymptotie (Lo. non-hydredynamie) part of the salution will persist over a larger distance from the boundary. Preliminary work on this problem. indicates that the v, are possibly absent altogether, but i they do exist they will bbe close to Zio in absolute value. Thus the above eriterion for the validity of ‘the hydrodynamie approximation i still a good ono166 MM. B. Williams 6. Diffuse reflexion Ti the ease of diffuse reflexion, = 1, and the expressions for {and ge, may be obtained in a elosed form. {is imply the fiat texan of (48) with, and g moy be found from (50) and (19). The result is (2K abate, 1,0) = Be) Hirt —eiteptem | acorey ee fap 1,0) nes p") HSE) + #26) * (4) where Hosp) = (Ble) pan) Bee «ss Similaly, L coped [eee ene MO) = Tf tore veo +e ftecte fas —ny fe.) x{Tacererney [aetna AEH [receneeuey fawn EE a0) ‘These expressions are generalizations of those given by previous enthors and are clearly more accurate. A special case of the above work which is of some interest ia the complete BG. approximation, ie. when we apply the approximation given by (31) to ‘the asymptotic distribution as woll This ease as been dealt with by Corcignani (1900). An immediate shortcoming of this approximation may he seen in the value for the viscosity. Using the hard-sphere model, wo find from (21) aud (22) that the exact value of #, is given by Pokeris & Alterman (1057) rl) = 016034, whereas for the B.G-K. model, which corresponds to setting K, = 0 in (21), a (lin) = 0-630862 ont) with seal ‘Thusan error of about 40 % in the bull flow propertis approsimation. (One of the virtues of the B.G.K. model is thot extremely simple expressions are available for & g(¢, ~,0) and 20). This is useful since these exact results an be used to check the accuracy of less accurate but more flexible methods of solving the transport equation, e.g. the variational and discrete ordinate tochniquos We find, using some properties ofthe yc, funetions given in the appendix, that arises from the B.G.K. () ae =2frahe, tor Kine teary of ones, 1. Sip flow ast — no [fieornee fan fs, a faerie: fanfSO5P ‘The pintogale ave csly oveluated but theresul wil not be given here ong to te longth Toro particular caves ar, however, worth quoting: (i) Vio) = A= constant, Bee ala |laesen/ |. ese. (09) 1 pede $e 5— (6-4 94)(18) tan (ii) Yee) =o. ro eee t, ‘The second case corresponds to a constant interaction cross-section between atoms, whereas the frst assumes a constant collision rete ‘Tn terms of the average mean free path J, where fracerruaie (a) + with He) = fe) (00) [fuori seo find for case (i): f/f = 0-764, cose {i}: ffl = 0°5825, and for the true hard- heroin rate a given in appendix B,£/— 0-0, ‘Thee value sompare with thon dedied fom the atiationa! method of Loyal & Feriger fllos: ens (), 0767; ene (i) 5792, and for be spliers, 6490, This stifingexemploof the power ofthe rvatonsl method Ifthe value of £ obtained by the new method presented in this paper (i.e. (48) with = 1) is eompered sth the value deed by the B.@-K. motel te. (8) ‘ut with b(e) = Vée)~, thon it: may be inferred that the new valuo of £is about 40% renter tian the B.G, vl, Wearviveat thi conluion by analogy with ie calculation ofthe vscwity coeficient which, fe recalled, also depends on tur average ovet ‘Togs conclusions are again eintitel by the aamerica wroak of Loyala& Persie. “Another quantity of nto wich may be stained in a fey simple manner isthe angular dstebution of partite iapinging onthe plat, vz, =k Fine m= gO Hem, o ‘where 1_{0) is givon in the appendis. Cercignani (1960) has given a simple value of (0), but we believe this to be ‘erroneous sinee it does not seem possible to reduce the expression further than the following quadrature: 1 24 aio) = =. (0)= 5 +f Thi crue hus boon coufimsad by Pref. Cesignani(psivate communication to the sasthor, 1908). wf ttertaf lan yem. 62)158 MAL. R. Wiltioms For the special exso of Vic) = A, wo find 2(0} = AKI (2m), aud for 7 340) = Kyl] 5, which aavees with Cereigoans formula 7. Summary and conclusions Anew method for treating houndary-value problems in the kinetic theory of gases has been developed which has the advantago of reproducing the aaymptotie flow properties accurately and giving a realise description of the molecular distribution function in the neighbourhood of a houndary. For the slip fow problem with a general diffaso-specular boundary condition ‘weave obtained expressions for the slip coeficiont, speod of low et the boundary ‘nd distribution of molecules incident on the plate, These results are more ao- ‘curate than aay yet derived and provide usefal boundary conditions for use with ‘the hydrodynamic equations when these are valid. ‘The main uncertainty in tho prosent method lies in the use of the B.G.K, ‘approximation for the tronsiont or boundary-layer effect. ‘This model predicts physically acosptable eigenvalue spectrum for the spatial operator of the Boltzmann equation, but may lack certain refinements associated with a more realistic energy exchange mechanism. This problom is undor investigation and results will be prosented soon, Inthe meantime we re ising the present technique to stucly other flow probloms, viz. Couette and Poiseuille low, and also heat transport botween parallel plates, ‘Theauthor isindobted to J. Spain forhis capable programming of the integrals, Appendix A. ‘The following properties ofthe function ye) are of use in simplifying some of the equations in the text. With y(c.) = (Se) + mie) 7-(ed/a) we find: 2 aeesee | aay pty Ve), a Tfpeeeren [las sca Fea oe 2ffecenaf nue 2 Soa 82 (aeetete f anne —p2r¥e.9 1 (a0) sai Sn a (48 ‘whore a primo indicates differentiation. ‘6,4 s closely related toe unetion arising in the study ofthe Milne problem in neutron transport thoory (Wiliams 1004) and is the velocity dependent equivalent of Chandraselhay's H-fanction (Chandrasschar 1960). ‘Equation (A) may bo devived by applying the Wiener-Hopf tchuique to the following equation: gia) = Kay d4s), (aa) ‘where d and X are defined in the text and ain=freeasine |" antBMER —— ay He a Kinetic theory of ges, F. Sip flow 159 epextoy (22), (ao “10a os) om wh we with Yee, —H,0) 8, Za- 10) = #5; [rect see ‘an Sen Pacote# Similaty 7 (07-{0) may be shown to be given hy 20) pera Sal (as Insertion of 1(u) leads to (57a) of the tos. Appenic8 Fortin ae mote elo fee en =e ord) wt, ‘where the ‘cross-section’ ro? is set equal to unity. ‘The average value of He), a8 defined by (60) of the toxt, is equal to 0-742808. REFERENCES Basrsanan, P. be, Gone, B.P.& Knoon, M. 1054 Phyo, Res 94, 8, Gancioxast, ©. 1962 an, Plge. 20, 210 Canoross, ©. 1006 ann, Phys 40, 400 Canosa, C.& Pant, G. 148 IE Nuows Glo 48, 6 Cusxonasnistan, 8. 1960 Baditiee Pranfer. New Yorks: Dover. Gnaraax, $, & Comte, T-C. 1900 The Modlenatcel Theory of Non-Usiform Gans Carabridgo Univesity Pres Davison, B. 1067 Nentron Transport Theory. Oford University Press nos, EP. & Jsemso, KA. 1059 Phyr. Mud, 2, 432 Kernan, 7B. 1948 Conon Appl. Medh- 1, 275. Kxans, HLA. 1049 Nuowo Cin. 6 Suppl, 887. Lovsa, 8.16. & Foran, JH 1007 Phyr. Plaid, 10, 1938. Novi, B. 1957 ‘The Wiener-Hopf Peokaigue. Oxford: Porgamon. Priaate, C.L, & Atemncan, Z, 1957 Prot. Nat Head, Soi, USA. 4, 008, Sime, 5.1. 1088 Ge flernaional Symparimn on Rargid Gas Dynemicep. 623. Bava by 6. Brinn. Asada Pro, Sox, 8. 1067e" Pros. Roy. Soe, A301, 387. Sowxe, 8. LOOT Proe Roy. Soe. A 301, $01 ‘Wase Gnaxe, C.8.& Umrawmnas, G.1. 1056 Engg. Hes. Inet Univcoty of Michipon Report Non ri22, (18). Wanuenis, MAR. IGE ae, Sei Bog. 18, 200, Winnasns, MC ML. 196 ‘The Slowing Down nd Thermaliztion of Weutrone Arteria: ‘North-Hollan Waassans, BLM. R, 1008 J. Nucl Swen, 22, 688,