APJ ACADEMY

XI CHEMISTRY TEST I
Every Question carried the same mark Attend everything Date : 03.08.2017

1. Given 3.50 mL of sulfuric acid (98.0% w/w) calculate the number of mmols
in the solution (density: 1.840 g/mL).

2. Given 8.00 g of HBr calculate the volume (mL) of a 48.0% (w/w) solution.
(MW HBr: 80.9119 g/mol, density: 1.49 g/mL). Then, calculate the molarity.

3. How many milliliters of concentrated hydrochloric acid solution (36.0% HCl

by mass, density = 1.18 g/mL) are required to produce 18.0 L of a solution
that has a pH of 2.01? (Hint : [H+] = 10-pH ).

4. Determine the molarity of these solutions:

a) 4.67 moles of Li2SO3 dissolved to make 2.04 liters of solution.

b) 0.629 moles of Al2O3 to make 1.500 liters of solution.
c) 4.783 grams of Na2CO3 to make 10.00 liters of solution.
d) 0.897 grams of (NH4)2CO3 to make 250 mL of solution.
e) 0.0348 grams of PbCl2 to form 45.0 mL of solution.

5. A student placed 11.0 g of glucose (C6H12O6) in a volumetric flask, added

enough water to dissolve the glucose by swirling, then carefully added
additional water until the 100 mL mark on the neck of the flask was reached.
The flask was then shaken until the solution was uniform. A 20.0 mL sample
of this glucose solution was diluted to 0.500L. How many grams of glucose
are in 100 mL of the final solution?

6. Write the following numbers in scientific notation.

1. 1001 6. 0.13592
2. 53 7. -0.0038
3. 6,926,300,000 8. 0.00000013
4. -392 9. -0.567
5. 0.00361
7. For the following, write each with the correct number of significant figures.

1. 2.38617954 x 10-1 * 1.15197705 x 106

2. 3.0001 * 5
3. 1.12 x 105 * 6.06 x 105
4. 2.27513 x 103 * 1.9376 x 102
5. 2 x 101 * 3.0 x 101
6. 5.567 x 108 / 2.215 x 108
7. 2.775 x 10-4 * 4.775 x 104
8. 5 / 8.14 x 102
9. 4.7192 x 102 / 3.862 x 10-48

8. Solve the following equations using the correct number of significant figures.

a. 34.683 + 58.930 + 68.35112

b. 45001 - 56.355 - 78.44
c. 0.003 + 3.5198 + 0.0118
d. 36.01 - 0.4 15

9. Tin forms two compounds with chlorine, SnCl2 and SnCl4.

(a) When combined with the same mass of tin, what would be the ratio of the
weights of chlorine in the two compounds?
(b) In the compound SnCl2, 0.597 g of chlorine is combined with each 1.000 g
of tin. In SnCl4, how many grams of chlorine would be combined with 1.000 g of
tin?

10. Iron forms multiple different compounds with oxygen. Data from mass
composition studies is reported below for three unique iron oxides.
Mass of Oxygen
Substance Mass of Iron (g)
(g)
FeO 4.654 1.333
Fe2O3 9.308 4.000
UNKNOWN 13.963 5.333

Show that the mass data above for iron (II) oxide and iron (III) oxide follows the
Law of Multiple Proportions and propose a reasonable formula for Unknown.
11. I have two solutions. In the first solution, 1.0 moles of sodium chloride is
dissolved to make 1.0 liters of solution. In the second one, 1.0 moles of
sodium chloride is added to 1.0 liters of water. Is the molarity of each
solution the same? Explain your answer.

12. A 78.0 g sample of an unknown compound contains 12.4 g of hydrogen.

What is the percent by mass of hydrogen in the compound?

13. Two unknown compounds are tested. Compound I contains 15.0 g of

hydrogen and 120.0 g of oxygen. Compound II contains 2.0 g of hydrogen and
32.0 g of oxygen. Are the compounds the same?

14. Benzoic acid is a compound used as a food preservative. The compound

contains 68.8% carbon, 4.95% hydrogen, and 26.2% oxygen by mass. What is
benzoic acids empirical formula? Benzoic acid has a molar mass of 122.12
g/mol. What is the molecular formula for benzoic acid?

15. Ribose is an important sugar found in RNA. Ribose has a molar mass of
150.0g/mol and is composed of 40.0% carbon, 6.67% hydrogen and the rest
oxygen. What is the empirical and molecular formula for ribose?

16. Polymers are long chains of small repeating molecules called monomers
that are linked together, much like a paper clip chain that you may have made
when you were younger. Their formulas have the monomer is listed in brackets
with a number listed on the outside that tells us how many monomers we
have linked together. Polyvinyl alcohol has a formula of [-CH2CHOH-]n. If n =
1000, what would be the percent composition of each element?

17. Many molecules our bodies need are many atoms strung into long complex
structures. An example is Vitamin B12, whose formula is C63H88CoN14O14P.
What is the percentage composition of each element?

18. A certain compound was analyzed and found to have the following
composition: 54.6% carbon, 9.0% hydrogen, 36.4% oxygen. The molar mass of
the compound is 176 g. What is the molecular formula of the compound?
19. Carbon tetrachloride, CCl4(g), can be synthesized according to the reaction
represented below. A chemist runs the reaction at a constant temperature of
120C in a rigid 25.0 L container.

CS2(g) + 3 Cl2(g) CCl4(g) + S2Cl2(g)

Chlorine gas, Cl2(g), is initially present in the container at a pressure of 0.40 atm.
(i) How many moles of Cl2(g) are in the container?
(ii) How many grams of carbon disulfide, CS2(g), are needed to react completely
with the Cl2(g) ?

20. An aqueous solution is prepared by diluting 3.30 mL acetone (d = 0.789

g/mL) with water to a final volume of 75.0 mL. The density of the solution is
0.993 g/mL. What is the molarity, molality and mole fraction of acetone in this
solution?

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