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Procedia Engineering 64 (2013) 671 680
International Conference On DESIGN AND MANUFACTURING, IConDM 2013 &RPPHQW>6@Elsevier to update with volume
and page numbers.
Abstract
In the present study the wear behavior of aluminium alloy LM25 reinforced with SiC particulate and further addition of TiO2
particulate fabricated by stir casting process is investigated. The wear resistance and frictional properties of hybrid metal matrix
composite are studied by performing dry sliding wear test using a pin on disk wear tester. The experiments are conducted at a
constant sliding velocity of 1.04m/s and sliding distance of 628m over a various load of 3,4,5kg for addition of particulate
volume fraction of SiC 7.5% and increase in volume fraction by 2.5% & 5% TiO2. The results show that, the reinforcement of
the metal matrix with SiC and TiO2 reduces the wear rate at room temperature. An attempt has also been made by keeping SiC
percentage constant and increasing the TiO2 percentage it also proves wear rate decreases as the TiO2 content increases. The
results also indicate that the wear of the test specimen increases with the increasing load and sliding distance. The coefficient of
friction decreases with load and increasing volume content of reinforcement. The worn surfaces are examined by Scanning
Electron Microscope to study the wear mechanism. At high speeds mechanical mixed layer (MML) and lubricating property of
TiO2 exhibits between the composite pin and steel and thereby reducing the wear rate. The wear mechanism changes from
severe abrasive wear to mild oxidative wear as the distance increases.
2013
2013TheTheAuthors. Published
Authors. by Elsevier
Published Ltd.
by Elsevier Ltd. Open access under CC BY-NC-ND license.
Selection and peer-review under responsibility of the organizing and review committee of IConDM 2013.
Selection and peer-review under responsibility of the organizing and review committee of IConDM 2013
Keywords : Dry sliding wear; LM25-Al alloy hybrid composite; wear mechanism
1. Introduction
Metal matrix composite materials are finding increased application in aerospace and automobile industries due to
their enhanced properties such as high strength, high stiffness, and good wear resistance. Hybrid composite
materials are advanced composite materials reinforced with more than one reinforcement material in order to
1877-7058 2013 The Authors. Published by Elsevier Ltd. Open access under CC BY-NC-ND license.
Selection and peer-review under responsibility of the organizing and review committee of IConDM 2013
doi:10.1016/j.proeng.2013.09.142
672 G. Elango and B.K. Raghunath / Procedia Engineering 64 (2013) 671 680
achieve the high hardness, tensile strength at room and elevated temperature. This gives rather high degree of
freedom in material design [1].
Nomenclature
The mixed layer had microstructural features comprising of a mixture of ultrafine grained structure in
which the constituents varied depending on the sliding loads[16]. Once the MML is formed, it provides a surface
protection before critical condition are reached and then loose debris get detached from the mixed layer, in
agreement with the wear behavior observations that the wear rate was lower at an intermediate load range with the
presence of the MML. The MML was not uniform in thickness across the entire wear track and it actually
exhibited a wavy shape in the cross section of the worn surfaces. The wear rate thus would be influenced by the
formation and detachment of the MML in the load range used[16].The MML formed with material comes from
three sources the counter-face, the matrix and particles[17].
The sliding wear behavior of the composite is found to be a function of many factors such as volume
fraction and particle size of reinforcement, hardness and strength of matrix alloy, applied load, environmental
temperature etc. The investigation of sliding wear properties of aluminium MMCs with reinforcement such as SiC,
Al2O3, TiC, TiB2 and graphite has been carried out by the researchers [18-22]. The review of literature indicated
that, most of the studies on wear of metal matrix composites is mainly under taken on Al-SiC, Al-Al2O3 based
composite system. The wear properties on Al+SiC+TiO2 has not been done and has been considered for the present
investigation, in which the TiO2 particles has excellent combination of mechanical and wear resisting and
lubricating properties. The hybrid composite material becoming the new trend of composite material led to the
wear investigation of LM25+SiC and LM25+SiC+TiO2 to analyze the enhanced property.
The aim of the present investigation is to evaluate the dry sliding metal- metal wear behavior of LM25
alloy, discontinuously reinforced with two different types of particles such as SiC and TiO2 .The stir casting
method is chosen for the manufacturing of hybrid metal matrix composites. The effect of TiO2 addition on the
reinforcement and the applied load in the dry sliding metal-metal wear behavior of composite is investigated using
a pin on disk wear tester. The microstructure of the specimen are studied for the particle distribution and worn
surfaces were examined by using scanning electron microscope.
2. Manufacturing of LM25 hybrid metal matrix composite material
The manufacturing of aluminium metal matrix (LM25+SiC) and hybrid aluminium metal matrix
composite (LM25+SiC+TiO2) is carried out by stir casting method. LM25 aluminium is taken as the matrix
material, SiC and TiO2 are considered as the particle reinforcement materials.
The stir casting involves the incorporation of SiC and TiO2 reinforcement particle into liquid LM25
aluminium melt and allow the mixture to solidify. The crucial part of fabrication is to create good wetting between
the particle reinforcement and liquid aluminium alloy melt. The simplest and most commercially used technique is
stir casting or vortex technique. The vortex technique involves the introduction of preheated reinforcement
particles into the vortex of molten alloy created by rotating impeller. Several aluminium companies adopted this in
commercial scale [23, 24].
In the vortex method the matrix material LM25 is melted, it is stirred vigorously by a mechanical stirrer to
form a vortex at the surface of the melt and the reinforcement material SiC and TiO2 is then introduced at the side
of the vortex. The process parameters such as pouring temperature of 850c to 900c, stirring speed of 500rpm,
preheating temperature of the reinforcement 500c to 550c is chosen.
LM25 alloy is melted in a graphite crucible in a induction type electric resistance furnace When the
temperature of the melt reaches 825C, after complete melting and degassing of the LM25 alloy by nitrogen, a
simple four blade alumina coated stainless steel stirrer is introduced into the melt and stirring is started . The depth
of immersion of the stirrer was maintained at about two thirds depth of the molten metal.
The reinforcement particle sizes are SiC 25m and TiO2 50m respectively. The reinforcement particle is
preheated to 500C for an hour before addition. Preheating of the reinforcement particles is necessary to avoid
moisture from the particles. Otherwise there is a chances of agglomeration of particulate occurs due to the moisture
and gases present in the particles. The mixture of preheated reinforcement particles is added inside the vortex of
LM25 alloy melt, during mixing a vigorous stirring is done to have complete wetting of particles and the matrix
LM25 alloy.
After complete addition of the particle into the melt (various reinforcement at different interval), the
composite material is tilt poured into the preheated (250C) permanent steel mould of size 300mm length and
50mm diameter and allowed to cool in atmospheric air. The billet is then removed from the mould . The LM25
hybrid composite with different volume fraction of reinforcement (LM25 +7.5%SiC, LM25 +SiC+ 2.5%TiO2 and
674 G. Elango and B.K. Raghunath / Procedia Engineering 64 (2013) 671 680
LM25 +SiC+ 5%TiO2) are produced and wear specimen are prepared by machining. The nominal chemical
composition of LM25 aluminium alloy is presented in Table 1.
Elements Cu Si Mg Mn Fe Ti Ni Zn Sn Al
percentage 0.17 6.81 0.51 0.03 0.29 0.103 0.006 0.06 <0.001 Balance
3. Experimental procedure
The sliding experiments are conducted at room temperature in a pin on disc wear testing machine (Wear
and Friction monitor TR-201). The pins are loaded against the disc by a dead weight loading system. The pin
specimen is flat ended with 8mm diameter and 20mm length. The disc test piece is 100mm in diameter and 10mm
in thickness. They slide on the disc by a diameter of 50mm. The material of the disc is hardened steel of HV698.
Wear test on composite specimen LM25, LM25 +SiC, LM25 +SiC+ 2.5%TiO2 and LM25 +SiC+ 5%TiO2 are
carried out under dry sliding condition at three different applied loads of 29.43N (3Kgf), 39.24N (4Kgf) and
49.05N (5Kgf) for a total sliding distance 628m at a constant sliding speed of 1.04m/s.Wear testing parameters say
sliding speed, sliding distance, are maintained same for all the tests specimen. During the test the relative humidity
and temperature of the surrounding atmosphere is about 50% and 25C respectively. The test duration is 10
minutes at a constant disc speed of 400 rpm for all the test.
The vertical height (displacement) of the specimen is continuously measured using linear variable
differential transformer (LVDT) of accuracy 1m during the wear test and the height loss is taken as wear of the
specimen. The photographic view of the pin on disk wear tester used in this investigation is shown in Fig. 1. An
experimental graph showing the height loss or wear in m against sliding time in seconds obtained from wear
testing is shown in Fig. 2.
The sliding speed and the sliding distance travelled by the test specimen on complete travel of the experiment or in
a particular interval of time is calculated by using the following equation:
Sliding speed in m/sec = DNT / 60000
Where D = Diameter of wear track
N= Disc speed in rpm
T= Test duration in seconds
G. Elango and B.K. Raghunath / Procedia Engineering 64 (2013) 671 680 675
(a) (b)
Fig. 2 Typical graphical result from pin on disk type wear testing machine (a) wear in m and
(b) Frictional force in N
From the observation of the figures (Fig. 3(a) Fig. 3(d)), it has been revealed that the addition of TiO2 particles
improve the performance of the materials by reduced wear. The figure also indicated that the minimum wear rate is
observed for LM25 +7.5%SiC+5% TiO2 composites followed by LM25 +7.5% SiC+ 2.5%TiO2. Unreinforced
alloy is prone to the maximum wear.
Fig. 3 Wear rate of unreinforced alloy and composites at applied loads of (a) 29.43N (b) 39.24N (c) 49.05N as a function of sliding distance
(d) at the end of maximum sliding distance (628 m) as a function of volume percentage of reinforcement.
alloy, composite and all hybrid composite, the increease in the applied load decreases the frictional coefficient [66].
The load has significant effect on both the wear rate and coefficient of friction.
Fig. 5 Optical micrograph of (a) unrreinforced alloy (b) LM25+ SiC 7.5% reinforcement
(c) LM25+SiC 7.5% & TiO2 2.5% reinforccement and (d) LM25+SiC7.5% & TiO2 5% reinforcement
Fig. 6 shows the wear track observed on the surfacee of LM25 alloy and its hybrid composite material. These SE EM
micrographs are taken at a scale of 5 mm. The grapphs clearly indicate how the wear takes place on the top surfaace
of the LM25 alloy and hybrid composite materialss. The graphs show that the wear intensity is more without tthe
reinforcement. The increase in the reinforcement reeduces the wear rate, and the surface observed is rougher due to
the ceramic particle exposed in resisting the wear oof the material while sliding on the wear disc. The wear debris
obtained while sliding shows that the size of the debris increases with the increasing load. The pull out of tthe
reinforcement particles causes abrasion on the m matrix surface resulting in severe deformation of particles aand
platelets.
(a) (b)
(c) (d)
Fig.6 SEM photographs of the wear track in 5mm (a) unreiinforced alloy and composites with (b) LM25+ SiC 7.5% reinforcement (c)
LM25+SiC 7.5% & TiO2 2.5% and (d) ) LM25+SiC7.5% & TiiO2 5% vol. fraction after complete sliding distance with maximum load of 5kkg
Fig. 7 shows that composite material has much rougher surface than the unreinforced alloy. The composite
material exhibits cavities and large grooved regionss on the wear surfaces and also contains the ceramic particles in
the cavities and some region and are pulled out. In I case of samples subjected to 49.04 N load the width of tthe
grooves and size of the dimples is greater than thosse on surface worn on 29.43N load. It indicates change of miild
to severe wear with increases in load due to greaterr plastic flow in sliding surface of the specimen at higher loaads
[25]. In composite material the Fig. 7(b) is subjecteed to severe wear and Fig. 7(d) is subjected to mild wear due to
low and high reinforcement respectively. Dimples are formed due to removal of material. The particle pull outt is
G. Elango and B.K. Raghunath / Procedia Engineering 64 (2013) 671 680 679
due to the poor particle /matrix bonding [25]. Thhis indicates the abrasive wear mechanism of the composiite
material while resisting the delaminating process. The
T wear resistance is more in case of high volume percentagge.
The wear mechanism if been analyzed for the reinforcement added in this experimental study reveals many reasonns
for the lower wear rate of this hybrid compositte, formation of Mechanical mixed Layer MML when thhe
temperature raises, due to the particle reinforcement SiC undergoes chemical interaction during sliding and form ms
SiO2 which acts like a lubricant, especially at highh speeds[28]. The protection cover provided by the MML is
observed to increases with the increasing volume ffraction of reinforcement[29]. The lubricating property of thhe
Titanium dioxide also been seen during the sliding w which gives the lower wear rate. The intension of increasing thhe
percentage of TiO2 particulate alone in the compositte is to study its influence of lubricating nature in the wear ratte,
this has also been proved that wear resistance of the hybrid composite increases as the TiO2 percentage increases.
(a) (b)
(c) (d)
Fig. 7 SEM photographs of the worn surfaces in 50m (a) unreinnforced alloy and composites with (b) LM25+ SiC 7.5% reinforcement, (c)
LM25+SiC 7.5% & TiO2 2.5% and (d) LM25+SiC7.5% & TiO O2 5% vol. fraction after complete sliding distance with maximum load of 5kgg
6. Conclusion
The Dry sliding wear behavior of this hybrid
h metal matrix composite (LM25+SiC+TiO2) led to thhe
following conclusion:
(1) As usual result, particulate reinforcement commposite has high strength, hardness and wear resistance wheen
compared with matrix material the wear resisstance increases in the hybrid composite material when the SiiC
and TiO2 is added as reinforcement Unreinforced aluminium alloy exhibits more wear followed by SiiC
reinforced binary metal matrix composites and then the hybrid composite (LM25+SiC+TiO2)
(2) As the load is increased, the change from miild to severe wear takes place on the unreinforced alloy, metal
matrix composites and hybrid metal matrix coomposites.
(3) The wear rate decreases with increasing TiO2 volume content of the reinforcement, the reason is lubricatinng
property and hardened nature of the TiO2 particulte favors for the increased wear resistance
(4) The coefficient of friction decreases with inccrease in particle reinforcement and load (for the fixed size oof
SiC and TiO2 particulates) The coefficient off friction and wear rate of the hybrid composite LM25 +SiC C+
5%TiO2 is less when compared with the matrrix alloy and the binary composite.
680 G. Elango and B.K. Raghunath / Procedia Engineering 64 (2013) 671 680
(5) The result of the scanning electron microscope shows that composite alloy has much rougher surface than
the unreinforced alloy. This indicates the abrasive wear mechanism which is due to hard ceramic particles
embedded in the surface of the composite.
(6) The result also proves that lubricating nature of reinforcement material enhances the wear resistance and
this property can be considered as a factor in design of new material for different application.
(7) Dry sliding wear test are performed under different applied loads for two types of ceramic particles. It is
suggested to study the wear behavior with other types of ceramic and/or same ceramic with different range
of particle sizes this may provide more detailed understanding on the effect of abrasive particle
characteristics on the wear mechanism.
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