Justin Brown Gamma/Phi/ Wilson Equation

Find Bubblepoint
Binary System Composition A B C
1 n-hexane 9.2033 2697.55 48.78
2 benzene 9.2675 2788.51 52.36
Psat=E^A-(B/T(dg K)+C) 16.05719
Givens: Psat=E^ A-(B/T(dg K)+C) 14.58257
x1 0.25
x2 0.75
P 2 atm
a12 169.92 cal/mol
a21 173.93 cal/mol
V1 145 cm3/mol
V2 95 cm3/mol
R 1.98722 cal/K mol

B11 -1360 cm3/mol

B12 -1218 cm3/mol
B22 -1086 cm3/mol
del12 9.4 cm3/mol
R2 82.06 cm3atm/mol*K

Equations
T 370.932125 3.02E-12 0=A-B/(TK-C)-Ln psat1
Psat1 2.292798762 1.57E-12 0=A-B/(TK-C) -ln Psat 2
Psat2 1.672546775 1.62E-10 0=x1 Gam 1 Psat 1 - y1*P*PHI1
y1 0.343880519 8.46E-11 0= x2 Gam 2 Psat2 - y2*P*PHI2
y2 0.656092478 7.29E-10 0=1-y1-y2
Gamma1 1.21594745 4.56E-11 0= -ln(x1+x2 Lam12)+ x2 W - ln Gam1
Gamma2 1.033957626 1.27E-10 0= -ln(x1 Lam21 +x2) -x1 W - ln Gam 2
Lmda12 0.520277582 2.01E-12 0= Lam12/ (x1 +x2 lam 12) -Lam21/(x1 Lam21 +x2) -W
Lmda21 1.205501385 9.11E-11 0=V2/V1 * e^ (-a12/RT) -Lam12
W -0.333926737 1.9E-11 0=V1/V2 * e^ (-a21/RT) -Lam21
PHI 1 1.013423846 1.89E-10 0=PHI1 - e^((B11*(P-Psat1)+P*y2^2*del12)/T/R2)
PHI 2 0.988439976 2.97E-10 0=PHI2 - e^((B22*(P-Psat2)+P*y1^2*del12)/T/R2)
ph1 0.914743561 1.02E-12 0=PHI1 -ph1/phsat1
ph2 0.931181455 4.16E-14 0=PHI2 - ph2/phsat2
phsat1 0.90262774 6.67E-12 0=phsat1 - e^(B11*Psat1/R2/T)
phsat2 0.942072022 1.09E-15 0=phsat2 - e^(B22*Psat2/R2/T)

4.19E-05 Solver this to zero

Gamma/Phi/ Wilson Equation
Find Bubblepoint
Binary System Composition A B C
1 n-hexane 9.2033 2697.55 48.78
2 benzene 9.2675 2788.51 52.36
Psat=E^A-(B/T(dg K)+C) 15.32132
Givens: Psat=E^ A-(B/T(dg K)+C) 13.90369
x1 0.5
x2 0.5
P 2 atm
a12 169.92 cal/mol
a21 173.93 cal/mol
V1 145 cm3/mol
V2 95 cm3/mol
R 1.98722 cal/K mol

B11 -1360 cm3/mol

B12 -1218 cm3/mol
B22 -1086 cm3/mol
del12 9.4 cm3/mol
R2 82.06 cm3atm/mol*K

Equations
T 367.890888 5.06E-11 0=A-B/(TK-C)-Ln psat1
Psat1 2.116949197 8.24E-11 0=A-B/(TK-C) -ln Psat 2
Psat2 1.537243327 2.65E-10 0=x1 Gam 1 Psat 1 - y1*P*PHI1
y1 0.564915483 1.85E-10 0= x2 Gam 2 Psat2 - y2*P*PHI2
y2 0.435067636 2.85E-10 0=1-y1-y2
Gamma1 1.073151445 3.45E-14 0= -ln(x1+x2 Lam12)+ x2 W - ln Gam1
Gamma2 1.113573846 5.13E-11 0= -ln(x1 Lam21 +x2) -x1 W - ln Gam 2
Lmda12 0.519284501 2.03E-12 0= Lam12/ (x1 +x2 lam 12) -Lam21/(x1 Lam21 +x2) -W
Lmda21 1.203149861 1.46E-10 0=V2/V1 * e^ (-a12/RT) -Lam12
W -0.40861654 4.53E-11 0=V1/V2 * e^ (-a21/RT) -Lam21
PHI 1 1.005389177 1.37E-10 0=PHI1 - e^((B11*(P-Psat1)+P*y2^2*del12)/T/R2)
PHI 2 0.983675301 1.24E-10 0=PHI2 - e^((B22*(P-Psat2)+P*y1^2*del12)/T/R2)
ph1 0.913912621 1.63E-10 0=PHI1 -ph1/phsat1
ph2 0.93075914 5.73E-13 0=PHI2 - ph2/phsat2
phsat1 0.909025332 1.9E-10 0=phsat1 - e^(B11*Psat1/R2/T)
phsat2 0.946204935 1.09E-11 0=phsat2 - e^(B22*Psat2/R2/T)

4.17E-05 Solver this to zero

Gamma/Phi/ Wilson Equation
Find Bubblepoint
Binary System Composition A B C
1 n-hexane 9.2033 2697.55 48.78
2 benzene 9.2675 2788.51 52.36
Psat=E^A-(B/T(dg K)+C) 14.94816
Givens: Psat=E^ A-(B/T(dg K)+C) 13.55965
x1 0.75
x2 0.25
P 2 atm
a12 169.92 cal/mol
a21 173.93 cal/mol
V1 145 cm3/mol
V2 95 cm3/mol
R 1.98722 cal/K mol

B11 -1360 cm3/mol

B12 -1218 cm3/mol
B22 -1086 cm3/mol
del12 9.4 cm3/mol
R2 82.06 cm3atm/mol*K

Equations
T 366.3099543 5.13E-11 0=A-B/(TK-C)-Ln psat1
Psat1 2.029700379 1.46E-11 0=A-B/(TK-C) -ln Psat 2
Psat2 1.470324452 1.78E-11 0=x1 Gam 1 Psat 1 - y1*P*PHI1
y1 0.771321454 4.64E-10 0= x2 Gam 2 Psat2 - y2*P*PHI2
y2 0.2286531 6.47E-10 0=1-y1-y2
Gamma1 1.014763665 1.1E-11 0= -ln(x1+x2 Lam12)+ x2 W - ln Gam1
Gamma2 1.220892678 1.5E-13 0= -ln(x1 Lam21 +x2) -x1 W - ln Gam 2
Lmda12 0.518763801 8.9E-13 0= Lam12/ (x1 +x2 lam 12) -Lam21/(x1 Lam21 +x2) -W
Lmda21 1.201922067 1.48E-10 0=V2/V1 * e^ (-a12/RT) -Lam12
W -0.454128781 4.55E-14 0=V1/V2 * e^ (-a21/RT) -Lam21
PHI 1 1.0013684 8.11E-11 0=PHI1 - e^((B11*(P-Psat1)+P*y2^2*del12)/T/R2)
PHI 2 0.981396327 2.06E-10 0=PHI2 - e^((B22*(P-Psat2)+P*y1^2*del12)/T/R2)
ph1 0.913512564 1.05E-11 0=PHI1 -ph1/phsat1
ph2 0.930629525 6.75E-12 0=PHI2 - ph2/phsat2
phsat1 0.912261274 4.91E-12 0=phsat1 - e^(B11*Psat1/R2/T)
phsat2 0.948268334 7.11E-12 0=phsat2 - e^(B22*Psat2/R2/T)

4.09E-05 Solver this to zero