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Chapter 5:
Material Balance for
Multi-Unit Operations
Process Flowsheet (Flow Chart)
2. Input/Output Diagram: All major inputs and outputs streams and their
stoichiometric balances are illustrated, according to the potential chemical
pathways.
3. Functions Diagram: All the major functions of the process and materials
flow to and from those functions are specified. The functions include reaction
boxes, separation boxes, finishing boxes, etc.
5. Process Flowsheet: Details for each function are described, ready to use.
Process Flowsheet Development
Sodium Dodecylbenzene Sulfonate Surfactant
Manufacturing
Input/Output Diagram
Function Diagram
Operation Diagram
Process Flowsheet
MB for Multiple Units Process
Example 1: on MB for Multi-units Process
Example 2: on MB for Multi-units Process
Recycle System
The stream containing the recycled material is known
as a recycle stream.
Because of relatively high cost of industrial feeds,
recycle of unused reactants/feed is a common
practice.
Recovery of catalyst, circulation of working fluids,
dilution of process streams, control of process
variables, etc., are all reasons for applications of
recycle system.
Recycle ratio = mass of recycle/mass of fresh feed
Example 3: Evaporative Crystallizer
The filter cake consists of crystal and a solution that contains 36.4% K2CrO4 by
mass; the crystals account for 95% of total mass of filter cake. The solution
that passes through the filter, also 36.4% K2CrO4, is the recycled stream.
Recycle
The feed to the reactor contains 28.0 mole% CO2, 70.0mole% H2, and 2.0
mole% inerts. The single-pass e conversion of hydrogen is 60%. Calculate the
molar flow rates and molar compositions of the fresh feed, the total feed to
the reactor, the recycle stream, and the purge stream for a production rate of
155 kmol CH3OH /hr.
Recycle and Purge in the synthesis of Methanol
Bypass
Bypass is a fraction of feed stream that is diverted around the
unit and combined with the output streams of such a unit. By
varying the fraction of the feed that is bypassed, we can vary the
composition and properties of the product.
A stream containing 5.15wt% chromium is contained in the wastewater from
a metal finishing plant. The wastewater stream is fed to a treatment unit that
removes 95% of the chromium in the feed and recycles it to the plant. The
residual liquid stream leaving the treatment unit is sent to a waste lagoon.
The treatment unit has a maximum capacity of 4500 kg wastewater/hr. If the
wastewater leaves the finishing plant at a rate higher than the capacity of the
treatment unit, the excess by passes the unit and combines with the residual
liquid leaving the unit, and the combined stream goes to the waste lagoon.
Wastewater leaves the finishing plant at a rate of 6,000 kg/hr. Calculate the
flow rate of liquid to the waste lagoon, and the mass fraction of Cr in this
liquid.
Example 8: Bypassing wastewater to waste Lagoon