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PHYSICAL CHEMISTRY

TARGET : JEE (Main) 2017

Course : ABHINAV (EA) NO. 18

This DPP is to be discussed in the week (10-08-2015 to 15-08-2015)


DPP No. # 18
Total Marks : 54 Max. Time : 40 min.
Single choice Objective ('1' negative marking) Q.1 to Q.10 (3 marks, 2 min.) [30, 20]
Multiple choice objective ('1' negative marking) Q.11 to Q.12 (4 marks, 2 min.) [08, 04]
Subjective Questions ('1' negative marking) Q.13 to Q.14 (4 marks 5 min.) [08, 10]
Match the Following (no negative marking) Q.15 (8 marks, 6min.) [08, 06]

1. For the reaction, A + 2B 2C, the rate constants for the forward and the backward reactions are
1 104 and 2.5 102 respectively. The value of equilibrium constant, K for the reaction would be :
A + 2B 2C vfHkf;k ds fy;s vxz vkSj i'p~ vfHkf;k ds nj fu;rkad e'k% 1 104 rFkk 2.5 102 gSaA
vfHkf;k ds fy;s lkE;koLFkk fu;rkad K dk eku D;k gksxk %
(1) 1 104 (2) 2.5 102 (3*) 4 103 (4) 2.5 102

2. An equilibrium system for the reaction between hydrogen and iodine to give hydrogen iodide at 765 K in a 5
litre volume contains 0.4 mole of hydrogen, 0.4 mole of iodine and 2.4 moles of hydrogen iodide. The equilibrium
constant for the reaction is : H2(g) + I2(g) 2HI(g)
765 K ij gkbMkstu vkSj vk;ksMhu dh f;k djkdj gkbMkstu vk;ksMkbM izkIr djrs gaSA lkE;okLFkk ij fudk; esa 5 yhVj
vk;ru esa gkbMkstu ds 0.4 eksy] vk;ksMhu ds 0.4 eksy vkSj gkbMkstu vk;ksMkbM ds 2.4 eksy jgrs gSaA vfHkf;k ds fy;s
lkE;koLFkk fu;rkad fuEu gksxk % H2(g) + I2(g) 2HI(g)
(1*) 36 (2) 15 (3) 0.067 (4) 0.28.
Sol. H2 + 2 2HI
0.4 0.4 2.4
2 .4 2 .4
K= = 36 (Since volume term is cancelled)
0 .4 0 .4

3. For a gasesous reaction, 2A + B 2C, the partial pressures of A, B and C at equilibrium are 0.3 atm, 0.4
atm and 0.6 atm respectively. The value of Kp for the reaction would be : [Chemical Equilibrium]
,d xSlh; vfHkf;k 2A + B 2C ds fy;s lkE; ij A, B vkSj C ds vkaf'kd nkc e'k% 0.3 atm, 0.4 atm vkSj 0.6
atm gaSA vfHkf;k ds fy;s Kp dk eku D;k gksxk %
(1*) 10 atm1 (2) 1/10 atm1 (3) 0.2 atm1 (4) 5 atm1

4. For the equilibrium in a closed vessel PCI5 (g) PCI3 (g) + CI2(g),
Kp is found to be double of Kc. This is attained when :
PCI5 (g) PCI3 (g) + CI2(g) ,d can ik=k esa fuEufyf[kr lkE; ds fy,] Kp dk eku Kc ls nksxquk gSA ;g kIr gksrk gS
tc%
(1) T = 2 K (2) T = 12.18 K (3*) T = 24.36 K (4) T = 27.3 K
Sol. Kp = Kc (RT)n
2Kc = Kc (RT)n
2 = (RT)1
2
T= = 24.36 K
0.0821

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1
5. Kp / Kc for the reaction CO(g) + O (g) CO 2 (g) will be :
2 2
1
CO(g) + O (g) CO 2 (g) vfHkf;k ds fy, Kp / Kc dk eku gSa %
2 2
1
(1) 1 (2) RT (3*) (4) R T
RT

6. For the reaction


H2(g) + I2(g) 2HI(g),
the equilibrium constant Kp changes with
(1) total pressure (2) catalyst
(3) the amounts of H2 and I2 present (4*) temperature
H2(g) + I2(g) 2HI(g),
vfHkf;k ds fy;s lkE;koLFkk fu;rkad Kp fdlds lkFk ifjofrZr gksxk %
(1) dqy nkc (2) mRizsjd
(3) H2 vkSj I2 dh mifLFkr ek=kk (4*) rki

7. For the equilibrium 2H2O(g) 2H2 (g) + O2(g), equilibrium constant is K1.
For the equilibrium 2CO2 2CO(g) + O2 (g), equilibrium constant is K2.
The equilibrium constant for CO2(g) + H2(g) CO(s) + H2O(g) is :
2H2O(g) 2H2 (g) + O2(g) lkE; ds fy,] lkE; fLFkjkad K1 gSA
2CO2 2CO(g) + O2 (g) lkE; ds fy,] lkE; fLFkjkad K2 gSA
rks CO2(g) + H2(g) CO(s) + H2O(g) lkE; ds fy,] lkE; fLFkjkad gksxk

K1 K1 K2
(1) K1 K2 (2) K (3) K2 (4*) K1
2

8. For the reaction A(g) + B(g) C(g) at equilibrium, the partial pressure of the species are PA = 0.15 atm,
PC = PB = 0.30 atm. If the capacity of reaction vessel is reduced, the equilibrium is reestablished. In the new
situation, partial pressure A and B become twice. What is the partial pressure of C?
A(g) + B(g) C(g) vfHkf;k
ds fy;s lkE; ij Lih'kht dk vkaf'kd nkc PA = 0.15 atm, PC = PB = 0.30 atm gSA
;fn vfHkf;k ik=k dh {kerk esa deh vkrh gS vkSj lkE; iquZLFkkfir gksrk gS] rks ubZ ifjfLFkfr esa A vkSj B dk vkaf'kd nkc
nqxquk gks tkrk gSA C dk vkaf'kd nkc D;k gksxk \
(1) 0.30 (2) 0.60 (3*) 1.20 (4) 1.80

9. The unit of equilibrium constant KC of a reaction is mol2 l2. For this reaction, the product concentration
increases by -
(1*) increasing the pressure (2) lowering the temperature
(3) lowering the pressure (4) both B and C

,d vfHkf;k ds lkE; fu;rkad KC dh bdkbZ mol2 l2 gSaA fuEu }kjk mRikn lkUnzrk c<+k;h tk ldrh gSa -
(1*) nkc o`f) ls (2) rki dks de djds (3) nkc dks de djus (4) B rFkk C nksuksa ls

Sol. KC = (mole/litre)n
where n = no of moles on product side no. of moles on reactant side
Hence n = 2
so moles on reactant side > moles on product side
so on increasing pressure reaction will get shifted in forward direction.

10. For the reaction (1) and (2) : A B+C ....(1)


D 2E ....(2)

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Given K P1 : K P2 : : 9 : 1
If the degree dissociation of A and D be same then the total pressure at equilibria (1) and (2) are in the ratio
(Assume reaction are started with equal number of moles of A and D).

(1) rFkk (2) vfHkf;k ds fy, % A B+C ....(1)


D 2E ....(2)
fn;k x;k gSa KP1 : K P2 : : 9 : 1
;fn A rFkk D dh fo;kstu nj leku gks rks lkE; (1) rFkk (2) ij nkc dk vuqikr fuEu gSa
(;g ekudj fd vfHkf;k A rFkk D ds izkjEHk esa leku eksyks dks fy;k x;k gSa))
(1) 3 : 1 (2*) 36 : 1 (3) 1 : 1 (4) 0.5 : 1

Sol. A B+C
1 0 0
1 = (1 + )

2
Kp1 = . p1
1 2
D 2E
1 0
1 2 = (1 + )

4 2
K p2 = . p2
1 2

K p1 p1
K p2 = 4p
2

p1 Kp1
so p2 = 4 . Kp 2 = 4 9 = 36 : 1

11. For the reaction , A + B 3 C , if ' a ' moles/litre of each ' A ' & ' B ' are taken initially , then the correct
relation about concentrations at equilibrium is :
(1*) [A] [B] = 0 (2*) 3 [B] + [C] = 3 a (3*) 3 [A] + [C] = 3 a (4) [A] + [B] = 3 [C]
vfHkf;k] A + B 3C ds fy, ;fn A rFkk B R;sd ds 'a ' moles/litre kjEHk esa fy;s tkrs gksa] rks lkE;koLFkk ij lkUnzrk
dk lgh lEcU/k fuEu gaS %
(1*) [A] [B] = 0 (2*) 3 [B] + [C] = 3 a (3*) 3 [A] + [C] = 3 a (4) [A] + [B] = 3 [C]

12. For which of the following equilibria, is Kp Kc :


fuEu esa ls fdl lkE; ds fy, Kp Kc gksxk %
(1*) 2H2(g) + O2(g) 2H2O(g) (2*) CH4(g) + H2O(g) CO(g) + 3H2(g)
(3) N2(g) + O2(g) 2NO(g) (4*) COCl2(g) CO(g) + Cl2(g)

13. The equilibrium constant for the following reaction , H2 (g) + Br2 (g) 2 HBr (g) is 1.6 105 at 1024 K. Find
the equilibrium pressure of HBr if 10 bar of HBr is introduced into a sealed container at 1024 K initially.
fuEu vfHkf;k]
H2 (g) + Br2 (g) 2 HBr (g) ds fy, 1024 K ij lkE;koLFkk fu;rkad 1.6 105 gSA HBr dk lkE;koLFkk nkc Kkr
dhft,] ;fn kjEHk esa 1024 K ij ,d can ik=k esa 10 bar HBr dks fy;k tkrk gksA
Sol. H2(g) + Br2(g) 2HBr(g)
Intial pressures 0 0 10.0 bar
At equilibrium p/2 p/2 (10.0-p)
p 2HBr
Kp
pH2 pBr2

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(10 p)2
1.6 10 5
(p / 2)(p / 2)
Taking square root of both sides
10 p
4 10 2
p/2
10
200 p = 10 - p ; p bar
201

1 10
p H2 p / 2 bar 2.5 10 -2 bar ; PBr2 p / 2 2.5 102 bar ; PHBr 10 p 10 bar .
2 201

14. PCI5 dissociates into PCI3 and CI2 in a 2 L flask about 600C. At equilibrium, mixture is found to contain 1
mole PCI5 and 2 moles each of PCI3 and CI2. Calculate :
(i) equilibrium molar concentrations
(ii) equilibrium mole fractions
(iii) equilibrium constants Kc for the chemical equilibrium:
PCI5(g) PCI3(g) + CI2(g)
2 yhVj {kerk ds ,d ik=k esa yxHkx 600C rki ij PCI5 dk fo;kstu PCI3 rFkk CI2 esa fd;k tkrk gSA lkE;koLFkk ij feJ.k
esa 1 eksy PCl5 rFkk PCl3 o Cl2 R;sd ds 2 eksy ik;s tkrs gSaA vr% x.kuk dhft, %
(i) lkE; eksyj lkUnzrk,sa
(ii) lkE; eksy fHkUu
(iii) jklk;fud lkE; ds fy, lkE; fLFkjkad Kc
PCI5(g) PCI3(g) + CI2(g)
Sol. (i) Molar concentrations (eksyj lkUnzrk,sa) :
mol 1
[PCI5] = = 0.5 mol L1
L 2
2
[PCI3] = = 1.0 mol L1
2
2
[CI2] = = 1.0 mol L1
2
(ii) Mole fractions (eksy fHkUu) :
Total moles at equilibrium = 1 + 2 + 2 = 5
nPCI5 1
XPCI = n = = 0.2
5 total 5

nPCI3 2
XPCI = n = = 0.4
3 total 5

nCI2 2
XCI = n = = 0.4
2 total 5
(iii) Equilibrium constants (lkE; fLFkjkad) :
[PCI3 ][CI2 ] 1 1
Kc = [PCI5 ] = = 2 (mol L1)1 = 2 L mol1
0 .5

15. Match the following . (fuEu dks lqesfyr dhft,A)


Reaction Degree of dissociation of reactant in terms
(Homogeneous gaseous phase) of equilibrium constant
vfHkf;k lkE;koLFkk fu;rkad ds inksa esa vfHkdeZd ds fo;kstu dh ek=kk
lekaxh xSlh; voLFkk
1. A + B 2 C (a) k 1 k
2. 2 A B + C (b) k 2 k
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3. A + B C + D (c) 2 k 1 2 k

1 1 2 k
4. AB A + B (d)
2 2 2 2 1 2 k
Ans. 1b, 2d, 3a, 4c

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