(Objective)

Q#1: Tick the Wright answer? (10)

I). Pressure remaining constant, at which temperature the volume of a gas become twice of what
it is at :-

(a): 546 0 (b): 200 0 (c): 546K (d): 273K

ii). If absolute temperature of a gas is double and the pressure is reduced to one half, the volume
of the Gas will
1
(a): Remain unchanged (b): Increase four times (c): Reduce to 4 (d): Be double

iii). The order of rate of diffusion of gasses , , is ?

(a). NH3 > O2 > l2 > O2 (b). NH3 > O2 > O2 > l2

(c). Cl2 > O2 > O2 > H3 (d). NH3 > CO2 > l2 > SO2

iv). The deviation of a gas from ideal behavior is maximum at ?

(a). 10 0 5 (b). 10 0 2 (c). 100 0 2 (d). 0 0 5

v). A real gas obeying Vander Waals equation will resemble ideal gas if

(a). Both "a" & "b" are large (b). Both "a" & "b" are small

(c). "a" is small & "b" is large (d). "a" is large & "b" is small.

vi). Calorie is equivalent to:

(a). 0.4184 J (b). 41.84 J (c). 4.184 J (d). 418 J

vii). The value of the general gas constant R in S.I units is:

(a). 8.3143 KJ/K.mol (b). 8.3143 J 1 1

(c). 0.08213 1 1 (d). 62.43 1 1

viii). Partial pressure of oxygen in the lungs is:

(a). 760 torr (b). 320 torr (c). 159 torr (d). 116 torr

ix). The density of methane at 2atm pressure at 27 is :

(a). 26g / 3 (b). 0.26g / 3 (c). 1.30g / 3 (d). 0.13g / 3

x). Two gases & are enclosed in a porous vessel. The comparison of effusion rates will be:

(a). 2 effuses four times faster than 2 (b). 2 effuses four times faster than 2

(c). 2 effuses sixteen times faster than 2 (d). They have equal rates of effusion
 (Subjective)

Q#2: Write a short note on 10 questions? (20)

1. State Dalton's law of partial pressure also gives its

expression?
2. Define one atmosphere pressure also write down it's

equivalence to ?
2
3. Draw the graph between P and PV?
4. Give two important scales of thermometry. How are these
related?
5. Show that density of an ideal gas is directly proportional to
its molar mass?
6. What is Avogadro's law?
7. Differentiate between Diffusion and Effusion?
8. Define critical temperature with one example?
9. What is joule Thomson effect?
10. At what conditions gases show non-ideal behavior?
11. Write down the two faulty postulates of kinetic
molecular theory of gasses?
12. What is plasma and write down its two applications?
Q#3: Do both long questions? (20)

1. (a). Write down the postulates of the kinetic molecular

theory of gases? (5)
(b). Working at a vacuum line, a chemist isolated a gas in
a weighting bulb with the volume of 255 3 , at a
temperature of 25 0 and under a pressure in the bulb of 10
torr. The gas weighted 12.1mg. What is the molecular
mass of this gas?
(5)
2. (a). Derive Vander Waals equation for real gases? (6)
(b). Calculate the mass of 1 dm3 of NH3 gas at 30C 0 and
1000mmhg pressure, considering that NH3 is behaving
ideally? (4)