TECHNOLOGICAL INSTITUTE OF THE A. 320 B.

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PHILIPPINES MANILA C. 360 D. 128
CH342 ANALYTICAL CHEMISTRY 14. Ksp of AgCl at room temperature is 1 x 10 10. Calculate the
NAME:__________________________________ Ag+ ion concentration in ppm in a 0.01M NaCl solution.
DATE:MARCH 13, 2014 A. 0.001079 B. 0.0024
ENGR. LORRAINE CARRILLO C. 0.0035 D. 0.0042
INSTRUCTIONS: Encircle the correct answer and
provide the solutions for problem solving questions 15. In an acidic solution, 25ml of 0.021M KMnO 4 oxidize
1. The conjugate acid of NH3 Fe2+ to Fe3+. Calculate the mass of Fe2+ (55.85g) oxidized
a. HOH b. NH4+ c. OH- d. NH2 a. 14.66mg b. 25.32mg
c. 2.55mg d. 146.6mg
2. In a dilute solution, the concentration of water is
a. 5.56 M b. 10.5 M c. 55.6 M d. NOTG 16. The presence of the following cations in solutions maybe
confirmed by conducting flame tests, except:
3. What mass of Ba(IO3)2 (487 g/mol) can be dissolved in a. Ba+2 b. Na+1 c. Ca+2 d. Ni+2
500.0 mL of water at 25C? Given the ffg:
17. In 100ml of 0.2M NH3 solution was added 50 ml of 0.3M
a. 0.104g b. 0.178 g c. 0.245 g d. 0.328g NH4Cl solution. If Kb of NH3 is 1.75 x 10-5, calculate the pH
of the final mixture
4. What volume of 0.12M BaCl2 is required to precipitate the a. 5.62 b. 8.38 c. 5.92 d. NOTG
BaSO4 after the oxidation of a sample of 0.1 g of ore which is
approximately 80 % FeS2? 18. Find the pH of a solution made by diluting one drop (0.04
A.11.1 mL B. 20.3 mL C. 22.4 mL D. NOTG mL) of 0.10 N HCl to 10 liters.
A. 6.37 B. 7.24 C. 8.14 D. 8.55
5. The chemical name of Turnbulls blue is
a. ferrous ferricyanide c. cuprous chloride 19. A 0.7500 g sample of an alloy steel yielded on electrolysis
b. ferric ferrocyanide d. cupric chloride 0.1532 g of a mixed deposit of Co and Ni. This is dissolved,
and the precipitated nickel dimethylglyoxine (NiC8H14N4O4)
6. The most commonly used reagent in the standardization of weighs 0.3560 g. What is the percentage of the Ni in the
acids alloy? A
a. K2SO4 b. borax a. 9.64% Ni; b. 10.79%Ni
c. BaCl2 d. Na2CO3 c. 12.43% Ni d. 13.79%Ni
20. An indicator which is a weak monobasic acid is blue in a
7. A 0.0722M acid has pH of 3.11, what is the Ka of this acid? strongly acid solution and yellow in a strongly basic one. If
a. 4.2 x 10-6 b. 8.4 x 10-6 Kind is 10 10, what is the pH when 40% of the indicator is in
c. 8.4 x 10-7 d. 1.2 x 10-7 the yellow form?
a. 7.82 b. 8.82 c. 9.82 d. 10.82
8. An iodide sample which weighs 3.000g is analyzed by the 21. A buffer has been prepared by mixing 250 mg NH4Cl and
Volhard process; 49.50 mL 0.2000 M AgNO3 is added, and 200 mL of 0.1 M NH3 solution. What is the pH of this after
6.50 mL 0.1000 M KSCN is needed to titrate the excess silver. 10 mM HCl has been added? The addition of the acid dilutes
Calculate the percentage of iodide in the sample. the mixture to 250 mL.
A. 25.36% B. 32.18% C. 39.13% D. NOTG a. 9.85 b. 9.09 c. 10.85 d. 11.09
22. Which of the following pipets 10 ml, 20 ml, 25 ml, 50
9. In gravimetric analysis, digestion of the precipitate ml, 100 ml should be used to measure the sample taken for
decreases titration of a water whose total hardness is approximately 900
a. particle size b. total surface area of the particle ppm CaCO3 if the EDTA solution available has a CaCO3 titer
c. filterability of the precipitate d. adsorbed materials of 0.8385 mg?
a. 10 ml, b. 20 ml, c. 25 ml, d. 50 ml,
10. What is the percentage of Fe3O4 in an ore sample which 23 24. Palladium (II) and gold (III) can be determined
weighed 0.5350 g? The sample was dissolved by fusion with simultaneously by reactions with methiomeprazine
KHSO4, oxidized by Br2 water, and the iron was precipitated (C19H24N2S2). The absorption maximum for the Pd complex
as hydrous ferric oxide. The ignited ferric oxide weighed occurs at 480 nm, while for the gold complex is at 635 nm.
0.5178 g. Molar absorptivity data at these wavelengths are as follows:
A. 85.23% B. 88.42% C.93.55% D. NOTG Molar Absorptivity
480 nm 635 nm
11. The percentage MnO2 (MW=86.94) in a 0.5 g sample, Pd complex 3.55 x 10 3 5.64 x 10 2
3
which after addition of 50 ml of 0.10N FeSO4 solution Gold complex 2.96 x 10 1.45 x 10 4
required 16 ml of 0.08 N K2Cr2O7 solution for back titration is A 25.0 mL sample was treated with excess methiomeprazine
A. 16.17 B. 32.34 C. 48.51 D. 64.68 and subsequently diluted to 50 mL. Calculate the molar
concentration of Pd and Au in the sample if the diluted
12. A sample of pyrite, FeS2 (MW=119.97), contains only solution has an absorbance of 0.533 at 480 nm and 0.590 at
inert impurities and weights 0.5080 g. After the sample has 635 nm when measured in a 1-cm cell.
been decomposed and dissolved, a precipitate of 1.561 g of Au 23. a. 3.60 x 10 -5M b. 5.60 x 10 -5M
-5
BaSO4 (MW=233.40) is obtained. If the calculated percentage c. 4.60 x 10 M d. 6.60 x 10 -5M
of S (MW=32.06) in the sample is 42.21% what weight of Pd a. 1.20 x 10 -4M b. 2.20 x 10 -4M
ignited precipitate would have been obtained if the Fe c. 1.60 x 10 -5M d. 2.60 x 10 -5M

(MW=55.85) in the solution had been precipitated as Fe (OH) 3 25. I can be separated from other halides by precipitation as
and ignited as Fe2O3 (MW=159.7)? PdI2 and weighed as such or reduced in a current of H2 to Pd.
A. 0.2670 g B. 0.217 g C. 0.2985 g D. 0. 3025 g A 0.5000-g sample of KI and NaCl and inert impurities gave
a precipitate of mixed silver halides which weighed 0.8000 g.
13. If 50 ml of a sample of water required 6.4 ml of EDTA A 0.2000-g sample yielded 0.04250 g metallic palladium. Find
solution for titration and each ml of the EDTA solution is the percentage of NaCl in the sample.
equivalent to 0.40 mg Ca (MW=40), the ppm CaCO 3 A.66.10% B. 27.18% C. 69.21% D. NOTG
(MW=100) hardness is