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A. Valero
Accounting and
L. Serra Thermoeconomics. Part II:
J. Uche1
e-mail: javiuche@unizar.es
Applications
CIRCE Foundation Part II of this paper develops the mathematical formulations of three applications of the
(Centre of Research for Energy Resources thermoeconomic analysis methodology described in Part I of the paper: the operation
and Consumptions)/University of Zaragoza, diagnosis study, including new concepts that helps to separate different contributions to
c/Mara de Luna 3, those inefficiencies; the local optimization process in case of special conditions for the
50018 Zaragoza, Spain whole plant, and the benefit maximization (a direct application of the exergy costs ac-
counting analysis). The operation diagnosis, which is the most complex and sophisticated
application, is presented with the help of an example: the co-generation plant, as it was
described in Part I. DOI: 10.1115/1.2134731
m
Introduction E0 * g j
Exergy Cost Accounting and Thermoeconomics finds out how xi
= k x
i=1
j
i
1
energy and resources degrade, which systems work better, how to
improve designs to reduce consumption and prevent residues from which expresses the effect on additional resource consumption
damaging the environment. Assessing the cost of the various when an internal parameter xi is modified.
streams and processes in a plant helps to understand the process of In order to clarify the explanation of the proposed method we
cost formation, from the input resources to the final products. use the simple example a more complex one applied to a real
Despite of their importance and the valuable and useful infor- power plant can be found in Valero et al. 1 presented in Part I,
mation they provide, the exergy and/or thermoeconomic costs of a the co-generation plant depicted in Fig. 1 of Part I, whose design
complex system are only the tip of the iceberg in Thermoeconom- and operational exergy flow values are shown in Table 1. The
ics. They are the starting point for further thermoeconomic appli- plant has two products: process steam in the Heat Steam Recovery
cations. In this Part II are presented the fundamentals of thermo- Generator HRSG, flow 7 together with the electric energy pro-
economic diagnosis and optimization of complex energy systems, duced in the turbo-generator flow 6.
including local optimization and benefit maximization. Special at-
tention is focused to the inefficiency diagnosis because it requires Technical Exergy Saving. Once the exergy flows have been
the introduction of new concepts: induced and intrinsic malfunc- supplied by an appropriate performance test or a model simulator,
tions, and dysfunctions. the irreversibilities in each productive unit can be obtained from
the exergy balance. But not all exergy losses can be saved in
practice. In fact, the potential exergy saving is limited by technical
Operation Diagnosis and/or economic constraints. It also depends on the decision level
Diagnosis is the art of discovering and understanding signs of that limits the actions to be undertaken. In contrast to conven-
malfunction and quantifying their effects. In the case of Exergy tional thermodynamic analysis, Exergy Cost Accounting and
Cost Accounting and Thermoeconomics, the effect of a malfunc- Thermoeconomics assume a reference situation of the plant oper-
tion is quantified in terms of additional resources consumed to ating under optimized design conditions. From this perspective, in
obtain the same production, both in quality and in quantity. To do the co-generation plant Fig. 1 of Part I only 133 kW e.g.,
that, it is needed: 11914-11781 of the 7.06 MW of total irreversibilities e.g.,
11914-2500-2355 can be saved with respect to design optimized
A procedure that accurately determines the state of the plant conditions.
a simulator or Data Acquisition System could provide Therefore, the additional fuel consumption can be expressed as
enough data to perform the mass, energy, entropy and ex- the difference between the resource consumption of the operating
ergy plant balances. plant and the resource consumption for a reference or design op-
A theory to provide the concepts and tools to understand and timized condition with the same production objectives:
explain the causes of this state.
FT = FT FT0 2
The methodology presented here is based on the Structural
Theory formalism presented in Part I to provide the tools to in- and it can be broken up into the sum of the irreversibilities of each
vestigate the causes of the irreversibilities and the cost formation process unit:
process. The basis of the inefficiency diagnosis is focused on the
n n
marginal cost k* when production is modified: applying the
chain rule of mathematical derivatives, we can get to the equation FT = IT = I I = I
j
0
j j 3
1 j=1 j=1
Journal of Energy Resources Technology Copyright 2006 by ASME MARCH 2006, Vol. 128 / 9
Flow kW 1 2 3 4 5 6 7 8
Impact on Resources Consumption. The fuel/product diagram calculated following Eq. 4, as is written in Table 4.
is the source point to start up the diagnosis of a complex system. Equation 18 in Part I is used to obtain the increment of the
Once it is built for the design and operating conditions, Eqs. 14 total resources of an operating plant with respect to the reference
and 15 of Part I are automatically solved and then the diagnosis conditions:
can be studied. Table 2 shows the F/P diagram corresponding to
the cogeneration plant of our example. For the sake of simplicity FT = teP0 + teP 5
we did not consider thermal and mechanical exergies as separate The increase of the process unit production from Eq. 15, Part I,
entities. Flow 8, produced in part in the combustor and in the may be expressed in terms of the unit exergy consumption as:
compressor, also leaves the system as a residue. Following the
productive structure depicted in Fig. 2 of Part I, the way to com- P = Ps + KPP0 + KPP 6
plete this table is the following.
hence, applying Eq. 16 from Part I, we obtain:
1st row P0: The only fuel coming from the environment
P0 = E1 is fuel of the combustor F1. P = PPS + KPP0 7
2nd row P1: The product of the combustor P1 = E3 E2 is If we want to analyze the fuel impact due to an increment of the
fuel of the turbine F3 = E3 E4 and the HRSG F4 = E4 exergy unit consumption of the process units, Eq. 5 could be
E8. The auxiliary variable r1 = E3 E2 / E3 corresponds to written as:
the part of the fuel of the turbine coming from the combus-
tor. So the final quantity to put in column F3 is r1 E3 FT = teP0 + t*PKPP0 + t*PPs 8
E4. Similarly, the final value in column F4 is r1 E4 If no change in the total production of the plant is assumed, then
E8. the last term could be neglected:
3rd row P2: The product of the compressor P2 = E2 is also
fuel of the HRSG and the turbine. In this case, the exergy FT = te + tk*PKPP0 9
ratio r2 for multiplying the F3 and F4 columns in row P2 is
or in scalar format showing the ij elements:
r 2 = E 2 / E 3.
4th row P3: The products of the turbine are the net work
leaving the plant F0 = E6 and the work delivered to the
compressor, which is the fuel of the compressor F2 = E5. Table 3 KP matrix for design conditions in the cogeneration
5th row P4: The HRSGs product leaves the cogeneration plant
plant and it is therefore an external output F0 = E7
e 1,7769 0,0000 0,0000 0,0000
In order to bring together the problem of the impact of re-
sources consumption with inefficiency diagnosis we need to know KP 0,0000 0,0000 0,7588 1,0505
the increase of the unit exergy consumption of each process unit 0,0000 0,0000 0,2971 0,4110
0,0000 1,1472 0,0000 0,0000
of the plant j. A performance test or a simulator can provide 0,0000 0,0000 0,0000 0,0000
the actual values of the unit consumptions, which can be com- k 1,7769 1,1472 1,0559 1,4616
pared with the design values or different plant states.
The values of the unit exergetic consumption increase are found
as:
ij = ijx ijx0 4
To do that, the KP matrices in the operating and design condi-
tions are firstly needed, starting from the F/P table see Table 2 for
the design conditions. Table 3 shows the KP matrix for the
design conditions.
The ij values obtained in this table are calculated by dividing
each component of the jth column of the F/P table by the product
P j. Then the ij values for the plant in Fig. 1 can be easily
Table 2 Fuel and energy flows kW in design conditions for Fig. 1 Fuel impact and technical saving
the co-generation plant shown in Fig. 1 part I
Table 4 Increase of unit exergetic consumption 100ij
F0 F1 F2 F3 F4 Total
e 0.4006 0.0000 0.0000 0.0000
P0 0 11,781 0 0 0 11,781
P1 0 0 0 4,156 2,474 6,631
KP 0.0000 0.0000 0.1667 0.3857
P2 0 0 0 1,627 968 2,595 0.0000 0.0000 0.1593 0.4636
P3 2,500 0 2,977 0 0 5,477 0.0000 1.1147 0.0000 0.0000
P4 2,355 0 0 0 0 2,355 0.0000 0.0000 0.0000 0.0000
Total 4,855 11,781 2,977 5,783 3,443 k 0.4006 1.1147 0.0074 0.8493
MFi = Pi0ki = P
j=0
0
i ji 12
FT =
n
k
i=1
n
j=0
P,j ji
*
Pi0 10
by a process unit is defined as:
DIi = Fi MFi 14
Using the above equation, the additional resource consumption Table 5 shows the malfunctions, dysfunctions, impact on fuel and
FT also called Fuel Impact 3 can be expressed as the sum of increase of irreversibility of the example analyzed here. In this
the contributions of each process unit. The KP matrix is the case is not included matrix notation, but using similar equations
key to predict the impact on fuel of a physical variation of a than the previous 5, it should be calculated the dysfunction DFij
parameter in the system, because their coefficients ij represent representing the part of the ith component dysfunction generated
in some extent the efficiency deviation of each plant component by component j. Note that the total DI and DF must be equal, and
with respect to the operating performance of the plant under de- also the total fuel impact and irreversibility generated in the
sign conditions. The total deviation must therefore be multiplied system.
by the total product of that component, e.g. ji P0i which is called Intrinsic and Induced Malfunctions. From results in Table 5,
malfunction. As this product has an exergy cost that depends on we find out three malfunctions in the gas turbine cycle: one each
the position of the component in the system, the malfunction im- in the combustor, compressor and HRSG. But, in fact, the actual
plies an additional fuel consumption or fuel impact due to ineffi- operation values shown in Table 1 only correspond to a 1% de-
ciencies in a system see Eq. 10. crease in compressor isoentropic efficiency. This means that
The proposed method provides the exact values of the addi- HRSG and combustor efficiencies can be changed by varying
tional resource consumption of each process unit malfunction for compressor efficiency; in general there is an operating parameter
any operational state. Other methods, such as the Theory of Per- xr affecting the efficiency of the ith process unit of the plant and
turbations 4, only provide an approximate predictive value, thus, in most cases, also indirectly affecting the efficiencies of the
based on marginal costs Lagrange multipliers which is valid for other plant process units.
an operating state close to the reference conditions. According to their effect on the process units efficiency in a
Figure 1 compares the fuel impact and the increase of irrevers- system, plant operating parameters could be classified as:
ibilities or the technical exergy saving of each process unit and Local variables: They mainly affect the behavior of the process
also compares first column the malfunction and the fuel impact unit related to the variable, e.g, the isentropic efficiency of a tur-
for each process unit. Three malfunctions in the plant are shown bine. From a practical point of view, a variable is considered local
in the combustor, the compressor and the Heat Recovery Steam and therefore related to a subsystem when the total fuel impact
Generator HRSG. The largest irreversibilities increase is in the due to its perturbation is basically located in this process unit.
combustor, but the largest fuel impact is in the compressor. The Global and/or zonal variables: This is the case when an oper-
question that arises is, what causes the irreversibilities increase ating parameter cannot be associated with a specific process unit.
and the fuel impact, and how are they related? We must identify them as operating set points, environmental pa-
Malfunction and Dysfunction Analysis. The degradation of a rameters and the production load or fuel quality.
process unit forces other process units to adapt their behavior in The key of the malfunction analysis is the calculation of the
order to maintain their production conditions and modify their ij components representing the unit exergy consumption in-
irreversibilities. Figure 2 shows how an increase of the unit con- crease of each process unit, due to the variation of an operating
sumption of a process unit will not only increases the irreversibili- parameter xr, is:
ties on it but also the irreversibilities of the previous process unit.
The irreversibility increase of a generic systems process unit is ijr = ijx0 + xr ijx0 15
given by: Therefore, it will be possible to approximate the malfunction of a
I = KDP + KD UDP
0
11 process unit as the sum of the contributions of each operating
parameter:
From the above expression, we can distinguish two types of in-
creased irreversibilities: n
MFiL
n
rLi j=1
rji Pi0 17 min
k
n
i=0
kijk*P,i P j 19
In this section are presented two different applications of ther- n
moeconomic costs to the optimization. The first case local opti- ij z P,i
mization is oriented to the design of complex systems. The sec- C0,i
x
= k*P,i + Px 20
x x
ond one benefit maximization is oriented to a cost effective plant i=0
Luis M. Serra is permanent associate professor of the Mechanical Engineering Department at the Univer-
sity of Zaragoza since 1997. He has participated and led several research and development projects on
energy systems and energy saving in general and particularly on thermoeconomic analysis, process inte-
gration (polygeneration) and environmental assessment. Serra has been the co-recipient of the best paper
award on Advanced Energy Systems from ASME (Edward F. Obert Award 2003). He is author and co-author
of more than 70 papers and books and reviewer for several international journals, e.g., ASME Journal of
Energy Resources Technology, Solar Energy and International Journal of Life Cycle Assessment.
Dr. Javier Uche Marcuello. Ph. D. Industrial Engineer since June 2000. Assistant professor of the Uni-
versity of Zaragoza (Department of Mechanical Engineering) since October 2000. More than 40 papers in
international journals, book articles and international conferences (mainly in Desalination and integration
of water and energy issues). Two books about desalination and economic aspects of irrigation. Consultant
of the Government of Aragon in water issues.