Академический Документы
Профессиональный Документы
Культура Документы
Supervised By:
Prof. Dr. Rafiullah Khan
Submitted By:
Adeel-ur-Rehman E11-15-CE06
Hamood Ahmad E11-15-CE11
Younis Iqbal E11-15-PG06
Amir Bashir E11-15-PG11
We wish to acknowledge our debt to our guide Prof. Dr. Rafiullah for helping us with his knowledge
and expertise whenever we felt the need and also for his continued guidance in preparing this report in the
current form.
We wish to express our appreciation for the the library staff at Institute of Chemical Engineering &
Technology, University of the Punjab, Lahore, for co-operating with us to their best abilities during our project
and their help in acquisition of related books and other data.
Those who contributed indirectly in accomplishing this report through their discussions and criticism,
our classmates.
Last but not least, our parents and siblings whose prayers and help were the driving force for our work.
Adeel-ur-Rehman
Amir Bashir
Hamood Ahmad
Younis Iqbal
Contents
Chapter 1: Introduction ....................................................................................................................................... 1
1.1. Polyester .............................................................................................................................................. 1
1.2. Classification of Polyesters .................................................................................................................. 1
1.2.1. Thermoplastic Polyesters ............................................................................................................ 1
1.2.2. Thermosetting Polymers ............................................................................................................. 1
1.3. Types of Polyesters .............................................................................................................................. 1
1.3.1. On Basis of Composition.............................................................................................................. 1
1.3.2. On the Basis of Application.......................................................................................................... 2
1.3.3. On the Basis of Structural Differences/Bonding.......................................................................... 2
1.4. Importance of Polyester ...................................................................................................................... 3
1.5. Consumption of Polyester ................................................................................................................... 3
1.6. Uses of Polyester ................................................................................................................................. 4
1.6.1. Usage of Polyester Films.............................................................................................................. 4
1.6.2. Usage of Polyester in Medical Field............................................................................................. 4
1.6.3. Usage of Polyester Fibers ............................................................................................................ 4
Uses of Polyester Fibers .................................................................................................................................. 4
1.7. Polyester Fiber ..................................................................................................................................... 5
1.7.1. Criteria for Fiber Forming Polymers ............................................................................................ 5
1.8. Economical Prospective ....................................................................................................................... 5
1.9. Uses of PET Polyester .......................................................................................................................... 7
1.9.1. Uses of Polyester for Apparel Purposes ...................................................................................... 7
1.9.2. Industrial Uses ............................................................................................................................. 7
1.9.3. Other Uses ................................................................................................................................... 8
1.10. Conversion of Chips to PET Fiber ..................................................................................................... 9
1.10.1. Spinning ....................................................................................................................................... 9
1.11. Types of Spinning........................................................................................................................... 10
1.11.1. Melt Spinning............................................................................................................................. 10
References: .................................................................................................................................................... 11
Chapter 2: Process Selection ............................................................................................................................. 12
2.1. PET Polymerization ............................................................................................................................ 12
2.1.1. General Description of PET Polymerization............................................................................... 12
2.1.2. Why Two Step Reaction? ........................................................................................................... 12
2.2. Types of PET Polymerization ............................................................................................................. 12
2.2.1. Batch Process............................................................................................................................. 12
2.2.2. Continuous Process ................................................................................................................... 13
2.3. Advantages of Continuous Process over Batch Process .................................................................... 13
2.4. Contrasting the DMT & TPA Processes .............................................................................................. 14
2.5. Difference between DMT & TPA Processes....................................................................................... 14
2.6. Transesterification Process................................................................................................................ 15
2.7. Take Over of DMT Process by TPA Process ....................................................................................... 15
2.8. Basis for the Process Selection .......................................................................................................... 15
2.8.1. Advantages of TPA over DMT .................................................................................................... 15
Chapter 3: Selected Process Description ........................................................................................................... 16
3.1. Direct Esterification ........................................................................................................................... 16
3.2. Reactions ........................................................................................................................................... 16
3.3. Raw Materials .................................................................................................................................... 16
3.3.1. Ethylene Glycol .......................................................................................................................... 16
3.3.2. Terephthalic Acid ....................................................................................................................... 17
3.4. Process Stage ..................................................................................................................................... 18
3.4.1. TPA Unloading and Storage ....................................................................................................... 18
3.4.2. EG Unloading and Storage ......................................................................................................... 18
3.4.3. TDO and Catalyst Preparation ................................................................................................... 18
3.4.4. Slurry Making ............................................................................................................................. 18
3.4.5. Esterification Stage .................................................................................................................... 19
3.4.6. Polycondensation ...................................................................................................................... 20
Chapter 4: Material Balance .............................................................................................................................. 17
4.1. Nomenclature .................................................................................................................................... 17
4.2. Reactions: .......................................................................................................................................... 17
4.3. Molecular Weights of Materials ........................................................................................................ 17
4.4. Overall Material Balance ................................................................................................................... 18
4.4.1. Stoichiometric Calculations ....................................................................................................... 18
4.5. Nomenclature of Streams ................................................................................................................. 19
4.6. Detailed Material Balance ................................................................................................................. 19
4.6.1. Slurry Section (TPA + EG Mixing Tank) ...................................................................................... 19
4.6.2. Esterification Section ................................................................................................................. 21
4.6.3. Polycondensation Reactors ....................................................................................................... 31
Chapter 5: Energy Balance ................................................................................................................................ 44
5.1. Esterification Reactor 1 (ER-1)........................................................................................................... 44
5.1.1. Description................................................................................................................................. 44
5.1.2. Stream Properties ...................................................................................................................... 45
5.1.3. Calculation of Energy Requirements for Stream 1 .................................................................... 46
5.1.4. Total Energy Requirement ......................................................................................................... 47
5.2. Esterification Reactor 2: .................................................................................................................... 48
5.2.1. Description................................................................................................................................. 48
5.2.2. Stream Properties ...................................................................................................................... 49
5.2.3. Calculation of Energy Requirements ......................................................................................... 49
5.2.4. Total Energy Requirement ......................................................................................................... 50
5.3. Polymerization Reactor 1 .................................................................................................................. 51
5.3.1. Description................................................................................................................................. 51
5.3.2. Stream Properties ...................................................................................................................... 51
5.3.3. Calculations of Energy Requirement ......................................................................................... 52
5.3.4. Total Energy Requirement ......................................................................................................... 52
5.4. Polymerization Reactor-2 .................................................................................................................. 53
5.4.1. Description................................................................................................................................. 53
5.4.2. Stream Properties ...................................................................................................................... 53
5.4.3. Calculations of Energy Requirement ......................................................................................... 54
5.4.4. Total Energy Requirement ......................................................................................................... 54
5.5. Poly-Condensation Reactor ............................................................................................................... 55
5.5.1. Description................................................................................................................................. 55
5.5.2. Stream Properties ...................................................................................................................... 55
5.5.3. Calculations of Energy Requirement ......................................................................................... 56
5.5.4. Total Energy Requirement ......................................................................................................... 56
Chapter 6: Equipment Design ............................................................................................................................ 57
6.1. Storage Units ..................................................................................................................................... 57
6.1.1. Storage Tank of TPA................................................................................................................... 57
6.1.2. Storage Tank of EG .................................................................................................................... 59
6.2. Mixing Tank ....................................................................................................................................... 61
6.2.1. Design of Slurry Mixer ............................................................................................................... 61
6.3. Esterification Reactors....................................................................................................................... 67
6.3.1. Design of Esterification Rector 1 (ES-1) ..................................................................................... 67
6.3.2. Design of Esterification Rector 2 (ES-2) ..................................................................................... 71
Chapter 7: Instrumentation & Process Control ................................................................................................. 75
7.1. Instrumentation................................................................................................................................. 75
7.1.1. Measurement ............................................................................................................................ 75
7.1.2. Control ....................................................................................................................................... 75
7.2. Incentive for Chemical Process Control............................................................................................. 76
7.2.1. Safety ......................................................................................................................................... 76
7.2.2. Product Specification ................................................................................................................. 76
7.2.3. Environmental Regulations ....................................................................................................... 76
7.2.4. Operational Constraints ............................................................................................................ 76
7.2.5. Economics .................................................................................................................................. 76
7.3. Elements of Control System .............................................................................................................. 77
7.3.1. The Chemical Process ................................................................................................................ 77
7.3.2. The Measuring Instrument or the Sensors ................................................................................ 77
7.3.3. Transducers ............................................................................................................................... 78
7.3.4. Transmission lines ..................................................................................................................... 78
7.3.5. Controller ................................................................................................................................... 78
7.3.6. The Final Control Element ......................................................................................................... 78
7.4. Modes of Control............................................................................................................................... 79
7.4.1. Different Types of Control Actions ............................................................................................ 79
7.4.2. Composite Control Modes......................................................................................................... 79
7.5. Selection of Controller ....................................................................................................................... 79
7.5.1. Usage of a Simple Proportional Controller: ............................................................................... 80
7.5.2. Usage of a PI Controller ............................................................................................................. 80
7.5.3. Usage of a PID Controller .......................................................................................................... 80
7.6. Control Loops..................................................................................................................................... 80
7.6.1. Feed Back Control Loop ............................................................................................................. 81
7.6.2. Feed Forward Control Loop ....................................................................................................... 81
7.6.3. Ratio Control Loop ..................................................................................................................... 81
7.6.4. Auctioneering Control Loop ...................................................................................................... 81
7.6.5. Cascade Control Loop ................................................................................................................ 81
7.7. Instrumentation of Slurry Tank ......................................................................................................... 82
7.8. Instrumentation of Esterifier ............................................................................................................. 83
7.9. Instrumentation of Poly-condensation Reactor ................................................................................ 84
Chapter 8: Cost Estimation ................................................................................................................................ 85
8.1. Introduction of Cost Estimation: ....................................................................................................... 85
8.1.1. Accuracy and purpose of capital cost estimates ....................................................................... 85
8.1.2. Classification of Capital Cost Estimations .................................................................................. 85
8.1.3. Capital investment:.................................................................................................................... 85
8.1.4. Fixed Capital: ............................................................................................................................. 86
8.1.5. Working Capital: ........................................................................................................................ 87
8.1.6. Operation Cost........................................................................................................................... 87
8.1.7. Cost Indices ................................................................................................................................ 88
8.1.8. Summary of Production cost: .................................................................................................... 88
8.2. Purchased Cost .................................................................................................................................. 89
8.2.1. Nomenclature: ........................................................................................................................... 89
8.2.2. Purchased cost of TPA Storage tank: ......................................................................................... 89
8.2.3. Purchased Cost of EG: storage tank: ......................................................................................... 89
8.2.4. Purchased Cost of Slurry Tank: .................................................................................................. 90
8.2.5. Purchased cost of esterifier PR-1 .............................................................................................. 90
8.2.6. Purchased cost of Esterifier reactor PR-2 .................................................................................. 90
8.2.7. Total cost of esterifiers: ............................................................................................................. 90
8.2.8. Purchased cost of Polycondensation Reactor RA-21: ............................................................... 91
8.2.9. Purchased cost of Polycondensation Reactor RA-31: ............................................................... 91
8.2.10. Purchased cost of Polycondensation Reactor RA-41: ............................................................... 91
8.2.11. Purchased cost of condensers: .................................................................................................. 92
8.2.12. Purchased cost of pumps: ......................................................................................................... 92
8.2.13. Purchased cost of coil: ............................................................................................................... 93
8.2.14. Total purchased equipment cost: .............................................................................................. 94
8.3. Total Physical plant Cost (PPC): ......................................................................................................... 94
8.3.1. Fixed Capital: ............................................................................................................................. 95
8.3.2. Working Capital: ........................................................................................................................ 95
8.4. Summary of Production Costs: .......................................................................................................... 95
8.4.1. Variable cost: ............................................................................................................................. 95
Chapter 1
Introduction
Chapter 1 Introduction
Chapter 1: Introduction
1.1. Polyester
Polyester is a category of polymers which contain the ester functional group in their main chain or
Polyester refers to the various polymers in which the backbones are formed by esterification and condensation
of poly functional alcohols and acids. Polyester can also be defined as long-chain polymers chemically
composed of at least 85% by weight of an ester and a dihydric alcohol and a terephthalic acid. Although there
are many polyesters, the term polyester as a specific material most commonly refers to a polyethylene
terephthalate (PET).
Although polyesters can be either thermoplastic or thermosetting, however, the most common
polyesters are thermoplastic.
They consist of low molecular weight liquids used as plasticizers and as reactants in forming urethane
polymers, and linear, high molecular weight thermoplastics such as polyethylene terephthalate.
2
Chapter 1 Introduction
Table 01-1: Classification of Unsaturated Polyesters:
Talking about the apparel sector which consumers around 39.4% of the polyester fiber that is
produced every year, top weight fabrics, underwear, night wear and high pile fabrics are made using
polyesters. Now talking about household and interior textiles, 16.9% of the polyesters that are produced every
year are consumed in this sector. Major consumption includes sheets and pillow cases, blankets, bed ticking
and towels. Lastly, carpets and rugs use 5.4% of the polyester fibers and are produced annually.
3
Chapter 1 Introduction
1.6. Uses of Polyester
As polyesters usually offer high tenacity and durability, it is often used in outerwear. The overall
strength of the fiber is so high that it can withstand constant and repetitive movements. In addition to the
tenacity and durability, most polyesters that are in use in todays market have very high hydro-phobic
properties. Thus, they can be used in wet environments without any damage to the outerwear. It is often used
in pants, shirts, suits and bed-sheets either by itself or as a blend because of its wrinkle resistant property and
its ability to retain its shape.
In industries, adhesive tapes, plastic cards, labels, lamination films and enhancement films are made
up of polyester films. As far as its usage in electrical equipment is concerned, motor wires and cables as well
as transformer insulation wires can be made from polyester films. In magnetics, video tapes, audio cassettes
while in case of imaging, micro-film printing and X-ray films use the polyester films.
In industries, adhesive tapes, plastic cards, labels, lamination films and enhancement films are made
up of polyester films. As far as its usage in electrical equipment is concerned, motor wires and cables as well
as transformer insulation wires can be made from polyester films. In magnetics, video tapes, audio cassettes
while in case of imaging, micro-film printing and X-ray films use the polyester films.
4
Chapter 1 Introduction
1.7. Polyester Fiber
Polyester fiber is a manufactured fiber in which the fiber forming substance is any long-chain synthetic
polymer composed of at least 85% by weight of an ester of a substituted aromatic carboxylic acid, including
but not restricted to substituted Terephthalic units, p(-R-O-CO-C6H6-CO-O-) and para-substituted hydroxyl-
benzoate units, p(-R-O-CO-C6H6-O-).
By far, the greatest use of polyester is in synthetic fibers, primarily for apparel. Polyester fibers provide
ease of care benefits in apparel and improved mill processing economics on modern, high productivity
machines, its high mechanical properties, good thermal stability, low moisture regain, rot resistance and
abrasion resistance make it useful in a wide range of non-apparel and industrial applications, such as hose
cord, ropes, sailcloth, coated sheeting, conveyor belts, pillows, sleeping bags and carpet.
1. A fiber forming polymer should possess sufficiently high molecular weight with preferably narrow
molecular weight distribution. High structural regularity for inherent capacity to crystallize and polar
groups for easy absorption of moisture, dyes, finishes and textile auxiliaries.
2. A fiber making substance should have long molecules so that sufficient length to breadth ratio can be
obtained in fiber produced from it.
3. The polymer should have high degree of inter-molecular cohesion power. Inter-molecular cohesion is
generally expressed in terms of crystallinity of polar characteristics.
4. A fiber forming polymer may also possess rubber-like properties in certain conditions. It will impart
the polymer, a sensitiveness to thermal and mechanical influence. At certain conditions, the polymer
should behave brittle, glass-like amorphous character and sometimes hard crystalline properties. The
fiber making process requires the polymer to traverse the plastic, rubbery and oriented states for the
production of useful properties.
5. At normal working conditions, the polymer should withstand certain treatment in terms of mechanical
properties, thermal properties and chemical properties. So the polymer should have,
i. A high softening point
ii. Adequate tensile strength over a fairly wide temperature range.
iii. A proper modulus or stiffness.
Polyethylene terephthalate (PET) is one of the widely applied polymers. From annual production
viewpoint, PET is in the second rank among synthetic polymers equally with polypropylene. This is due to its
excellent balance of properties such as impact strength, resistance to creep under pressure, low permeability
to carbon dioxide, high melting point, thermal and hydrolytic stability.
5
Chapter 1 Introduction
6
Chapter 1 Introduction
1.9. Uses of PET Polyester
1.9.1. Uses of Polyester for Apparel Purposes
Continuous polyester filament by virtue of its strength and dimensional stability has been widely used
in fine and delicate dress material, nets and tires, but its great success has been in blends with some of the
natural fibers in its staple form. In blends with cotton it has been popular for shirts which need little ironing.
Polyester is frequently claimed for light garments, e.g. blouses and lingerie made from synthetic fibers that
need no ironing. In the staple form polyester has been used for socks, which are fairly comfortable.
Fishing nets of polyester fibers are used for fishing trawlers, due to their extremely low water
absorption and they are extremely high at the high time of haulage from the sea and also allowed to be rapidly
dried.
7
Chapter 1 Introduction
1.9.2.5. Dryer Canvases
Dryer canvases for paper manufacture are subjected to the most severe conditions found in textile
usage. Polyester fiber exhibits most excellent results because of characteristics such as, considerable wet
strength and resistance to abrasions on wetting, low wet elongation, low absorption of water and rapid drying,
resistance to heat, and high dimensional stability.
1.9.2.6. Hoses
Polyester fiber possesses outstanding qualities for fire and industrial hoses as it is endowed with the
following properties required for fibers in use for hoses:
Curtains in polyester net are popular, and because there resistance behind glass to sunlight is good
and because polyester can be died fast they usually have a long life.
8
Chapter 1 Introduction
It is frequently claimed for light garments e.g. blouse and lingeries made from synthetic fibers that
need no ironing. This may be true if they are washed very carefully, so threat no compression is applied whilst
wet and crumpling, there are no sharp creases but nevertheless, such garments those made from polyester
can be washed almost indefinitely, blouses which drape like heavy silk but can be washed like cotton are made
from polyester, whereas nylon is subjected to disadvantage that after long wear it grey. Polyester does not
suffer from this defect, so that the useful life of polyester garments would not be cut short.
The general methods for the conversion of organic polymers to fibers are known as spinning technology.
1.10.1. Spinning
The term spinning means any process that produces continuous filaments, yarns or threads. Spinning
turns short staple fibers such as cotton or wool and relatively short filaments or fiber strands such as flax,
ramie, jute, sisal etc. into continuous yarns. The mass of fibers or fiber strands is parallelized by carding and
combing processes into silvers and roving from they are appropriately picked up in the spinning frame in well-
designed clusters under controlled speed and then twisted together so that the fibers duly grip one another
to produce what known as spun yarn.
1. Melting
2. Dissolution in a suitable solvent medium, is extruded or spun out through the fine holes of a spinneret
as fine continuous filaments.
The extruded melt/solution jets or filaments of any length are suitably hardened by following
processes
1. Cooling and drawing (melt spinning)
2. Solvent evaporation (dry-spinning) in a hot chamber in some cases.
3. Polymer coagulation or regeneration in a non-solvent medium contained in an open trough or vessel
(wet spinning).
A drawing process subsequent or even simultaneous to spinning is commonly followed in each case.
Continuous fine filaments spun and axially oriented in this way, and crimped if desired, may be cut into
fiber clusters of convenient short staple lengths. These may then be further spun into yarns applying
appropriate drawing and twists in much the same way as for cotton and other staple fibers.
The essential step of any spinning technique is the transformation of a solid polymer into a liquid state
so that it may be extruded through fine holes and the emergent jets then returned without loss of form
to a coherent solid state. A practical spinning technology and machine must be sufficiently flexible in
operation to allow the efficient and economic production of a wide range of yarns of high quality and
uniformity. By a wide range of yarns is meant a variety of filament numbers, diameters and physical
properties from one given polymer type.
9
Chapter 1 Introduction
1.11. Types of Spinning
There are two types of spinning processes:
1. Melt spinning
2. Dry spinning
The processing equipment for continuous filament yarn and staple fiber is very similar of converting
chips into fibers.
In the melt head of spinning units dried polymer chips are gravity fed from a storage hopper and are
melted in an oxygen free atmosphere against a heated plate or grid. A gear type of pump is used to control
the flow of molten polymer and the polymer is filtered before being extruded through a spinneret in to air at
room temperature. In the continuous filament yarn process, the multifilament thread line is converged several
feed below the spinneret and passed over slowly rotating spin finish wheel, which applies oil in water emulsion
in order to lubricate the yarn and reduce static. The yarn is collected finally on a spill bobbin, which is surface
driven at a constant speed of several thousand feet per minute.
Yarns from several spinnerets are converted into one large and wound up at constant speed on
aluminium cans.
During the spinning process, polyethylene terephthalate are quenched rapidly below tile glass rubber
temperature (80oC) and spun yarn is completely amorphous. In the solid state, polyethylene terephthalate can
be amorphous or process various degrees of crystallinity depending on its thermal and mechanical condition
and density of material can be used as a measure of its crystallinity.
Synthetic fiber derive their strength and flexibility largely from the presence of oriented polymer chain
units locked in position chemical cross-links, but no crystallization or orientation processes are possible below
80oC, its glass rubber transition temperature. Below this temperature the amorphous regions are locked by a
glass like structure and unable to yield to applied stress, but above 80oC, certain molecular segments possess
sufficient thermal energy to revolve so that under applied stress the polymer molecules will be able to wriggle
past each other, become oriented and crystallized.
10
Chapter 1 Introduction
1.11.1.2. Drawing Process
Upon extrusion from the spinneret the PET filament does not have all the desired characteristics
because of the random arrangement of the super polymer molecules. The fibers are therefore drawn or
elongated.
The temperature conditions and the extent to which the fibers are drawn depend upon the properties
desired, the pet fibers are usually drawn to 5 times their original length (which results in a fiber diameter that
is one fifth the original size upon extrusion from the spinneret) of higher tenacity fiber is to be produced, the
filaments are drawn to a greater extent, as this increases the linear molecular orientation of the fiber, as they
emerge from the drawing process and meet cold air, the filaments solidify generally, the PET polyester
filaments are drawn hot because this procedure produces more uniform fibers.
Below the glass-rubber transition temperature of 80oC, the tensions required to draw spun filaments
of polyethylene terephthalate are likely to break them or at least produce voids in the filaments. Temperature
well above 80oC the material is rubber like and draws in spinning stretch. A pin is used rather than a plate,
because the drawing zone and ensure that the spin yarn is subjected to low feed tension. Drawing machine
may consist essentially of a feed roll, a hot pin, a draw roll and a standard ring and traveler wound up system.
The drawn yarn is called finally on drawn crystal bobbins and has about one turn per inch of twist in either s
or z series. Staple fiber drawing machine is designed on a similar principle to that used for filament but is of
much heavy construction and capable of dealing yarn tows of the order of several hundred thousand deniers.
After leaving tile staple fiber drawing machine, the drawn tow is feed into a crimping device. The
drawn crimpled tow is then heat set and cut into suitable staple fiber lengths by rotary cutter before passing
through an opening device which separates tile fibers and sprays them with textile dressing or finish. Bailing,
packing and labeling constitute the final stages of the staple fiber manufacturing process.
References:
1. Menachem Lewin and Eli. Pearce, Handbook of Fiber Chemistry, Second Edition, 1998, Marcel
Dekker, Inc.
3. Arun Pal Aneja, Polyethylene Terephthalate Feedstock Selection and Process Options, Chemical Age
of India, 29(9), 1978.
11
Chapter 2
Process Selection
Chapter 2 Process Selection
1. Esterification
2. Polycondensation
In the first step, esterification of acid and alcohol undergoes producing an intermediate (bis-
hydroxyethylene terephthalate, (BHET) as the main monomer for Polycondensation. Regarding a reversible
reaction, the side product is extracted in order to perform reaction up to high conversions. In the second step
that is called as polycondensation oligomers and polymer chains undergo reaction to produce long polymer.
The by-product of polycondensation is removed in order to increase the rate of polycondensation and chain
length.
1. Batch Process
2. Continuous Process
12
Chapter 2 Process Selection
2.2.1.1. Solid Phase Polymerization (SPP)
Continuous polymerization units of either type are quite satisfactory for fibers, films or cast objects of
relatively modest molecular weight (0.6 intrinsic viscosity) produced on large continuously operating
equipment. When high molecular weight polymer of high purity is required, however, particularly for a
discontinuous operation, solid phase polymerization can be attractive.
In this process, chips, usually from a conventional finisher, are pre-crystallized in a tumble drier at 140-
150oC, the temperature is then raised, and polymerization is carried out under high vacuum or inert gas sweep.
Although solid state diffusion is slower than diffusion through a liquid, the distance involved are much shorter
so the overall effect is to raise molecular weight quickly. Since the reaction temperature is below the molecular
weight quickly. Since the reaction temperature is below the softening point, the chips do not sinter together
and the lower reaction temperature disfavors the degradation reaction.
All melt polymerizations reach an equilibrium stage where the chain-forming and chain breaking
reactions balance each other and no net chain growth occurs. Solid-sate polymerization works because it
allows chain-growth to proceed while minimizing chain-breaking, owing to the different kinetics and activation
energies of the two different sets of reactions. Usually melt-polymerized PET has an intrinsic viscosity (IV) of
about 0.67. It is quite possible by using the SPP process to raise the IV to 0.8-1.10.
13
Chapter 2 Process Selection
Table 2-1: Comparison between Batch and Continuous Process for PET Production
Polymerization and spinning units operate Polymerization and spinning units operate
independently. continuously.
As starting materials, it was because of the non-availability of terephthalic acid of sufficient purity in
the early years of the polyester production. This reason behind this was that TPA was a rather intractable
substance and is sparingly soluble in most solvents, and sublimes without melting at about 300oC. It was
therefore difficult to purify and polymerize.
14
Chapter 2 Process Selection
2.6. Transesterification Process
This polymerization process was based upon an ester-interchange (EI) reaction between DMT and EG.
In the ester-interchange process, DMT and an excess of glycol are heated together in the presence of various
EI catalysts. Manganese (II) acetate or zinc (II) acetate is typically used for this transesterification step, these
being the best catalysts for this reaction.
The methyl ester group undergoes an exchange reaction with the glycol hydroxyl groups and the much
more volatile methanol distills out, via a fractionating column, thus upsetting the equilibrium, and driving the
reaction to completion. The product is a mixture of BHET and low molecular weight oligomers.
In the second step, the DGT is heated to about 280oC under high vacuum to carry out melt phase
polycondensation. The principle volatile eliminated is EG.
For the second step in the DMT route, the catalyst from the first step (zing or manganese) is
sequestered or deactivated with phosphoric acid and another catalyst for polycondensation, most commonly
antimony triacetate or antimony trioxide is added. This is because zinc and manganese are considered poor
polycondensation catalysts. The literature indicates that the reactivity of metals for the polycondensation
reaction (second step) follows the trend Ti>Sn>Sb>Ge>Mn>Zn. Moreover, for the first step, namely the
transesterification of DMT with EG, the catalytic activity trend follows the reverse order, with zinc being
amongst the most active. For the polycondensation reaction, Sb compounds are commercially established
(compared with Sn and Ti) because the resulting polymer has the most favorable balance of properties. Note,
in a usual operation, it is possible to go from step 1 to step 2 without isolating the DGE. However, if desired,
the DGT and oligomers formed in step 1 can be isolated and used later for melt polycondensation (step 2).
1. When EG is treated with DMT, methanol is produced as by-product. By means of distillation the by-
product is separated but on the other hand, TPA route does not give any by-product which is to be
distilled of. The capacity of the plant increases in TPA route.
2. Because methanol is eliminated from the process system, polymerization rates tend to be higher and
polymer quality is improved.
3. TPA gives about 15% higher yield of polyester as compared with DMT due to difference in molecular
weights.
4. TPA gives higher production due to faster rate of esterification, reduced glycol to be taken off in
polycondensation and reduced raw material weight to produce ratio.
5. The capital investment to construct a polyester fiber plant based on TPA is at least 20% less than one
based on DMT.
6. TPA process needs less EG as compared with DMT. Thus less EG is to be recovered during
polycondensation resulting in lower investment for EG recovery and recycle system. This in turn
promote energy conservation.
15
Chapter 2 Process Selection
7. TPA has high bulk density than DMT and hence requires less storage as compared with DMT.
8. TPA process is safe as methanol is not evolved during esterification while in DMT process methanol is
produced as by-product. Methanol is highly inflammable and can cause explosion, so the system must
have explosion proof equipment which add to capital cost in DMT process.
9. Catalyst is used either in very small quantity or not used in TPA esterification. This gives better color
of the polymer, higher spin pack life in spinning and lower breakages in stretching.
10. The time to reach a given molecular weight is less with TPA than with its dimethyl ester.
16
Chapter 3
Process Description
Chapter 3 Selected Process Description
TPA is used instead of DMT and so it is called the TPA process. Because methanol is eliminated from
the process system, polymerization rates tend to be higher and polymer quality is improved. Also the metal
content of the TPA polymer is less than the DMT polymer, as only one catalyst (for polycondensation) is used
for step 2, and hence the thermal stability of the polymer is higher.
The TPA route to PET is made up of two steps. The first is the esterification of terephthalic acid with
ethylene glycol (EG) to convert to pre-polymer that contains Bis-hydroxyethyl terephthalate (BHET) and short
chain oligomers.
The esterification is not complete, and some acid end-groups remain in the pre-polymer. The
esterification by-product water is removed via a column system.
The second reaction step is polycondensation, in which mainly the following transesterification
reaction, lead to step-growth polymerization in the melt phase.
The reversible nature of the reactions demand that the condensates ethylene glycol (EG) and water
are removed from the melt efficiently by using high vacuum.
3.2. Reactions
In the early stages of the process, esterification reactions are dominant. These reactions are reversible
with equilibrium constants close to unity. Polymerization reactions involve the nucleophilic attack of the
terminal ester group. In one chain by the terminal alcohol group of a second chain. These reactions lead to
rapid molecular growth. The polymerization reactions are also reversible, with the equilibrium constant
slightly below unity.
Rearrangement reactions involve ester groups inside the chain. These reactions are responsible for
randomizing the molecular weight distribution and redistributing segments inside the polymer chain. Since
the number of internal ester group is much higher than the number of terminal ester groups, the molecular
weight distribution approaches the most probable distribution.
Which is then hydrolyzed with lime slurry or with sodium hydroxide solution to 1,2-epoxyethane
(ethylene oxide).
A more modern process oxidizes ethane directly to 1,2-epoxyethane using air and a silver catalyst at
250-325oC and 1-3 MPa. Direct oxidation avoids the use of chlorine (which is converted to a by-product
without value, but is complex with an expensive catalyst, and needs careful control-some of ethane is oxidized
through to carbon dioxide.
16
Chapter 3 Selected Process Description
The epoxy-ethane is converted to the diol by reaction with water at about 180oC. A specification sheet
of properties of ethylene glycol (EG) is given in Table 3-1
Fractional distillation of the mixed aromatics gives a xylene fraction which typically, is composed of:
The boiling points are too closed together for economic separation by fractional distillation, but the
higher melting 1,4-dimethylbenzene can be separated by crystallization from the cooled liquid. Several stages
are needed to obtain the maximum yield of the isomer at better than 98% purity. The proportion 1,4-
dimethylbenzene in the xylene fraction is improved by isomerizing the ortho and meta isomers over metal
oxide catalysts, and the aromatization and isomerization stages can be combined.
There are several processes for the oxidation of 1,4-dimethylbenzede to acid. This route uses nitric
acid as oxidizing agent about 30% acid at 180oC or so. The product is contaminated with some nitro-substituted
acids.
Liquid phase catalytic air oxidation processes have been devised, and are now widely used. Cobalt
salts, or manganese salts activated by bromine, are employed as catalysts in acetic acid solution. Oxidation of
the first methyl group to carboxylic acid is easier than oxidation of the second, hence 4-methylbenzene
carboxylic acid (p-toluic acid) is the main impurity. Physical properties of terepthalic are given in Table 3-2
17
Chapter 3 Selected Process Description
Catalyst (Antimony triacetate) which is also in powder form is dissolved in EG in the mixing tank and
big particles are separated by the filter and the catalyst solution is stored in the storage tank.
18
Chapter 3 Selected Process Description
3.4.5. Esterification Stage
A positive displacement pump leads the slurry with additives to the esterification stage, which consist
of two reactors arranged in series. In this esterification stage, TPA and EG react and get converted into BHET.
The reaction is typically un-catalyzed and form low molecular weight oligomers and water. Both the
esterification reactors are single vessels with turbine agitators (paddle type) having four baffles and inner coils.
In each of them reaction pressure is at 2-4 psig. This type of reactor has the advantage that heat transfer can
take place at relatively low temperature of heating surface due to high heat exchanger areas.
Thus the amount of unwanted diethylene glycol (DEG) formed is less and the negative influence of this
product on final product is low. The direct esterification is continued until the required degree of conversion
in the second stage is achieved. One thing which is worth mentioning here is that since esterification is
occurring from the beginning to the end of PET synthesis, it is an equilibrium reaction and thus removal of the
condensed water is necessary to minimize the hydrolysis of the formed ester group. After the required
retention the mixture is transferred from the first esterifier to the 2nd esterifier by the pump.
3.4.5.2. EG Recovery
Recovery and recycle of EG is important. The efficient recycling is realized by feeding the vapors to a
condenser, which condenses a solid glycol-oligomer solution for recycle. This solution is the introduced in a
distillation column to separate the reaction by produced (H2O) from EG.
3.4.5.3. Reactions
The reaction conditions in the Esterifier are given in Table 3-3.
Table 3-3: Reactor Conditions during Esterification Reaction
3.4.5.4.1. Temperature
Higher temperatures are needed for esterification, usually in the range of 240-260oC. This is because
at lower temperature the rate of reaction (or reactor performance) is limited by the low solubility of PTA in
EG and also PTA does not melt even at 225oC. Also like most of the other reactions the speed of esterification
approximately doubles with a 10oC rise in temperature.
However, the use of a large excess also entails disadvantages, e.g. prolonging the total reaction time,
due to the necessity to distill off the excess of glycol and formation of higher amount of EG. Industrially,
19
Chapter 3 Selected Process Description
however, the employment of a small excess has generally given satisfactory results so that the reaction is
performed, e.g. with about one half molar excess of glycol.
In our esterifier retention time is four hours because, selecting that retention time the influences of temporary
disturbances of the process (e.g. power failures etc.) on the uniformity of the final product is minimized due
to the presence of large amounts of product in the apparatus. The influence of harmful side reactions is also
minimized.
3.4.6. Polycondensation
Polycondensation is carried out in three stage continuous polycondensation apparatus. In this step
polycondensation of BHET to PET occurs with the removal of EG as by-product. The reversible nature of the
reaction demands that the condensates ethylene glycol (EG) and water are removed from the melt efficiently
to assure rapid polymerization. This is done by carrying out polymerization under high vacuum. The degree of
vacuum in the reactors increases towards downstream so the vacuum degree of each reactor is moderate for
the degree of polymerization.
The first polycondensation reactor (low polymerizer) and the second polycondensation (intermediate
polymerizer) reactors are a series of stirred tank reactors with turbine type impellers (pitched blade). Because
in these two reactors, the melt viscosity remains relatively low, the EG and water condensation products
formed during the process can evaporate efficiently.
When the molecular weight increases further, the melt viscosity of PET becomes so high that bubble
formation is hindered even under applied vacuum, and EG and water have to diffuse out. Hence it is critical to
reduce the diffusion path at the following reaction stage in order to improve removal of EG and water.
Therefore to provide for the efficient removal of ethylene glycol, the polymerization should be carried out in
a vessel which provides for the maximum area generation and having an agitator that should provide for the
maximum exposure of the reaction mass to the effects of vacuum. These purposes are achieved in the third
polymerizer (high polymerizer) which is a wiped film or a disc reactor. The disc reactor consists of a heated
horizontal cylinder, which contains a number of discs in slanting positions. The discs are arranged in the form
of a cage without a continuous shaft, so that they are immersed in the material being poly-condensed and
transport the material slowly through the apparatus. A part of the material which is retained on the disk is
transported upwards from the sump and slides back again in the form of a thin film. The large surface area so
formed allows a quick removal of mono-ethylene glycol from the poly-condensing material.
The pressure differences and gravity causes the transport of poly-condensation material between the
three polycondensation stages. Polyester from the last polycondensation stage is either directly spun into
fibers, or extruded into 2-4mm thick strands that solidify due to the cooling and are cut into somewhat
cylindrical chips for future processing.
3.4.6.1. Reactions
The reactor conditions in ES-2 are given in Table 3-4
Table 3-4: Reactor Conditions during Esterification Reaction
20
Chapter 3 Selected Process Description
3.4.6.2. Reaction Parameters
3.4.6.2.1. Effect of Temperature
Degree of polymerization increases considerably when the temperature is raised from 265oC to 285oC.
The reaction speed is also increased by increasing the temperature. Raising temperature above 285oC exerts
a slight influence on the reaction speed and in general does not have a favorable effect on the characteristics
of the polycondensate. The thermal degradation of the polymer also increases with increase in temperature
from 285oC to 300oC.
Temperature below 260oC is also not used as the melting point of polyethylene terephthalate is about
260oC and hence some solidification of the polymer may occur at low temperature.
3.4.6.2.4. Catalyst
For better rate of reaction, increase in temperature alone does not help much as at higher temperature the
reactor performance is limited by the solid-liquid mass transfer rate i.e. the upper limit of temperature is
correlated with the boiling point of either alcohol or acid or the ester formed. Thus upper limit of temperature
will be governed by the most volatile component. It is therefore necessary that esterification reaction is carried
out in the presence of some suitable catalyst.
The traditional polymerization catalysts used in the formation of PET is antimony which has the best all-round
properties amongst PET catalysts during melt polymerization, leading to high productivity and polymers with
good thermal stability. The most common of the antimony-containing catalysts are antimony trioxide,
antimony triacetate which are added at the start of the polycondensation.
21
Chapter 4
Material Balance
Chapter 4 Material Balance
The material balance is a very important stage in the plant design process and is applied in order to
determine the total mass entering and leaving the system (in our case, the polyester plant) as a whole as well
as the mass entering and leaving each component of the system separately. This is done in order to determent
the number as well as size of the equipment to be used and also for determining the energy requirements for
the whole process. Also it is an important need for better control of the process.
4.1. Nomenclature
The nomenclature of the terms used are given below:
4.2. Reactions:
The reactions involved in the process are mentioned below:
17
Chapter 4 Material Balance
4.4. Overall Material Balance
= 19936.8 kg/
19936.8
1 kg of PET Requires TPA = 23102.07
= 0.8630
= 3595.782 kg.
= 14896.8 kg
14896.8
1 kg of PET requires EG = = 0.645 kg
23102.07
= 2686.772 kg
EG Required = 2686.772 kg
EG Entering = 2955.45 kg
EG recovered = 1613.31 kg
= 1342.1412 kg
18
Chapter 4 Material Balance
4.5. Nomenclature of Streams
M1 = Mass flow rate of TPA in kg/hr.
M2 = Mass flow rate of EG in kg/hr.
M3 = Mass flow rate of slurry (TPA + EG + Water) in kg/hr.
M4 = Mass flow rate of (EG + H2O) regenerated during reaction in Esterification Reactor-1 (ES-1)
in kg/hr.
M5 = Mass flow rate of BHET (monomer) + unreacted TPA + Unreacted EG + Water
M6 = Mass flow rate of (EG + H2O) regenerated during reaction in Esterification Reacton-2 (ES-2)
in kg/hr.
M7 = Mass flow rate of TPA (unreacted) + BHET in kg/hr. + Unreacted EG + Water
M8 = Mass flow rate of (EG + H2O) regenerated during reaction in Polycondensation Reactor-1
(PR-1) in kg/hr.
M9 = Mass flow rate of polymer formed in PR-1 in kg/hr.
M10 = Mass flow rate of (EG + H2O) regenerated in Polycondensation Reactor 2 (PR-2) in kg/hr.
M11 = Mass flow rate of polymer formed in PR-2 in kg/hr.
M12 = Mass flow rate of (EG + H2O) regenerated during polycondensation reaction in
Polycondensation Reactor-3 (PR-3) in kg/hr.
M13 = Mass flow rate of final product (PET) in kg/hr.
M14 = Mass flow rate of (EG + H2O) from distillation column in kg/hr.
M15 = Mass flow rate of 95% pure EG from distillation tower in kg/hr.
19
Chapter 4 Material Balance
15 = Weight fraction of EG in M15
Total Balance
M1 + M2 + M15 = M3
M3 = 6636.142 kg/hr.
EG Balance
M2 + M15 = M3 wEG
wEG = 0.445
Similarly,
TPA Balance
wTPA = 0.542
Water Balance
wwater = 0.013
Hence,
20
Chapter 4 Material Balance
4.6.2. Esterification Section
In the esterification section, EG and TPA react to form BHET and water. The water produced and some
mass of EG is vaporized due to high temperature maintained in the reactor. The vaporized products are taken
out of the reactor separately while the reaction mixture is sent to the next reactor for further conversion
Where,
M4 = Mass flow rate of (EG + H2O) generated during reaction in Esterification Reactor (ES-1)
5 = Weight fraction of EG in M5
Total Balance
M3 = M4 + M5
6636.142 kg/hr. = M4 + M5
21
Chapter 4 Material Balance
TPA Balance
For 95% Conversion:
= 3595.782 kg/hr.
= 3415.99 kg/hr.
3415.99
Moles of TPA reacted = 166.14
= 20.561 kmoles/hr.
= 179.79 kg/hr.
EG Balance
Mass of EG entering the reactor ES-1 = 0.445 6636.142
= 2955.449 kg/hr.
= 2 20.561
= 41.122 kmoles/hr.
= 41.122 62.07
= 2552.434 kg/hr.
= 403.016 kg/hr.
= 6.493 kmoles/hr.
22
Chapter 4 Material Balance
BHET Balance
Moles of BHET produced in reactor = Moles of TPA Reacted
= 20.561 kmoles/hr.
= 20.561 254.24
= 5227.41 kg/hr.
Water Balance
Mass of Water entering the reactor ES-1 = 0.012 6636.142
= 84.91 kg/hr.
= 2 20.561
= 41.122 kmoles/hr.
= 41.122 18
= 740.193 kg/hr.
= 825.104 kg/hr.
= 45.84 kmoles/hr.
Composition of Streams
Assuming that 60% of unreacted MEG and 70% of water generated in the esterification reactor is obtained in
the vaporized form. Thus,
= 577.573 kg/hr.
= 241.81 kg/hr.
M4 = 577.573 + 241.81
= 819.38 kg/hr.
241.81
wEG4 = 819.38
= 0.295
577.573
wwater4 =
819.38
= 0.705
Also, For M5
= 247.531 kg/hr.
= 161.206 kg/hr.
24
Chapter 4 Material Balance
Hence,
= 5815.937 kg/hr.
5227.41
wBHET = 5815.937
= 0.90
179.79
wTPA = = 0.030
5815.937
161.206
wEG = 5815.937
= 0.028
247.531
wwater = = 0.042
5815.937
Hence,
25
Chapter 4 Material Balance
4.6.2.2. Esterification Reactor 2 (ES-2)
Where,
M5 = Mass flow rate of BHET + Unreacted TPA + Unreacted MEG + Water entering the reactor.
M6 = Mass flow rate of (EG + H2O) generated during reaction in Esterification Reactor (ES-2)
M7 = Mass flow rate of BHET + Unreacted EG + Unreacted EG + Water Leaving the reactor ES-2
= Weight fraction of EG in M7
Total Balance
M5 = M6 + M7
5815.937 kg/hr. = M4 + M5
26
Chapter 4 Material Balance
TPA Balance
For 95% Conversion:
= 179.79 kg/hr.
= 170.80 kg/hr.
170.80
Moles of TPA reacted =
166.14
= 1.03 kmoles/hr.
= 8.989 kg/hr.
EG Balance
Mass of EG entering the reactor ES-1 = 0.028 5815.937
= 161.21 kg/hr.
= 2 1.03
= 2.06 kmoles/hr.
= 2.06 62.07
= 127.62 kg/hr.
= 33.585 kg/hr.
= 0.541 kmoles/hr.
27
Chapter 4 Material Balance
BHET Balance
Mass of Water entering the reactor ES-2 = 0.90 5815.937
= 5227.41 kg/hr.
= 1.03 kmoles/hr.
= 1.03 254.24
= 261.37 kg/hr.
= 5488.781 kg/hr.
Water Balance
Mass of Water entering the reactor ES-2 = 0.042 5815.937
= 247.5313 kg/hr.
= 2 1.03
= 2.06 kmoles/hr.
= 2.06 18
= 37 kg/hr.
= 284.541 kg/hr.
= 15.81 kmoles/hr.
Composition of Streams
Assuming that 60% of unreacted MEG and 70% of water generated in the esterification reactor is obtained in
the vaporized form. Thus,
= 199.179 kg/hr.
28
Chapter 4 Material Balance
Moles of water removed as vapors = 11.065 kmoles/hr.
= 20.15 kg/hr.
Therefore,
M6 = 199.179 + 20.15
= 219.33 kg/hr.
199.179
wwater6 =
219.33
= 0.908
20.15
wEG6 =
219.33
= 0.092
Also, For M7
= 85.36 kg/hr.
= 13.43 kg/hr.
29
Chapter 4 Material Balance
Hence,
= 5596.566 kg/hr.
5488.781
wBHET = 5596.566
= 0.981
8.989
wTPA = = 0.0016
5596.566
13.43
wEG = 5596.566
= 0.0024
85.36
wwater = = 0.015
5596.566
Hence,
30
Chapter 4 Material Balance
4.6.3. Polycondensation Reactors
In the polycondensation reactors, polymerization begins. BHET acting as monomer form long chains
by connecting with other monomer molecules. Ethylene glycol (EG) is produced as a by-product and is
removed continuously in order to push the reaction in the forward direction.
Where,
M7 = Mass flow rate of BHET + Unreacted TPA + Unreacted MEG + Water entering the reactor.
M8 = Mass flow rate of (EG + H2O) generated during reaction in Polycondensation Reactor (PR-1)
M9 = Mass flow rate of PET + Unreacted EG + Unreacted EG + Water Leaving the reactor PR-1
= Weight fraction of EG in M7
Total Balance
M7 = M8 + M9
5596.566 kg/hr. = M7 + M9
31
Chapter 4 Material Balance
TPA Balance
Mass of TPA entering the reactor PR-1 = 0.0016 5596.566
= 8.989 kg/hr.
BHET Balance
Mass of BHET entering the reactor PR-1 = 5488.781 kg/hr
It is assumed that all of BHET starts converting into polymer hence no BHET is obtained at the outlet of the
reactor.
PET Balance
Degree of Polymerization achieved in the reactor PR-1 = 30
Moles of PET Produced in the reactor PR-1 =
= 21.589/30
= 0.7196 kmoles/hr.
= 5827.17 kmoles/kg
= 0.7196 5827.17
= 4193.421 kg/hr.
EG Balance
Mass of EG entering the reactor PR-1 = 13.434 kg/hr.
32
Chapter 4 Material Balance
Moles of EG entering the reactor PR-1 = 0.216 kmoles/hr.
1
Moles of EG produced in the reactor =
301
= 21.589 = 20.8694 kmoles/hr.
30
= 1295.364 kg/hr.
= 1308.798 kg/hr.
Water Balance
Mass of water entering reactor PR-1 = 85.362 kg/hr.
Composition of Streams
Assuming that 95% of unreacted MEG and 80% of water in the polymerization reactor is obtained in the
vaporized form. Thus,
= 68.290 kg/hr.
= 1243.354 kg/hr.
Therefore,
M8 = 68.290 + 1243.354
= 1311.644 kg/hr.
68.290
wwater8 = 1311.644
= 0.052
1243.354
wEG8 = 1311.644
= 0.948
Also, For M9
33
Chapter 4 Material Balance
Mass of unreacted PTA leaving the reactor = 8.989 kg/hr.
= 17.072 kg/hr.
= 65.44 kg/hr.
34
Chapter 4 Material Balance
Hence,
= 4284.922 kg/hr.
4284.922
wPET = 4284.922
= 0.979
8.989
wTPA = 4284.922
= 0.0021
65.44
wEG = 4284.922
= 0.015
17.072
wwater = 4284.922
= 0.0040
Hence,
35
Chapter 4 Material Balance
4.1.1.1. Polymerization Reactor 2 (PR-2)
Where,
M9 = Mass flow rate of PET + Unreacted TPA + Unreacted MEG + Water entering the reactor.
M10 = Mass flow rate of (EG + H2O) generated during reaction in Polycondensation Reactor (PR-2)
M11 = Mass flow rate of PET + Unreacted EG + Unreacted EG + Water Leaving the reactor PR-2
Total Balance
M9 = M10 + M11
36
Chapter 4 Material Balance
TPA Balance
Mass of TPA entering the reactor PR-2 = 0.0016 5596.566
= 8.989 kg/hr.
Water Balance
Mass of water entering reactor PR-2 = 17.072 kg/hr.
PET Balance
Mass of PET30 entering the reactor = 4192.421 kg/hr
= 0.2399 kmoles/hr.
= 17357.37 kmoles/kg
= 0.2399 17357.37
= 4163.642 kg/hr.
EG Balance
Mass of EG entering the reactor PR-2 = 65.4397 kg/hr.
37
Chapter 4 Material Balance
Moles of EG produced in the reactor =
entering
9030
= 90
0.7196
= 0.4798 kmoles/hr.
= 29.7784 kg/hr.
= 95.218 kg/hr.
Composition of Streams
Assuming that 95% of unreacted MEG and 80% of water in the polymerization reactor is obtained in the
vaporized form. Thus,
= 13.658 kg/hr.
= 90.46 kg/hr.
Therefore,
= 104.12 kg/hr.
13.658
wwater10 = 104.12
= 0.131
90.46
wEG10 =
104.12
= 0.869
= 4.761 kg/hr.
Hence,
= 4180.807 kg/hr.
4162.642
wPET = 4180.807
= 0.996
8.989
wTPA = 4180.807
= 0.0022
4.761
wEG = 4180.807
= 0.00114
3.414
wwater = 4180.807
= 0.0008
Here,
39
Chapter 4 Material Balance
4.1.1.2. Polycondensation Reactor 3 (PR-3)
Where,
M11 = Mass flow rate of PET + Unreacted TPA + Unreacted MEG + Water entering the reactor.
M12 = Mass flow rate of (EG + H2O) generated during reaction in Polycondensation Reactor (PR-3)
M13 = Mass flow rate of PET + Unreacted EG + Unreacted EG + Water Leaving the reactor PR-3
Total Balance
M11 = M12 + M13
40
Chapter 4 Material Balance
TPA Balance
Mass of TPA entering the reactor PR-3 = 0.0016 5596.566
= 8.989 kg/hr.
Water Balance
Mass of water entering reactor PR-3 = 3.414 kg/hr.
EG Balance
Mass of EG entering the reactor PR-3 = 4.761 kg/hr.
12090
= 120
0.2399
= 0.05997 kmoles/hr.
= 3.722 kg/hr.
= 8.483 kg/hr.
PET Balance
Mass of PET90 entering the reactor = 4163.642 kg/hr
= 0.1799 kmoles/hr.
41
Chapter 4 Material Balance
= 23122.47 kmoles/kg
= 0.1799 23122.47
= 4159.92 kg/hr.
Composition of Streams
Assuming that 95% of unreacted MEG and 80% of water in the polycondensation reactor is obtained in the
vaporized form. Thus,
= 2.732 kg/hr.
= 8.059 kg/hr.
Therefore,
= 10.791 kg/hr.
2.732
wwater12 = 10.791
= 0.253
8.059
wEG12 =
10.791
= 0.747
= 0.683 kg/hr.
42
Chapter 4 Material Balance
Moles of water leaving with reaction mixture = 0.0379 kmoles/hr.
= 0.424 kg/hr.
Hence,
= 4170.017 kg/hr.
4159.92
wPET = 4170.017
= 0.998
8.989
wTPA = = 0.0021
4170.017
0.424
wEG = 4170.017
= 0.0001
0.683
wwater = = 0.0002
4170.017
43
Chapter 5
Energy Balance
Chapter 5 Energy Balance
Q2
(2)
(1)
BHET
PTA Esterification Reactor 1 PTA
Q1 MEG Q4
(245C) MEG
Water
Water
(45C)
(245C)
(3)
Water
MEG
(245C)
Q3
Figure 1: Block Diagram Presenting the Overall Heat Inputs and Outputs in Esterification Reactor-1 (ES-1)
Where,
Q2 = Heat required to raise the temperature of reactants up to the required conditions and the heat of
reaction.
Q3 = Heat content of water and mono-ethylene glycol mixture leaving the reactor.
Q4 = Heat going out with the product and the unreacted reactants.
5.1.1. Description
An inlet stream comprising of a mixture of mono-ethylene glycol (MEG), purified terepthalic acid
(PTA), and water enters the water at a temperature of 47oC. The temperature of the reactants (MEG & PTA) is
raised to 245oC. At this temperature they react to form Bis-hydroxy ethylene terephthalate. The reaction is
endothermic therefore requires heat input in the reactor.
{ }={ }{ }
44
Chapter 5 Energy Balance
The heats of formation of reactants and the heat of formation of products are presented in Table 5-1.
Table 5-1: Heat of formation of reactants and products.
{ } = {(261.80) + 2(57.79)} {(195.02) + 2(92.97)} = +. /
{ } = + /
Table 5-2: Thermal properties of streams entering and leaving the esterification reactor.
45
Chapter 5 Energy Balance
5.1.3.1. Water
The heat required to raise the temperature of water present in feed stream 1 from 45oC to 245oC can be
calculated as follows:
106.9 245
= (45 1 + 106.9 2 ) +
Where,
= Heat required per unit time to raise the temperature of water in the stream from 45oC to 245oC.
= A total of mass feed rate of water entering the reactor and the mass of water produced in unit time as
result of chemical reaction.
Taking average specific heat capacities at given temperatures and bringing them out from integration term
as constants.
106.9 245
= (18.0313 45 + 8.18 106.9 ) +
= 10593.417 + 441086.25
= . /
Here,
= Heat required per unit time to raise the temperature of PTA in the stream from 45oC to 245oC.
46
Chapter 5 Energy Balance
Where,
= Heat required per unit time to raise the temperature of MEG in the stream from 45oC to 245oC.
= Latent heat of vaporization of MEG at 4 psig and 205.32oC estimated to be 12534.52 kcal/kmole.
Taking average specific heat capacities at given temperatures and bringing them out from integration term
as constants.
205.32 245
= (43.02 45 + 26.17 205.32 + )
= . /
= (3540) (20.561)
= 72785.94 /
= . /
47
Chapter 5 Energy Balance
Q2
(2) (5)
BHET BHET
PTA Esterification Reactor 2 PTA
Q1 Q4
MEG (255C) MEG
Water Water
(245C) (255C)
(4)
Water
MEG
(255C)
Q3
Figure 2: Block Diagram Presenting the Overall Heat Inputs and Outputs in Esterification Reactor-2 (ES-2)
5.2.1. Description
The outlet stream from esterification reactor 1 (ES-1) containing Bis-hydroxy ethylene terephthalate
(BHET), mono-ethylene glycol (MEG), purified terephthalic acid (PTA) enters the esterification reactor-2 (ES-2)
where its temperature is increased to 255 and the pressure is reduced to 2 psig. Further conversion of PTA
and MEG into BHET takes place in the reactor. The reaction being endothermic requires heat input. In addition,
heat is also required to raise the temperature of feed from 245oC to 255oC. A simplified block diagram
representing the heats entering and leaving the system (esterification reactor) is shown in Figure 2.
Where,
Q2 = Heat required to raise the temperature of reactants up to the required conditions and the heat of
reaction.
Q3 = Heat content of water and mono-ethylene glycol mixture leaving the reactor.
Q4 = Heat going out with the product and the unreacted reactants.
48
Chapter 5 Energy Balance
5.2.2. Stream Properties
The thermal properties of streams entering and leaving the esterification reactor are given in Table
5-3.
Table 5-3: Thermal properties of the streams entering and leaving the esterification reactor.
= . ( )
Where,
= Heat rate required to raise the temperature of inlet stream up to desired temperature.
= Final/Desired temperature.
Here,
= 6791153.316 /
49
Chapter 5 Energy Balance
5.2.3.2. Heat Input Required to Vaporize the Water Produced
The heat input rate required to raise the water produced in the reactor as vapors can be calculated as
follows:
= =
= 37.01 536.79
= 19866.60
= (3540) (1.028)
= 3639.12 /
50
Chapter 5 Energy Balance
5.3. Polymerization Reactor 1
Q2
(5) (7)
BHET PET
PTA Polymerization Reactor 1 PTA
Q1 Q4
MEG (280C) MEG
Water Water
(255C) (280C)
(6)
Water
MEG
(280C)
Q3
Figure 3: Block Diagram Presenting the Overall Heat Inputs and Outputs in Polymerization Reactor-1 (PR-1)
5.3.1. Description
In the Polymerization Reactor-1 (PR-1), polymerization of monomer begins. The temperature of the
reactor is maintained at 280oC therefore, energy must be provided to the feed stream of polymerization
reactor to raise its temperature to the suitable conditions. The polymerization reaction is slightly exothermic.
According to the literature, the heat of reaction is about 20 kcal/mol of MEG given out. The heat released as
a result of exothermic reaction is usually ignored because it is almost negligible in heat balance. A simplified
block diagram of the streams carrying energy, entering and leaving the reactor are shown in Figure 3.
= . ( )
Where,
= Heat rate required to raise the temperature of inlet stream up to desired temperature.
= Final/Desired temperature.
Here,
= 17946228.36 /
5.3.3.2. Heat Input Required to Vaporize MEG Produced
The heat input rate required to raise the MEG produced in the reactor as vapors can be calculated as
follows:
= =
= 7.65
13945.82
= 106685.523
= (7.65
) (20000
)
= 153000 /
52
Chapter 5 Energy Balance
5.4. Polymerization Reactor-2
Q2
(7) (9)
PET (DOP=30) PET (DOP=90)
PTA Polymerization Reactor 2 PTA
Q1 Q4
MEG (285C) MEG
Water Water
(280C) (285C)
(8)
Water
MEG
(285C)
Q3
5.4.1. Description
In the Polymerization Reactor-2 (PR-2), the degree of polymerization of the polymer under process is
increased further. The temperature is increased further to 285oC. MEG is released during the further
polymerization in an exothermic reaction. A simplified block diagram of the streams carrying energy, entering
and leaving the reactor are shown in Error! Reference source not found..
53
Chapter 5 Energy Balance
5.4.3. Calculations of Energy Requirement
5.4.3.1. Heat Input for Raising the Temperature of Stream 7
The heat required to raise the temperature of stream 7 from 280oC to 285oC is calculated as shown
below:
= . ( )
Where,
= Heat rate required to raise the temperature of inlet stream up to desired temperature.
= Final/Desired temperature.
Here,
= 1984861.57 /
5.4.3.2. Heat Input Required to Vaporize MEG Produced
The heat input rate required to raise the MEG produced in the reactor as vapors can be calculated as
follows:
= =
= 0.48
13945.82
= 6693.994
= (0.48
) (20000
)
= 9600 /
54
Chapter 5 Energy Balance
5.5. Poly-Condensation Reactor
Q2
(9) (11)
PET (DOP=90) Poly-Condensation PET (DOP=120)
PTA PTA
Q1
MEG Reaction MEG
Q4
Water (285C) Water
(285C) (285C)
(10)
Water
MEG
(285C)
Q3
Figure 4: Block Diagram Presenting the Overall Heat Inputs and Outputs in Poly-Condensation Reactor
5.5.1. Description
In the Polycondensation reactor, the degree of polymerization of the polymer under process is
increased further and the finally completed and the polymer having a degree of polymerization of 120 is
obtained as product. The temperature and pressure are maintained constant. MEG is released during the
further polymerization in an exothermic reaction. A simplified block diagram of the streams carrying energy,
entering and leaving the reactor are shown in Figure 4.
55
Chapter 5 Energy Balance
5.5.3. Calculations of Energy Requirement
5.5.3.1. Heat Input Required to Vaporize MEG Produced
The heat input rate required to raise the MEG produced in the reactor as vapors can be calculated as
follows:
= =
= 0.248
13945.82
= 3458.563
= (0.248
) (20000
)
= 4960 /
= 3458.563 4960
= . /
56
Chapter 6
Equipment Design
Chapter 6 Equipment Design
Basis = 1 Day
= 86.29 tons/day
6.1.1.1. Calculations
Where,
So,
H1 = 1.3D
Now,
Where,
57
Chapter 6 Equipment Design
Q = 60o (Assumed),
H2 = 2
tan(60)
H2 = 0.866 D
1
Volume of cone = 3
( 4 2 0.866 )
So,
= 1.02D3 + 0.2266D3
Thus,
1.2466D3 = 62.45 m3
D3 = 50.096 m3
D = 3.686 m
As,
H1 = 1.3 D
So,
H1 = 1.3 3.686
H1 = 4.792 m
H2 = 0.866 3.686
H2 = 3.192 m
Total height = H1 + H2
= 4.792 + 3.192
It contains the minimum Cr and Ni that gives a suitable austenitic structure. The carbon contents
are low enough, for heat treatment not to be normally needed with thin sections to prevent weld decay.
58
Chapter 6 Equipment Design
6.1.1.3. Suggested Design
Shape = Conical
No. of units = 1
2
Area of tank = 4
= 10.673 m2
EG required = 2.687 24
= 64.482 tons/day
= (1.115)(1000)
= 1115 kg/m3
= 1.115 tons/m3
= 57.832 m3
Where,
H = 1.3 D
Volume of vessel = 4
2
= 4
2 1.3
59
Chapter 6 Equipment Design
Volume of vessel = 1.026 D3.
So,
1.021D3 = 63.615 m3
D3 = 62.307 m3
D = 3.964 m
So,
H = 1.3 D
H = 1.3 3.964
H = 4.121m
It contains the minimum Cr and Ni that gives a suitable austenitic structure. The carbon
contents are low enough, for heat treatment not to be normally needed with thin sections to prevent
weld decay.
No. of units = 1
2
Area of tank = 4
60
Chapter 6 Equipment Design
= 3595.782 kg/hr
= 1353.22 kg/hr
= 1602.227 kg/hr
= 84.91 kg/hr
Equation Used
=
Vr = ?
Vo = ?
=
Where,
= Density of mixture
6.2.1.1. Calculations
Total mass flow rate in the mixing tank,
G = M1 + M2 + M3 + M4
G = 6636.142 kg/hr
1353.22+1602.227
Weight fraction of EG = 6636.142
XEG = 0.445
61
Chapter 6 Equipment Design
Similarly,
XTPA = 0.542
XWater = 0.013
As,
= 6636.142/1333.015
So,
Vo = 4.978 m3/hr
Tmix = Vr/Vo
Vr = Tmix Vo
= 1.167 4.978
Vr = 5.809 m3
Vr = 6.39 m3
Where,
H = 1.3 D
Volume of Mixer = 4
2
= 4
2 1.3
1
= 3
(4) 3
D3 = 6.39/0.2618
D3 = 24.408
D = 2.9 m
62
Chapter 6 Equipment Design
As,
D = 2.9 m
H = 1.3D
H = 3.77 m
Minimum wall thickness required to ensure that the vessel is sufficiently rigid to withstand its own
weight includes corrosion allowance of 2mm = 5+2 = 7 mm.
Pi = pmix g h
= 1333.015 * 9.8*2
Pi = 26127.09 N/m2
J = 0.85
D = 2.9 m
e = 3.30184 10-4 m
e = 0.330184 mm
= 7.33084 mm
63
Chapter 6 Equipment Design
6.2.1.4. Impeller Design Nomenclature
S1 = DT/Da =3
S2 = E/DT = 1/3
S3 = L/DT = 0.25
S4 = W/Da = 1/5
S5 = 1/DT = 1/12
Da = Diameter of impeller, m
DT = Diameter of tank, m
L = Length of blade, m
W = Width of blade, m
J = Width of baffle, m
1. S1 = DT/Da =3
Da = DT/3
= 2.9/3
Da = 0.967 m
2. E/DT = 1/4
E = DT 1/3
E = 2.9 1/3
E = 0.967 m
3. L/Da = 0.25
L = 0.25 0.967
L = 0.25(0.967)
L = 0.242 m
4. W/Da = 1/5
W = 1/5 Da
W = (1/5) 0.967
W = 0.193
J/DT = 1/12
J = DT/12
= 2.9/12
J = 0.242 m
64
Chapter 6 Equipment Design
6.2.1.6. Power Requirement to Drive the Agitator
Number of baffles = 4
N = Number of Revolutions
Da = Diameter of impeller
gc = conversion factor
(2 )
Re No. =
n = 100 rpm
= 1.66 rps
Da = 0.967
mix = 1100 cp
= 11 poice
= 1.1 kg/ms
So,
3 5
P =
= 28951.13 Watt
= 2.895 kW
65
Chapter 6 Equipment Design
6.2.1.7. Material of Construction
Material of construction of TPA storage tank is stainless steel type -304. Type 304 (18/8 stainless steel)
is a type of austenite stainless steel, which because of its uniform structure is desired for corrosion resistance
and is the most generally used stainless steel.
It contains the minimum Cr and Ni that gives a suitable austenitic structure. The carbon contents are
low enough, for heat treatment not to be normally needed with thin sections to prevent weld decay.
Wall thickness = 7 mm
66
Chapter 6 Equipment Design
6.3. Esterification Reactors
6.3.1. Design of Esterification Rector 1 (ES-1)
TPA going to ES-1 = 3595.782 kg/hr
Vo = 4.98 m3/hr
Tres = VR/Vo
VR = Volume of Reactor
As we know that,
Tres = VR/Vo
VR = Tres Vo
= 4 4.98
VR = 19.92 m3
VR = 19.92 m3
VR = 21.912 m3
Now
H = 1.3DT
Volume of reactor = 4
2
= 4
2 1.3
DT3 = 21.912/1.0205
DT3 = 21.461 m
DT = 2.779 m
H = 1.3DT
= 1.3(2.779)
H = 3.612 m
67
Chapter 6 Equipment Design
6.3.1.1. Wall Thickness
Minimum wall thickness required to ensure that the vessel is sufficiently rigid to withstand its own
weight including corrosion allowance of 2mm = 10 mm
Pi = pmix g h
Pi = 47290.04 N/m2
D = 2.779 m
J = 0.85
F = 95 N/(mm)2 at 245oC.
75768.561
=
229473872.9
e = 8.1398 10-4 m
e = 0.81398 mm So,
= 10.81398 mm
S1 = DT/Da =3
S2 = E/DT = 1/3
S3 = L/DT = 0.25
S4 = W/Da = 1/5
S5 = 1/DT = 1/12
Da = Diameter of impeller, m
DT = Diameter of tank, m
L = Length of blade, m
W = Width of blade, m
J = width of baffle, m
68
Chapter 6 Equipment Design
6.3.1.4. Impeller Design Calculations
S1 = DT/Da =3
Da = DT/3
= 2.779/3
Da = 0.926 m
E/DT = 1/4
E = DT 1/3
E = 2.779 1/3
E = 0.926 m
L/Da = 0.25
L = 0.25 0.926
L = 0.232 m
W/Da = 1/5
W = 1/5 Da
W = (1/5) 0.926
W = 0.185
J/DT = 1/12
J = DT/12
= 2.779/12
J = 0.232 m
69
Chapter 6 Equipment Design
6.3.1.5. Power Requirement to Drive the Agitator
Number of baffles = 4
N = Number of Revolutions
Da = Diameter of impeller
gc = conversion factor
(2 )
Re No. =
n = 100 rpm
= 1.66 rps
Da = 0.926 m
mix = 1100 cp
= 11 poice
= 1.1 kg/ms
So,
3 5
P =
= 23352.68 Watt
= 23.895 kW
70
Chapter 6 Equipment Design
6.3.2. Design of Esterification Rector 2 (ES-2)
= 1285 kg/m3
Vo = 4.52 m3/hr
Tres = VR/Vo
VR = Volume of Reactor
As we know that,
Tres = VR/Vo
VR = Tres Vo
= 4 4.52
VR = 18.104 m3
VR = 19.914 m3
Now
H = 1.3DT
As,
Volume of reactor = 2
4
= 4
2 1.3
DT3 = 19.914/1.0205
DT3 = 19.514 m3
DT = 2.692 m
71
Chapter 6 Equipment Design
Now,
H = 1.3DT
= 1.3(2.692)
H = 3.499 m
Pi = pmix g h
Pi = 44075.5 N/m2
D = 2.692 m
J = 0.85
F = 95 N/(mm)2 at 255oC.
e = 7.353 10-4 m
e = 0.7353 mm
So,
= 10.7353 mm
72
Chapter 6 Equipment Design
6.3.2.3. Impeller Design for Esterification Reactor
S1 = DT/Da =3
S2 = E/DT = 1/3
S3 = L/DT = 0.25
S4 = W/Da = 1/5
S5 = 1/DT = 1/12
Da = Diameter of impeller, m
DT = Diameter of tank, m
L = Length of blade, m
W = Width of blade, m
J = width of baffle, m
S1 = DT/Da =3
Da = DT/3
= 2.692/3
Da = 0.8974 m
E/DT = 1/4
E = DT 1/3
E = 2.779 1/3
E = 0.8974 m
L/Da = 0.25
L = 0.25 0.8974
L = 0.2243 m
W/Da = 1/5
W = 1/5 Da
W = (1/5) 0.8974
W = 0.1795
J/DT = 1/12
J = DT/12
= 2.692/12
73
Chapter 6 Equipment Design
J = 0.2243 m
N = Number of Revolutions
Da = Diameter of impeller
gc = conversion factor
(2 )
Re No. =
n = 100 rpm
= 1.66 rps
Da = 0.8974 m
mix = 1100 cp
= 11 poice
= 1.1 kg/ms
So,
3 5
P =
= 19243.33 Watt
= 19.24333 kW
74
Chapter 7
Instrumentation
&
Process Control
Chapter 7 Instrumentation & Process Control
7.1. Instrumentation
It is carried out to monitor the key process variables during plant operation. Instruments may be
incorporated in automatic control loops or used for the manual monitoring of the process operation. There
may be manual or automatic computer data logging system. Instruments monitoring critical process variables
will be fitted with automatic alarms to alert the operators to critical and hazardous situations.
Industry pursuit of increasingly stringent process control and safety requirements led to an early
adaptation of computational techniques in this field.
Today, a wide range of computing devices, ranging from imbedded microprocessors to dedicated
computers, is commonly employed throughout the industry. The class explores the technical foundations of
process and control instrumentation in use, and covers the practical aspects of its deployment.
7.1.1. Measurement
Instrumentation can be used to measure certain field parameters (physical values). Some of the
variables include:
Pressure
Flow
Temperature
Level
Density
Radiation
Frequency
Current
Voltage
Inductance
Capacitance
Resistivity
Chemical Composition
7.1.2. Control
In addition to measuring field parameters, instrumentation is also responsible for providing the ability
to modify some field parameters to keep the process variables at a desired value.
75
Chapter 7 Instrumentation & Process Control
7.2. Incentive for Chemical Process Control
A chemical plant is an arrangement of processing units (reactors, heat exchanger, pumps, distillation
columns, absorbers, evaporators, tanks etc.), integrated with one another in a systematic and rational manner.
The overall objective of plant is to convert certain raw materials into desired products using available sources
of energy, in the most economical way.
In its operation, a chemical plant must satisfy several requirements imposed by its designers and the
general technical, economic and social conditions in the presence of ever-changing external influences
(disturbances). Among such requirements are the following:
7.2.1. Safety
The safe operation of a chemical process is a primary requirement for the well-being of the people in
the plant and for its continued contribution to the economic development.
7.2.5. Economics
The operation of a plant must confirm to the market conditions, that is, the availability of the raw
materials and the demand of the final products. Furthermore, it should be as economical as possible in the
utilization of raw materials, energy, and capacity and human labor. Thus, it is required that the operating
conditions are controlled at given optimum levels of minimum operating cost, maximum profit and so on.
76
Chapter 7 Instrumentation & Process Control
7.3. Elements of Control System
In almost every configuration, we can distinguish the following hardware elements.
The measuring means depend upon the types of variable, which is to be measured, and these variables
must be recorded also. Following are some typical sensors, which are used for different variable
measurements.
i) Pressure Sensors
ii) Temperature Sensors
iii) Flow rate Sensors
iv) Level Sensors
A good device for the measurement depends upon the environment in which it is to be used. Like a
thermometer, it is not a good measuring device, as its signal is not rapidly transmitted. So signal transmission
is very important in selecting the measuring device. So the measuring device must be rugged and reliable for
an industrial environment.
77
Chapter 7 Instrumentation & Process Control
7.3.3. Transducers
Many measurements cannot be used for control until they are converted to physical quantities such
as electric voltage and current pneumatic signal. For example, stream gauges are metallic conductors whose
resistance changes when mechanical strain is imposed on it. Thus, they can be used to convert a mechanical
signal to electric one.
Many times the measurements coming from a device are very weak and these must be amplified to
get the things right. So it is very often to find amplifiers in the transmission lines to the controller. For example,
the output of a thermocouple is only a few millivolts so they must be amplified to few volts to get the
controller.
7.3.5. Controller
This is the hardware element that has intelligence. It receives the information from the measuring
device and decides what action must be taken out. The older controllers were of limited intelligence, could
perform very limited and simple operations and could implement very simple control laws. The use of digital
computers in this field has increased the use of complicated control laws.
78
Chapter 7 Instrumentation & Process Control
7.4. Modes of Control
There are various modes in which the process can be controlled. The different modes depend upon
the types of controllers and the action it takes to control any process variable. Actually, the controller action
is dependent on the output signal of the transmitter. This signal is compared with the set point to the
controller and the error between these two is used to control the process. Different controllers react in
different manner to control this off-set between the controlled variable and the set point.
On off control
Proportional control
Integral Control
Rate or derivative control
Composite control
Following are the typical composite control modes which are actually used:
Proportional-Derivate Controller
Proportional-Derivate Controller
Proportional Integral Derivative Controller
Pneumatic controllers
Electronic controllers
Hydraulic controllers
Usually, type of controller is selected using only quantitative considerations stemming from the analysis
of the system and ending at the properties of that particular controller and the control objective. Proportional,
Integral, and Derivative control modes also affect the response of the system.
79
Chapter 7 Instrumentation & Process Control
Following is the summarized criterion to select the appropriate controller for any process depending
upon the detailed study of the controller and control variable along with the process severity.
In other words, the following criterion is used for the selection of a best controller
80
Chapter 7 Instrumentation & Process Control
7.6.1. Feed Back Control Loop
It is a mechanism, process or signal that is looped back to control a system within itself. Such a loop is
called a feedback loop. Intuitively, many systems have an obvious input and output, feed the part of the output
so as to increase the input is positive feed; feedback part of the output in such a way as to partially oppose
the input negative feedback.
In general terms, a control system has input from an external signal source and output to an external
load; this defines a natural sense (or direction) or path of propagation of signal; the feed forward sense or
path describes the signal propagation from input to output feedback describes signal propagation in the
reverse sense. When a sample of the output of the system us fed back, in the reverse sense, by a distinct
feedback path into the interior of the system, to contribute to the input.
For the first selector, the two inputs will be the first two signals from the device being controlled. For
each subsequent selector, one signal will be the output signal from the previous selector, while the other input
signal will be the next signal from the device.
81
Chapter 7 Instrumentation & Process Control
7.7. Instrumentation of Slurry Tank
In the mixer tank, three feeds are coming which are going out as one. These feeds include recycled
ethylene glycol, fresh ethylene glycol and terepthalic acid. Fresh ethylene glycol and TPA and mixed in a pre-
determined ratio and to maintain the stoichiometric quantities of these different streams.
A ratio control loop is used so that to ensure proper process going on in the slurry tank. Level
measurement is also critical parameter in slurry tank, so level is controlled through placing a valve; transmitter
and level controller on a fail open valve of the level in the vessel increase the given set point, the controller
will control the level by opening the valve.
And if the level in the slurry tank decreases the given set point the controller, control the level by closing
the valve.
82
Chapter 7 Instrumentation & Process Control
83
Chapter 7 Instrumentation & Process Control
84
Chapter 8 Cost Estimation
Chapter 8
Cost Estimation
Chapter 8 Cost Estimation
Auxiliary facilities such as utilities, land and civil engineering works. It is once only cost that is not
recovered at the end of the project life, other than scrap value.
i. Direct cost
ii. Indirect cost
86
Chapter 8 Cost Estimation
Start-up
initial catalyst charges
raw material and intermediate in the process
finished product inventories
funds to cover outstanding accounts from customer
Most of the working capital is recovered at the end of the project. The total investment needed for a
project is the sum of the fixed and working capital.
Working capital may vary from as low as 5% of the fixed capital for a simple. Single product, process
with little or no finished product storage to as high as 30% for a process producing a diverse range or product
grade for a sophisticated market, such as synthetic fiber. Typical figure for petrochemical plant is 15% of the
fixed capital.
The cost of producing a chemical product will include items listed below they are divided into two
groups
Fixed Cost
Variable Cost
Certain items can be classified without question but the classification the other items will depend on
the accounting practice of the particular organization. The items may also be classified differently in the cost
sheet and cost standards prepare to monitor the performance of the operating plant. For the purpose of the
fixed cost items for which they be held accountable.
87
Chapter 8 Cost Estimation
Present cost/Index at present time = Original cost/Index value at time of Original cost.
Sub-total A
Fixed Cost
1. Maintenance 5 to 6% of fixed capital
2. Operating labor from manual estimates
3. Laboratory costs 20-23% of (6)
4. Supervision 20% of item (6)
5. Plant overheads 50% of item (6)
6. Capital cost 15% of fixed capital
7. Insurance 1% of Fixed capital
8. Local taxes 2% of Fixed capital
9. Royalties 1% of fixed Capital
Sub-division B
Sub-Division C
88
Chapter 8 Cost Estimation
C = Cost constant
S = 31.28m3/day
C = 4350
N = 0.55
= 57797.42 $
= 6870.16 $
S = 32.68m3/Day
C = 4350
n = 0.55
= 29603.59 * 2
= 59207.18
= 70378.73
89
Chapter 8 Cost Estimation
= 5500 * 2 * 1
` = 11000$
= 12915.10$
S = 6.7130m
C = 0.45
Ce = 31000(6.71)0.45
Ce = 73010.75
Ce = 73010.75 * 1.0257
Ce = 86786.84 $
S = 5.2m3
C = 31000
n = 0.45
Ce = 31000 * (5.2)0.45
= 65097.33
Ce = 65097.33 * (1.025)7
= 77380.26$
= 86786.84 $ + 77380.26 $
90
Chapter 8 Cost Estimation
Total cost of both esterifiers = 164167.1088$
S = 9.2m3
C = 31000
n = 0.45
Ce = 31000 * (9.2)0.45
= 84152.34$
Ce = 84152.34 * (1.025)7
= 100030.68$
S = 8.4m3
C = 31000
n = 0.45
Ce = 31000 * (8.4)0.45
= 80776.94$
Ce = 80776.94 * (1.025)7
= 96018.39$
S = 8.2m3
C = 31000
n = 0.45
Ce = 31000 * (8.2)0.45
= 79905.73$
Ce = 79905.73 * (1.025)7
= 94982.80$
91
Chapter 8 Cost Estimation
Cost of Polycondensation reactor RA-41 = 94982.80$
= 1850 * (1.025)9
= 2310.39 $
= 11551.98 $
= 1345.48 Kg/hr
= 1115 Kg/m3
= 1.21m3/hr
= 3.36 * 10-4m3/sec
= 10808 * 1.0259
= 1348.77$
= 3818.82 Kg/hr
= 1304.29 Kg/m3
= 8.11 * 10-4m3/hr
92
Chapter 8 Cost Estimation
Considering 2.5% increase for year (based on 2002),
= 2020 * 1.0259
= 2522.70$
= 7.43 * 10-4m3/sec
= 2800 * 1.0259
= 3496.82$
= 7.33 * 10-4m3/hr
= 2600 * 1.0259
= 3247.04$
= 3195 $
93
Chapter 8 Cost Estimation
= 7980.23$
= 3195 $
= 261621.73$
= 457838.03$
= 13081.87$
= 65405.43$
= 98108.15$
94
Chapter 8 Cost Estimation
= 327027.17$
= 981-85.15$
= 32702.72$
= 98108.15$
= 649314.9 ( 1 + 0.4 + 0.70 + 0.20 + 0.10 + 0.15 + 0.50 +0.15 + 0.05 + 0.15 )
PPC = 2207670.49$
= 160056.11$
= 3361178.322$
1 Terephthalic Acid
2 Ethylene glycol
95
Chapter 8 Cost Estimation
= 117886.40n * 1050
= 39206692.66 $
Company general operating experience including sales expenses general overheads and research and
development
= 0.2 * 39206692.66
= 7841338.53 $
= 47048031.15 $/year
Production cost:
Production cost per Kg =
= 47048031.15$/year
97