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ALDEHYDES
Representatives
Oxidation Reactions
Linear Polymerization
Cyclic Polymerization
Addition Reaction
KETONES
***Difference in structure between aldehydes and ketones affects their properties in two ways
(reactivity):
1. Aldehydes are easily oxidized while ketones can also be oxidized but with difficulty.
2. Aldehydes are usually more reactive than ketones toward nucleophilic addition.
(a) TollensTest, (b) Fehlings Test, (c) Schiffs Test and (d) addition of NaOH to ketones will
have no reaction or negative result. This illustrates the ketones being non-reactive.
(a) Addition of NaHSO3 and (b) iodoform test on the other hand, generates a positive result.
Representative
Acetone
Representatives
Acetic acid and propionic acid have irritating odor and are liquid in form while the rest are
odorless and in solid form. It should also be noted that the degree of acidity decreases as the
hydrocarbon chain increases.
In terms of solubility, all except acetic acid are immiscible/insoluble with water. All are
miscible/soluble with organic solvents such as ether and ethanol.
Chemical Properties
b.
2. Reaction with Ferric Salts
3. Millons test
This tests for the presence of phenolic group in salicylic acid. It is also used for the
determination of a specific amino acid in biochemistry.