Se realiz el experimento de degradacin y mineralizacin de Tartrazina mediante Electro-Oxidacin, para

DATOS - ARTICULO CODIFICADO DECODIFICADO

CIPPM MA PH DCY1 DDQOY2 A B C CIPP MA PH DCY1 DDQOY2
1 40 7.5 4.5 91.42 61.97 -1 -1 0 20 5 4.5 96.31 76.92
2 40 10 6 96.86 77.47 1 -1 0 60 5 4.5 64.11 43.59
3 40 7.5 4.5 89.62 60.56 -1 1 0 20 10 4.5 97.61 66.67
4 20 7.5 6 95.91 64.1 1 1 0 60 10 4.5 74.88 53.85
5 20 10 4.5 97.61 66.67 -1 0 -1 20 7.5 3 96.81 58.97
6 60 7.5 6 60.61 42.31 1 0 -1 60 7.5 3 41.38 56.41
7 20 7.5 3 96.81 58.97 -1 0 1 20 7.5 6 95.91 64.1
8 60 5 4.5 64.11 43.59 1 0 1 60 7.5 6 60.61 42.31
9 20 5 4.5 96.31 76.92 0 -1 -1 40 5 3 89.12 71.83
10 60 10 4.5 74.88 53.85 0 1 -1 40 10 3 79.49 70.42
11 40 5 6 97.21 67.61 0 -1 1 40 5 6 97.21 67.61
12 60 7.5 3 41.38 56.41 0 1 1 40 10 6 96.86 77.47
13 40 7.5 4.5 91.77 73.24 0 0 0 40 7.5 4.5 91.42 61.97
14 40 5 3 89.12 71.83 0 0 0 40 7.5 4.5 89.62 60.56
15 40 10 3 79.49 70.42 0 0 0 40 7.5 4.5 91.77 73.24

DESCRIPINFERCENTSUPERIO (+1)
Concentr 20 40 60
Densidad 5 7.5 10
pH 3 4.5 6

Xp = 40 20
Xi = -1
Xi = 1
OTRA FORMA:
Xi = -1
Xi = 1

CONCUERDA CON STATGRAPHICS EL ANOVA

CIPPM MA PH DCY1 DDQOY2

1 40 7.5 4.5 91.42 61.97
2 40 10 6 96.86 77.47
3 40 7.5 4.5 89.62 60.56
4 20 7.5 6 95.91 64.1
5 20 10 4.5 97.61 66.67
6 60 7.5 6 60.61 42.31
7 20 7.5 3 96.81 58.97
8 60 5 4.5 64.11 43.59
9 20 5 4.5 96.31 76.92
10 60 10 4.5 74.88 53.85
11 40 5 6 97.21 67.61
12 60 7.5 3 41.38 56.41
13 40 7.5 4.5 91.77 73.24
14 40 5 3 89.12 71.83
15 40 10 3 79.49 70.42
Electro-Oxidacin, para determinar las variables ms relevantes para el proceso de Electro-Oxidacin, se fijaron los parmetros de cond

INGRESO DE DATOS EN DESIGN EXPERT V7

DESIGN EXPERT V7

AMBOS COINCIDEN LOS RESULTADOS

TRABAJANDO CON VALORES REALES O DECO
CIPP MA
20 5
60 5
20 10
60 10
20 7.5
60 7.5
20 7.5
60 7.5
40 5
40 10
40 5
40 10
40 7.5
40 7.5
40 7.5
fijaron los parmetros de conductividad y agitacin de la solucin en 1060 uS/cm y 340 rpm, respectivamente. Con estos valores fijoas,

STATGRAPHICS CENTURIO XVI

IDEN LOS RESULTADOS

CON VALORES REALES O DECODIFICADOS. INGRESO DE DATOS EN STATGRAPHICS CENTURION XVI
PH DCY1 DDQOY2
4.5 96.31 76.92
4.5 64.11 43.59
4.5 97.61 66.67
4.5 74.88 53.85
3 96.81 58.97
3 41.38 56.41
6 95.91 64.1
6 60.61 42.31
3 89.12 71.83
3 79.49 70.42
6 97.21 67.61
6 96.86 77.47
4.5 91.42 61.97
4.5 89.62 60.56
4.5 91.77 73.24
ente. Con estos valores fijoas, se realiz un Diseo Box - Behnken (DBB) que inclua las variables restantes: pH, Concentracin de coloran

STATISTICA V10

ENTURION XVI
pH, Concentracin de colorante y Densidad de corriente. Las variables de diseo de experimentos de Box - Behnken son:

STATGRAPHICS CENTURIO XVI

SE debe realizar el anlisis o correr el anlisi
 - Behnken son:

CENTURIO XVI
ar el anlisis o correr el anlisis: Primero DCY1 y luego DDQOY2, y a continuacin se corre MULTIRESPUESTA:
 NIVEL
DESCRIPCIN DE LA VARIABLE Inferior (-1)
Concentracin Inicial de Tartrazina (CI-ppm) 20
Densidad de Corriente (mA(cm2) 5
pH 3
 NIVELES
Centro (0) Superio (+1)
40 60
7.5 10
4.5 6
 VALORES CODIFICADOS VALORES REALES
Nivel codificado X1 X2 X3 CIPPM MA pH
-1 -1 0 20 5 4.5
Factorial 22 1 -1 0 60 5 4.5
para A y B -1 1 0 20 10 4.5
1 1 0 60 10 4.5
-1 0 -1 20 7.5 3
Factorial 22 1 0 -1 60 7.5 3
para A y C -1 0 +1 20 7.5 6
1 0 +1 60 7.5 6
0 -1 -1 40 5 3
Factorial 22 0 1 -1 40 10 3
para B y C 0 -1 1 40 5 6
0 1 1 40 10 6
0 0 0 40 7.5 4.5
Centro del Diseo 0 0 0 40 7.5 4.5
0 0 0 40 7.5 4.5
%DC %DDQO
96.31 76.92
64.11 43.59
97.61 66.67
74.88 53.85
96.81 58.97
41.38 56.41
95.91 64.10
60.61 42.31
89.12 71.83
79.49 70.42
97.21 67.61
96.86 77.47
91.42 61.97
89.62 60.56
91.77 73.24
RESULTADOS DE DESIGN EXPERT V7

b0 b1 b2
125.70333 1.64979 -20.723
 b3 b12 b13 b23 b11 b22 b33
-3.26833 0.10255 -0.16025 0.75133 -0.02673 0.91087 0.39241

1.64979 b1
b= -20.72300 b2
-3.26833 b3

-0.026730 0.051275 -0.080125

B= 0.051275 0.910870 0.375665
-0.080125 0.375665 0.392410

-13.735522 3.18898997 -5.8575231

inv(B) = 3.18898997 1.07371582 -0.3767479
-5.8575231 -0.3767479 1.71299649

-13.735522 3.18898997 -5.8575231

B^-1b = 3.18898997 1.07371582 -0.3767479
-5.8575231 -0.3767479 1.71299649

-69.601848 34.8009239 x1
X(s) = -15.758113 -0.5 7.8790564 x2
-7.4549747 3.72748733 x3

Y(s) = 125.70333 0.5 34.8009239 7.879056399

0.5 -118.04613
Y(s) = 125.70333 -59.023064
Y(s) = 66.6802659
los resultados coinciden con STATISTICA V10.
 1.64979
-20.72300
-3.26833

1.64979
3.7274873 -20.72300
-3.26833
 RESULTADOS DE STATISTICA V10

b0 b1 b2
-300.247 111.656 267.168

lo correcto en codificar y en escala real

X0 X1 X2 X3 Z1 = PE Z2 = pH Z3 = FE
1 -1 -1 -1 0.2 2.3 2.000
1 1 -1 -1 0.4 2.3 2.000
1 -1 1 -1 0.2 3.5 2.000
1 1 1 -1 0.4 3.5 2.000
1 -1 -1 1 0.2 2.3 6.000
1 1 -1 1 0.4 2.3 6.000
1 -1 1 1 0.2 3.5 6.000
1 1 1 1 0.4 3.5 6.000
1 -1.682 0 0 0.132 2.9 4.000
1 1.682 0 0 0.468 2.9 4.000
1 0 -1.682 0 0.3 1.89 4.000
1 0 1.682 0 0.3 3.90 4.000
1 0 0 -1.682 0.3 2.9 0.640
1 0 0 1.682 0.3 2.9 7.360
1 0 0 0 0.3 2.9 4.000
1 0 0 0 0.3 2.9 4.000
1 0 0 0 0.3 2.9 4.000
1 0 0 0 0.3 2.9 4.000
1 0 0 0 0.3 2.9 4.000
1 0 0 0 0.3 2.9 4.000
 b3 b12 b13 b23 b11 b22 b33
3.427 -70.375 22.2 0.477 -30.085 -46.229 -0.798

111.65600 b1
b= 267.16800 b2
3.42700 b3

-30.085000 -35.187500 11.100000

B= -35.187500 -46.229000 0.238500
11.100000 0.238500 -0.798000

0.00683441 -0.0047189 0.09365474

inv(B) = -0.0047189 -0.0184067 -0.0711398
0.09365474 -0.0711398 0.02832175

0.00683441 -0.0047189 0.09365474

B^-1b = -0.0047189 -0.0184067 -0.0711398
0.09365474 -0.0711398 0.02832175

-0.1766762 0.08833809 PE1

X(s) = -5.6883565 -0.5 2.84417826 PH2
-8.4521034 4.22605171 FE3

Y(s) = -300.247 0.5 0.08833809 2.844178264

0.5 784.219575
Y(s) = -300.247 392.109787
Y(s) = 91.8627874
los resultados coinciden con STATISTICA V10.
Y_TOC(%)
74.83
65.01
55.68
31.15
85.92
96.04
71.24
62.29 RESULTADOS DE SAS
87.28
89.42
61.03
24.22
65.29
95.10
88.15
88.63
88.93
88.45
87.85
88.32

LOS PTIMOS COINCIDEN CON STATISTICA V10

111.65600
267.16800
3.42700

111.65600
4.2260517 267.16800
3.42700