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1. What's Corrosion?
Corrosion is an electrochemical process in which a current leaves a structure at
the anode site, passes through an electrolyte, and re-enters the structure at the
cathode site. For example, one small section of a pipeline may be anodic
(positively charged) because it is in a soil with low resistivity compared to the
rest of the line. Current would leave the pipeline at that anode site, pass through
the soil, and re-enter the pipeline at a cathode (negatively charged) site. Current
flows because of a potential difference between the anode and cathode. That is, the
anode potential is more negative than the cathode potential, and this difference is
the driving force for the corrosion current. The total system (anode, cathode,
electrolyte, and metallic connection between anode and cathode) is termed a
corrosion cell.
4. Galvanic Corrosion?
The Anode and Cathode are on the same surface of the pipe. The soil, or medium, is
the electrolyte. A closed electric circuit exists in an ionic current flowing
between Cathode and Anode in the soil, then electronic current between cathode and
anode inside the metal.
6. Possible Solutions?
Plan A: Coating. Especially with Zinc-rich coatings. It's a possible solution. But
its disadvantages are that it's not a sufficient way of protection against
corrosion. Moreover, scratches at installation, periodic repainting, and hardships
of repainting of some structures, all of that makes it really hard to rely on
Coating alone.
Plan B: Cathodic Protection.
8. Corrosive Medium:
Soil consists of solid particles and pores filled with moisture and air. Soils with
a high proportion of sand have very limited storage capacity for water, whereas
clays are excellent in retaining water. Soils with high moisture content, high
electrical conductivity, high acidity, and high dissolved salts will be most
corrosive.
For water, it's a matter of mineral content. The more the minerals, the less the
resistivity, the more the corrosivity.
10.2.1. Anodes:
A range of materials have been used as non-consumable anodes for impressed-current
systems. The sort of properties required by these anodes are:
1. good electrical conduction,
2. low rate of corrosion,
3. good mechanical properties, able to stand the stresses which they may be
subjected to during installation and in service,
4. readily fabricated into a variety of shapes,
5. low cost,
6. able to withstand high current densities at their surfaces without forming
resistive barrier oxide layers, etc.
Again. It's not necessary to use more active anodes than the structure to be
protected. Anodes are used with a carbonaceous backfill to:
- increase effective size of the anode.
- lower the anode-to-ground resistance.
- extend the life of the anode.
There're to types of anodes:
- Inert (or non-consumable), like Platinized anodes (a few micrometers-thick
coating of Platinum on Titanium or Niobium), graphite.
- Consumable anodes (scrap steel, high-Si Cr cast iron).
10.2.3. Applications:
ICCP is preferably used when high current is required or the electrolyte's
resistivity is high. As it provides better protection, ICCP is used on Piplelines,
Tanks, and well-casing.