Procedure Hydrolysis of etyl asetat

1. Hydrolysis of etyl asetat in weak acid

50 mL Acetic acid 0,5 M

- Poured into Erlenmeyer label A

- Added 45 mL aquadest
- Let it in room temperature for 15
minutes

Solution in Erlenmeyer A

20 mL etyl asetat

- Poured into Erlenmeyer label B

- Let it in room temperature for 15
minutes

Solution in Erlenmeyer B

5 mL Solution B

- Poured into Erlenmeyer label A

- Stired it
- Let it in room temperature for 5
minutes
Blend solution

- Repeat this step with time 10, 20, 30,

40, 50 dan 60 menit

Blend Solution
 50 mL cool aquadest

- Poured into erlenmeyer C

- Added 10 ml blend solution
- Titration with NaOH 0,2 M

Volume of NaOH

Solution A (residue)

- Let it for some day

- Titration to use determine hydrolysis
process

Finish point of hydrolisis

Titration of blanco solution

5 ml acetic acid

- Poured into erlenmeyer

- Titration with NaOH 0,2 M

Volume of NaOH

2. Hydrolysis of etyl asetat in strong acid

50 mL HCl 0,5 M

- Poured into Erlenmeyer label A

- Added 45 mL aquadest
- Let it in room temperature for 15 minutes

Solution in Erlenmeyer A
 20 mL etyl asetat

- Poured into Erlenmeyer label B

- Let it in room temperature for 15
minutes

Solution in Erlenmeyer B

5 mL Solution B

- Poured into Erlenmeyer label A

- Stired it
- Let it in room temperature for 5
minutes
Blend solution

- Repeat this step with time 10, 20, 30,

40, 50 dan 60 menit

Blend Solution

50 mL cool aquadest

- Poured into erlenmeyer C

- Added 10 ml blend solution
- Titration with NaOH 0,2 M

Volume of NaOH

Solution A (residue)

- Let it for some day

- Titration to use determine hydrolysis
process

Finish point of hydrolisis

 Titration of blanco solution

5 ml HCl

- Poured into erlenmeyer

- Titration with NaOH 0,2
M

Volume of NaOH

REACTION

H+
CH3COOC2H5 (aq) + CH3COOH (aq) + H2O (l) C2H5OH (aq) + CH3COOH (aq)

CH3COOH (aq) + NaOH (aq) CH3COONa (aq) + H2O(l)

H+
HCl (aq) + NaOH (aq) NaCl (aq)+ H2O(l)
 CALCULATION
Minimum volume
M NaOH x V NaOH Blanco (L)
M CH3COOH =
V CH3COOH

M CH3COOH x V CH3COOH
V NaOH =
M NaOH

Maximum Volume
(M CH3COOH x V CH3COOH) + (M CH3COOC2H5 x V CH3COOC2H5)
V NaOH =
M NaOH

mmol CH3COOC2H5 = M CH3COOC2H5 x V CH3COOC2H5

mmol CH3COOH (Catalis) = M CH3COOH x V CH3COOH

mmol NaOH titration = mmol H+ catalis + mmol H+ product

mmol H+ produuct = mmol CH3COOC2H5 reaction (x)