Академический Документы
Профессиональный Документы
Культура Документы
1. Arrhenius theory of acids and bases is suitable for strong acids and bases only. Bronsted-
Lowry theory (BLT) is more general and can be applied to any acid and base. Lewis theory
of acids and bases are suitable for complex ions and compounds with electron pairs. [Lewis
theory is not in the syllabus]
2. Common acids and bases
a. 7 strong acids: HCl, HBr, HI, HNO3, H2SO4, HClO4 and HClO3
b. 6 strong bases: NaOH, KOH, LiOH, Ca(OH)2, Ba(OH)2 and Sr(OH)2
c. Common weak acids: HF, H3PO4, CH3COOH (all carboxylic acids), HCN, HNO2, HClO,
HClO2, H2CO3 and H2SO3
d. Common weak bases: ammonia and amines (methylamine, ethylamine etc)
c. i. Weak acid is represented by HA. The general equation for acid dissociation is
HA(aq) + H2O(l) H3O+(aq) + A-(aq)
Acid Base Hydronium ion related anion
ii. Weak base is represented by B. The general equation for base dissociation is
B(aq) + H2O(l) BH+(aq) + OH-(aq)
Base Acid related cation Hydroxide ion
iii. The acid dissociation constant, Ka and base dissociation constant, Kb can be
written for all acids and bases, in the same way that we write Kc and Kp for any
reaction.
Ka and Kb values are large for strong acids and bases. Logically, stronger
acids and bases dissociate better. Thus, equilibrium lies away from them,
producing more ions.
Ka and Kb values are small for weak acids and bases because less ions
are produced.
1
e. Example of base dissociation and its conjugate acid-base pairs
i. NH3(aq) + H2O(l) NH4+(aq) + OH-(aq) ; NH4+/NH3 and H2O/OH-
ii. CH3NH2(aq) + H2O(l) CH3NH3+(aq) + OH-(aq) ;CH3NH3+/CH3NH2 and
-
H2O/OH
iii. Equilibrium lies towards the left in all of the above such that value of Kb is always
small
f. Polyprotic acids are acids that can donate more than one proton. Each proton is donated
in successive steps. E.g. H2SO4 and H3PO4
g. Amphiprotic acids are acids that can either behave as an acid or a base. Amphiprotic
acids arise from polyprotic acids. E.g HSO4- , H2PO4- , HPO42- , HSO3-
4. The strength of binary acids (HX, where X is a halogen) can be determined by:
a. anion radius: the smaller the anion radius, the weaker the acid because of greater
attraction b/w H+ and X-. Greater attraction means more difficult to rip off the proton
b. bond energy: the greater the bond energy, the weaker the acid because it takes more
energy (thus more difficult) to rip off the proton
therefore, in the order of increasing acid strength: HF < HCl< HBr < HI
5. Self-ionization of water
a. Water is amphiprotic. By definition, it self-ionizes such that for each water molecule that
loses a proton, another water molecule gains it.
H2O(l) + H2O(l) H3O+(aq) + OH-(aq)
Base Acid Conj acid Conj base
b. Equilibrium lies far to the left as H3O+ is a stronger acid than H2O. This is reflected by Kw
(25oC) = [H3O+ ][OH- ] = 1.0 x 10-14
c. This value of Kw applies to pure water and all dilute aqueous soln
d. In a neutral solution, we expect [H3O+ ] = [OH- ] = 1.0 x 10-7M
e. An acidic soln has [H3O+] > [OH-] while a basic soln has [H3O+] < [OH-]. Refer to Fig 18.6
in the textbook
b. We can express the concentration of any quantity in this manner: pY = -log [Y], whatever
Y represents.
E.g. pOH = - log [OH-] pKa = - log Ka
pKb = - log Kb pKw = pH + pOH = 14.00 (how is this derived?)
2
c. Looking back at Kw
Kw = [H3O+ ][OH- ]
pKw = pH + pOH
- log Kw = - log [H3O+] log [OH-]
14.00 = - log10 (10-7) log10 (10-7)
= 7.00 + 7.00
= 14.00
3
8. Salts and salt hydrolysis
a. A salt is just an ionic compound. Salts completely ionize when dissolved in water. Thus,
ions are produced.
b. Most ions are capable of demonstrating acidic or basic properties when dissolved in
water. An acidic ion donates a proton while a basic ion accepts a proton. This is what we
call salt hydrolysis, the reaction of salt or ions in water.
ii. Compare the Ka and Kb values, the greater value is the prevailing property
If Ka > Kb , the salt is acidic. If Ka < Kb , the salt is basic
E.g. The salt NH4ClO has Ka (NH4+) = 5.6 E-10 & Kb (ClO-) = 3.6 E-7.
Therefore, this salt is basic
The salt NH4F has Ka (NH4+) = 5.6 E-10 & Kb (F-) = 1.4 E-11. Therefore,
this salt is acidic
4
10. Buffers
a. Buffers are solutions of weak acid and its salt (e.g. HF and F-) or weak base and its salt
(e.g. NH3 and NH4+)
b. Buffers resist changes in pH when small amounts of either acids (H+) or bases (OH-) are
added e.g. human blood. It can takes up acid and base w/o much change in pH
c. Therefore, the use of buffer is most useful when conducting experiments which require a
strict range of pH
d. A good buffer is such that the conj acid-base pairs are present in equal amounts
(equimolar). E.g. a soln of 0.5 M HF and 0.5 M F-
e. Buffer capacity: the amount of acid or base a buffer can neutralize before the pH begins
to change appreciably. Increased component amounts increases the buffer capacity.
f. How does a buffer work? All added H+ ions will react w/ A- to form HA. All added OH-
ions will react w/ HA to form A-
H+(aq) + A-(aq) HA(aq)
g. Thus, the formation of weaker conj pairs is able to maintain the pH of a soln
h. The pH of a buffer can be determined by applying the Henderson-Hasselbach eqn. This
eqn can be used for both types of buffer.
pH = pKa + log [A-]
[HA]
i. The pOH of a buffer soln can be determined by using the following eqn. This eqn can be
used for both types of buffer.
pOH = pKb + log [BH+]
[B]
j. Acid-base equilibrium calculation involving buffered solutions
Common questions are: What is the pH after the addition of strong acid/base and
change in pH of the buffered soln
To perform the calculations:
i. Keep in mind that small amounts of strong acid or base will completely
react with the buffer.
ii. Keep track of the new conc of buffer components
iii. Apply the Henderson-Hasselbach eqn to find the new pH
iv. Calculate the change in pH = pHfinal pHini
5
11. Acid-base indicator
a. An acid-base indicator is a soln of weak acid and its conj base that exhibit different
colors at different pH
b. Used in titration of acids and bases to signal the endpoint. The endpoint occur a few
drops after the equivalence point. Equivalence point is usually not accompanied by color
changes.
c. Need only to be familiar with phenolphthalein (best pH range 8-10) and methyl red (best
pH range 4-6).
d. Can choose any indicator for strong acid-strong base titrations, phenolphthalein for weak
acid-strong base titrations and methyl red for weak base-strong acid titrations.