Cc C @ Ar (awis base ic of New York at Binghamton, Department of Chemistry Chemistry 108, Introductory Chemistry I, Exam 1, February 25, 2010 Version A You have 90 minutes to complete this exam. Answer ALL questions. Fill in the appropriate selection on your scantron form. 1) At25°C, what is the pH of a 10.0 M HNO; solution? Qi Nitric Quick (6 a abrong acid ) 10 HNO, —> We + NOw oy [ 3 eo tovom' oe (oon S 2) For which of the following values of the equilibrium constant does the reaction mixture contain essentially products? @u0 | B) 10! one c) 10° @) 10! e) 10” ©, prodetts gounssed 3) Inthe reversible reaction HCQQ(ag) dQ — ey ay OH-(aq) Which are the Bronsted acids? bee a) HCOO” and HCOOH, b) HCOO” and OH ©) 20 and OF ayo and HCOOH 8) H,O, HCOOH, and OH™ 4) For the hypothetical reaction 2A +B — 2C + D, the initial rate of disappearance of A is 2.0 x 107 mol/(L - s). What is the initial rate of disappearance of B? a) 14% 10" mol/L: s) Ae trate 9 B b) 8.0.x 10? mol(Ls) 4 rate 1 ao 1.0 x 10 mol/(L- s) d) 1.4 10? mol/(L -s) * 10% mol((L- ; ek yale @ dicapprarente 2 5) Which ofthe following species cannot act asa Lewis base? x py-® we a) S™ : b) SH d) HO hon ©) HS A Leche one Axaniore® = rate. g g g /up kelp)” bn-0 ke= Ke 6) For which of the following equilibria does Ke = Ky? a) CO(e) + 3Ha(g) —= CHa(g)+H20(g) QY’n = 2-4 a> b). HBr(g) — Ha(g) + “Br.(/) b aes oS ¢) Na(g) + 3Hs(g) —= 2NHS(@) fs FE d) CaO(s) + CO2(g) CaCOs(s) Oo (308) H,0(@) —* COxg) +H) yan ‘ ©) ne hes 7) Which of the following statements is incorrect concemiing the addition of a catalyst to an equilibrium reaction system? a) The catalyst increases the rate of both the forward and the reverse reaction. ) Ifthe reactants are capable of forming many different products, a catalyst may selectively speed up one reaction over another. ¢). The catalyst speeds up the attainment of equilibrium. b The catalyst increases the yield of the products. ) The catalyst is not consumied in either the forward or the reverse reaction. 8) Atagiven temperature, a first-order reaction has a rate constant of 2.5 * 10° s". ‘The time required for the reaction to be 60% completed is a) 1208 (tw CAN __ yt (u Oy == IS KIB Xt b) 240s, ae 370s, ENS. be lnoy Cc D 4405. 0% Complited, #0 is remaining Sgr kto3e? ©) 5208, . £4665 9) Ina first-order reaction, the half-life is 144 minutes. What is the rate constant? £- 270 (2 xy (buses tore Imin = Gotee a. s B) 1.16 x 10%s? laponin = TS0€ uF OL 2 5990 A aes neuxbo = Qbuy0S e) 481 107s" 10) Predict which acid is the strongest. > Hoo ~ £lechOnngativily @ tee bh g) HCIOs Coutal atom 2) Hein — Nuinbee q ouyn atoms:11) Each of the following reactions is first order in each reactant and second order overall. Which reaction is fastest if the initial concentrations of the reactants are the same? All reactions are at 298 K. a) C102 + 0; CI0,+0, — k=3.0x 10"? em’ ‘molecules’ Rate = LLATS b) ClO; + NO CIO +NO> 3.4.x 10" cm*molecule"s™ Dad a )) CIO + NO Cl+NOz 1.7x 10" em’molecules* ae C— ) ClO + Or + ClO; +O; 1.5x 10" cm'molecules™ eI CBZ e) None of the above 1 12) Which expression correctly describes the equilibrium constant K; for the following reaction? 4NH,(g) + 502g) == 4NO(g) + 6H20(g) [N H,]+5[0,] Onto 6 Ro 1-0) po ede b) x 2880 ]estH.0] c Saasfo.) tnt |t £02 3 x Nolo “" [NaI[e.] 3 [yx] [0] 9) «Hot * [No Jo} 13) Rank HPO., HyPO,", and HPO,” in order of increasing acid strength, b 4 pervs a) HPO; < HPO, HPO?” < HPO. < HPO, ica = ] 1,00, eS @ HPOr HSO, > CH:COOH > HCN > HCO,” Which of the following is the strongest base? i: 10K co; Toe hong acd, Xo anja gate low iy W a «(von hk 3 chicos For Wis acid, He Conjugate ae wd J , a) so. : Meo <= Hot + C2 e) Br tos + Wad = Mal Grong Conjugs you aud oe 16) For the following reactién systems at 500 K I. 2NOCI(g) == 2NO(g) + Cla(g); Kp = 1.7 x 107 IL. 2NO3(g) === 2NO(g) + O2(g); Kp = 5.9 x 107 IIL 2$03(g) == 2S0,(g) + Oa(g); Kp = 1.3 x 10° ‘The reactions tendency to go to completion increases in the order Kp is lang , products yevoured Ib @ NOx(g); AH = 28.6 KI the rate constant is k= 4.64 x 10° s" at -3°C, and the activation energy is 53.7 kl/mol. What is the rate constant at 21°C? C Wy = 3% 2 0s a) 871x108s' = [Ua = ea) by)3.27 x 108s ‘wy. EN 4, ©) 4.64% 108 st \ a d) 5.05 x 10° s" ee 6470 . ) e) 3.96 x 10's! Fu xs Fy. (290 2%, 18) What is a conjugate acid-base pair for the following equilibrium? HOW + NE (oa) — NH,(aa) + H,0"(a) a) H,0 is an acid and H,0" is its conjugate base. ® NH," is an acid and NH; is its conjugate base. @) H,0 is an acid and NHb is its conjugate base. B 4) HO is a base and NH; is its conjugate acid. ¢) Hi, is a base and NH." is its conjugate acid. 19) The concentration of HO" in a solution is 8 x 10% M at 25°C. What is its hydroxide-ion concentration? a) 8x 10°M . b) 1x 10° M oe yO" S = ~ho 10 it We lag Qaypth = log 8x : = ©) 2x 10M ‘ f= d) 2% 107M = 3 1x10" M Wow + 96" = P i el (Od: por: |4 7 “pote = [oy Cond 4 CS owy= pe = prexion! Mm20) Which of the following reactions is not an example of homogeneous catalysis? a) 2H20,(ag) => 21,01 + 04g) homoprrous Nag) + 3Hx(@) —22> antn(g) Wutrogentors Hag) 2 ©) CHsCO:CH;(ag) + H0() ——“2-> CH;CO;H(aq) + CHOH(ag) omeqone us OD d) 20;(g) “> 30,9) rom oganeous se (a ©) 8:05? (aq) + 20 (ag) —=—“2-> 2802-(ag) + 1x(aq) Yo noqened 4s 21) Which of the following statements is correct concerning the neutralization of sulfurous acid by a strong base? 20H (aq) + HSO,(aq) > $O3* (ag) + 2H20(1) a) HySOs is an Arrhenius acid, but not a Bronsted-Lowry acid. Hp, increases @ H,S0 is a Bronsted-Lowry acid, but not an Arrhenius acid. pbvosiong HD" y H,SO3 is both an Arrhenius acid and a Bronsted-Lowry acid. t Cc HpSOs is neither an Arrhenius acid nor a Bronsted-Lowry acid. |}, (0, (an dowete ©) H,S0; is a Lewis base. * etaton + g 22) The following data were obtained for the hypothetical reaction {{ £04 0 > 1,07 + u 2A + B— products. oS vy, tf {Ah [Blo(M) Initial Rate (M/s) 0.2 OL 5 4 02 02 20 Dote = CAT LRI™ 06 on 45 ee ‘What isthe overall order ofthis reaction? wCayr L9d " c 20 A ( a) 0 > b) 1/2 1 / 3 an =H ed n= 2 23) Consider the following equilibrium at 25°¢: OV®VAKl ovder - yy g 4 Hook + 2ICKg) —= h(g) + Ch(g); AH = 27 kJ; Kp = 6.2 10° Which of the following would be true ifthe temperature were increased to 100°C? Endotuerme he . (The value of Kp would increase. clnerensing temperature ¢qpuilubrien °%. The concentration of ICl(g) would increase. Bbigk ty Ha right The partial pressure of I; would increase. (i a a) Lonly b) 2only c) 3only d) 1 and2 only (©) and 3 onlyC- 24) A second order reaction A + A — products has a rate constant of 2.0 x 107 ‘L/(mol - s). If the initial concentration of the reactant is 0.340 mol/L, how long will it take for the concentration to become 0.170 mol/L? a) 35s b) 74s Ore 1500s e) 350s At equilibrium, the mixture will contain which of the following (u Less than 1 mol of CHsOH B) 1 mol CH;OH ©) More than 1 mol CH3OH but less than 2 mol 4) 2 mol CH;0H e) More than 2 mol CH;0H 26) At 0°C, the ion-product constant of water, Kw, is 1.20 * 10". What is the pH of pure water at 0°C? a) 7.000 b) 7.560 c) 6.880 d) 7.460 2a thd Pay > KE te 4706 25) A mixture initially consisting of 2 mol CO and 2 mol Hy comes to equilibrium with methanol, CH;OH, as a product: CO(g) + 2H2(g) <—» CH3OH (g) kas = SHOACOH-T u ee pepoxi® @) none of these Ke Yt 27) What is the hydroxide-ion concentration in a solution formed by combining 200. mL of 0.16 M HCI with 300. mL of 0.091 M NaOH at 25°C? (Kw = 1.0.x 10") HCl(aq) + NaOH(aq) + NaCl(ag) + H,0()) iy) Li x 107M Melee g fet = DALY OYEM = O10 SQDF miley \px (° sig eq =IGOe y bet be be lets Ahan 4 {Ciao 1 xo Ka ZAG HOF = GrPeGes pls log © Cue. pie -loy Eerie = t46 a2 wl b) 16 x 10P MMOL g NOOR = orgie vom ©) 10x 107M MOS oF LCL camaining Unvescked = (7032-00973 )0.055M— Malovity g HOt o = 0:004 Moly ©) 0.091 M Ria (oe coke ee ose Cee edatee hen / won ee = (HON COWT 28) Equilibrium is established at 1000K, where K. = 281 for the reaction : 280r(g) + Ox(g) —= 2S0s(2) Por] = Lori The equilibrium amount of O,(g) in a 0.185-L flask is 0.00247 mol. What is the ratio of [SOs] to [SOz] in this equilibrium mixture? a) ) - °) 1.27 4.66 1.94 2.89 0.73 CLsosh = (3465 CERIN oa Co foonnt £05"| = 0.0004 Fmt = hq ogee Q-0134M Uc (Oe\ = 29/x ory) = 2ISR 629) Given the equilibrium constants for the following reactions: ACu(s) + O2xg) —= 2Cu20(s); Ki 2CuO(s) —= Cur0(s) + 402(g); Ko ‘What is K for the system 2Cu(s) + Or(g) === 2CuO(s) equivalent to? a Ki xXK b) (Ka) AK) Sj QD Kk) a (&)"MK) °) (Kia) 30) The rate law for a reaction is found to be Rate = K{A}*[B]. Which of the following © ® In, mechanisms gives this rate law? Glow Leg «He take dletewming thee i A+B <— E (fast) E+B—>C+DGlow) Dots -KfeE3 et I. A+B — E (fast) Ki CAWlRI = KaCES E+A—>C+DGlow) CES= h CalCOI > 1 = =A+A>E(slow). a y-lire i n-kead E+B—C+D (fast) fate = Ku carcnt™ only : a Ionly a — 2 ©) ‘Monly T: Date = W rs | le d) — Twoof these “Wy C440 Bt = Ve eT] fel- 4 ©) None of these [Dose = [ety Enrces\ Ie. 31) A and B react to produce C according to the chemical equation: oe mee Amounts of A and B are added to an equilibrium reaction mixture of A, B, and C so that when equilibrium is again attained, the amounts of A and B are doubled in the same volume. How is the amount of C changed? a) Concentration of C is tripled b) Concentration of C is doubled @ ©) Concentration of C is quadrupled ® Concentration of C remains the same e) None of these Ke is Constant - ke a6} x£c3 eb Sauces «a Lag 0.094 actd ivnigas Completely Wel > Weg, * Coy, Use this information to answer question 32 and 33. EM male Co.kio ‘A solution was prepared by dissolving 0.300 L of HCI(g), measured at STP (0°C, 1 atm), in enough water such that the total volume of the solution is 2.50 L. (R= 0.0821 L- atm/(K - mol)) 32) What is the concentration of hydronium ions (H;0°) in the 2.50 L solution? a) 0.0189M a4 Cc 4 Re N= 10302 = OOlTA mls d) (0.0457 M OUR aI x RTS . oan Nulavity = groiartiley 2 p-008 36 | 33) What is the pH of the 2.50 L solution? — a) (babys argo & 2271 11.729 : | 2% 2 7.000 pl - lo cyt = — toy oons3s DO 2) 1.873 Use this information to answer question 34 and 35. Dinitrogen tetroxide decomposes to form nitrogen dioxide in a second-order reaction: 1 $ Dea rako N204(g) — 2NOx(g) ‘At 400.0 K, the rate constant for this reaction has been measured to be 2.9 x 10° Li(mol - s). Suppose 0.639 mol of N:O4(g) is placed in a sealed 17.8-L container 03m at 400.0 K and allowed to react. i= initioh O-b39euls5, 34) What x concentration of N20.(g) after 2.28 x 10° s has elapsed? (@) 0.0290 M a uke ek Deore it EN O44 © CNP) i QoeniM ghp.q Ban DMEMT ELL = Dae Hee 2) oogsmM >t OOUIM Cheba = 0-02%0b 35) What is the total pressure inside the vessel after 2.28 x 10° s has elapsed? Cee twitiat CNeDu] = 0'03S9M 94 at b) 0.953 atm rurcaining ON204T = D/O 90M oc) 148atm GN 04 Consumed 00 3EGM- 010 290K oe = 01 00684M Al atm pontSourstion ENO Aker aaevwte = ax or00bO9 36) Consider the endothermic reaction? ——~—___ = 0-012gM \noat + Nog) + Ox(g) —=2NO(g) AH = +180 kK) - A . ! - . v _ ‘At 2000 K the equilibrium constant is 5.0 x 10%. At 2500 K the value ofthe [J = M PL Enon equilibrium constant Ne WO28 GD Is greater than 5.0 x 10% Fotad Moloviky coro 240 1010138 Altctve Lcot is By Isles than 5.0.x 10%. Oy eS oo 4seM ococtant. 9) 185.0x10* — CEngavsemic 1% ny : Paes Coe e, = DOH HORI KA06 FOiSieg Aemporetuara sqpildbriven Slijt te tha iqhs | = IA 06 adm, Unereacing do produ ets, NOg, .