ORGANISATION OF SAFETY + ENVIRONMENT SPE-EPS 1/4

PRODUCT/SAFETY-SPECIFICATION VERSION: 3
PRODUCTNAME: Rev.date: 24-sep-2007
ELECTROLYTIC POLISHING SOLUTION

1: Identification of the product and the company

Company: Dentsply Austenal, Dentsply International Inc, 570 West College Avenue, P.O. Box 872,
York, PA, 17405-0872, USA, Tel.: +1 717-845-7511, www.austenal.dentsply.com.
EU-representative: Elephant Dental B.V., Verlengde Lageweg 10, 1628 PM Hoorn, Netherlands,
Tel.: +31/229-259000, www.elephant-dental.com.
Trade name: Electrolytic Polishing Solution
Product group: Consumables
Use of the product: Electrolytic polishing of cobalt-chromium alloys
Contra-indication: Do not use in the mouth
*Packaging: Bottle of 1 liter
Art. nr.: 8046001

2: Composition / Information on ingredients

Hazardous ingredients: CAS-nr. Symbol R/S-phrases Weight %
Ethylene Glycol (C2H6O2) 107-21-1 Xn R 22 78 - 83 %
Sulfuric Acid (H2SO4) 7664-93-9 C R35 17 - 22 %
Calcium Hypochlorite (CaCl2O2) 7778-54-3 O, C, N R 8-22-31-34-50 < 0.5 %
Triton X-45 - - - < 0.1 %

3: Hazard identification
Inhalation: Damaging effects on the mucous membrane and upper respiratory tract. May cause lung
edema, nausea, vomiting and drowsiness
Skin: Corrosive, redness, pain, severe burns can occur.
Eyes: Corrosive, material can cause blurred vision, redness, pain and severe tissue burns. Can
Ingestion: Corrosive, material can cause severe burns of the mouth, throat and stomach. Large doses will
cause vomiting, diarrhea, rapid respiratory and heart rate, leading to collapse and
unconsciousness with convulsions. Death from respiratory arrest or cardiovascular collapse
may follow.
Carcinogenicity: Inadequate data on which to classify in terms of carcinogenicity in humans and/or animals
Medical conditions
aggravated by exposure: Pre-existing skin disorders, eye problems, impaired liver, kidney or respiratory function.
*Potential environmental
effects: Acids are harmful for ground water

4: First aid measures

Inhalation: Remove to fresh air; if necessary give artificial respiration or oxygen. Contact a physician.
Skin: Immediately flush with plenty of water, remove contaminated clothes. Residual acid can be
neutralized with 2% NaHCO3 (sodium bicarbonate solution). Contact a physician.
Eyes: Flush with plenty of water including under eyelids. Contact a physician.
Ingestion: Contact immediately an emergency medical center
Other: -
*Special first-aid remedies: Eye washing device
Remarks for the physician: -

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 ORGANISATION OF SAFETY + ENVIRONMENT SPE-EPS 2/4
PRODUCT/SAFETY-SPECIFICATION VERSION: 3
PRODUCTNAME: Rev.date: 24-sep-2007
ELECTROLYTIC POLISHING SOLUTION

5: Fire fighting measures

Explosive limits in air:
Auto ignition temperature:
Flammability classification:
Extinguishing media:
Unusual fire and explosion:
hazards:
Protection and procedures
for firefighters:
Ethylene glycol: 3.2 - 53vol%
Ethylene glycol 398C / 748F
1
Dry chemical, foam, carbon dioxide (CO2). Do not use water on material. Product will react
with water releasing chlorine gas. Do not use dry ammonium compound or carbon
tetrachloride type extinguishers.
Liquid will react with most metals to yield flammable hydrogen gas. Use care not to ignite
hydrogen gas. Toxic gases and vapors may be released if involved in fire.
Wear fully protective clothing, including rubber gloves, chemical suit, rubber protective
footwear and self-contained breathing apparatus with full face piece, operated in the positive
mode.

6: Accidental release measures

Personal precautions: Appropriate personal protection equipment, keep unprotected persons at distance.
Environmental precautions: Isolate spill area, neutralize with 2% NaHCO3 (sodium bicarbonate solution), do not flush into
sewer. Absorb spill with sand or universal binder, place in chemical container for disposal.
Containment techniques: Absorb spill with liquid-binding material (e.g. sand, universal binder, diatomaceous earth).
Evacuation procedures: -
Reporting requirements: Report to national and/or local authorities when material is entered into the sewage system or
soil.

7: Handling and storage

Handling practices and
warnings : Avoid any eye or skin contact. Wash thoroughly after handling. Do not smoke, eat or drink.
Storage practices and Store in a cool and dry location. Keep bottles tightly closed. Do not store with oxidizing,
warnings: and caustic materials.

8: Exposure control and personal protection

PEL ethylene glycol:
*TLV ethylene glycol:
PEL sulfuric acid:
TLV sulfuric acid:
Personal protective
equipment:
Respiratory protection:
Eye protection:
Skin protection:
Hygienic measures:
50 ppm
127 mg/m3
1 mg/m3
0.2 mg/m3
Good ventilation at the workplace. Eye wash station in the immediate work area
No special requirements if exhaust hood is used
Safety glasses or safety goggles or full face shield
Wear protective work clothing
No eating, drinking or smoking at the workplace. Wash hands after work and before breaks.
Observe the usual precautionary measures regarding the handling of chemicals

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 ORGANISATION OF SAFETY + ENVIRONMENT SPE-EPS 3/4
PRODUCT/SAFETY-SPECIFICATION VERSION: 3
PRODUCTNAME: Rev.date: 24-sep-2007
ELECTROLYTIC POLISHING SOLUTION

9: Physical and chemical properties

Form: Liquid
Color: Clear, yellow
Odor: Odorless
pH: 0.2
*Boiling point/-interval: > 195C / > 383F
Melting point/-interval: N.a.
Flashpoint: 111C / 232F
*Auto ignition temperature: 398C / 748F
Vapor pressure: N.a.
Density: 1.24 g/ml
Solubility in water: Completely

10: Stability and reactivity

Conditions to avoid: Moisture
Materials to avoid: Water, strong oxidizing and reducing agents
Hazardous decomposition
products: Carbon dioxide, carbon monoxide, oxides of sulfur, chlorine gas
Hazardous polymerization
possible: Yes No
Stability: Good
Additional information: -
*Shelf life: 1.5 Year

11: Toxicological information

*Acute oral toxicity:
*Acute dermal toxicity:
Inhalative:
Skin irritation:
Eye irritation:
Ingestion:
Chronical effects:
LD50: 4700 mg/kg rat (ethylene glycol)
LD50: 2140 mg/kg rat (sulfuric acid)
LD50: 9530 mg/kg rabbit (ethylene glycol)
LC > 510 mg/m3/2h (rat) (sulfuric acid)
Irritant
Irritant
Irritant
Irritant
Reproductive and mutagenic effects have been observed on tests with laboratory animals.
Ethylene glycol may cause central nervous system effects, stimulation followed by depression.
Causes kidney damage which can be fatal Exposure may also result in damage to eyes,
cardiovascular system or liver.

12: Ecological information

Persistence and degradability: Biodegradable
*Water toxicity: Class 1
Ecotoxicity effects: -
Accumulation: None

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 ORGANISATION OF SAFETY + ENVIRONMENT SPE-EPS 4/4
PRODUCT/SAFETY-SPECIFICATION VERSION: 3
PRODUCTNAME: Rev.date: 24-sep-2007
ELECTROLYTIC POLISHING SOLUTION
13: Disposal considerations
Product: Consult state, local or national regulations to ensure proper disposal
Uncleaned packaging: Clean with water. Consult state, local or national regulations to ensure proper disposal
Recommendation: Consult state, local or national regulations to ensure proper disposal

14: Transport information

UN nr.: 3264
Technical name: Corrosive liquid, acidic, inorganic, n.o.s. (contains sulfuric acid and ethylene glycol)
LQ nr. for packing-units: LQ 22

Land transport ADR/RID/GGVSE (Germany)

ADR/RID class 8
Packing group II
ADR/RID label 8
Danger code 80

Sea transport IMDG/GGVSee

Proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (contains sulfuric acid and ethylene
glycol)
IMDG-class 8
Packing group II
EmS-code -
Marine pollutant: -

Air transport ICOA-TI/IATA-DGR

ICOA/IATA-class 8
Packing group II

15: Regulatory information

Labeling according to EU-directives (2004/73/EG or) 2001/60/EG.
Symbol: Xn, C
R-phrases: R22 Harmful if swallowed
R 35 Causes severe burns
S-phrases: S 13 Keep away from food, drink and animal feeding stuffs
S 26 In case of contact with eyes rinse immediately with plenty of water and seek medical
advice
S 28 After contact with skin, wash immediately with plenty of water
S 36 Wear suitable protective clothing
S 39 Wear eye/face protection
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible)
*Additional information: UN 3264

16: Other information

This safety data sheet is according EU-directives 91/155/EEG, 93/112/EG and 2001/58/EG.
Changes since the last version are highlighted with *. This version replaces all previous versions.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other materials or in any process,
unless specified in the text.

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