ENTHUSE, LEADER & ACHIEVER COURSE

(ALL PHASE)
TARGET : AIPMT 2015
FULL SYLLABUS
MAJOR TEST
DATE : 10 - 01 - 2010
ALLEN RE-AIPMT DATE : 27 - 06 - 2015
ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 2 2 4 1 3 4 2 2 1 1 3 2 2 3 2 1 2 4 2 3
Que. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. 2 4 1 2 3 2 4 3 3 3 2 1 4 4 2 1 B 3 1 2
Que. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 3 3 2 4 2 3 2 2 4 4 4 1 1 1 2 1 4 3 3 2
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
Ans. 4 2 1 2 3 2 3 1 1 2 1 3 2 1 4 2 2 4 1 3
Que. 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
Ans. 3 2 3 2 2 1 4 1 2 3 1 2 1 3 1 4 2 3 4 4
Que. 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
Ans. 4 1 3 4 2 4 1 2 1 2 3 3 4 3 1 1 4 3 4 4
Que. 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140
Ans. 3 1 4 1 2 2 3 2 1 3 2 2 2 4 3 3 3 2 3 3
Que. 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160
Ans. 3 4 3 3 4 2 3 1 1 1 3 3 1 3 2 2 3 2 3 3
Que. 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180
Ans. 3 2 3 2 2 4 4 1 4 3 1 4 4 1 2 1 3 3 3 2
HINT SHEET
1. 12 3 2He4
6C
The energy required for this process is given by
3.
Q = [3 MHe MC]c2
Q = [3 4.00388 12]u c2

MeV
Q = (0.01164 u) 931.5 = 10.842 MeV
u i same

2. The ratio of number of nuclei of X1 to that of X2

(
r 10-2 ) r
Rsmall = 10-2 t =
after time t is N = e
1 N 1 ( ) t
2

r1 r
N 0 e -6 lt 1 Rbig = = = Rsmall
\ = 1 t t
N 0 e -3 lt e
V = iR & H = i2Rt0
1 1 1
or 3 lt
= 3lt = 1 \t=
e e 3l

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L
FCB = BI (sin 180) = 0
2

BIL 3
4. FAC =
2
r r r
FAB + FAC + FCB = 0
when key open when key closed
3R 4R r r r 3BIL
Req = Req = FAB = -FAC FAB = e
2 3 2
2V 3V
i0 = iC = d d d
3R 4R = +
8. 2 2 2 1.5
5. Electric field towards the right
(High potential W4 = W3 > W2 = W1 to low
= 1.67
potential)
f0
9. = m f0 = 14 5 = 70cm
fe
0I
6. B due to outer loop = 4 (sin 45 + sin 45) L = f0 + fe = 75 cm
4p L
2 10. V = V1 + V2 + V3

0I 1 Q 1 -2Q 1 3Q
= (2 2) = + +
4 pe0 R 4 pe 0 R 4pe0 R
pL
Flux linked with smaller loop = B.A
1 2Q
(Assuming B as uniform since l <<<< L) =
4pe0 R
0I 11. Magnetic field in first quadrant at point (x, y)
f= 2 2l2
pL
r mI m ( 3I ) r
B= 0 e+ 0 = 0 x = 3y
f 2py 2px
As f = MI So M =
I 12. Here PA = PB and FB > FA
so piston will move towards right.
2 2 0 l 2
So M= 50
pL
13. For (A ) : a = = 25ms2, contact force
1+ 1
7. By right hand palm rule
between A and B = 1 25 = 25N
For (B) : For system, reaction given by
A ground = 20 + 30 = 50N
30
L
For block A reaction between A &
Lcos30
i B = 50 10= 40N
C B
For (C) : For motion of A, NAB 10 = 1 25
Lsin30
NAB = 35N
For (D) : For motion of A, NAB = 1 35
r
direction of Fm is inward for AC & outward for AB = 35N
Now
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2 c 3 108
14. I=
E , E1 = 1 C1 ER1 , vm = =
m 52 / 25
R1 + R 2 2 R1 + R 2
13 (52 / 25)
Time taken = 9 10 -8 s
1 ER 2
2
E1 R12 C1 3 108
E2 = C2 =
2 R1 + R 2 E 2 R 22C 2 1
21. mv 2 = pv 2 m = 2p
2
15. In constant acceleration motion distance trav-
1 2
elled in consecutive seconds are in ratio kx = qx 2 k = 2q
2
1:3:5:7:9.....
16. Given circuit can be reduced to m p
Therefore T = 2 p k = 2p q
R
A B 22. Q (EC - EB) + (EB - EA) = (EC - EA)
dv n hc hc hc ll
17. Here, acceleration = v =kx , where k is = + l3 = 1 2
dx l 3 l1 l 2 ;
l1 + l 2
v2 x n +1 n +1

a constant. \ = k or v x 2
2 n + 1

Power P = Fv ( x n ) x ( ) =x
n +1
2
3n +1

2

.
3n + 1 23.
For P to be independent of x, =0
2
Dx=0
1 Dx=l Dx=2l
or n = Dx=3l
3 S1 S2
Dx=4 l Dx=4l
18. For any body momentof inertia is minimum 4l
about its centre of mass.
Dx=0
2 2
For sphere Imin = MR 2 so I MR 2
5 7 Where Dx = Path diffrence
19. At minimum deviation QR must be parallel 10V
to base of the triangle. 24. ( V0 )max = = 5V
2
A B Y
5 53
20. sin q = air 0 0 1
13 P
25. Y =A+B 0 1 1
medium
12m q 13m 1 0 1
Q 1 1 0
5m
So, output is zero when both inputs are one. In all
m sin q = (1) sin 53
other cases output is one.
5 4 52 26. qin = q1 + q2 + q3
m = m =
13 5 25 ur ur q r r r r r
and E.dA = in where E = E1 + E 2 + E3 + E 4
e0
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dU e2
27. F =-
dx

dU
For equilibrium =0
dx
1/ 6 e1
-12a 6b 2a
13
+ 7 =0 x=
x x b e max = e12 + e 22
rr
28. W.D. = F.S = (5i + 3j).(2i - j) = 7J
e max e12 + e 22
e rms = =
29. The magnetostatic field line and induced electric 2 2
field line can form closed loops. 32. P2V = constant
Hence correct options are (b) & (d). 2
RT
30. In the absence of external torque, angular V = constant
momentum remains conserved. V
Here we first obtain the expression for angular V T2 T V1/2
speed w in terms of angular momentum L
T (3V )1/ 2
T = V1/ 2 = 3
0
L = Iw ...(i)
0 0
Since moment of inertia depends on the radius of
the sphere and hence the volume of the sphere. T = 3T0
DI Dw 33. m1C1(TT1) = m2C2(T2T)
So =- C1 (305 293) = C2 (313 305)
I w
C1 2
Dw 2 DR C1 12 = C2 8 =
=- C2 3
w R
as I R2 r r
34. By COLM p i = pf
since R V1/3 r r
Initially momentum p i = 0
Dw 2 DV
So =- So to make final momentum zero particle C should
w 3 V
move along direction BG with speed v.
dw 2 35. Maximum energy stored in capacitor
\ 100 = 1% = 0.67%
w 3
Q2
31. As <Sinwt> = <coswt> = <sinwt coswt> = 0 U max =
2C
1
and <sin2wt> = <cos2wt> = The energy is stored equally in electric and
2
magnetic fields.
so rms of 'e'
So energy in electric fields
= < e2 >
1 Q2
= < e12 sin 2 wt + e 22 cos2 wt + 2e1e 2 sin wt cos wt > E=
2 (2C)
e12 e 22
= + +0 Q2 1 Q 2 Q
2 2 Now = Q =
2C 2 2C 2
e12 + e 22 36. P = hrg
=
2
P 2000
h= =
rg 1.06 103 9.8 = 0.193 m ; 0.20 m
or
by phasor method

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13.6 Z 2 dQ kA
38. En = - eV 44. = Dq
n2 dt l
For ground state, n = 1 ML2 T -3 L
\ [k] = = MLT -3 q-1
E 1 = 13.6 Z eV
2
L q
2

Here, E 1 = 122.4 eV 1 1 1 1 6K
= + +
\ 122.4 = 13.6 Z2 45. K eq 3K 2K K Keq = 11
or Z=3
r = (t2 4t + 6) + t2 j r = (2t 4) +2t j m 11m
39. r i v i \ T = 2 p K = 2p
r eq 6K
and a = 2 ( i + j )
r r MgCl 2 Mg2+ + 2Cl-
when a ^ vr then a vr = 0; t = 1s
48.

40. FBD of block MgSO4 Mg2 + + SO 24-

(i) chloride ion in solution = 0.6 mol
f \ 0.3 mol MgCl2 is present in solution
(ii) sulphate ion in solution = 0.2 mol
ma N \ 0.2 mol MgCO4 is present in solution,
(iii) \ Mg+2 ion in solution = 0.3 + 0.2 = 0.5 moles
mg 49. Si-metalloid, Ga-metal F, N, C - non metal
50. No. of sterocentres =4
Here f = mg, N = ma No. of possible steroisomers = 2n = 24 = 16
But f mN h h
51. l1 = , l2 =
2me 50 2me 200
g
So mg mma a m l1 200 2
\ = =
l2 50 1
B 52. order of IP - 2 < 4 < 3 < 1
2v
53. + 3H 2 2NH 3
v v2 N2
41. A v initial 2mol 6mol 0
v
At eq m
2 -1 6-3 2

[ NH3 ] =
2
4 4
\KC = =
[ N2 ][ H2 ] 1 27 27
3

vB 2v 2
= = 54. Conjugate base is more resonance stabilized
vA v 2 1
55. MgO > Al2 O3 > SO 3 > Cl 2 O 7 : basic nature
42. For maximum level of water in tank basic amphoteric acidic

A1u1 = A2u2 Cl
OMe CH3
56.
A
A4= 2gh > > >
2
+ve charge at bridge
64 stabilized by stabilized by Destabilized
h= = 3.2m +M of OCH3 H-effect of CH3 by -I of Cl head C-atom
2g
57. In CuSO4.5H2O
l (i) Ionic bond [Cu+2 & SO42]
43. = 0.1 l = 0.2 (ii) Coordination bond [Cu+2 & H2O]
2
(iii) Hydrogen bond [SO42 & H2O]
v 1450
f= = = 7250 Hz
l 0.2
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1 1 68. Transfer of hydride ion (H) to second molecule
58. pH = 7 - pK b - logC is r.d.s. This tendency is inhanced by electron
2 2
donating groups (OMe shows +M)
1 1 70. KMnO4 + conc. HCl MnCl2 + Cl2
= 7 - 12 - log 0.1
2 2 H+
KCl + K2Cr2O7 CrO2Cl2
= 7 - 6 + 0.5 = 1.5
MnO2 + conc. HCl MnCl2 + Cl2
\[ H + ] = 10 -1.5 KCl + F2 KF + Cl2
= 10 0.5 10 -2 = 3.2 10 -2 M 71. [Ni(en)3]2+ is more stable than [NiCl6]4 due to
chelation effect of ethylene diamine
59. CO = 3.0, NO = 2.5, N2 = 3.0, NO+ = 3.0, NO
= 2.0, C6H6 = 1.5, ClO2 = 1.5, HCOO = 1.5, BO3 72. (a) D 0 Cr +2 < Cr +3 (b) D 0 H 2 O < CN -
3
= 1.0, ClO3 = 1.6, CO32 = 1.33
(c) D 0 3d < 4d < 5d (d) D 0 Ni+2 < Ni +4
61. 1.C2, O22 and Li2 all have zero unpaired electron
74. (a) Van Arkel Method - Ti, Zr
2. Bond order of He2 molecule = 0 (b) Solvay Process - manufacture of Na2CO3
O O
62. CaOCl2
+ CHCl3
(c) Cupellation - refining of Ag form Pb
C CH3 C O
H2O
Ca (X) (d) Poling - refining of Cu form Cu2O
Cl2 hv
C O
NH2
75. (i) NH3 + Hg2Cl2 Hg + Hg
O CCl4 Cl2
(Z)
(Y)
(fire extinguisher)
-CaCO3 dry distillation (ii) Zn +2 + NaOH Na 2 [ Zn ( OH )4 ]
( )
excess ( so lub le )

O (iii) 'AgF' soluble in water

C
(iv) ( NH 4 )2 Cr2 O 7
D
N 2 + Cr2 O3
(product)
NH4 NO3 N 2O + 4H 2O
Cl Cl
77. Moles of KMnO4 Vf = moles of FeC2O4 Vf
63. (BeCl2)2 Be Be Be = 6 e
3
Cl Cl moles of KMnO4 5 = 1 (1+21) =
5
AlF3 is a ionic compound 79. When AB interactions are stronger than those
64. Na2B4O7.10H2O = Na2[B2O5(OH)4].8H2O between AA or BB then these type of solutions
will show negative deviation from Raoult's law
OH and form maximum boiling azeotrope.
O
B
O 81. 1
O N 2O 5 N2O4 + O2
H O B B OH 2
2Na+ O
B
O
After 20 sec 114m 0 0
OH
P
114 - P P
Two boron atom sp3 and next two boron atom sp2 2
hybridised. P
total pressure = 133 = 114 +
CH3 2
\ P = 38 mm
65. both the groups are electron donating -dP - ( 76 - 114 )
Rate reaction = =
OH dt 20
i.e. why benzene ring has highest electron density = 1.9 mm/sec
in this compound. = 2.5 103 atm sec1
66. (1)SO2 + O3 SO3 + O2
82. DH 0 = SDH f0 ( products ) - SDH f0 ( reactants )
(2) Only diamond and graphite have dangling
bond =[(110.5) + (241.8)] [393.5+0]
(3) Cl2 + NH3 (excess) NH4Cl + N2 = 352.3 + 393.5
(4) Br2 + NaOH (hot + conc.) = +41.2 kJ
NaBr + NaBrO3 + H2O.
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85. Ph3CCl is formed. Ph4 C is not formed due to 1 4 5 . NCERT Pg. # 279
steric hindrance. 146. NCERT Pg. # 279 fig. 18.1
86. Conjugate acid of guanidine is most stable due to 147. NCERT Pg. # 309
three equivalent resonating structure.
148. NCERT Pg. # 263
NH2 : NH2 152. NCERT Pg. # 130-131
+
.. H .. 153. NCERT Pg. # 127
H2N C NH H2N C NH2
Guanidine 154. NCERT Pg. # 284
conjugate acid 156. NCERT Pg. # 168
157. NCERT Pg. # 296
.. 158. NCERT Pg. # 295
NH2 NH2
.. .. 160. NCERT Pg. # 46,47,53,55
NH2 C NH2 H2N C NH2
161. NCERT Pg. # 325 fig. 21.7
three equivalent resonanting structure
162. NCERT Pg. # 153
164. NCERT Pg. # 151
E 108
87. W= It = 1.25 10 -3 15 60 168. NCERT Pg. # 136
F 96500 169. NCERT Pg. # 47
= 1.259 103 g
170. NCERT Pg. # 54
1.259 10 -3 1 171. NCERT Pg. # 49, 50, 51
Ag + =
108 0.1 172. NCERT Pg. # 112
= 1.16 10 M
4
173. NCERT Pg. # 272
89. 29 mL of 0.2 N H2SO4 neutralize 29 mL of 0.2 174. NCERT Pg. # 274
N NH3 175. NCERT Pg. # 335
29 0.2 14 176. NCERT Pg. # 333
29 mL of 0.2N NH3 contains gN
1000 177. NCERT Pg. # 304
29 0.2 14 179. NCERT Pg. # 50
% of N = 100 = 16.2% 180. NCERT Pg. # 63
1000 0.5
CH 3COO -
CH 3 COOH + H+
90. (
In ab. of HCl C 1 - a ) Ca ( Ca )
In Pr. of HCl C (1 - a ) C a ( Ca + 0.01)

( Ca )( Ca + 0.01)
1.69 10 -5 =
C (1 - a )
1.69 10 = 0.01 a'
5

\ a' = 1.69 103

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