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Total Number of Pages: 29 including this cover page and without Appendix
1. PURPOSE ........................................................................................................... 6
1.1 General issue...................................................................................................... 6
1.2 Purpose .............................................................................................................. 6
2 SCOPE ................................................................................................................ 6
2.1 Interdependence with Management Plans .......................................................... 7
2.2 Revisions of Method Statement Documents ....................................................... 8
3 ROLES AND RESPONSIBILITIES ..................................................................... 8
4 EQUIPMENT AND MATERIALS USED .............................................................. 8
4.1 Equipment used .................................................................................................. 9
4.2 Material used ...................................................................................................... 9
5 QUALITY ASSURANCE / QUALITY CONTROL ................................................ 9
5.1 Handling and Storing of Materials ....................................................................... 9
6 HEALTH, SAFETY, ENVIRONMENT .................................................................. 9
7 JOB HAZARD ANALYSIS ................................................................................ 10
8 METHODOLGY ................................................................................................. 10
8.1 Temporary Works ............................................................................................. 10
8.2 Operation .......................................................................................................... 10
8.2.1 Introduction .................................................................................................... 10
8.2.2 Bi-component grouting system ....................................................................... 11
8.2.3 Mix Design ..................................................................................................... 24
8.2.4 Maintenance table ......................................................................................... 25
8.2.5 Secondary grouting ........................................................................................ 26
Employers
002 Qatar Rail
Personnel
Director Tunnel
004 PSH
Works
Project Manager
005 PSH
TBM
008
009
010
* The final distribution may be modified after consultation with Qatar Rail.
This document was composed exclusively for the Qatar Railway Green Line Project. All the
requirements listed in the above referred contract document were taken into account. All the
PSH JV companies have Quality Management System Certificate of ISO 9001: 2008,
Certificate of ISO 14001: 2004 of Environmental Management System. Furthermore all the
parties apply the BS OSHAS 18001: 2007 on Occupational Health and Safety Management
System.
1.2 Purpose
The purpose of this Method Statement is to demonstrate the approach and procedures to be
followed to execute Grouting works of Segmental Lining in a safe manner to an approved and
controlled methodology to demonstrate a thorough and considered understanding and
approach, all in accordance with applicable standards, codes of practice and project
specifications. It also highlights dependencies on other MSs before the Grouting of Segmental
Lining can be executed. The Job Hazard Analysis in Appendix 2 identifies the hazards and
the safe systems of work to be followed when conducting the activity
2 SCOPE
Scope of this MS is the execution of Grouting works of Segmental Lining at all tunnels. This
process follows those described in MS for Tunnel Excavation Methodology (TBM) and Fire
Hazard.
This document includes the following either in the main body or in the Appendices:
Note: DVE verified Construction Drawings will be in place at the time of starting the works.
Specifications:
Title Code Status
Concrete Mix Designs Grade C50 M008-PSH-PMT-MAR-00088 D (NOWC)
Annulus Grout M008-PSH-PMT-MAR-00362 C-SONO
Specification - Concrete Structures M008-PSH-STR-SPE-00001 Submitted
Materials and Workmanship M008-PSH-CIV-SPE-00001 D (NOWC)
Specifications - Civil
Materials and Workmanship M008-PSH-TUN-SPE-00001 D (NOWC)
Specifications - Tunnel
Procedure:
Title Code Status
Confined Space Procedure M008-PSH-HMS-PRO-00010 Submitted
Reports:
Title Code Status
Durability Report Stations, Shafts & M008-PSH-STR-RPT-00001 C-SONO
In-situ Tunnels
Plans:
Title Code Status
Project Management Plan M008-PSH-PRJ-PLN-00003 D (NOWC)
HSE Plan M008-PSH-HMS-PLN-00001 D (NOWC)
HSE Plan M008-PSH-HMS-PLN-00002 C (SONO)
Project Quality Plan M008-PSH-QMS-PLN-00002 D (NOWC)
Risk Management Plan M008-PSH-RSK-PLN-00002 Submitted
Traffic Management Plans M008-PSH-TTM-PLN-00001 Submitted
Method Statement for Grouting of Segmental Lining Rev 04
- Green Line Underground Project
7/29
Emergency Response Plan M008-PSH-HMS-PLN-00003 D (NOWC)
Construction Environmental M008-PSH-EMS-PLN-00001 C (SONO)
Management Plan
The grouting works will be executed by the TBM team under supervision of the
superintendent.
The Emergency Response Plan is in place and will be strictly adhered to.
In the event of any accident the HSE Incident Escalation Matrix will be followed at all times.
Site nurse will be available across both shifts with the Green Line doctor available as
necessary.
8 METHODOLGY
The preparation and safety review activities have been completed and all relevant Permits to
Work have been approved and issued by HSE.
8.2 Operation
8.2.1 Introduction
To eliminate or minimize the risk of settlement behind the shield, the annular gap between the
segmental lining and the actual excavated diameter has to be backfilled during TBM advance.
The major advance of the bi-component system is a rapid fixation of the ring.
The bi-component grout is injected under pressure through grout lines in the tail skin into the
annular gap limiting the redistribution of stress in the soil body as a result of the tunnel
excavation.
Component A is prepared on the surface, transported through the tunnel via a 3 steel pipe to
the holding tank on the TBM back-up with a capacity of 7 m. Component B is transferred from
the MSV to the holding tank by means of a transfer pump (see Figure 8.2-1). The PLC
controlled screw pumps feed the grout lines integrated in the tail skin. The PLC system adjusts
the flow rates of the pumps to keep the pressure in the annulus within pre-set limits.
The Bi-component system's main advantage lies in rapidly fixing the ring and evenly
transferring the ground forces onto the segment. The support given to the TBM from the last
constructed ring during tunneling facilitates ring twisting and shifting. This is because the rings
must take up both the torque and tunneling forces. However, rapid setting of the bi-
components can considerably reduce the inclination of the rings to twist and shift. They, in
turn, can absorb tunneling forces and backup loads that much quicker.
Component A (mixture of water, cement, Bentonite and a stabilizer) is mixed with Component
B (accelerator) at the end of the injection lines and injected into the annular gap. The quality
of the backfill components used is significant in terms of eliminating ring movement and
distortion and in achieving complete filling of the annular gap.
Metallic tank with mixing apparatus is used for transfer storage of Component A
Component B is supplied in tanks by the MSVs to the TBM and is kept in plastic tanks
until use.
High-pressure water cleaner: is used to clean the grouting lines at the tail skin.
Pump station including flow- and pressure meter for each of the 6 grout lines in the tail
skin is supplied by one progressing cavity pump for the grout (component A) and one
progressing cavity pump for the accelerator (component B), resulting in excellent
control over the filling process. The advantage of the progressing cavity pumps over
piston pumps is their continuous supply of grout / accelerator.
Bentonite is a mixture of clay minerals and will absorb substantial amounts of water to swell.
The bentonite proportion ensures that Component A is thixotropic in nature. This means that
during the loading phase the mixtures structural strength is reduced and the material becomes
more fluid from the input of kinetic energy and the viscosity is getting lower. The effect of the
material stabilizing is for structure strength to rise as the viscosity is raised.
Cement is the binding agent for the slurry and largely determines the solidifying time and
hardening of the mixture. The water/cement figure w/z = represents the weight ratio of water
to cement and is an important factor in setting the required mixture properties. This figure for
Component A lies between 2 and 3. It has an impact on the flowability and also affects hold
time of the slurry.
The stabilizer is supplied in a liquid form. The liquid variant has the benefit of being easier to
dose and to mix.
The TBM operates on a periodic principle. This means Component A is not constantly used.
It has a stopping time which is dependent on the TBM drive. It must therefore have a certain
durability in which it does not set and can still be pumped. If this durability is exceeded, then
the slurry in the storage tanks and supply lines is to be disposed.
The mixture sequence and mixing times impact on the durability of Component A. The mixing
times are laid down by the manufacturer of the mixing units and must be adjusted during the
test phase. They are important for producing a homogeneous material mixture and they also
affect both the quality and durability of Component A.
The component B will be stored in 3 Silos on the surface (22,000 liters each) for 2 TBMs. Via
a pipe the IBCs, which are installed on the MSVs, will be filled and transported to the TBM.
If the 20 m buffer tank is on the minimum level the mixing unit will start to mix component A
until the maximum level is reached on the tank. Additionally an automatic mode is installed
to give a signal from the TBM that the transfer pump has to start, if the minimum level on the
Component A tank on the TBM is reached, until the tank is filled.
The MTW2000 is a high-shear mixer dispersing one phase or ingredient (liquid, solid, gas)
into a main continuous phase (liquid), with which it would normally be immiscible. The impeller,
together with the stationary component (Scroll), known as a stator, is located on the bottom of
the mixing tank containing the solution to be mixed to create shear. The high-shear mixer can
be used to create emulsions and suspensions.
Fluid undergoes shear when one area of fluid travels with a different velocity relative to an
adjacent area. A high-shear mixer uses the rotating impeller powered by an electric motor, to
Method Statement for Grouting of Segmental Lining Rev 04
- Green Line Underground Project
15/29
"work" the fluid, creating flow and shear. The tip velocity, or speed of the fluid at the outside
diameter of the rotor, will be higher than the velocity at the center of the rotor, and it is this
velocity difference that creates shear.
The stationary component (Scroll) is used in combination with the rotor, and is referred to as
the stator (see Figure 8.2-5). The stator creates a close-clearance gap between the rotor and
itself and forms an extremely high-shear zone for the material as it exits the rotor.
In the MTW2000 batch high-shear mixer, the components to be mixed (whether immiscible
liquids or powder in liquid) are fed from the top into the mixing tank containing the mixer on a
rotating shaft at the bottom of the tank. Such mixer is usually used where faster processing by
volume is the major requirement.
Inside the tank, each shaft is equipped with two paddles (Figure 8.2-7). One is located half
way down the tank; the other is positioned at the bottom and is fitted with a scraping rubber
blade.
Volume 20m/h
Power 22 kW
Diameter Tunnel line 3
Pressure relieve valve 16 bar
The mixture flows a short distance to the end of the tail skin into the gap to be backfilled (see
Figure 8.2-8). The bi-component grout hardens and consolidates rapidly.
The basic principle of the Bi-component system is shown on the enclosed schematic.
8.2.2.4.2 Position of grout and grease lines in the tail skin of the shield
The position of the grouting lines and the greasing lines are shown in Figure 8.2-9.
Consumption:
8.2.2.4.5 Tanks
Tank of Component A is shown in Figure 8.2-12; data shown in Table 8.2-5.
Volume: 7 m
Dimensions approx.: 7100mm x 800mm x 1400mm
Number of agitators: 5
Power (each): 2.2 kW
The tank (with agitation) made of steel is used to store component A until its usage.
The injection box is bolted to the injection line in which the suspension is conveyed. Because
of its contact with both components it is important to clean it at the end of the injection with
pressure water (flushing).
Feed pumps: are installed outside the mixing unit and forward the Component A
mixture through the tunnel supply line to the TBM.
The flow rate of component A should be at least 20 l/min each line. The flow rate depends
on the advance rate of the TBM. When the advance rate is not enough to reach 20 l/min the
two top lines should be used only.
Manual Mode:
Automatic mode:
System stop
max pressure
regulation
Pressure
active
min pressure
regulation
active
advance stop
Time
Figure 8.2-15 Pressure range for automatic mode
The individual grout lines are preselected on the display. One or more lines may be
selected. The flow rate, calculated from the advance rate, is distributed to the
selected grout lines:
Pressure and flow in all active lines is monitored by means of pressure transducers and flow-
meters.
The pressure will be not greater than one bar above the prevailing hydrostatic pressure at the
location of grouting.
The theoretical grout injection rate is derived from the TBM advance speed, cut diameter and
outside diameter of the segmental lining. In praxis more grout than the theoretical volume of
the annular gap has to be injected to account for grout volume reduction as a result of bleeding
caused by consolidation. The system is designed to cope with injection rates up to 40% higher
than theoretically required. A correction factor can be set by the operator.
Following Mix Design will be used, see also ITP and Material Approval Request.
Component A
Water 875 kg
Bentonite 42 kg
Pozzolith 55R 5 kg
Component B
Roc SA 430 7%
8.2.4.1 Cleaning
Experience has shown that it is useful to clean the grout lines periodically. Therefore tools
such as a cutter of the company Rothenberger or a flushing device (see Table 8.2-7and
Figure 8.2-16) with high pressure water will be used.
When the hole for proof grouting is accessible from the platform, drilling the segment
preformed hole in accordance with predefined drilling pattern. The length will be
adapted to each case (see Figure 8.2-18, Figure 8.2-19).
Positioning of the injection insert at the boring end.
Check the relief valve functioning and adjust the pressure according to the usual
pressure and the line loss. The head loss in the line is determined by a no load test
before the injection.
Inject the grout.
Stop the injection when the max pressure of 4 bar, is accomplished. Close the valve.
Cleaning and inner wall washing to avoid grout trace before hardening.
Take off the injection inserts about 24h after the injection.
A resurfacing takes place in the borehole.
8.2.5.2 Operating process for the secondary grouting TBM 848 / 849
For the secondary grouting of the first 70 m of TBM 848 / 849 the secondary grouting will be
executed from the Doka scaffold.
Usually, the proof grouting takes place on the top of the ring.
When the hole for proof grouting is accessible from the platform, drilling the segment
preformed hole in accordance with predefined drilling pattern. The length will be
adapted to each case (see Figure 8.2-18, Figure 8.2-19).
Positioning of the injection insert at the boring end.
Check the relief valve functioning and adjust the pressure according to the usual
pressure and the line loss. The head loss in the line is determined by a no load test
before the injection.
Inject the grout.
Stop the injection when the max pressure fixed is accomplished. Close the valve.
Cleaning and inner wall washing to avoid grout trace before hardening.
Take off the injection inserts about 24h after the injection.
A resurfacing takes place in the borehole.
It is the same as for the repair works of segments, described also in M008-PSH-TUN-MES-
00020.
DOCUMENT TITLE: METHOD STATEMENT FOR GROUTING OF SEGMENTAL LINING DOCUMENT TYPE: METHOD STATEMENT
Comments on Rev.0
GeneralIssues
Section1.1
1 2 Changereferencefrom"TenderDocument.."to"Contract i SeeAppendix1forContractor'sreply. Closed
page6/33
Document."(Volume7Section13.4)
RolesandResponsibilities
ThisMSwillbereaddirectlywithvarioushigherleveltunnellingMS's,
Section4 thereforepleaselimitthereferencedpersonneltotheindividualswithdirect
2 1 ii SeeAppendix1forContractor'sreply. Closed
page8/33 responsibilityforthegroutingoperations.(Volume7Section13.4)
ShouldaMaterialsEngineerbeconsidered.
SurveyControl
Section6 Thewordingshouldreflectthatthegroutingoperationlimitsanypotential
3 1 i SeeAppendix1forContractor'sreply. Closed
page10/33 groundsettlementandshouldrefertotheMonitoringandInstrumentation
MSfortunnellingoperations.Volume7Section13.4
Access/Egress
Section8.1.4
4 1 Thissectionshouldbelimitedtotunnellingoperations.Referencecanbe i SeeAppendix1forContractor'sreply. Closed
page12/33
madetogeneralsiteaccessdocument.(Volume7Section13.4)
PlantOperations
Section8.1.6
5 1 Thissectionneedstoberevisedtoreflectthespecificwork i SeeAppendix1forContractor'sreply. Closed
page13/33
operation.(Volume7Section13.4)
Comments on Rev.2
Sections6&10 Health,SafetyandEnvironment
8 ST 1 i SeeAppendix1forContractor'sreply. Closed
page(s)8&28/29 Thissectionisrepeated.Pleasemergeallinformationinonesinglesection.
SecondaryGrouting
Thegroutingmixforsecondarygroutingisthesameasfor Open.
Pleaseconfirmifgroutingmixwillbethesameasforprimarygrouting.
Pleaseconfirmifgroutingmixwillbe
Pleaseoutlinespecificprocedureforchoiceofsegmentsandinjection primarygrouting
thesameasforprimarygrouting.
Section8.2.5 locationforsecondarygroutingandpersonresponsibleforfinaldecision. Thesecondarygroutimgwillbeexecutedpermanently
9 ST 1 Pleaseoutlinespecificprocedurefor
page25/29 Sections8.2.5.1and8.2.5.2containsimilarinformation.Pleasemergeinto each5thring choiceofsegmentsandinjection
onesection. Themaximumpressureforthesecondarygroutingis4bar locationforsecondarygroutingand
Pleaseconfirmifthesecondarygrouting,Section8.2.5.2,describedfor SeealsoMassBalanceReport personresponsible.
tunnels848&849willbeapplicabletoalltunnels.
Section8.2.3 MixDesign
MixDesign. IsthemixdesignprovidedthefinalMixDesign?
10 JG Page23/29and 1 ComponentAisgiveninKG.ComponentBisgivenin%.Ifpossiblekindly i SeeAppendix1forContractor'sreply. Closed
Appendix1ITPItem provideconsistentunits.
1.5. TheMaterialsApprovalRegisterdated5Augustdoesnotprovidethelatest
finalmixdesign.
Appendix1ITPItem Grouting
11 JG 2 i SeeAppendix6 Open.
2.6 KindlyprovideanexampleoftheGroutingInspectionForm.
JHARepeatedinMS
ThereisasignedandunsignedcopyofthesameJHAinthisMS.
13 KJS JHA 2 i SeeAppendix1forContractor'sreply. Closed
MergethecopiessothatthereaderonlyhasonecopyofJHAtorefertoin
thisMS.
HighPressureFlushingEquipment
Thehazardsidentifieddonotincludeworkersbeingstruckbyhighpressure
JHA
14 KJS 1 flushingliquid. i SeeAppendix1forContractor'sreply. Closed
item#16
Includeaitemidentifyingthishazardandassociatedcontroltominimize
workerexposureintheJHA.
LackofConfinedSpacesControls
Thecontrolsdonotincludetheconfinedspacepermitsystemwhenentering
JHA
15 KJS 1 thetanktocleanit. i SeeAppendix1forContractor'sreply. Closed
item#22
IncludetheHSEMS"confinedspaceentrypermitsysteminthisitemofthe
JHA.
WorkingatHeight
ThecontrolsidentifytrainedMachineOperatorsabletousethemachinesas
JHA
16 KJS 1 acontrolforworkingatheight?Why? i SeeAppendix1forContractor'sreply. Closed
item#25
Thecontrolsshouldbeforeveryonewhoisworkingatheighttobetrained
fortheworkinthisMS.
UseofSDS'sasControlMeasure
TherearenumerousitemsintheJHAwhereworkersinteractwiththe Open.
JHA componentA&Bgrout.Whereworkerscancontactthegroutcomponents SDSoutlineshazardsandcontrol
17 KJS 1 i SeeJHA2730
General referencetotheSDS'sshouldbestatedasacontrolmeasureintherelated methods.Itshouldbereferencedin
itemsintheJHA. JHA.
IncludethereferencetotheSDS'sintheappropriateitemsintheJHA.
PMC/CPO Comments/Reply Status Chief Technical Office (CTO) Engineer/Delegated Party D&B Contractor
COMMENTS/STATUS
Reviewers Name Position COMMENTS/STATUS RECOMMENDED BY CTO NO OBJECTION BY (Where necessary) REPLY APPROVED BY
RECOMMENDED BY PMC
Construction
Daniel Dowling Name: John Swann Name: Name: Name:
Manager
TITLE / NAME: Grouting of Segmental METHOD STATEMENT REF. No.: M008-PSH-TUN-MES-00013 ITP No.: M008-PSH-QMS-ITP-00100 Rev.2
(refer to latest revision)
Lining DATE: 13-Jan-16
Component A:
Water (potable ) = 875 kg
Bentonite = 42 kg Project Manager
Volume 7 Clause 13.4.2.1
1.5 Grout Mix Design submittal SRC 42.5 = 316 kg Prior to commencing the works Mix design records H H Tunnel/ Site Engineer /
MS Clause 8.3.2
Pozzolith 55R = 5 kg QC Engineer
Component B:
Roc SA430 = 7% (Nominal )
Any work item that does not meet the acceptance criteria shall be reworked and reinspected; failure to satisfactorily rework deficient items shall result in the raising of NCR.
Method Statement
PSH-QMS-ITP-Q-27 for Grouting of Segmental Lining Rev 04 35/82
Rev.02, 14May2014
page 2 of 3
TITLE / NAME: Grouting of Segmental METHOD STATEMENT REF. No.: M008-PSH-TUN-MES-00013 ITP No.: M008-PSH-QMS-ITP-00100 Rev.2
(refer to latest revision)
Lining DATE: 13-Jan-16
Any work item that does not meet the acceptance criteria shall be reworked and reinspected; failure to satisfactorily rework deficient items shall result in the raising of NCR.
Method Statement
PSH-QMS-ITP-Q-27 for Grouting of Segmental Lining Rev 04 36/82
Rev.02, 14May2014
Method Statement for Grouting of Segmental Lining Rev 04 37/82
Appendix 3
JHA Execution
Task Steps Hazard Impact (likelihood) Controls
Step What could hurt me / others or Responsibility
What am I going to do? What harm could occur? What must be in place to prevent harm? (include specific responsibilities where applicable)
impact on the environment
Only authorized persons allowed on site. Operation team to control access to site at all times. Stop work and
Potential of injury or accident or vandalism Site Engineer /
pit lowering, station construction, report to supervisor in case of unauthorized person accessing site.
1 Access and egress Runover by vehicle Foreman / HSE
stock pile, vehicle contact Maintained clear and visible fencing, hoarding and edge barriers and signage.
Risk of falling in open excavation Engineer
Construction Manager
/ Project Engineer /
Respiratory Problems / Harming / Breathing /
2 General Tunnel Works Working Environment All personel must have a full medical test to proof of physical items Site Engineer / QA and
General Items
HSE Engineer / Plant
Operator
Site Engineer /
Hearing loss Use the proper and the minimum requirement of PPEs.
Foreman / HSE
3 Operate plant Excessive noise and vibration Hand and arm vibration syndrome (HAVS) Monitor noise and vibration. Do not exceed the daily exposure level.
Engineer / Surveyor /
Disturb nearby residents Review methology if problems occur.
Plant operator
Site Engineer / HSE
Silica lung disease Use the proper and the minimum requirement of PPEs.
Dust generated during plant Engineer /
4 Operate plant Breathing problems, Use proper ventilation and dust exhaust system, spray water on affected areas.
operation Environment Manger /
Environmental hazard Monitor air samples.
Plant Operator
Site Engineer / HSE
Equipment on fire Burning Every equipment must be equipped with fire extinguisher. Engineer /
5 Operate plant
Emission of toxic gases Respiaratory problems Deployment of proper ventilation system. Frequent checking of air quality of the working area. Environment Manger /
Plant Operator
Site Engineer /
Protection of cables and using low-voltage equipment. Before commencing any maintance works, all electrical
6 Using electrical equipment Electician system Electric shock Foreman / HSE
equipment must be isolated from the main. Proper and frequent maintanincing of the equipment.
Engineer
Site Engineer /
Hearing loss Use the proper and the minimum requirement of PPEs, ear muffs / plugs@80db(A)-85.
7 Using of manual equipment Noise and vibration Foreman / HSE
Hand arm vibration syndrome Monitor noise and vibration. Review methology if problems occur. Use the vibrating equipment in short terms.
Engineer
Site Engineer /
Working in harsh environment Drink plenty of water, cover exposed body parts, wear proper PPEs and sun protection, apply sun screen. Shaded
8 Heat Stress and dehydration Heat Stroke, Dehydration Foreman / HSE
(high temperature and humidity) areas will be provided.
Engineer
Site Engineer /
Working in harsh environment
9 Sand, dust Eye injury / breathing issues Proper eye protection must be worn at all times. Wear proper dust mask if necessary. Foreman / HSE
(wind blow/dust)
Engineer
Ensuring a clean and tidy workplace (housekeeping) to prevent trips, and slips. Do proper housekeeping. Site Engineer /
Working in harsh environment
10 Slips, trips and falls Slips, trips and falls Establishing emergency planning procedures, including first aid. Provide good quality of lighting, spillages of liquid Foreman / HSE
(on work sites)
being cleaned promptly. Engineer
Site Engineer /
Use the proper and minimum PPEs all time (eye, breath, hand protection). Good maintenance.
11 Concrete pumping Burst hose / fitting Concrete works - skin / eye injury Foreman / HSE
Regular inspection of equipment.
Engineer
Site Engineer /
Injury caused by using inappropriate Risk should be eliminated or reduced through the use of lifting aids, reducing the load, dividing or sharing the load,
12 Manual handling Back injury Foreman / HSE
lifting methods. provide training in ergonomic lifting techniques
Engineer
Site Engineer /
Entrapment hazard, shock, damage Proper eye protection must be worn at all times. Wear proper dust mask if necessary. Control of the pumps are
13 Working with static pumps Cuts, eye injury, loss of limbs Foreman / HSE
to the eyes. disconnected before open its.
Engineer
Site Engineer /
Use the proper and minimum PPEs all time (eye, breath, hand protection). Good maintenance.
14 Component A - Mixture process Mixture spraying on workers Harmful to skin Foreman / HSE
Regular inspection of equipment.
Engineer
Site Engineer /
During disposal, slurry spilling on Environmental Use the proper and minimum PPEs all time (eye, breath, hand protection). Good maintenance.
15 Storage tank of Component B Foreman / HSE
workers When in contact with workers, harmful to body Regular inspection of equipment.
Engineer
Site Engineer /
Use the proper and minimum PPEs all time (eye, breath, hand protection).
16 High pressure water cleaner Flying pieces/chips on workers Cuts, bruises Foreman / HSE
Be aware to other workers in surrounding
Engineer
Site Engineer /
Leakage in transit and storage Environmental Use the proper and minimum PPEs all time (eye, breath, hand protection). Good maintenance.
17 Stabilizer supplied in liquid form Foreman / HSE
Sillage during handling Skin irritation, other harmful effects to skin Regular inspection of equipment.
Engineer
JHA Execution
Task Steps Hazard Impact (likelihood) Controls
Step What could hurt me / others or Responsibility
What am I going to do? What harm could occur? What must be in place to prevent harm? (include specific responsibilities where applicable)
impact on the environment
Component A - Slurry stored in Site Engineer /
During disposal, slurry spilling on
18 tanks, to be disposed when Harmful effects to skin Use the proper and minimum PPEs all time (eye, breath, hand protection). Foreman / HSE
workers
passed durability date Engineer
Site Engineer /
During disposal, slurry spilling on
19 Filling of Component B Harmful effects to skin Use the proper and minimum PPEs all time (eye, breath, hand protection). Foreman / HSE
workers
Engineer
Site Engineer /
Equipment suddenly stops Workers manually trying to fix Use the proper and minimum PPEs all time (eye, breath, hand protection).
20 Hands / limbs / clothing getting jammed in equipment Foreman / HSE
working equipment, unsupervised Stop power / electricity before repairing
Engineer
Site Engineer /
Use the proper and minimum PPEs all time (eye, breath, hand protection). Good maintenance.
21 Buffer tank Electrocution Electrocution, injuries Foreman / HSE
Regular inspection of equipment.
Engineer
Use the proper and minimum PPEs all time (eye, breath, hand protection). Site Engineer /
Cleaning of storage tanks for
22 Four openings for cleaning Spraying on skin, eyes Open all openings during cleaning. Always one worker being outside to secure Foreman / HSE
Component A
Following Confined Space Procedure Engineer
Site Engineer /
Contact with excess grout in grout Harmful reaction to skin Use the proper and minimum PPEs all time (eye, breath, hand protection). Good maintenance.
23 Manuel cleaning of equipment Foreman / HSE
tank Injury to eyes Regular inspection of equipment.
Engineer
Site Engineer /
Use the proper and minimum PPEs all time (eye, breath, hand protection).
24 Drilling the segment Drilling, flying pieces Injury, cuts, bruises Foreman / HSE
Be aware to other workers in surrounding
Engineer
Site Engineer /
Eliminate the hazard by of falling by using the proper PPEs (e.g. helmet, safety shoes, harness).
25 Working at heights Falling from height Potential of serious injury or accident Foreman / HSE
Workers must be fully trained and qualified and can use machines only.
Engineer
Working scaffold to be fixed properly in accordance with shop drawings and manufacturer's instructions
Falling from the working scaffold
Inspect working scaffold prior to use and regularly during usage Site Engineer I
Collapse of working scaffold
26 Working on scaffold Injury, fatality Maintain working scaffold clean at all times General Foreman I
Tripping (congested, limited working
Do not store material and tools on the working scaffold HSE
area at the working scaffold)
Wear appropriate PPE
Site Engineer /
Use the proper and minimum PPEs all time (eye, breath, hand protection).
27 Using Grouting mixture Inhalation aerosol Injury, fatality Foreman / HSE
In case of inhalation remove to fresh air and seek medical attention.
Engineer
Site Engineer /
Use the proper and minimum PPEs all time (eye, breath, hand protection).
28 Using Grouting mixture Skin contact Injury, fatality Foreman / HSE
In case of contact wash immediatly with plenty of water and soap.
Engineer
Site Engineer /
Use the proper and minimum PPEs all time (eye, breath, hand protection).
29 Using Grouting mixture Contact with eyes Injury, fatality Foreman / HSE
Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist
Engineer
Site Engineer /
Use the proper and minimum PPEs all time (eye, breath, hand protection).
30 Using Grouting mixture Ingestion Injury, fatality Foreman / HSE
In case of ingestion rinse mouth immediately and then drink plenty of water, seek medical attention.
Engineer
Use the proper and minimum PPEs all time (eye, breath, hand protection). Site Engineer /
31 High pressure water cleaner Struck person Injury, fatality Be aware to other workers in surrounding Foreman / HSE
Dont pointing the beam at other people Engineer
REVISION G
BASE RL
Environmental
Health Safety
IDENTIFIED RISK EVENT
ID
EXISTING CONTROL P
TRUCK
a Designated roads
A General site Injury C 3 H
b Speed limits
1 movement of Collision between Trucks
c Trucks Licenced operators
B Fatality E 4 M
d
a Designated roads
A General site Injury C 3 H
b Speed limits
2 movement of Collision with light vehicle
c Trucks Licenced operators
B Fatality E 4 M
d
a Designated roads
A General site Injury D 3 M
b Speed limits
3 movement of Roll over / tipping over
c Licenced operators
B Trucks Fatality E 4 M
d
a Water tankers on site
A General site Exceeds dust limits B 2 H
b Traffic movements creates
4 movement of
c Trucks excessive dust / noise
B Exceeds noise limits D 2 L
d
a Designated roads
A Excavated Accident - fatality E 4 M
b Overdriving heap or deep Speed limits
5 material heap /
c Excavation excavation edge Licenced operators
B Accident - injury D 3 M
d Berms / barriers
a Water tankers on site
A Exceeds dust limits B 2 H
b Loading and
6 Creates excessive dust / noise.
c unloading trucks
B Exceeds noise limits D 2 L
d
a Designated roads
A Failure to adequately designate Accident - injury D 2 L
b Roads and Speed limits
7 (incl signage etc) areas - roads,
c designated areas walkways etc leads to accident Accident - fatality Licenced operators
B E 4 M
d
a Designated areas for refuel
8 A Refuelling on site Spill in uncontained area Environmental issue C 2 M
b
EXCAVATOR
a Designated roads
A Surface Mobile Injury D 3 M
b Speed limits
47 Equipment (SME) Collision between SME's
c / Excavator Licenced operators
B Fatality E 4 M
d
a Designated roads
A Surface Mobile Injury D 3 M
b Speed limits
48 Equipment (SME) Collision with light vehicle
c / Excavator Licenced operators
B Fatality E 4 M
d
Environmental
Health Safety
IDENTIFIED RISK EVENT
ID
EXISTING CONTROL P
a Designated roads
A Surface Mobile Injury D 3 M
b Speed limits
49 Equipment (SME) Roll over / tipping over
c / Excavator Licenced operators
B Fatality E 4 M
d
a Water tankers on site
A Surface Mobile Exceeds dust limits C 2 M
b Traffic movements creates Plant moves very slowly
50 Equipment (SME)
c / Excavator excessive dust / noise
B Exceeds noise limits E 2 L
d
a Water tankers on site
A Exceeds dust limits B 2 H
b Distance to boundary
51 Loading trucks Creates excessive dust / noise.
c
B Exceeds noise limits C 2 M
d
a
52 A Hydraulic lines Burst line Environmental issue C 2 M
b
a Designated areas for refuel
53 A Refuelling on site Spill in uncontained area Environmental issue C 2 M
b
a Restricted areas
A Unauthorised personal entry in Injury D 3 M
b
54 Boom area of swinging boom - person
c hit by boom / bucket
B Fatality E 4 M
d
a Water tankers on site
A Exceeds dust limits C 2 M
b Use of excavator Creates excessive dust / noise Distance to boundary
55
c as rock breaker (vibration). Exceeds noise / vibration
B C 2 M
d limits
a Restricted areas
A Results in fly rock - fragment of Injury D 2 L
b Use of excavator Inside excavation
56 rock that flies off and impacts
c as rock breaker PPE / glasses
B person in area Fatality E 4 M
d
a Restricted areas
A Injury D 3 M
b Mechanical failure allows boom Maintenance
57 Raised boom
c to drop on worker
B Fatality E 4 M
d
a Restricted access near wall
A Injury D 3 M
b Working in Regular inspections of wall
58 Failure of slopes
c excavation Cabin protection
B Fatality E 4 M
d Wall protection / stabilisation
a Restricted access near wall
A Injury D 3 M
b Working in Rock fall from unprotected Regular inspections of wall
59
c excavation slopes of excavation Cabin protection
B Fatality E 4 M
d Wall protection / stabilisation
BULLDOZER / GRADER
a Designated roads
A Surface Mobile Injury D 3 M
b Speed limits
97 Equipment (SME) Collision between SME's
c /Bulldozer Licenced operators
B Fatality E 4 M
d
a Designated roads
A Surface Mobile Injury D 3 M
b Speed limits
98 Equipment (SME) Collision with light vehicle
c /Bulldozer Licenced operators
B Fatality E 4 M
d
a Designated roads
A Surface Mobile Injury D 3 M
b Speed limits
99 Equipment (SME) Roll over / tipping over
c /Bulldozer Licenced operators
B Fatality E 4 M
d Slow moving
Environmental
Health Safety
IDENTIFIED RISK EVENT
ID
EXISTING CONTROL P
a Designated roads
A General site Injury D 3 M
b Speed limits
146 movement of Collision between Trucks
c Trucks Licenced operators
B Fatality E 4 M
d
a Designated roads
A General site Injury D 3 M
b Speed limits
147 movement of Collision with light vehicle
c Trucks Licenced operators
B Fatality E 4 M
d
a Designated roads
A General site Injury D 3 M 2 L
b Speed limits
148 movement of Roll over / tipping over
c Trucks Licenced operators
B Fatality E 4 M 2 L
d
a Maintenance programme
A Injury, spill C 2 M 2 M
b Steel components
149 Pumping Concrete Burst pipe / failed equipment
c
B Fatality, spill E 4 M 2 L
d
a
150 A Hydraulic lines Burst line Environmental issue C 2 M
b
a Designated areas for refuel
151 A Refuelling on site Spill in uncontained area Environmental issue C 2 M
b
Method Statement for Grouting of Segmental Lining Rev 04 45/82
BASE RL
Environmental
Health Safety
IDENTIFIED RISK EVENT
ID
EXISTING CONTROL P
LIGHT VEHICLE
a Designated roads
A Surface Mobile Injury D 3 M
b Speed limits
245 Equipment (SME) Collision between SME's
c / Bucket Loader Licenced operators
B Fatality E 4 M
d
a Designated roads
A Surface Mobile Injury D 3 M
b Speed limits
246 Equipment (SME) Collision with light vehicle
c / Bucket Loader Licenced operators
B Fatality E 4 M
d
a Designated roads
A Surface Mobile Injury D 3 M
b Speed limits
247 Equipment (SME) Roll over / tipping over
c / Bucket Loader Licenced operators
B Fatality E 4 M
d
a Water tankers on site
A Exceeds dust limits C 2 M
b Surface Mobile Traffic movements creates Plant moves very slowly
248 Equipment (SME)
c / Bucket Loader excessive dust / noise
B Exceeds noise limits E 2 L
d
a Water tankers on site
A Exceeds dust limits B 2 H
b Distance to boundary
249 Loading trucks Creates excessive dust / noise.
c
B Exceeds noise limits C 2 M
d
a
250 A Hydraulic lines Burst line Environmental issue C 2 M
b
Method Statement for Grouting of Segmental Lining Rev 04 46/82
BASE RL
Environmental
Health Safety
IDENTIFIED RISK EVENT
ID
EXISTING CONTROL P
DRILL
Environmental
Health Safety
IDENTIFIED RISK EVENT
ID
EXISTING CONTROL P
a Area inspection
A Uneven surface, poor load Load falls - injury D 3 M
b Positioning crane - Use of outriggers
399 carrying capacity or subsurface
c soil conditions Certified operators
B voids causes crane to topple Load falls - fatality E 4 M
d
a Positioning of Load falls crane topples - Area inspection
A Outrigger punctures through D 3 M
b crane on man injury Use of outriggers
400 structure - causes crane to
c made surface / Load falls crane topples - Certified operators
B topple E 4 M
d structure fatality
a Load inspected
A Exceeds safe load of crane / Load falls - injury E 3 L
b All equipment inspected
401 Load to be lifted rigging equipment - lift
c equipment fails Certified operators
B Load falls - fatality E 4 M
d Equipment certified
a Load inspected
A Load to be lifted outside safe Load falls - injury D 3 M
b All equipment inspected
402 Load to be lifted radius of operation of crane -
c crane topples Certified operators
B Load falls - fatality E 4 M
d Equipment certified
a Load falls crane topples - Certified operators
A Results in excess horizontal D 3 M
b injury
403 High wind loads on crane - cause s crane
c to topple Load falls crane topples -
B E 4 M
d fatality
a Equipment inspected
A Rigging gear, Load falls - injury D 3 M
b Damaged or in poor condition - No Go Zones under load
404 shackles, chains
c fails dropping load Certified operators
B etc Load falls - fatality E 4 M
d
a Equipment inspected
405 A Hydraulic lines Burst line Environmental issue C 2 M
b
a Load falls - injury + Equipment inspected
A E 4 M 2 L
b environmental No Go Zones under load
406 Hydraulic lines Burst Line
c Load falls - fatality +
B E 5 H 2 L
d environmental
a Equipment inspected
A Electro / Load falls - injury D 3 M
b Failure of item results in loss of No Go Zones under load
407 Mechanical
c control of load
B equipment Load falls - fatality E 4 M
d
Site inspection
A Electric burns - injury D 2 L
Certified operators
408 Overhead services Contact with electrical cable
B Electrocution - fatality E 4 M
a Trained operators
A Rotating Operator contacts rotating Accident minor injury D 3 M
b Area cordoned off
413 equipment - cutter equipment - caught in rotating
c head plant (or loose clothing caught) Accident - fatality
B E 4 M
d
a Restricted areas
A Unauthorised personal entry in Injury C 2 M
b Cutterhead boom / Trained operators
414 area of swinging cutterhead -
c arm person hit
B Fatality E 4 M
d
a Restricted areas
A Action of cutting Results in fly rock - fragment of Injury C 2 M
b Inside excavation
415 rock - face of rock that flies off and impacts
c excavation person in area PPE / glasses
B Fatality E 4 M
d
a Restricted areas
A Injury D 3 M
b Raised boom / Mechanical failure allows boom Maintenance
416
c arm to drop on worker Safety valve on system
B Fatality E 4 M
d
Method Statement for Grouting of Segmental Lining Rev 04 48/82
BASE RL
Environmental
Health Safety
IDENTIFIED RISK EVENT
ID
EXISTING CONTROL P
a Uneven surface, poor load Load falls, unit topples - Area inspection
A Positioning D 3 M
b carrying capacity or subsurface injury Use stabilizers (if fitted)
446 telehandler - soil
c conditions voids causes telehandler to Load falls, unit topples - Certified operators
B topple E 4 M
d fatality
a Edges of pits or heaps unable to Load falls, unit topples - Keep load low
A C 2 M
b Ground conditions carry load, uneven surfaces, injury Drive slowly
447
c while moving slippery conditions etc - load Load falls, unit topples - Certified operator
B shifts E 4 M
d fatality Use seat belts
a Load falls, unit topples - Licenced driver
A Driving too fast (in corners), C 2 M
b Driving - moving / injury Load low to ground
448 need to brake for third party etc -
c carrying load load shifts - roll over Load falls, unit topples - Use seat belts
B E 4 M
d fatality
a Restricted areas
A Injury D 3 M
b Raised boom / Mechanical failure allows boom Maintenance
449
c arm / forks / arm / forks to drop on worker Safety valve on system
B Fatality E 4 M
d
a All services identified / removed
A Injury D 3 M
b Overhead services Travel with load low to ground
450 Contact with services / lines
c and power lines Full area inspection
B Fatality - electrocution E 4 M
d
a Environmental issue / Maintenance
451 A Hydraulic lines Burst line C 2 M
b injury
a Refuelling areas
452 A Refuelling on site Spill in uncontained area Environmental issue C 2 M
b
a Designated roads
A Injury D 3 M
b Tele handler / Collision with light (or other) Speed limits
453
c forklift movement vehicle Licenced operators
B Fatality E 4 M
d
a Site lighting
A Injury D 3 M
b Mobile / moving Impact pedestrian (worker) on Speed limits
454
c equipment site Licenced drivers
B Fatality E 4 M
d Designated zones
a Water tankers on site
A Exceeds dust limits E 2 L
b Mobile / moving Traffic movements creates
455
c equipment excessive dust / noise
B Exceeds noise limits E 2 L
d
a Load falls, unit topples - Keep load low
A C 2 M
b Load exceeds or near capacity injury Test lift
456 Load size (weight)
c of unit - causes unit to topple Load falls, unit topples - Certified operator
B E 4 M
d fatality Use seat belts
Method Statement for Grouting of Segmental Lining Rev 04 49/82
BASE RL
Environmental
Health Safety
IDENTIFIED RISK EVENT
ID
EXISTING CONTROL P
a Area inspection
A Uneven surface, poor load Unit topples - injury D 3 M
b Positioning man Use stabilizers (if fitted)
462 carrying capacity or subsurface
c lift - soil conditions Certified operators
B voids causes man lift to topple Unit topples - fatality E 4 M
d
a All services identified / removed
A Injury D 3 M
b Overhead services Full area inspection
463 Contact with services / lines
c and power lines
B Fatality - electrocution E 4 M
d
a Restricted areas
A Injury D 3 M
b Raised boom / Mechanical failure allows boom Maintenance
464
c arm / forks / arm / forks to drop on worker Safety valve on system
B Fatality E 4 M
d
a Observe load placards
A Unit topples - injury D 3 M
b Load exceeds or near capacity Test lift
465 Load size (weight)
c of unit - causes unit to topple Certified operator
B Unit topples - fatality E 4 M
d
a Activity not permitted
A Push / move / drive man lift Unit topples - injury D 3 M
b Repositioning man Cannot move while in use
466 while boom raised and person in
c lift Certified operator
B basket Unit topples - fatality E 4 M
d
a Activity not permitted
A Load exceeds or near capacity Unit topples - injury D 3 M
b Using basket / Observe rules for use
467 of unit or creates off centre load-
c boom to lift load Certified operator
B causes unit to topple Unit topples - fatality E 4 M
d No side loads permitted
a Environmental issue / Maintenance
468 A Hydraulic lines Burst line C 2 M
b injury
a Refuelling areas
469 A Refuelling on site Spill in uncontained area Environmental issue C 2 M
b
Do not use in wind
A Unit topples - injury D 3 M
Wing creates side load - Use stabilizers (if fitted)
470 Use in high wind
causes man lift to topple Certified operators
B Unit topples - fatality E 4 M
Manufacturers safe use rules
Inspect prior to use
A Unit topples - injury D 3 M
Tyre failure during Causes / permits uneven load - Use stabilizers (if fitted)
471
use causes man lift to topple Certified operators
B Unit topples - fatality E 4 M
Environmental
Health Safety
IDENTIFIED RISK EVENT
ID
EXISTING CONTROL P
Hand Gloves
Maintaining Roller/ Hand Gets caught in moving
478 A Injury D 3 M
Compactor part Training
Spill Kit
480 A Refuelling on site Fuel Spill Environmental Incident C 2 M
Designated person to refuel
Operating/Maintai Spill Kit
481 A Oil leakage on site Environmental Incident C 2 M
ning equipment
Conveyor
Manual Handling - improper Training
482 A Assembly/Erection Injury C 2 M
handling of tools
Lift Plan
A Injury D 3 M
Working under lifted load - Load Adequate Lifting Gear
483 Assembly/Erection
falls
B Fatality E 4 M
Trained workers
A Injury D 3 M
Operating Pinch points- hands or clothing Mesh Guards
485
Conveyor caught in moving parts No Loose clothing
B Fatality E 4 M
Application procedure
The substrate must be clean and free from loose
particles and preferably damp. Fresh standard
Portland cement should be used because the
reaction time is increased by prolonged storage.
Preliminary tests are recommended for cements
providing high sulphate resistance.
BASF_CC-UAE/Roc_SA430/v1/10_13
The technical information and application advice given in this BASF publication are based on the present state of
STATEMENT OF our best scientific and practical knowledge. As the information herein is of a general nature, no assumption can be
RESPONSIBILITY made as to a product's suitability for a particular use or application and no warranty as to its accuracy, reliability or
completeness either expressed or implied is given other than those required by law. The user is responsible for
checking the suitability of products for their intended use.
Field service where provided does not constitute supervisory responsibility. Suggestions made by
NOTE BASF either orally or in writing may be followed, modified or rejected by the owner, engineer or contractor since
they, and not BASF, are responsible for carrying out procedures appropriate to a specific application.
Page: 1/13
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 10.06.2013 Version: 2.0
Product: MasterPozzolith 55R also POZZOLITH 55R
(ID no. 30601107/SDS_GEN_EU/EN)
Date of print 31.08.2013
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Operating Division Construction Chemicals
Possible Hazards:
May cause sensitization by skin contact.
Hazard symbol(s)
Xi Irritant.
R-phrase(s)
R43 May cause sensitization by skin contact.
S-phrase(s)
S2 Keep out of the reach of children.
S24 Avoid contact with skin.
S37 Wear suitable gloves.
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.
Not applicable
3.2. Mixtures
Chemical nature
formaldehyde...%
Content (W/W): >= 0.2 % - < 1 % Acute Tox. 3 (Inhalation - vapour)
CAS Number: 50-00-0 Acute Tox. 3 (oral)
EC-Number: 200-001-8 Acute Tox. 3 (dermal)
REACH registration number: 01- Skin Corr./Irrit. 1B
2119488953-20 Skin Sens. 1
INDEX-Number: 605-001-00-5 Carc. 2
H314, H311, H331, H301, H317, H351
Hazardous ingredients
according to Directive 1999/45/EC
formaldehyde...%
Content (W/W): >= 0.2 % - < 1 %
CAS Number: 50-00-0
EC-Number: 200-001-8
REACH registration number: 01-2119488953-20
INDEX-Number: 605-001-00-5
Hazard symbol(s): T
R-phrase(s): 23/24/25, 34, 40, 43
Carc. Cat. 3
For the classifications not written out in full in this section, including the indication of danger, the
hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
After contact with skin, wash immediately with plenty of water and soap. Under no circumstances
should organic solvent be used. If irritation develops, seek medical attention.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce
vomiting unless told to by a poison control center or doctor.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: allergic symptoms
Further information:
The degree of risk is governed by the burning substance and the fire conditions. If exposed to fire,
keep containers cool by spraying with water. Collect contaminated extinguishing water separately, do
not allow to reach sewage or effluent systems. Contaminated extinguishing water must be disposed
of in accordance with official regulations.
Suitable materials for containers: High density polyethylene (HDPE), Low density polyethylene
(LDPE)
Further information on storage conditions: Keep only in the original container in a cool, dry, well-
ventilated place away from ignition sources, heat or flame. Protect from direct sunlight.
The substances without values are not listed in the occupational exposure regulations for the validity
area of this safety data sheet.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
Form: liquid
Colour: light yellow
Odour: almost odourless
pH value: approx. 6.0 - 9.0
slightly alkaline
Melting temperature: approx. 0 C
boiling temperature: > 100 C
(1,013 hPa)
Flash point: > 100 C
Evaporation rate:
not determined
Flammability: not flammable
Lower explosion limit:
not applicable
Upper explosion limit:
not applicable
Vapour pressure:
not applicable
Density: approx. 1.00 - 1.30 g/cm3
(25 C)
Relative vapour density (air):
not determined
Solubility in water: soluble
(20 C)
Thermal decomposition: No decomposition if stored and handled as prescribed/indicated.
Viscosity, dynamic: approx. 50 - 300 mPa.s
(25 C)
Explosion hazard: not explosive
Substances to avoid:
strong acids, strong bases, strong oxidizing agents, strong reducing agents
Acute toxicity
Irritation
Respiratory/Skin sensitization
Assessment of sensitization:
May cause sensitization by skin contact.
Assessment of mutagenicity:
The chemical structure does not suggest a specific alert for such an effect. Based on available Data,
the classification criteria are not met.
Carcinogenicity
Assessment of carcinogenicity:
Reproductive toxicity
Developmental toxicity
Assessment of teratogenicity:
The chemical structure does not suggest a specific alert for such an effect. Based on available Data,
the classification criteria are not met.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Based on our experience and the information available, no adverse health effects are expected if
handled as recommended with suitable precautions for designated uses. The product has not been
tested. The statements on toxicology have been derived from the properties of the individual
components.
The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vPvB (very
persistent/very bioaccumulative).
The product does not contain substances that are listed in Regulation (EC) 1005/2009 on
substances that deplete the ozone layer.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.
Land transport
ADR
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
RID
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
14.1. UN number
See corresponding entries for UN number for the respective regulations in the tables above.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases,
and the hazard statements, if mentioned in section 2 or 3:
C Corrosive.
T Toxic.
N Dangerous for the environment.
35 Causes severe burns.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
34 Causes burns.
40 Limited evidence of a carcinogenic effect.
43 May cause sensitization by skin contact.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Skin Corr./Irrit. Skin corrosion/irritation
Acute Tox. Acute toxicity
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.
Page: 1/9
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 21.10.2011 Version: 3.0
Product: MasterRoc SA 430 also MEYCO SA 430
(ID no. 30599098/SDS_GEN_EU/EN)
Date of print 20.07.2013
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Operating Division Construction Chemicals
2. Hazards Identification
Label elements
EEC Directives
The product does not require a hazard warning label in accordance with EC Directives.
Possible Hazards:
No specific dangers known, if the regulations/notes for storage and handling are considered.
Other hazards
3. Composition/Information on Ingredients
Mixtures
Chemical nature
4. First-Aid Measures
Description of first aid measures
First aid personnel should pay attention to their own safety. Remove contaminated clothing.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
After contact with skin, wash immediately with plenty of water and soap. If irritation develops, seek
medical attention.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce
vomiting unless told to by a poison control center or doctor.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.
Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
The substances without values are not listed in the occupational exposure regulations for the validity
area of this safety data sheet.
Exposure controls
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Combination filter for gases/vapours of
organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type ABEK).
Hand protection:
impermeable gloves
Synthetic rubber gloves
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
light protective clothing
Form: liquid
Other information
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Conditions to avoid
See MSDS section 7 - Handling and storage.
Incompatible materials
Substances to avoid:
strong acids, strong bases, strong oxidizing agents
Acute toxicity
Irritation
Respiratory/Skin sensitization
Assessment of sensitization:
The product has not been tested. The statement has been derived from the properties of the individual
components.
Assessment of mutagenicity:
The chemical structure does not suggest a specific alert for such an effect. The product has not been
tested. The statement has been derived from the properties of the individual components.
Carcinogenicity
Assessment of carcinogenicity:
The chemical structure does not suggest a specific alert for such an effect.
Reproductive toxicity
Developmental toxicity
Assessment of teratogenicity:
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Based on our experience and the information available, no adverse health effects are expected if
handled as recommended with suitable precautions for designated uses. The product has not been
tested. The statements on toxicology have been derived from products of a similar structure and
composition.
Bioaccumulative potential
The product does not fulfill the criteria for PBT (persistent/bioaccumulative/toxic) or vPvB (very
persistent/very bioaccumulative).
Waste key:
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling
after being thoroughly cleaned.
Land transport
ADR
Not classified as a dangerous good under transport regulations
RID
Not classified as a dangerous good under transport regulations
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
If other regulatory information applies that is not already provided elsewhere in this safety data sheet,
then it is described in this subsection.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of
the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.
Flow (SEC.) Gel Time Density Bleeding (%) Initial Set Time (MPA) Volume Required
Date Certificate 3
Time Ref No: Marsh Cone (SEC.) (KG/M ) BS 8110 ASTM C403 Batched M Samples
Sampled Number
1 2 AVG 1 Hr. 2 Hr. 3 Hr. 4 Hr. 5 Hr. 8 Hr. 11 Hr. 14 Hr. 17 Hr. 20 Hr. 23Hr. 24 Hr. 1 Hr. 2 Hr. 3 Hr. 5 Hr. 10 Hr. 15 Hr. 20 Hr. 24 Hr. 1/25m
< 15 Sec < 15 Secs > 0.05 > 0.3 > 1.0
04-12-15
05-12-15 2:00 7.9 7.9 7.9 9.8 1258 28 36 48 0.19 0.55 7.17
05-12-15 8:00 7.9 7.9 7.9 7.1 1273 28 39 48 0.15 0.52 5.52
05-12-15 23:00 7.9 7.9 7.9 9.7 1272 25 40 49 0.21 0.58 6.90
06-12-15 20:00 7.9 7.9 7.9 10.1 1251 23 34 44 0.14 0.69 7.45
06-12-15 22:00 7.9 7.8 7.9 10.4 1238 25 35 45 0.15 0.66 6.90
06-12-15 23:00 7.9 7.8 7.9 10.3 1242 24 35 46 0.18 0.63 7.17
07-12-15 1:00 8.1 8.2 8.1 9.8 1218 18 35 50 0.14 0.58 6.34
07-12-15 7:00 7.9 7.9 7.9 7.1 1269 20 33 43 0.14 0.47 5.52
07-12-15 10:00 7.9 8.0 7.9 7.1 1264 23 35 45 0.14 0.50 5.52
07-12-15 15:00 7.9 7.9 7.9 7.1 1270 19 31 41 0.15 0.52 5.52
07-12-15 18:00 8.2 8.2 8.2 9.7 1234 15 34 49 0.14 0.61 6.62
07-12-15 22:00 8.2 8.3 8.3 9.5 1248 13 35 48 0.15 0.63 7.17
08-12-15 7:00 7.9 7.9 7.9 7.1 1255 19 30 46 0.15 0.52 5.79
08-12-15 11:00 7.9 8.0 7.9 7.1 1251 16 28 44 0.15 0.50 5.52
08-12-15 17:00 7.9 8.0 8.0 9.7 1308 15 25 36 0.22 0.63 6.90
08-12-15 23:00 7.8 7.9 7.9 10.0 1287 18 29 39 0.19 0.58 7.17
09-12-15 7:00 8.0 8.1 8.0 7.5 1216 18 39 53 0.15 0.52 5.52
10-12-15
11-12-15
12-12-15 8:00 7.9 7.9 7.9 7.5 1273 29 40 49 0.15 0.52 5.52
13-12-15
14-12-15
15-12-15
16-12-15
17-12-15
18-12-15
19-12-15 0:00 8.2 8.2 8.2 9.4 1208 9 11 13 0.14 0.52 6.07
19-12-15 8:00 8.0 8.1 8.1 7.5 1269 21 33 45 0.14 0.50 5.52
19-12-15 12:00 8.1 8.1 8.1 7.5 1270 24 35 48 0.14 0.52 5.52
19-12-15 19:00 8.2 8.1 8.2 9.5 1184 10 13 14 0.14 0.50 5.52
20-12-15 10:00 8.1 8.2 8.1 7.5 1280 21 30 44 0.14 0.47 5.52
21-12-15
22-12-15
23-12-15
24-12-15 12:00 8.0 8.0 8.0 7.5 1238 24 39 48 0.14 0.50 5.52
24-12-15 15:00 7.9 7.9 7.9 7.4 1240 25 39 49 0.14 0.52 5.52
25-12-15
26-12-15 8:00 8.0 8.0 8.0 7.6 1296 25 39 48 0.14 0.52 5.79
27-12-15 0:00 8.1 8.1 8.1 9.6 1218 9 14 23 0.15 0.55 6.07
27-12-15 10:00 8.0 8.1 8.1 7.6 1269 20 33 43 0.14 0.50 5.52
27-12-15 13:00 8.1 8.1 8.1 7.5 1272 18 30 40 0.14 0.47 5.52
Flow (SEC.) Gel Time Density Bleeding (%) Initial Set Time (MPA) Volume Required
Date Certificate 3
Time Ref No: Marsh Cone (SEC.) (KG/M ) BS 8110 ASTM C403 Batched M Samples
Sampled Number
1 2 AVG 1 Hr. 2 Hr. 3 Hr. 4 Hr. 5 Hr. 8 Hr. 11 Hr. 14 Hr. 17 Hr. 20 Hr. 23Hr. 24 Hr. 1 Hr. 2 Hr. 3 Hr. 5 Hr. 10 Hr. 15 Hr. 20 Hr. 24 Hr. 1/25m
< 15 Sec < 15 Secs > 0.05 > 0.3 > 1.0
27-12-15 21:00 8.2 8.1 8.2 9.5 1184 10 13 19 0.14 0.50 5.52
28-12-15 6:00 8.2 8.2 8.2 7.6 1287 23 30 44 0.14 0.52 5.52
29-12-15 9:00 8.1 8.2 8.2 7.5 1259 20 29 44 0.14 0.50 5.79
29-12-15 12:00 8.2 8.2 8.2 7.6 1262 23 31 46 0.14 0.52 5.79
30-12-15
31-12-15 1308.0 53
27039
Total Compliance % 72
8.0
6.0
4.0
2.0
0.0
0 100 200 300 400 500 600 700 800 900 1000 1100 1200 1300 1400 1500 1600 1700 1800 1900 2000 2100 2200 2300 2400 2500
Setting Mpa
16.0
1 Hour Set Time 2 Hrs
14.0
12.0
Set Time 24 Hours
10.0
Mpa
8.0
6.0
4.0
2.0
0.0
1 101 201 301 401 501 601 701 801 901 1001 1101 1201 1301 1401 1501 1601 1701 1801 1901 2001 2101 2201 2301 2401
16.0
Gel Time
Gel Time - Seconds
14.0
12.0
10.0
Seconds
8.0
6.0
4.0
2.0
0.0
0 100 200 300 400 500 600 700 800 900 1000 1100 1200 1300 1400 1500 1600 1700 1800 1900 2000 2100 2200 2300 2400 2500