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1A.Mohd Mustafa Al Bakri, 1G. Che Mohd Ruzaidi, 2M.N. Norazian, 1H. Kamarudin & 1S. Mohammad Tarmizi
1Schoolof Material Engineering and 2School of Environmental Engineering, Universiti Malaysia Perlis, P.O Box 77, d/a Pejabat
Pos Besar, 01007 Kangar, Perlis.
email: mustafa_albakri@unimap.edu.my
ABSTRACT
Quantities of polymer wastes have been increased these recent years due to the boost in
industrialization and the rapid improvement in the standard of living. In Malaysia, most of polymer
wastes is abandoned and not recycled. This situation causes serious problems such as wastage of
natural resources and environmental pollution. Polymer products such as synthetic fibers, plastics
and rubber belong to petrochemical compound and uneasily degrade in the natural environment.
Plastic materials are not easily biodegradable even after a long period. In fact wide variety of waste
materials can be utilized as inert in cement matrix. In this research, trash bag plastics are used as
polymer wastes HDPE for preparation of the polymer concrete (PC). The aim of this work is to
study the properties and characterization of polymer HDPE as the replacement of coarse
aggregate in concrete. Heating process were done at five different temperature; 160C,
170C,180C, 190C and 200C . Five compositions of coarse aggregate with different crushed
stone: HDPE waste ratios were used that are 0:100, 15:85, 30:70, 45:55, and 60:40 by volumetric
method. The comparisons of conventional concrete with polymer waste as coarse aggregate were
investigated. The effects of polymer wastes on the workability and strength of the concrete with
fresh and hardened concrete tests were analyzed. The compressive strength was measured after
28 days and it was found that the PC is suitable for nonstructural usage. As for cost analysis, the
results showed that the PC is more cost effective than conventional concrete.
1. Introduction
Since landfill sites in general are becoming overcrowded and expensive for waste procedures, and
then wherever possible, materials going to disposal should be minimized. If the production of the waste can
not be prevented, then it is attractive to create an alternative use in another process before considering
disposal. The benefits of his recycling can be economical, due lower costs of removing the waste, such as
reduction in pollution and contamination (Dhir Newlands Csetenyi, 2003).
This paper presents data to show the polymer wastes in Malaysia are not 100% recycled. Polymer
recycling has been through reprocessing of the waste materials into other polymeric items or energy
recovery from complete combustion. However, polymer reprocessing is limited in the number of recycling
cycle, since contamination and thermal degradation result from the steps of melting and reshaping
(Mustafa, 2007).
Development of concrete with non-conventional aggregate such as polystyrene foam wastes,
HDPE, PET and others plastic were used in concrete to improve the properties of the concrete and reduce
cost. By using these plastic wastes in concrete its will lead to sustain the concrete design and greener the
environments.
2. Experimental Programme
The target of the experimental program was to determine the contribution of the waste aggregate type
to the development of the strength behavior of the confined concrete. The experimental program also
comprises the following:
1) To study the characterization of HDPE polymer waste aggregate to compare with crushed stone
coarse aggregate.
2) To study the behavior of fresh and hardened concrete with polymer waste coarse aggregate and
compare the respective properties with conventional concrete.
3) To produce the lightweight polymer concrete for multi purpose use.
2.2 Characterization
Thermal analysis was performed using a Differential Scanning Calorimeter (DSC) by Research
Instrument with a constant nitrogen flow rate at 20 ml/min. The investigated temperature range was
between 20 -180C. The samples were heated at 15C/min up to 180C, held at the temperature for 5
minute and cooled at 15C/min until 20C. Each sample (4-6 mg) was weighed and sealed in the
aluminium vessel.
Heat the plastics waste after shaped it in the oven following the result from DSC over the melting
temperature. Heat the plastics waste with different temperature stat 160-200C to search the best
temperature to give the best properties to aggregate in concrete.
After the heat treatment, the characterization for aggregate testing was determined such as size
and shape, surface texture, water absorption, color, and compression test.
Compression test cube test and flexural test for beam were determined using Universal Testing
Machine, operated at 3.0 kN/sec crosshead speed. All the result was performed after the cubes failure
occurred. The results of the compression test and flexural test were obtained by averaging the values at
least three measurement.
2.3 Procedure
2.3.1Mixing
The raw materials like water, Portland cement, sand and coarse aggregate was mixed. The mix of
design depends on the mix proportion ratio is 1:1.75:2.75.This ratio is referred from the previous research
of Yun-Wang Choi, etc., 2005 [12] were used waste PET bottles as coarse aggregate. In this research the
different only with ratio plastics waste to crushed stone were used (100% plastic waste, 80:20, 60:40 and
100% crushed stone) with water cement ratio are same 0.5 . The mixing process with homogeneous to
ensure the proper coating of cement on aggregate. The mixing process also must be through and not
rushed. During the mixed the raw materials together, add small amounts of water while mixing. The
consistency should be similar to that of cookie dough.
2.3.2 Mix proportion
The constituents were used in different fractions to determine mixture proportions that would yield
the targeted compressive strength at the test age of 28 days. The optimum mix proportions include cement,
sand, coarse aggregate, plastics waste and water to yield a cubic meter of concrete. Table 1 showed for all
the sampling plastics waste coarse aggregate concrete mixes were designed by the volumetric method with
the same water cement ratio is 0.5 .
Table 1: Mix proportion for concrete design
Mix Proportion
( Plastics waste : Gravel )
M1 ( 100 : 0 % )
M2 ( 80:20 % )
M3 (60:40 % )
M4 ( 0: 100 %)
2.3.3Slump test
Workability is that property of the concrete which determines its ability to be placed, compacted
and finished. Workability is often defined in terms of the amount of mechanical energy, or work, required to
fully compact concrete without segregation. Workability may be measured by the slump test, compacting
factor test and Vebe test. In the laboratory, the entire model of mix proportion measured by the slump cone
test.
water
color weight before, w1 weight after, w2 absorption
(g) (g) (%)
% water : W2 - W1 x 100 %
absorption W1
3.1.6 Color
Plastic trash bag has many types of color. The color of plastic depends on the pigment during the
processing of bag plastics. In this research, the color of aggregate will make as attraction different with the
crushed stone.
3.1.7 Compressive Strength and Flexural Strength
Table 3: Properties of Plastics Waste Coarse Aggregate Concrete and Conventional Concrete Mixes at 28 days
The mechanical properties of plastics waste coarse aggregate are presented in Table 3. The
results presented in the Table showed the fresh plastics waste coarse aggregate has lower water
absorption and smooth surface texture of the plastics waste coarse aggregate. Plastics usually not absorb
water although the aggregate after modified in heated; the plastics waste aggregate more dense. During
the mixing process, it can be reduce water content was used.
The compressive strength for cubes varied from 11-19 MPa. As far as strength are concerned, the
basic trend in the behavior of plastics waste coarse aggregate concrete is not significantly different from
that of the conventional crushed stone aggregate for lightweight concrete.
The flexural strength varied from 9-15MPa. The variations in flexural strength between plastics
waste concrete and conventional concrete are slightly very small. Form the fracture surface showed the
plastics waste not has strong interlocking bonding with cement.
4. Conclusion
The aim of this research was to evaluate the recyclability of domestic plastics waste as coarse aggregate
for concrete. From the results and discussion, the following conclusions are drawn:
1) The physical analysis of plastics waste coarse aggregates gave the value of 12-17 MPa in
compressive strength, 1400-1550 kg/m3 for density concrete, 5-7% in water absorption for
aggregate, and suitable as coarse aggregate for concrete. However, the size and shape can be
achieved in range 14-20 mm but the aggregate have smooth surface which are considered to
severely affect their workability.
2) The compressive and flexural strength of concrete containing the plastics waste a decreasing when
the plastics waste increase. The concrete containing plastics waste aggregate of 60:40 % mixing
ratio gave the highest strength properties. The connection between plastics waste aggregate and
crushed stones will give the higher strength and better properties.
3) Additionally, the mechanical properties of the concrete did not display any notable differences
depending on color of the plastic waste aggregate. The color or pigment of plastics waste will give
the attraction to the decoration products.
4) This research also has more potential application to produce light weight concrete, cost saving on
raw materials from plastics waste and to minimize the polymer waste as a municipal solid waste
and suitable for decorative and landscaping product for attractive appearance.
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