Nama : Fachri Fachrul Qashmal

NIM : 14521279

1. Hexamine dibuat dari ammonia dan formaldehyde mengikuti reaksi berikut ini :
4NH3 + 6HCHO (CH2)6N4 + 6H2O
(A) (B) (C) (D)

Hasil eksperimen menunjukkan bahwa persamaan kinetika reaksi :

2
rA = kCACB

K= 1,42 x 103 27200 E dalam J/mol

.

Reaksi dijalankan di dalam RATB pada kondisi adiabatis, tekanan atmosferis, dan suhu

36oC . Umpan terdiri dari dua arus yaitu larutan ammonia 4,06 mol/L dan larutan
formaldehyde 6,32 mol/L. Kedua arus memiliki laju alir volumetris yang sama.

Jika diinginkan produk hexamine pada arus keluar reaktor sebesar 15.000 ton/tahun
dengan konversi sebesar 87% , hitung volume reaktor yang dibutuhkan.

Komponen Mula-mula (mol) Bereaksi (mol) Sisa

NH3 FA0 FA0.X FA = FA0 - FA0.X
HCHO FB0 (6/4) FA0.X FB = FB0 - (6/4) FA0.X
(CH2)6N4 FC0 (1/4) FA0.X FC = FC0 + (1/4)FA0.X
H2O FD0 (6/4) FA0.X FD = FD0 + (6/4) FA0.X
Total FT0 FT = FT0 + [(6/4) + (1/4 )- (6/4) - 1] FA0.X
Penyelesaian :

4NH3 + 6HCHO CH2)6N4 + 6H2O

(4A) (6B) (1C) (6D)

Neraca Massa :

[(Rate of flow of A in) + (Rate of flow of B in)] [(rate of flow A out) + (rate of
flow B out)] [rate of reaction] = [rate of accumulation]

Maka : 0 + 0 ( ) =0

Di mana : = 0 0.

B = B0 0.

B = B0 0. X

Sehingga,
FA0 + FB0 (FA0 FA0.X) (FB0- .FA0.X) (-rA)V= 0

(FA0.X+ .FA0.X) = (-rA)V

. .
V= ( ! )
#

$
.
V = (%&
&' )

Mencari FA0

4NH3 + 6HCHO (CH2)6N4 + 6H2O

(4A) (6B) (1C) (6D)

 () *+, ( * -., ( - !1 ( 5 3+6 (
Fc = / / / /
* -., 0) - !1 (22 34,1* ( *+, 3+6 (2 *+,/*+,3+6

Fc = 203,849 mol/menit

9
Fc =8 9 + . ;

(
Fc = 80 + . ;
2

(
Fc =2 .

2< ,>2? 3+6/34,1*

FA0 =
,>@

FA0 = 937,23 mol/menit

Mencari k
R = 8,314 Joule/mol K
T = 36C = 309 K

@
k = 1,42/10exp 8 HI
;

@
k = 1,42/10 exp J #
>, (2 ?%
KLMN

k = 0,0358R /STUW

Mencari CA dan CB
CA0 = 4,06 mol/L
CB0 = 6,32 mol/L

CA = CA0-CA0.X
CA = 4,06-(4,06 x 0,87)
CA = 0,5278 mol/L
 CB = CB0 - CA0.X
0
CB = 6,32 - 8 / 4,06/0,87;
2

CB = 1,0217 mol/L

Volume reactor yang di butuhkan ;

FAO = 937,235
X = 87% = 0,87
CA = 0,5278 mol/L
CB = 1,0217 mol/L
k = 0,0358 L mol s

Maka :
$
.
V = (%& &' )
Z KLM _ K[\]^
< ? @, ) < < ,>@
= `
K[\]^
KLM
5 Z
KLM
, )> < ,) @> < (, (@ 8 ;
KLM Z ` `

= 1722,492 Liter