CALCULOS Y RESULTADOS

Datos experimentales:

Alturas(cm) Tubo #1 Tubo #2 Tubo #3 Tubo #4 Tubo #5

En cada tubo 5.9 6 6 5.4 6.3
Tubo #1 comparado con el 1.6 1.9 2.7 5
Ecuaciones qumicas:
Fe(NO3)3(ac) + KSCN(ac) FeSCN(NO3)3(ac) + KNO3(ac)
Fe3+ + SCN- FeSCN2+
En el tubo #1(estndar) tenemos:
-5ml de KSCN(ac) 0.002M, #moles= 0.00001 moles, masa=
(0.00001mol).(97g/mol)= 0.00097g

-5ml de Fe(NO3)3(ac) 0.05M, #moles= 0.00025mol, masa=

(0.00025mol).(242g/mol)= 0.0605 g

En la reaccin:

Fe(NO3)3(ac) + KSCN(ac) FeSCN(NO3)3(ac) + KNO3(ac)

242 g/mol 97 g/mol 238 g/mol

0.0605 g 0.00097 g 0.00238 g
R.E. R.L #moles= 0.00001 mol

M = #moles/volumen = 0.00001mol/0.01L= 0.001mol/L=[FeSCN(NO3 )3 ]

FeSCN(NO3)3(ac) FeSCN2+ + 2NO3-(ac)

Inicio 0.001M - -
Rx 0.001M 0.001M 0.002M
Final 0 0.001M 0.002M

[FeSCN +2 ]estndar= 0.001M

En el tubo#2:
-Hallamos la concentracin de la solucin diluida de Fe(NO3)3(ac)
M1xV1 = M2xV2
(0.05M)x(10ml) = M2x(25ml)
M2= 0.02 #moles/L=[Fe(NO3 )3 ] = [Fe+3 ]inicial
 altura del estandar
-Relacin de alturas = = 5.1cm/6.8cm= 0.750
altura del tubo #2

-[FeSCN +2 ]eq=(Relacin de alturas)x[estandar]

= (0.750)x(0.001M)= 0.00075M
-[Fe+3 ]eq = [Fe+3 ]inicial - [FeSCN +2 ]eq= 0.02M 0.00075M= 0.01925M
-[SCN ]eq = [SCN ]iinicial - [FeSCN +2 ]eq= 0.002M 0.00075M= 0.00125M
[FeSCN+2 ]eq 0.00075
-Keq = [Fe+3 ]
= = 31.16
eq [SCN ]eq (0.01925)(0.00125)

En el tubo #3:

- Hallamos la concentracin de la solucin diluida de Fe(NO3)3(ac)

M1xV1 = M2xV2
(0.02M)x(10ml) = M2x(25ml)
M2= 0.008 #moles/L = [Fe(NO3 )3 ] = [Fe+3 ]inicial

altura del estandar

- Relacin de alturas = = 4.95cm/6.95cm= 0.712
altura del tubo #2

-[FeSCN +2 ]eq = (Relacin de alturas)x[estandar]= (0.712)x(0.001M)

= 0.000712M
-[Fe+3 ]eq= [Fe+3 ]inicial - [FeSCN +2 ]eq = 0.008M 0.000712M= 0.007288M

-[SCN ]eq= [SCN ]iinicial - [FeSCN +2 ]eq= 0.002M 0.000712M= 0.001288M

[FeSCN+2 ]eq 0.000712
- Keq = = = 75.85
[Fe+3 ] eq [SCN ] eq (0.007288)(0.001288)

En el tubo #4:

- Hallamos la concentracin de la solucin diluida de Fe(NO3)3(ac)

M1xV1 = M2xV2
(0.008M)x(10ml) = M2x(25ml)
M2= 0.0032 #moles/L = [Fe(NO3 )3 ] = [Fe+3 ]inicial
altura del estandar
- Relacin de alturas = = 4.55cm/6.75cm= 0.674
altura del tubo #2

-[FeSCN +2 ]eq = (Relacin de alturas)x[estandar]= (0.674)x(0.001M)

= 0.000674M
-[Fe+3 ]eq= [Fe+3 ]inicial - [FeSCN +2 ]eq= 0.0032M 0.000674M= 0.002526M

-[SCN ]eq= [SCN ]iinicial - [FeSCN +2 ]eq= 0.002M 0.000674M= 0.001326M

[FeSCN+2 ]eq 0.000674
- Keq = [Fe+3 ] [SCN ]
= = 201.22
eq eq (0.002526)(0.001326)
 En el tubo #5:

- Hallamos la concentracin de la solucin diluida de Fe(NO3)3(ac)

M1xV1 = M2xV2
(0.0032M)x(10ml) = M2x(25ml)
M2= 0.00128 #moles/L = [Fe(NO3 )3 ] = [Fe+3 ]inicial

altura del estandar

- Relacin de alturas = = 3.4cm/8.8cm= 0.386
altura del tubo #2

-[FeSCN +2 ]eq= (Relacin de alturas)x[estandar]= (0.386)x(0.001M)

= 0.000386M
-[Fe+3 ]eq= [Fe+3 ]inicial - [FeSCN +2 ]eq= 0.00128M 0.000386M

= 0.000894M
-[SCN ]eq= [SCN ]iinicial - [FeSCN +2 ]eq= 0.002M 0.000386M

= 0.001614M
[FeSCN+2 ]eq 0.000386
- Keq = [Fe+3 ] [SCN ]
= = 267.51
eq eq (0.000894)(0.001614)