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Akzo Nobel Functional Chemicals LLC

MATERIAL SAFETY DATA SHEET


Carbon Disulfide

1. CHEMICAL PRODUCT AND COMPANY INFORMATION


Product Name: Carbon Disulfide
Chemical Name: Carbon disulfide
Synonym: Carbon bisulfide; Dithiocarbonic anhydride
C.A.S. Registry No.: 75-15-0
Chemical Formula: CS2 (S=C=S)
Product Use: Chemical intermediate / Solvent
Manufacturer / Supplier
Akzo Nobel Functional Chemicals LLC
Sulfur Products
5555 Spalding Drive, Suite 100
Norcross, GA, 30092
Tel.: 1-770-246-4621 [Product & Technical Information]
Emergency Telephone Numbers
FOR CHEMICAL EMERGENCY (Spill, Leak, Fire, Exposure or Accident)
CHEMTREC (24-hr): (800) 424-9300 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands)
(703) 527-3887 (For calls originating elsewhere / collect calls are accepted)

CANUTEC (Canada): (613) 996-6666

FOR MEDICAL / HANDLING EMERGENCIES: 1-888-578-5387

Date of First Issue: January 4, 1995 Revision No.: 16.0


Revision Date: March 16, 2009 Changes: Section 8

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW

This material is considered hazardous by the OSHA Hazard Communication Standard [29 CFR 1910.1200]

DANGER !
Extremely flammable liquid and vapor.
Vapor may cause flash fire. May form explosive mixtures with air.
May be fatal if inhaled or swallowed.
Harmful if absorbed through the skin.
Causes skin, eye and respiratory tract irritation.
Overexposure may cause adverse effects to the central nervous system, reproductive
system and cardiovascular system.

Appearance and odor: clear colorless to slightly yellow liquid with an ether-like to slightly disagreeable sulfur
odor.

Fire and Explosion Hazards: This product is a highly flammable material. Under fire conditions, this product will
give off toxic and flammable vapor, which may travel to a source of ignition and flash back. Carbon disulfide
forms explosive vapor/air mixtures over a wide vapor concentration range.

POTENTIAL HEALTH EFFECTS [See Section 11 for additional information]


Primary Route(s) of Exposure: Skin contact, eye contact, skin absorption and inhalation of vapor.

Issue date: 16-Mar-09 MSDS No.: 16 084803


Revision No: 16.0 Page 1 of 9
Material Safety Data Sheet
Akzo Nobel Functional Chemicals LLC Carbon Disulfide

2. HAZARDS IDENTIFICATION (CONTINUED)


Acute Exposure
Inhalation Inhalation of vapor, mist, aerosol or fume of carbon disulfide may cause headache, nausea,
drop in blood pressure, dizziness, unconsciousness and possibly death. High concentrations of the vapor
may cause irritation of the nose.
Skin Contact Carbon disulfide can cause skin irritation. Splashes on the skin may cause blistering. This
product is readily absorbed through the skin resulting in nerve damage near the site of absorption.
Symptoms are similar to those for inhalation.
Eye Contact Eye contact may cause severe irritation. May cause permanent eye damage if not flushed
out immediately.
Ingestion If swallowed, this product may cause severe irritation or burns of the mouth, throat, esophagus
and stomach. Swallowing small amounts may cause vomiting, diarrhea and headache. Swallowing large
amounts may result in loss of consciousness and convulsions. Death has been reported following ingestion
of small amounts of carbon disulfide.

Chronic Exposure: Studies have reported adverse (harmful) effects on the central and peripheral nervous
systems and blood vessels. Exposure to carbon disulfide also carries a possible risk of impaired fertility and
harm to the unborn child.

Carcinogenicity: IARC, NTP, ACGIH and OSHA do not classify this material or its components as a
carcinogen or suspect carcinogen.

Medical conditions aggravated by exposure: Persons with pre-existing conditions related to central and
peripheral nervous systems, eyes, cardiovascular system, kidneys, liver and alcoholism.

POTENTIAL ENVIRONMENTAL EFFECTS (see section 12 for additional information)


This product is expected to be toxic to aquatic organisms (based on available data).

3. COMPOSITION / INFORMATION ON INGREDIENTS


INGREDIENTS [See section 8 for exposure limits] % (w/w) CAS Number

Carbon disulfide 100.0 75-15-0

4. FIRST AID MEASURES


Inhalation: Remove victim to fresh air while protecting yourself from exposure with an appropriate respirator.
Remove any contaminated clothing (preferably in a safety shower) to prevent further inhalation exposure. Use
gloves to avoid contaminating yourself. If the victim is having difficulty breathing or is not breathing, clear the
victims airway and start artificial respiration. Call 911 for emergency transportation. Avoid inhaling the victims
exhaled air. Artificial respiration can be supplemented by the use of a bag-mask respirator or manually triggered
oxygen supply capable of delivering one liter per second or more. If victim is breathing, supplemental oxygen
may be given from a demand-type or continuous-flow inhaler, preferably with a physicians advice. Monitor
breathing and pulse. If the victim stops breathing at any time, restart artificial respiration. If heart has stopped,
begin cardiopulmonary resuscitation immediately. Keep person warm and at rest. Get medical attention
immediately.

Skin Contact: Immediately flush skin with plenty of cool potable running water for at least 20 minutes while
removing contaminated clothing, shoes and equipment. Do not attempt to neutralize with chemical agents.
Obtain medical advice immediately. Wash contaminated clothing and shoes before reuse or discard.

Issue date: 16-Mar-09 MSDS No.: 16 084803


Revision No: 16.0 Page 2 of 9
Material Safety Data Sheet
Akzo Nobel Functional Chemicals LLC Carbon Disulfide

4. FIRST AID MEASURES (CONTINUED)


Eye Contact: Immediately flush eyes with large quantities of cool potable running water for a minimum of 15
minutes. If easy to do, remove contact lenses, if worn. Take care not to contaminate the victims healthy eye or
skin. Hold the eyelids apart during the flushing to ensure rinsing of the entire surface of the eye and lids with
water. DO NOT let victim rub eye(s). Do not attempt to neutralize with chemical agents. Oils or ointments should
not be used at this time. Get medical attention immediately. Continue flushing for an additional 15 minutes if a
physician is not immediately available.

Ingestion: Do not induce vomiting. If victim is conscious and alert, rinse mouth and give several glasses of
water to drink. Call a physician or a poison control center immediately. If vomiting occurs, keep head below hips
to reduce risk of aspiration. Give fluids again. Never give anything by mouth to a person who is unconscious or
convulsing.

Note to Physician: Attending physician should treat exposed patients symptomatically.

5. FIRE FIGHTING MEASURES


Conditions of Flammability: highly flammable liquid
Flash Point (Method): - 22F (-30C) / Closed Cup
Upper Flammable Limit (% by volume): 60%
Lower Flammable Limit (% by volume): 0.6%
Auto-Ignition Temperature: 194-203F / 90-95C

Extinguishing Media: Use water spray and/or foam to extinguish and cool fire and surroundings.

Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke, fumes or products of
combustion. Evacuate all non-essential personnel from the fire area. Stay upwind. Fire fighters should wear full-
face, self-contained breathing apparatus and impervious, fire resistant, protective clothing, gloves and boots. If
possible, move containers from the fire area. If not leaking, keep fire exposed containers cool with a water fog or
spray to prevent rupture due to excessive heat. High pressure water may spread product from broken containers
increasing contamination or fire hazard. If you do not have a continuous source of water, do not attempt to fight
a major fire.
Large carbon disulfide fires are best extinguished by completely blanketing the fire area with water spray, fog or
foam. This will help prevent possible re-ignition of the product. Continue application of the water spray/fog until
the fire area is completely cooled off. Do not walk through water-covered pools of carbon disulfide.
Contaminated buildings, areas and equipment must not be used until they are properly decontaminated. Dike
fire control water for later disposal. Do not allow contaminated water to enter waterways.

Fire and Explosion Hazards: This product is a highly flammable material. Under fire conditions, this product will
give off toxic and flammable vapors, which may travel to a source of ignition and flash back. Carbon disulfide
forms explosive vapor/air mixtures over a wide vapor concentration range.
Hazardous Combustion Products: Thermal decomposition products include carbon dioxide, carbon monoxide
and sulfur oxides. Carbon oxide sulfide may also be produced.

NFPA 704 Hazard Rating Health: 3 Flammability: 3 Instability: 1 Other: None


[ 0 Minimal 1 Slight 2 Moderate 3 High 4 Extreme ]

6. ACCIDENTAL RELEASE MEASURES


Spill or Leak / Cleanup: Safely stop source of spill, if possible. Remove all sources of ignition from the spill
area. If tools are need, they should be non-sparking. Dike area to prevent spill from spreading and cover with
water or foam. If permitted to enter sewers, this material may create a fire or explosion hazard. Prevent
formation of flammable and/or oxygen-deficient atmosphere in enclosed areas. A water fog, fine spray or blanket
of fire-fighting foam can be used to reduce vapors. Evacuate all non-essential personnel upwind.

Issue date: 16-Mar-09 MSDS No.: 16 084803


Revision No: 16.0 Page 3 of 9
Material Safety Data Sheet
Akzo Nobel Functional Chemicals LLC Carbon Disulfide

6. ACCIDENTAL RELEASE MEASURES (CONTINUED)


Any person entering an area of a significant spill or of an unknown concentration of gas or vapor should use a
NIOSH-approved, positive-pressure/pressure-demand, self-contained breathing apparatus. Protective equipment
to prevent skin and eye contact should be worn at all time. Do not enter areas over 2000 ppm of carbon
disulfide. Contact Akzo Nobel Functional Chemicals LLC for guidance.

NOTE The following CERCLA Section 103 reportable quantity applies to this product: RQ = 100 lb (45.4 kg)
The Superfund Amendments and Reauthorization Act (SARA) Section 304 requires that any release equal to or
greater than the reportable quantity established for that substance be immediately reported to the local
emergency planning committee and the State Emergency Response Commission. If the release of a substance
is reportable under CERCLA Section 103, the National Response Center must be notified immediately.

7. HANDLING AND STORAGE


Handling: Containers should be located in an area where they can be rotated regularly (first in, first out) and
visually inspected for damage or bulging on a regular basis. Use approved equipment for transport of containers
to avoid puncturing or rupturing containers. Do not use air pressure to empty containers. Wear protective
clothing including impervious protective coveralls or apron, a face shield, goggles and gloves or similar
protection when handling this product to avoid skin and eye contact. Wash thoroughly after handling and launder
all protective clothing and footwear or discard if necessary. Emergency eye wash and safety shower stations
should be available to those handling this material. Emptied containers may retain residues. Follow all warnings
and precautions even after the container is emptied.

Storage: Store away from foodstuffs or animal feed. Exercise due caution to prevent damage to or leakage
from the container. Firefighting equipment should be immediately available. Protect against lightning and static
electricity. Electrical installations and heating facilities should not be permitted in or near storage areas.
Contact Akzo Nobel Functional Chemicals LLC for guidance.

Maximum Storage Temperature: Not determined

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Applicable Exposure Limits: In addition to any exposure limits which may be displayed below, carbon
disulfide has a SKIN notation by OSHA, ACGIH and NIOSH, due to its toxicity by skin absorption.

OSHA PELs ACGIH TLVs NIOSH RELs AIHA WEELs


Chemical Name STEL / STEL / STEL / STEL /
TWA TWA TWA TWA
CEIL[C] CEIL[C] CEIL[C] CEIL[C]
30 ppm [C] 1 ppm 1 ppm 10 ppm
Carbon disulfide 20 ppm 1 N/D 3 N/D N/D
100 ppm 3.13 mg/m
3
3 mg/m 30 mg/m3
1
30-min peak per 8-hr shift [Ref: ACGIH Guide to Occupational Exposure Values, 2008 Edition]

BEI: On January 30, 2009, ACGIH ratified the Biological Exposure Index (BEI) for carbon disulfide. The sampling
time is End of shift, the BEI = 0.5 mg/g creatinine with notations of Ns (nonspecific) and B (background).

Legend:
CEIL: Ceiling Exposure Limit PEL: Permissible Exposure Limit REL: Recommended Exposure Limit
STEL: Short Term Exposure Limit TLV: Threshold Limit Value TWA: Time-Weighted Average
N/D: Not Determined WEEL: Workplace Environmental Exposure Level
ACGIH: American Conference of Governmental Industrial Hygienists
AIHA: American Industrial Hygiene Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration

IDLH (Immediately Dangerous to Life & Health) Concentration for Carbon Disulfide: 500 ppm

Issue date: 16-Mar-09 MSDS No.: 16 084803


Revision No: 16.0 Page 4 of 9
Material Safety Data Sheet
Akzo Nobel Functional Chemicals LLC Carbon Disulfide

8. EXPOSURE CONTROLS / PERSONAL PROTECTION (CONTINUED)


Engineering Controls Ventilation: Sufficient natural or mechanical ventilation must be provided to keep
concentrations of vapors or aerosol mists below applicable exposure limits and to help minimize exposures.
Where ventilation is inadequate based on conditions of use, personal protective equipment is needed. If use
conditions generate airborne aerosol, the material should be handled in an open (e.g. outdoor) or well ventilated
area.

Personal Protective Equipment (PPE)


Respiratory Protection: If use conditions generate vapor, mist or aerosol and adequate ventilation (e.g.,
outdoor or well-ventilated area) is not available, use a NIOSH-approved respirator to reduce potential for
inhalation exposure. Where exposure potential necessitates respiratory protection, use a NIOSH-approved,
positive-pressure/pressure-demand, air-supplied respirator.
Skin Protection: Skin contact with the product must be prevented through the use of suitable protective
clothing, gloves and footwear selected according to use condition exposure potential. Viton gloves are
recommended. Safety showers should be readily available in all areas where this material is handled.
Eye Protection: Eye contact with this material must be prevented through the use of chemical safety
splash goggles or a face shield selected with regard to use condition exposure potential. Contact lenses
should not be worn when working with carbon disulfide. Eye wash fountains or other means of washing the
eyes with a gentle low of water should be readily available in all areas where this product is handled or
stored. Water should be supplied through insulated or heat-traced lines to prevent freeze-ups in cold
weather.

Other Protection General Hygiene Considerations: Safety showers, with quick opening valves, which stay
open, and eyewash fountains, or other means of washing the eyes with a gentle flow of cool to tepid tap water,
should be readily available in all areas where this material is handled or stored. Water should be supplied
through insulated and heat-traced lines to prevent freeze-up in cold weather. Long sleeved clothing, such as
NomexTM IIIA may be used to minimize skin contact. All food and smoking materials should be kept in a
separate area away from the storage/use location. Eating, drinking and smoking should be prohibited in areas
where there is a potential for significant exposure to this material. Before eating, drinking and smoking, hands
and face should be thoroughly washed.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical State / Appearance / Odor: clear colorless to slightly yellow liquid with a disagreeable sulfur odor

Boiling Point: 115F (46.2C) at 760 mm Hg


Bulk Density: not applicable
Cloud Point: not determined
Evaporation Rate (Butyl Acetate=1): 22.6
Melting Point: - 169F (-111.6C)
Odor Threshold: < 1 ppm
pH: not applicable
Partition Coefficient (n-octanol/water): Log Po/w = 1.9
Pour Point: not determined
Solubility in water: 0.2% (2 g/L at 68F / 20C)
Solubility in other solvents: miscible with organic solvents
Specific Gravity (H2O = 1): 1.26 (at 68F / 20C)
Vapor Density (Air = 1): 2.63
Vapor Pressure: 39.7 kPa (at 68F / 20C)
Viscosity: 0.36 cps (at 73F / 22.8C)
Volatiles (% by weight): not determined
Other: none known

Issue date: 16-Mar-09 MSDS No.: 16 084803


Revision No: 16.0 Page 5 of 9
Material Safety Data Sheet
Akzo Nobel Functional Chemicals LLC Carbon Disulfide

9. PHYSICAL AND CHEMICAL PROPERTIES (CONTINUED)


Conditions of Flammability: highly flammable liquid
Flash Point (Method): - 22F (-30C) / Closed Cup
Upper Flammable Limit (% by volume): 60%
Lower Flammable Limit (% by volume): 0.6%
Auto-Ignition Temperature: 194-203F (90-95C)
< : less than > : greater than : approximately

10. STABILITY AND REACTIVITY


Stability: This product is stable at ambient temperatures and atmospheric pressures when kept in a closed
container. Exposure to ultraviolet light from sunlight may cause carbon disulfide vapor to ignite and explode.

Incompatibilities / Conditions to avoid: This product reacts incandescently with chemically active metals such
as aluminum, zinc, sodium and potassium. Contact with azides and inorganic acids can be explosive. Carbon
disulfide is incompatible with strong oxidizing and reducing agents. Avoid contact with sources of heat and
flame.

Polymerization: Hazardous polymerization is not expected to occur under normal temperatures and pressures.

Decomposition Products: Under fire conditions, the product supports combustion decomposes to give off toxic
materials such as carbons oxides and sulfur oxides. Carbonyl sulfide may also be produced.

11. TOXICOLOGICAL INFORMATION


INHALATION
Acute exposure: The acute LC50 (mice) for this product is 220 ppm for a 1-hour exposure. Inhalation of vapor,
mist, aerosol or fume of carbon disulfide may cause headache, nausea, drop in blood pressure, dizziness,
unconsciousness and possibly death. High concentrations of the vapor may cause irritation of the nose.
Chronic exposure: Rats were exposed to concentrations of approximately 50, 300 or 800 ppm for 6 hours/day,
5 days/week for a period of 90 days. The NOEL was 50 ppm. Reproductive, neurological and cardiac effects
have been reported in humans following repeated or prolonged inhalation exposure.

SKIN
Acute contact: Dermal toxicity (LD50) is not available for this product. Carbon disulfide can cause skin irritation.
Splashes on the skin may cause blistering. This product is readily absorbed through the skin resulting in nerve
damage near the site of absorption. Symptoms are similar to those for inhalation.
Chronic contact: Prolonged or repeated contact can cause loss of skin oils resulting in dry and scaly skin.
Moderate skin irritation can occur.

EYES: Eye contact may cause severe irritation. Eye contact may cause permanent damage if not flushed out
immediately.

INGESTION
Acute exposure: The oral LD50 for this product is greater than 2000 mg/kg (rat).
Chronic exposure: No data available.

SENSITIZATION: No data available.

CARCINOGENICITY: IARC, NTP, ACGIH and OSHA do not classify this material or its components as a
carcinogen or suspect carcinogen.

MUTAGENICITY: Carbon disulfide did not produce an increase in chromosomal aberrations in an inhalation in
vivo mouse micronucleus assay. It was not mutagenic in the Ames test.

Issue date: 16-Mar-09 MSDS No.: 16 084803


Revision No: 16.0 Page 6 of 9
Material Safety Data Sheet
Akzo Nobel Functional Chemicals LLC Carbon Disulfide

11. TOXICOLOGICAL INFORMATION (CONTINUED)


REPRODUCTIVE TOXICITY: Carbon disulfide was not teratogenic to rats at oral doses up to 600 mg/kg/day
when administered during days 6 to 16 of gestation. Pregnant rabbits were exposed by inhalation to carbon
disulfide at concentrations of 60, 100, 300, 600 or 1200 ppm on for 6 hours/day on days 6 to 18 of gestation. The
NOEL was 300 ppm for developmental toxicity and 600 ppm for maternal toxicity.

NEUROTOXICITY: Prolonged or repeated exposure to high levels of carbon disulfide can cause effects to the
central and peripheral nervous systems (decrease in conduction velocity).

OTHER TOXICOLOGICAL EFFECTS: Several studies have indicated an increased risk of coronary heart
disease from exposure to carbon disulfide. In addition, effects on blood pressure and cholesterol levels have
been reported in some epidemiology studies.

TARGET ORGANS: Eyes, skin, respiratory system, central and peripheral nervous systems, cardiovascular
system and reproductive system.

12. ECOLOGICAL INFORMATION


Ecotoxicity: This product is expected to be harmful to aquatic life.

Test / Species Exposure / Duration Test Results


Guppies (Poecilia reticulata) 96-h LC50 = 3 mg/L
Zebra Fish (Brachydanio rerio) Early life stage NOEC = 1 mg/L
Daphnia Magna 48-h EC50 = 2 mg/L

Biodegradation: Carbon disulfide is readily biodegradable (80% in 28 days / Closed Bottle Test).

Other Ecotoxicity information: None known.

13. DISPOSAL CONSIDERATIONS


Waste Disposal: Material that cannot be used or chemically reprocessed and empty containers, except those
designed for multiple uses (returnable), should be thoroughly emptied and disposed of at an approved facility in
accordance with all applicable regulations. This product is a RCRA-listed hazardous waste on disposal due to
its flammability and toxicity characteristics. Generators of waste material are required to evaluate all waste for
compliance with RCRA and any applicable state and local disposal procedures and regulations. Dispose of
waste in accord with local, state and federal regulations. Incineration may be used where permitted by
regulations. NOTE! State and local regulations may be more stringent than federal regulations.

Container Disposal: Containers should be drained and cleaned of residual product before disposal. Do not
contaminate public waters with waste or rinsate. Empty containers should be disposed of in accordance with all
applicable laws and regulations. Contact Akzo Nobel Functional Chemicals LLC for guidance.

14. TRANSPORT INFORMATION


Shipping Information: This product is regulated for shipping as follows:

US DOT RQ, Carbon disulfide, UN1131, 3, PG I


Carbon disulfide, UN1131, 3 (6.1), PG I
Canada TDG
ERAP Index = 1000
IMDG Carbon disulfide, UN1131, 3 (6.1), PG I
IATA / ICAO Forbidden

Issue date: 16-Mar-09 MSDS No.: 16 084803


Revision No: 16.0 Page 7 of 9
Material Safety Data Sheet
Akzo Nobel Functional Chemicals LLC Carbon Disulfide

14. TRANSPORT INFORMATION (CONTINUED)


2008 Emergency Response Guidebook (ERG) No.: 131

Required Labels:
Primary Risk Label Flammable (class 3)
Subsidiary Risk Label Toxic (class 6.1)

Environmentally Hazardous Substances [49 CFR 172.101, Appendix A]:


Carbon disulfide has a Reportable Quantity (RQ) of 100 lb (45.4 kg)

15. REGULATORY INFORMATION


The components are subject to the following environmental regulatory lists:

U.S. STATE RIGHT-TO- CA


Substance Name CAA CERCLA IARC SARA
KNOW LISTS PROP 65
X CA / FL / IL / LA / MA / MN X
Carbon disulfide X N/R X
112 / NJ / PA / RI 302 / 313

National Chemical Inventories Status:

Canada New
Substance US EU Australia Japan Korea Philippines China
Zealand
Name TSCA DSL NDSL EINECS AICS ENCS KECI PICCS IECSC
NZIoC
Carbon
X X X X X X X X X
disulfide
N/R = Non Regulated X = Listed and/or Regulated

Legend
AICS Australian Inventory of Chemical Substances
CA List California Directors List of Hazardous Substances
CA Prop 65 California Proposition 65
CAA Clean Air Act, 112
CERCLA CERCLA Hazardous Substances
DSL Domestic Substances List Canada
EINECS European Inventory of Existing Commercial Chemical Substances
ENCS Japan Existing and New Chemical Substances
FL List Florida Substance List
IARC International Agency for Research on Cancer Carcinogens Groups 1, 2A or 2B
IECSC China Inventory of Existing Chemical Substances
IL List Illinois Toxic Substances Disclosure to Employees Act
KECI Korea Existing Chemicals Inventory
LA List Louisiana Right-to-Know Reporting List
MA List Massachusetts R-T-K Substance List
MN List Minnesota Hazardous Substance List
NDSL Non-Domestic Substances List Canada
NJ R-T-K New Jersey R-T-K Hazard List
NZIoC New Zealand Inventory of Chemicals
PA List Pennsylvania Hazardous Substance List
PICCS Philippines Inventory of Chemicals and Chemical Substances
RI List Rhode Island Hazardous Substance List
SARA SARA Title III, 302 / 313
TSCA Toxic Substances Control Act USA

Canada WHMIS (Workplace Hazardous Materials Information System):


Class B2 [Flammable]
Class D1B [Material causing immediate and very toxic effects]
Class D2A & D2B [Material causing other toxic effects]
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.

Issue date: 16-Mar-09 MSDS No.: 16 084803


Revision No: 16.0 Page 8 of 9
Material Safety Data Sheet
Akzo Nobel Functional Chemicals LLC Carbon Disulfide

15. REGULATORY INFORMATION (CONTINUED)


Other Regulatory Information: WARNING! Carbon disulfide is known to the State of California to cause birth
defects and other reproductive harm.

16. OTHER INFORMATION


HMIS RATING
Health: 3* Flammability: 3 Physical Hazard: 0 Other: none
[ 0 Minimal 1 - Slight 2 - Moderate 3 - High 4 - Extreme * - Chronic Health Hazard (see 11)]

Other Information: None known.

Revision: Section 8

Prepared by: AkzoNobel, Technology & Engineering, [Tel. 312-544-7000]

Reviewed and Approved by: Akzo Nobel Functional Chemicals LLC (Sulfur Products) [Tel. 770-246-4621]

The information in this Material Safety Data Sheet should be provided to all who will use, handle, store, transport or otherwise be exposed to this product. All information concerning this product
and/or all suggestions for handling and use contained herein are offered in good faith and are believed to be reliable as of the date of publication. Akzo Nobel Functional Chemicals LLC, however,
makes no warranty as to the accuracy of and/or sufficiency of such information and/or suggestions, as to the product's merchantability or fitness for any particular purpose, or that any suggested
use will not infringe any patent. Nothing contained herein shall be construed as granting or extending any license under any patent. Buyer shall determine for himself, by preliminary tests or
otherwise, the suitability of this product for his purposes, including mixing with other products. The information contained herein supersedes all previously issued bulletins on the subject matter
covered. If the date of this document is more than three years old, please call to ensure that this sheet is current.

[00707_061108]

Issue date: 16-Mar-09 MSDS No.: 16 084803


Revision No: 16.0 Page 9 of 9

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