POR Cri cirri cae x \-20l Ss tere Series SSO oe 56/3/P wai. Roll No. eter = ary © yey Candidates must write the Code on the tile page of the answer-book. «pra aia a df ga wera Fi aa we 5B . Rega 3 a we ot oft fy mm sts Fee wt a omy & Ba \ + Bra sia a a fh wa emt 26 u eI © Ba Saw eran Ys ae a vee, wee aT eH otaea fre | oe reer ah yet S fry 15 fie ar ae fen en 2 we a Piao le # 10.15 = fem aren | 10.15 3 a 10.3038 we oe daa WR BST ak ge araft & dh 8 sac gfe wa ser Aad PAST | * Please check that this question paper contains 15 printed pages. * Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. + Please check that this question paper contains 26 questions. * Please write down the Serial Numher of the question before attempting it. * 15 minute time has been allotted to read this question paper. The question paper will be distributed at 10,15 am. From 10.15 a.m. to 10.30 am., the students will read the question paper only and will not write any answer on the answer-book during this period. war fess (were) CHEMISTRY (Theory) rata wrt: 3 ae ETA HB: 70 Time allowed : 3 hours Maximum Marks: 70 . 56/3/P 1 P.T.O.wart feat: @ @w aett wer sitter & 1 WET HEN L AS Tes aiht e-seT Wer & ait eden WET a fee 1 sie | (iii) Wer Her 6 B10 we Tg-serta WEF B sik eI TET & fee 2 ate | (iv) WRT Aw 11 B22 TH Hf ey-sera eT e silt ede ETH fie 3 aH F | (o) er Hea 23 ements Wer 2 ait sae ere 4 ae F 1 (vi) WRT Hear 24 3.26 ae else eT S ak Weds WET H fie 5 aie eI (vii) ae omega Bt, ah cat eacat ar yar at | Heap & svar BH sega wee General Instructions : () ~All questions are compulsory. (ii) - Questions number 1 to 5 are very short answer questions and carry 1 mark each. (iii) Questions number 6 to 10 are short answer questions and carry 2 marks each. (iv) Questions number 11 to 22 are also short answer questions and carry 3 marks each. (v) — Question number 23 is a value based question and carry 4 marks. (vi) Questions number 24 to 26 are long answer questions and carry 5 marks each, (vii) Use log tables, if necessary. Use of calculators is not allowed. 1 em aie wo agatha. am fafa : CH, = C - CH, - OH | CH, Write the IUPAC name of the given compound : CH, = C- CH, - OH | PON Cra CHg Circ leg2. 5. 6. 56/3/P 3 Zn? % Tam wg Ad F TAP Cu2* 3H rawr ia lea S| a? 1 ‘Zn?* salts are white while Cu2* salts are coloured. Why ? Prafatad gm F Sy after ata siftrs tet 8 sor: 1 cH, CH, -CH,-Br #1 CH3~C-CH, | Br Which would undergo Syl reaction faster in the following pair : CH, | CH; -CH,-Br and CH3-C-CH, | Br ZnS LA a Zot arre wel a feet order (ant) A snare at a2 How much charge is required for the reduction of 1 mol of Zn2+ to Zn? Tae St aRfeee mace sie afar rey al Peta | ear i Write the dispersed phase and dispersion medium of butter: iraeT (Pt(en), Cll at ag... aa fafa | ge sicdae ga ea wepR et aHTeIaAT Ray Tt B 2 2 aaa EAR. Tale ar si HI ee Prien sree af % re alt a fafar : 2 @ — tradetratarecc aetags — (i) Ween grctogetfiertec) Cee Paper P.T.O.Write down the IUPAC name of the complex [Pt(en),Cl,]2*. What type of isomerism is shown by this complex? OR Using IUPAC norms write the formulae for the following coordination compounds : @) Hexaamminecobalt(IIl) chloride (i) Potassium tetrachloridonickelate(II) 7. Prafefad at set antia ama & age wo Ff oaafeaa Alfie ; 2 @ — CgHs-NH2, CoH; -CH,-NH, CoH, -NH- CH, NH, NH, NH, = QO 10 Years q@) , > iret) Paper NO, CH, Arrange the following in increasing order of their basic strength : (@) -CgH; - NHp, CgH; - CH, - NH, ‘CgHs ~ NH - CHg NH, NH, NH, 06.66 NO, CH, 8. we safe fea flees a eerie cw yg fiers a after at dar BR HS UH apes rent sai 8? 2 Why does a solution containing non-volatile solute have higher boiling point than the pure solvent ? Why is elevation of boiling point a colligative property ? 56/3/P. 410. lL. Prafetad aust ft deat fafa : 2 (@) — H,S0, (i) XeOF, Write the structures of the following molecules : @ ASO Gi) XeOF, afiirar $< ofontia ffie | at aren fefae at arian ft a at oenfea wae | 2 Define rate of reaction. Write two factors that affect the rate of reaction. frafatad afiteasit % sels & yea song Ft aera ferflar : 3 @ | CH ~ CH = C- CH, + HBr —> CH, Gi) CH,~CH,~CH,~CH- CH, + KOH Sass Br Br Gaiy Q +CH,C1 Fisiefia AICI, Write the structure of the major product in each of the following reactions : @) CH, ~ CH =C- CH + HBr —> CH, Gi) CH,~CH,~ CH,~ CH- CH + KOH pemenoViel Br Br “a anhyd. AICI, Ga) a +CH,Cl ————"s 10 Years iri lol 5 P.T.O.12, 13. 14. 56/3/P 6 freafatad & fae ara air : @ Shia atenga Ghia > aftes ane 2 | Gi) daiadhtade At gent F Wai ar Fae Fa 2 | (ii) (CH,),C ~ 0 - CH,, HI aa often ah yer send & wf CH,OH 3k (CH,),C -1 2at @ 4 f (CH,)gC- OH ait CHI. Give reasons for the following : @ Phenol is more acidic than ethanol. (i) Boiling point of ethanol is higher in comparison to methoxymethane. ii) (CH,)C-O-CHg on reaction with HI gives CH,OH. and (CH,)3C - I as the main products and not (CH)3C - OH and CH,I. a Ufc TeHgBIet (CyH_0,) I 31 g Ie H 500 gH Yon Gan A, wa eT % fens ar after Afra | ret & fee K; = 1-86 K kg mol) Calculate the freezing point of the solution when 31 g of ethylene glycol (CyH_0,) is dissolved in 500 g of water. (Ky for water = 1-86 K kg mol”) frafafad vet at ofentia fie : @ asa Ure Be (fifa aie Ba) Gi) wight te Gi) the gaaa Define the following terms : @ Primitive unit cells (i) Schottky defect 10 Years (iii) Ferromagnetism irene) Paper15. 16. 17. Wa AMAR 300 KS 310K wate Star 8 aa TH we ALE AY APT aT eX fers 2x 10% a aga 4x 10 A aT ?2 | Beat Sal (E,) wT Ve ify (log 2 = 0-301, log 3=0-4771, log 4 = 0-6021) The rate constant of a first order reaction increases from 2x 10~ to 4 x 10-2 when the temperature changes from 300 K to 310 K. Calculate the energy of activation (E,). (b) (a) (b) (log 2 = 0-301, log 3 = 0-4771, log 4 = 0-6021) frafafaa sieeaat & car sit aren fear : @ — [CoF,)? Gi) IN(CN)? (FRAY HATH : Co = 27, Ni = 28) NH, 3 co # & aha favs dom ag } ae afte we wire Fare 2 sik sat 2 Write the hybridization and shape of the following complexes - @ — [CoFg® qi) IN«CN)J* -(Atomic number : Co = 27, Ni = 28) Out of NHg and CO, which ligand forms a more stable complex with a transition metal and why ? frefataa vel at vfenita fife : @ Gi) aren aft adam (ii) TBH (AednierRRN) Fretigs Define the following terms : @ Gi) (ii) 56/3/P Brownian movement Peptization - Multimolecular colloids ree [el P.T.O.18, (i) agai & sha hear} hd an fegra ae 37 Gi) ate Freepeioy Ff feaferemr At ae wpm Vict 8 2 (ai) “ore srrreT fever seen ft are’ B fra ata 2 2 3 @ Whats the principle behind the zone refining of metals ? (i) What is the role of silica in the extraction of copper ? (ii) How is ‘cast iron’ different from ‘pig iron’? 19. Refefaad ager & cael & am sik ett dear fafa ; 3 @ gs @) feta Gi) Gietlarghiet aetags Write the names and structures of the monomers of the following polymers : @) Buna-S i) Glyptal (ii) Polyvinyl chloride 20. (i) 3a Daggta HyN - OH afrar aa 2 aa Gt sere er aT a, WA fefax | Gi) Ue one sree ore efile aed Bait 2 (ii) fret Coat wi H sm ai adi we BHAT 3? 3 @ Write the product obtained when D-glucose reacts with HAN - OH. (i) Amino acids show amphoteric behaviour. Why ? (ii) _ Why cannot vitamin C be stored in our body ? ba Question 5 56/3/P 8 eu21. 56/3/P Prafafad Sacer ary a se : 8 (@) CgH,CONH, #1 CgH;NH,# i) Bieta at Sie Gi) Wrage a Gates aaa wa tie at Aefafad aftorest & aa santa fear stat 2, wa ara Tarahie aiteit a fear ; 3 @ Brad (i) “CHCl, + KOH Gi) HCL How do you convert the following : @ _ CgH,CONH, to CgH,NH, Gi) Aniline to phenol ii) Ethanenitrile to ethanamine OR Write the chemical equations involved when aniline is treated with the following reagents : @ Brg water Gi) CHCl, + KOH Gi HC) 2 10 Years irri) [ete P.T.O.22, Freafefiaa % fore aren aie: @ BRS aH TN, aH aire 31 Gi) wh igs wat & oh aegest 4 HyTe wad afte wae ares a Gi) Haat & seer Fite aiedior & fae we aged & ea A wg ame Give reasons for the following : @ Ny is less reactive at room temperature. (i) HyTe is the strongest reducing agent amongst all the hydrides of Group 16 elements. (iii) Helium is used in diving apparatus as a diluent for oxygen. 23, FAM seal A agdg ak saerg (ser) Ht sett Hem a aa, wH whe eae & fiftoer gael 3 ee Afar ar saris feet fret ara fiftreit atk ‘walt & araficreit = amifia fear | ae Feta feen en fh eget Fa ae an Ft agi aq Ft ont sik aad aegd 3a ag, Teh, qu, anfe sae woud ord | sai ae of Pla fren Pe eae te awe A Raa wai at one G2 ar eros ona aftard eT a soe TE | Ae wea, ft get 3 afteat eae F fee career aha aan ait gait area Ff agra Gan WT TT | safe fawn a ugar Prfatad seit & sr aie : @ At gach ert fea apa (eu aan A) wi vefifa fear ra? Gi) Um faenef & ea 4, ary ga farsa F BA ae Hearth 2 Gi) See ae S Ge eT eS 2 saeTT AAT | (iv) & wate & Th S fae fog aM S fee Fh floret afters (meer) sae Star @, Tear aT ae Lr 56/3/P 10 Question evel24, 56/3/P Seeing the growing cases of diabetes and depression among young children, Mr. Lugani, the principal of one reputed school organized a seminar in which he invited parents and principals. They all resolved this issue by strictly banning junk food in schools and introducing healthy snacks and drinks like soup, lassi, milk, ete. in school canteens. ‘They also decided to make compulsory half an hour of daily physical activities for thestudents in the morning assembly. After six months, Mr. Lugani conducted the health survey in most of the schools and discovered a tremendous improvement in the health of the students. After reading the above passage, answer the following questions : @ What are the values (at least two) displayed by Mr. Lugani ? (ii) _ As a student, how can you spread awareness about this issue ? (ii) What are antidepressant drugs ? Give an example. (Gv) Name the sweetening agent used in the preparation of sweets for a diabetic patient. (a) Frefefad st are afea ere alfa; @ 2a He wT aa TTY easit ae F (i) tara rgd fafea sree sracerd wefhia are | Gi) wefla Pree 4 Cut sre eg ae 2 (>) Preafeftad afte at got Afare : @ » 2Mn0,+ 4KOH+0,—> Gi)’ 2Na,CrO,+2H* > aaa 10 Years erent 1 Paper P.T.O.(a) zo Cr | Mo |} Fe | Co | mi | Cu arn [o91 [14a | 0-44 | -098 | -0a5 | s0sa EB? writ 3 fq me safepat 8 Arafattaa weil & sar ae : @ TR a STTaTG TART HTH 3 2 RE? (Cu?*/Cu) Gi) 4 wat ar Teli Ht Ger F aftr aeons 3 2 10 tay Gi) BHT THAR STE 2 Cr+ aT Fe Paar AT | @) Ureatad gem ve Ff sre sated wi Raunt € 2 Yai atk eroniaet & dha ware ft ats ww carrer fafa | 5 (a) Account for the following : (i) Zrand Hfhave almost similar atomic radii. (i) Transition metals show variable oxidation states. (ii) Cu*ion is unstable in aqueous solution. (b) Complete the following equations : @) 2Mn0,+ 4KOH+ 0, (i) 2NayCrO, +2 Ht — OR , Cr | Mn | Fe | Go | NM |G ani | 0.91 | 148 | -o44 | -028 | -025 | v0aa From the given data of E° values, answer the following questions : @ Whyis B20 value exceptionally positive ? (i) Why is Bea?” /atqy Valve highly negative as compared to other elements ? (ii) Which is a stronger reducing agent Cr2+ or Fe2+ ? Give reason. (b) Why do actinoids show a wide range of oxidation states ? Write one similarity between the chemistry of lanthanoids and actinoids. 56/3/P 12 10 Years Cir lola56/3/P (a) (b) © (a) (b) © CoHyOC! safes aa aren ws aes a’ aalg ag aoa A fee ara 2 | Prafatad alteensit 4 A, B, Cait Ds ated fetta : H,/ Pd-BaSO, NaOH aa (C,H,0Ccl). A > B ————> C —>D frafatad & ata Aq (sen) Fifi : @ CgH;- COCH, 3% CgH;- CHO 4 Gi) Fates ara otk Bea Hailes | 2ARreregea A ae fear | 5 wa tei2H (CH, - CO - Coe Seated Sees 3, at ea ger sare A ieee fafa (@) %n-Heg/Sig HCL Gi) TI,N - NHCONH./H* (ii) CH,MgBr 31% 38% aq H,O* Prafittan a Fa Taertiss & agd ee wor F qafeea Alfie : C,H;OH, CH3- CHO, CH;~- COOH afrat & Pafatad ga 7 ain eet & fae we ant Tas ate ‘afie : CH,CH,CHO 2X CH;CH,COCH, 3 eee PTO. eg(a) A compound ‘A’ of molecular formula C,H,OCI undergoes a series of reactions as shown below. Write the structures of A, B, C and D in the following reactions: H,/Pd-BaSO, dil. NaQH Heat (CHOC) A B ———> ¢ —>D (b) _ Distinguish between the following : ( — CgHs-COCH, and Celi; - CHO (i) Benzoic acid and methyl benzoate (©) Write the structure of 2-methylbutanal. OR (a) Write the structures of the main products when’ acetone (CH, ~ CO - CH,) reacts with the following reagents : (@) | Zn-Hgfeone. HCl (i) H.N - NHCONHL/H* (ii) CH,MgBr and then H,0* (b) Arrange the following in the increasing order of their boiling points : C,H;OH, CH;- CHO, CH;- COOH (©) _ Give a simple chemical test to distinguish between the following pair of compounds : CH,CH,CHO and CH,CH,COCH, 56/3/P 14 10 Years Cros eg26. Prafafta dar & fare faga-sres set (emt) ik AG ar vee Ae Mg (s) | Mg?* (0-001 M) || Cu2* (0-0001 M) | Cu (s) : Bo 0 = 404 femme? : Bint) ~ 7 237V: BY aejouy) = t O84V- aaa (a) KCI fer % 0-20 mol L-! et area 2-48 x 10-2 S m=! % 1 seA wieR areeat sit Retse-arT (0) viefer Are 1 Ren wz 26+) = 785 S om? mol"! atk 2 C1) = 765 S em? mol), >) whe Ge fea ver Ft aed 2 2 ae ys (Se) da A ate afte eI Fite? Calculate e.m.f. and AG for the following cell : Mg (s)| Mg?* (0-001 M) || Cu* (0-001 M) | Cu (s) Given : E° = -237V, E (tg?*/mig) 0 MGa2tfoay = * O84: -OR (a) The conductivity of 0-20molL7 solution of KCl is 248x102 Sem"! Calculate its molar ‘conductivity and 0O degree of dissociation (a). Given 1 (K*) = 73:5 S cm? mol! and 0 4 (Cl) = 765 Sem? mol}, (b) What type of battery is mercury cell ? Why is it more advantageous than dry cell ? 10 Years Try leg 5