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PO
80 Hard
Stearines PM F IV4 2
70
PM F IV3 4
60
POsIV3 5
PO
50 Soft POsIV14
40 Stearines POsIV2
30
Mid Fractions
20
10 Oleins
0
0 10 20 30 40 50 60 70
Temperature deg.C
2
How? --- Fractionation Process principles
Molten
fat
1. crystallisation
Slurry
2. solid/liquid separation
Olein Stearin
3
Importance of Solubility, eg. PPP in Palm
65
60
supercooling
on
Temperature (C)
a ti
55
dific
o
P P -m supersaturation
50 re P
pu o ne
e z
45 stabl
meta
40
35
1 10 100
Concentration PPP (%)
4
Crystallisation Processes
Temp slurry
Temp coolant
Time
Step-wise cooling.
Coolant inlet temperature is changed following time program
Crash cooling is with one fixed coolant temp ie. one step!
7
Delta cooling
Temperature
Temp Slurry
Temp coolant
Time
Delta cooling.
Maintain delta between slurry temperature and average
coolant temperature.
8
Pre-cooling
Temperature
Temp slurry
Temp coolant
No pre-cool
Time
Lipico
De Smet
Alfa Laval
Tirtiaux / JJ Lurgi
and various other suppliers
10
Coil type crystalliser
11
Tirtiaux style with Thermoplates
12
De Smet concentric crystalliser
13
Stirred crystallising slurry
14
Static or Quiescent crystallisers
De Smet
Oiltek
and others
15
Static crystallisation cooled plates
16
Quiescent crystallising in trays
17
Quiescently grown crystal slurry
18
Separation techniques
21
Membrane filter press
MEMBRANE SQUEEZE
LIQUID
22
Continuous separation with centrifuge
Westfalia Patented Process
23
Separation concept with centrifuge
Westfalia Patented Process
24
Solvent Fractionation: What if 75% crystals??
the
same < 80% yield of high
quality stearine
25
Fractionation is:-
From:
Simple, low stearine yields and low
efficiency S/L separation
To:
Sophisticated, high stearine yields and
efficient S/L separation
26
Why? --- eg. Fractions from palm oil
give added value!!
100 POfIV6 5
POfIV56
90
NMR Solids %
PO
80 Hard
Stearines PM F IV4 2
70
PM F IV3 4
60
POsIV3 5
PO
50 Soft POsIV14
40 Stearines POsIV2
30
Mid Fractions
20
10 Oleins
0
0 10 20 30 40 50 60 70
Temperature deg.C
27