NOMBRE: Ana Priscila APELLIDOS: Murro Salinas

A1) Busque en la revista Coordination Chemistry Reviews el trabajo inmediatamente

anterior al siguiente:
Ttulo: The chameleon-like coordinating ability of 2,3-di(pyridyl)pyrazine-type ligands
Autores: Barbara Floris, Maria Pia Donzello, Claudio Ercolani, Elisa Viola
Referencia: Coord.Chem.Rev., 347 , 115-140, 2017.
Y escriba los siguientes datos sobre el trabajo.

Ttulo: Structural diversity of copper(II) amino alcoholate complexes

Autores: PetriSeppl , ReijoSillanp y AriLehtonen

Pgina inicial-Pgina final: 98-114

A2) Busque en la revista Inorganic Chemistry el trabajo inmediatamente posterior al

siguiente:
Ttulo: Uranyl Ion Complexes with Long-Chain Aliphatic , -Dicarboxylates and 3d-
Block Metal Counterions
Autores: Pierre Thury and Jack Harrowfield
Referencia : Inorg.Chem., XX (X), XXXXXXXX, 2016.
Y escriba los siguientes datos sobre el trabajo:

Ttulo: Analysis of Redox Series of Unsymmetrical 1,4-Diamido-9,10-anthraquinone-

Bridged Diruthenium Compounds

Autores: Abhishek Mandal, Md Asmaul Hoque, Anita Grupp, Alexa Paretzki, Wolfgang
Kaim, and Goutam Kumar Lahiri
Volumen: 55 Nmero: 5 Pgina inicial-Pgina final: 21462156
DOI: 10.1021/acs.inorgchem.5b02541

A3) Busque en la revista Dalton Trans. el trabajo inmediatamente anterior al

siguiente:
Ttulo: Accessing perfluoroalkyl nickel(II), (III), and (IV) complexes bearing a readily
attached [C4F8] ligand
Autores: S. Yu, Y. Dudkina, H. Wang, K. V. Kholin, M. K. Kadirov, Y. H. Budnikova and D.
A.Vicic
Referencia: Dalton Trans., XXXX, XX, XXXXX-XXXXX
Y escriba los siguientes datos sobre el trabajo:
Ttulo: Gold trifluoromethyl complexes
Autores: Juan Gil-Rubio Y Jos Vicente
Volumen (Ao): 2015 Nmero: 44 Pgina inicial-Pgina final: 1943219442
DOI: 10.1039/C5DT02023A

B) Lea el trabajo de F.Albert Cotton, de referencia J. Chem. Soc., Dalton Trans., 2000,
1961 1968. Y escriba un resumen, en espaol en ingls, con un mximo de 2
pginas.

The chemistry of the transition elements is well differentiated from the other
elements chemistry in several ways:
- the formation of compounds in two or more oxidation states, were redox chemistry
takes a high importance.
- Transition elements compounds have a visible spectra, which provides a lot of
information a but them.
- Transition elements usually have one or more unpaired electrons, which allows them
to have magnetic properties.

The development in transition elements chemistry takes part mainly during the 19th
century, with the contribution of Alfred Werner and his concept of coordination
compounds and his general theory of how they behave. Inorganic molecular
compounds contain single atoms which are arranged in simple spatial geometrical
molecules. The central of Werners system is the concept of coordination numbers.
The most common number is 6 and its spatial organization is the octahedron around
the central metal atom. The vital points of this theory are:
- A metal atom is a discrete center with a set of ligands arranged.
- The number of arranged ligands are generally 4 or 6.
- The general concept of a ligand is a passive non metal donating an electron pair.
- Metal atoms were conceived as independent centers.
- Ligands were immutable entities attached to the metal center.
Nevertheless, there have been evolutionary developments since Werners theory.
Regarding the structural characterization, the X-ray crystallography allows us to
determine the shape and dimentions of coordination polyhedrons. In the
thermodynamic and kinetic fields, the latest datas allowed us to get more mechanistic
possibilities for many reactions and the creation of ligands invented and used in special
modes of complexation.
The work of Walter Hieber with metal carbonyls was essential in the discovery of their
reactivity and mechanical processes. It also helped in the development of the valence
theory, with the -donation and the -orbital acceptance. Also, the availability of fast
computers and the powerful spectroscopic tools have led an enormous progress in our
comprehension of how ligands are bound to metal atoms and the complex electronic
structure.
Developments take place in a lot of fields. In bio metallic chemistry, we have known
metallic complexes are involved in many life processes, so in the recent years, the
importance of metal ions has been really important. In organo-transition-metal
chemistry the reactivity of ligands took a high importance too. The organic ligands are
rearranged and transformed, taking part in the catalytic activity in transition metals.
The development of catalysis based on transition metal allows to create new catalysts
in which depends a lot of reactions. Also, for many organometallic compounds and
polynuclear metal carbonyls, nonrigidity or ligand scrambling form part of their
character. On the metal-metal bonding field, the metal atoms are not only attached to
ligands, they can be attached to other metal atoms, creating central clusters
surrounded by ligands. This is a now field of study with high importance. Transition
elements compounds arent only simple ionic salts, they can consist of infinite chains,
sheets or three-dimensional networks that exist only in the solid state. There is a rich
variety of solid state compounds that display highly varied physical, spectroscopic and
magnetic properties.
By last, the transition metals are playing a major role in supramolecular chemistry,
which are based on the use of transition metal complexes as structure-directing
elements.