s1 2014-2015

M
ry
TEST 1(b)
cHM s20 (PHYSTCALCHEMTSTRYrr)

Name :

Group : Date:

Fundamental constant:
Gasconstant(R) : 8.314J K-r mol-l
1 Pa m3: 1 J; 1 Pa: 1 Nm-2; I atm: 101.325kPa

QUESTTON 1

Define the term Isobaric processand give an example.

. O
I
A fo*t ;r, ,,"f'z,t^ lot o /ion * ,-,,",
/rn**-n
b'+' l'., ,/ra*/ /- Ft I / a^d-E v :t"hfumarks)
,.f ft* tta ue, i-nz
/*,<.O
0.01 mol of helium at25 oC is allowed to expand adiabatically and reversibly from 22.4 dm3to 44.8 dm3.
The molar heat capacity of helium at contant pressureis20.79 JK-imol-l.

Calculate:

D final temperature (3 marks)

CV,,, = Cp,n "-h R
= 24.-r1 I{troTt ' '( 8"\itt r Eau't-')
= /! ,v76,Jf r-'*o i' O
c =Cro* ) p roo| C
- t.
Tt = 7,.( U \2"=
r- '
2?&.
s/ x /:r"**t \"' :1t.
"l w ,-^,--,?,2 (6r,
.l T-r= /87'tcK
) CI
ii) work done during ddiabaticexpansion (2 marks)

VJ*d a lt x Cr,* y aT
0)
r k uu, f * ty c t t , - t ( , - 27e .
y 12. q, 76 lilK
- o,o lmol
i" 4A z - lg .-Ts|8t a
 -q

sL_20L4-2015

QUESTTON3

A strip of magnesiumof mass 15.0 g is dropped into a beaker of dilute hydrochloric acid. The
atmosphericpressureis 1.0atm andthetemperature
25 "C.

i) Write a balancedchemicalequationfor the abovereaction.

.
ii) Calculatethe work done(w) (in unit J) by the systemasa resultof thereaction.

r) hrTrs:+ rtlcl ,V) e ttrfl+ *trU, ,V) @ (6marks)

i'r
rt J
T/u <xf-t'r'ra! ,
7P*'trf t<tfrvr< i.r /, o ef^/, .^J l,/; : O @
A 4^ , = 3 r * . . 3 / r'.a t^i t'u: -f._ (y,_v)
'v V
l.f-g i4 -t
n :
>V-St x*P
L
@
t-t v r ' t ' ' x'Y --*nRT
vr
N = -fAV
fl^^e

,
pp
o p
,1
*D =
< 1 4 t --/'^
'"
D
//

'. l,i -('t:"('rztu,i)(gti + r k ' *. i ' )

Vl,,= n RT ( n8" i-rt()
"i
..'.LrJ '-- - lslq J
th

QUESTION 4 I) :
f
Consider a system consisting of 2.0 mol COz (g), initially at25 oC (10 atm) and confined to a cylinder of
cross-section10.0 cm'. It is allowed to expand adiabatically against an external pressureof 1.0 atm until
the piston has moved outwards through 20 cm. Calculate:

i) Heat(q)

ii) Work (w)

iii) Changeof internal energy (AU) (in unit J) (4 marks)

)) Hr"l cr )
L'
q = c l.- o'tubqh't
l, l- |l/\u+s

;;) Nark C"^t)

f,;: P.* A U
N s Ct.o/ r/trs P q ) ( ) o . ^ ) ( iQ , : n 2 )
r!' cfe : I Po u3 . /
,1
2
7
---r

51_2014-201.5

\trr2 Ail = I + Ln
/,

4U = A-zo
AU = -J o ;l -..
4

QUESTTONs

Calculatethe changein entropy(AS) if 1.0mol of liquid wateris heatedfrom 0 to 100"C underconstant

Molar heatcapacityunderconstantpressure(C0..)is 75.291JK-1mol-l.
pressure. (3 marks)

4s= d7
T
AD
dL- ncp,_dT Ae
As =ncp:, dT
T
=
lrf y 0)
^c7,rtJa, T
.'"AS, ,r1,, t_^k Ag
!:*,
= I m'lx rgl rr/n.;'/-
*, Tt/n";' /- ry
ry 89
L7?k

2 2 3,4 7 7X k- - tc>
&\\r